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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 955 records · Page 53
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Laboratory studies of Kapton degradation in an oxygen ion beam

Results are presented from a preliminary laboratory investigation of the degradation of the widely used polyimide Kapton under oxygen ion bombardment. Recent space shuttle flights have shown that Kapton and some other materials exposed to the apparent ram flow of residual atmosphere (at orbital velocity in low Earth orbit) lose mass and change their optical properties. It was hypothesized that these changes are caused by chemical interaction with atomic oxygen, aided by the 5-eV impact energy of atmospheric oxygen atoms in the ram. The reaction rate under O(+) bombardment seemed to be independent of incident energy over a wide range of energies. Although the flux of thermal ions in this experiment was much greater than the accelerated flux, the observed Kapton degradation was limited to the beam area and ram flow direction. This is consistent with an activation energy above the thermal energies but well below the beam energies. The results reproduce well the material loss, optical changes, SEM surface structure, and ram directionality of the samples returned by the shuttle. These factors, along with the lack of degradation under argon ion bombardment, are convincing evidence for ram flow oxidation as the mechanism of degradation.

Ferguson, D. C.↗
NASA NTRS2017

Ablation and Heating During Atmospheric Entry and Its Effect on Airburst Risk

Large meteoroids and asteroids entering the atmosphere endure tremendous heating from the shock heated air, and thereby lose a significant fraction of their mass during atmospheric entry a process known as ablation. The predicted evolution of the asteroids mass as it passes through the atmosphere can affect both the predicted energy deposition profile relevant to an airburst event, or the residual mass that strikes the ground in the case of an impact event. This presentation is divided roughly into two parts. In the first part, an overview of traditional models for heat transfer and ablation that are historically used in the meteor physics community is presented, and the validity in the asteroid entry regime discussed. Sensitivity analyses performed using the recently developed Fragment-Cloud Model (FCM) will be presented which show illustrate the range of sizes and entry parameters for which the predicted asteroid threat is most sensitive to the models for ablation and heat transfer. The second part of the presentation shall focus on recent work done under NASAs Asteroid Threat Assessment Project (ATAP) to develop new models for heat transfer and ablation using high-fidelity numerical simulation in concert with state-of-the-art experiments. Coupled computational fluid dynamics (CFD)radiation transport simulations preformed using the state-of-the-art entry modeling tools at NASA show that, for large meteoroids and asteroids, there can significant attenuation of the heat transfer to the surface (95 in some cases) by the products of ablation. In addition to the heat transfer, new models for the material response and ablation of asteroidal material have been developed [cite]. In the current work, we present finding from recent novel experiments performed in the arc jet facility at NASA Ames, which allows us to, in part, simulate the extreme environment experienced by the asteroid during entry. Briefly, the experimental set-up was comprised of a 1.5 conical article of machined H5 chondrite, which was exposed to a high-enthalpy flow resulting in approximately 4 kWcm2 of heating to the surface. A still frame capture from high-speed video taken during this experiment can be seen in Figure 1. In this figure, we can observe some of the major mechanisms for meteoroid ablation, such as melt flow, spallation (mechanical removal of material), and vaporization. Major findings from this, and other experiments will be discussed, as well progress on utilizing the data from the experiments to inform and develop improved models for ablation.

Asteroids↗
NASA NTRS1988

Models of steady state cooling flows in elliptical galaxies

A comprehensive set of steady state models for spherically symmetric cooling flows in early-type galaxies is presented. It is found that a reduction of the supernova (SN) rate in ellipticals produces a decrease in the X-ray luminosity of galactic cooling flows and a steepening of the surface brightness profile. The mean X-ray temperature of the cooling flow is not affected noticeably by a change in the SN rate. The external pressure around a galaxy does not markedly change the luminosity of the gas within the galaxy but does change the mean temperature of the gas. The presence of a dark matter halo in a galaxy only changes the mean X-ray temperature slightly. The addition of a distribution of mass sinks which remove material from the general accretion flow reduces L(X) very slightly, flattens the surface brightness profile, and reduces the central surface brightness level to values close to those actually observed. A reduction in the stellar mass-loss rate only slightly reduces the X-ray luminosity of the cooling flow and flattens the surface brightness by a small amount.

Vedder, Peter W.↗
DOE OSTI2026

A cell-centered AMR-ALE framework for 3D multi-material hydrodynamics. Part II: linesweep ALE rezoning for nonconformal block-structured AMR meshes

The simulation of flows presenting contact discontinuities, vorticity, and large variations in spatial scales can be performed in a framework coupling Arbitrary Lagrangian Eulerian (ALE) algorithms and Adaptive Mesh Refinement (AMR). This coupling requires adaptation of ALE rezoning techniques to meshes containing nonconformal nodes arising from both the AMR topology and the junction of mesh blocks. Here, in this paper, we present an ALE rezoning strategy that is compatible with such meshes, and that can also act as a disentangling algorithm. Emphasis is put on an algorithm that respects intrinsic Lagrangian mesh properties in order to preserve accuracy around discontinuities. To that end, we adapt the weighted linesweep algorithm to nonconformal block-structured AMR meshes. Then, we present control parameters introduced in the method for it to be applicable in practical situations. Notably, the method is coupled to a specific metric optimization in order to palliate some shortcomings of the linesweep method. Finally, numerical test cases are presented that feature the capabilities of the ALE-AMR algorithm for flows that present discontinuities, vorticity, and a variety of scales. Notably, we show that our ALE-AMR algorithm gives results at least similar to Euler-AMR, but provides better accuracy in cases where discontinuities are involved, thanks to a method that respects the Lagrangian features of the mesh. Additionally, it enables Euler-AMR-like computations on domains with temporally varying domain boundaries.

Adaptive mesh refinement↗
NASA NTRS2014

Theoretical Development of an Orthotropic Elasto-Plastic Generalized Composite Material Model

The need for accurate material models to simulate the deformation, damage and failure of polymer matrix composites is becoming critical as these materials are gaining increased usage in the aerospace and automotive industries. While there are several composite material models currently available within LS-DYNA (Registered), there are several features that have been identified that could improve the predictive capability of a composite model. To address these needs, a combined plasticity and damage model suitable for use with both solid and shell elements is being developed and is being implemented into LS-DYNA as MAT_213. A key feature of the improved material model is the use of tabulated stress-strain data in a variety of coordinate directions to fully define the stress-strain response of the material. To date, the model development efforts have focused on creating the plasticity portion of the model. The Tsai-Wu composite failure model has been generalized and extended to a strain-hardening based orthotropic material model with a non-associative flow rule. The coefficients of the yield function, and the stresses to be used in both the yield function and the flow rule, are computed based on the input stress-strain curves using the effective plastic strain as the tracking variable. The coefficients in the flow rule are computed based on the obtained stress-strain data. The developed material model is suitable for implementation within LS-DYNA for use in analyzing the nonlinear response of polymer composites.

Plasticity↗
NASA NTRSDate not supplied

Development of Langmuir and Spatially Resolved OES Diagnostics for Arc Jet Shock and Boundary Layer Measurements Relevant to Atmospheric Re-Entry Environments

The second-generation miniature Arc Jet Research Chamber (mARC) ground testing facility at NASA Ames requires physical characterization of its supersonic plasma flow to verify numerical models and material sample testing. Two types of plasma diagnostics will be utilized: Langmuir probes and optical emission spectroscopy (OES). Several single and triple Langmuir probes have been constructed and will be inserted parallel to the flow via a sweep arm to measure post-shock electron temperature and number density along radial profiles at different axial distances. Due to the high heat flux (200-3000 W/cm2) sweep durations are necessarily short (< 0.1 s). Measuring these properties near the probe surface provide characterization of the post-shock environment. This is an important metric for validating coupled CFD-material codes, and will provide insight into longstanding thermocouple anomalies attributed to charging of heatshield surfaces. An OES system has also been assembled to obtain spatially resolved density and temperature for various flow species. The system consists of a convex lens that forms an image of the plasma onto a 16-channel linear fiber array, which will simultaneously capture the spectra from sixteen different locations. The light emission from the plasma is then focused by a spherical mirror into a spectrometer and recorded with a camera. These measurements non-intrusively provide a new spatially resolved flow characterization capability. This will initially be used to resolve issues with shock radiation interference in pyrometer measurements of material surface temperature. The design of each diagnostic and any initial results will be discussed.

Ethan Main-Loam Leong↗
NASA NTRS2002

Reduction of Convection in Closed Tube Vapor Transport Experiments

The primary objective of this effort was to develop a method for suppressing convective flows during the growth of mercurous chloride crystals by vapor transport in closed tubes to levels approaching those obtained in the microgravity environment. Mercurous chloride was chosen because it is a technologically interesting acoustical optical material whose optical properties are believed to be affected by convective flows. Since the Grashof number scales as the cube of the smallest dimension in the flow system, reduction of the size scale can be extremely effective in reducing unwanted convective flows. However, since materials of practical interest must be grown at least on the cm scale, reduction of the overall growth system is not feasible. But if the region just above the growing crystal could be restricted to a few mm, considerable reduction in flow velocity would result. By suspending an effusive barrier in the growth ampoule just above the growth interface, it should be possible to reduce the convective velocity in this vicinity to levels approaching flows in microgravity. If successful, this growth technique will offer a screening test for proposed space experiments that involve vapor transport to see if reduction of convection will result in improved material and will set a new standard against which the improvements obtained in microgravity may be judged. In addition, it may provide an improved method for preparing materials on Earth whose growth is affected adversely by convection. If the properties of this material can be improved there is a potential commercial interest from Brimrose Inc., who has agreed to fabricate and test devices from the crystals we have grown. This report describes the development of the growth facility, the purification processes developed for preparing the starting material, and the results from growth experiments with and without the effusive baffle. Mercurous chloride turned out to be a more difficult material to deal with than originally anticipated. At growth temperatures, it is extremely sensitive to practically any impurity which causes it to form oxychlorides and/or to decompose into elemental mercury and bichloride of mercury. We were unable to find a suitable method for protecting the magnetic material used to suspend the effusion barrier from the attack of mercurous chloride vapor. Although we were successful in growing single crystals of mercurous chloride without the effusion baffle, they exhibited severe microcracking which we attribute to wall-induced thermal stresses. This leads us to believe that uncontrolled convection may not be the most important problem in the development of this material and a new growth process was attempted that eliminates the wall-induced stress. Unfortunately, the grant ran out before this new method could be adequately tested.

Naumann, R. J.↗
NASA NTRS1986

Design of fuselage shapes for natural laminar flow

Recent technological advances in airplane construction techniques and materials allow for the production of aerodynamic surfaces without significant waviness and roughness, permitting long runs of natural laminar flow (NLF). The present research effort seeks to refine and validate computational design tools for use in the design of axisymmetric and nonaxisymmetric natural-laminar-flow bodies. The principal task of the investigation involves fuselage body shaping using a computational design procedure. Analytical methods were refined and exploratory calculations conducted to predict laminar boundary-layer on selected body shapes. Using a low-order surface-singularity aerodynamic analysis program, pressure distribution, boundary-layer development, transition location and drag coefficient have been obtained for a number of body shapes including a representative business-aircraft fuselage. Extensive runs of laminar flow were predicted in regions of favorable pressure gradient on smooth body surfaces. A computational design procedure was developed to obtain a body shape with minimum drag having large extent of NLF.

Dodbele, S. S.↗
NASA NTRS2005

Aeroacoustic Characteristics of Model Jet Test Facility Flow Conditioners

An experimental investigation of flow conditioning devices used to suppress internal rig noise in high speed, high temperature experimental jet facilities is discussed. The aerodynamic and acoustic characteristics of a number of devices including pressure loss and extraneous noise generation are measured. Both aerodynamic and acoustic characteristics are strongly dependent on the porosity of the flow conditioner and the closure ratio of the duct system. For unchoked flow conditioners, the pressure loss follows conventional incompressible flow models. However, for choked flow conditioners, a compressible flow model where the duct and flow conditioner system is modeled as a convergent-divergent nozzle can be used to estimate pressure loss. Choked flow conditioners generate significantly more noise than unchoked conditioners. In addition, flow conditioners with small hole diameters or sintered metal felt material generate less self-noise noise compared to flow conditioners with larger holes.

Kinzie, Kevin W.↗
NASA NTRS2011

Active Flow Effectors for Noise and Separation Control

New flow effector technology for separation control and enhanced mixing is based upon shape memory alloy hybrid composite (SMAHC) technology. The technology allows for variable shape control of aircraft structures through actively deformable surfaces. The flow effectors are made by embedding shape memory alloy actuator material in a composite structure. When thermally actuated, the flow effector def1ects into or out of the flow in a prescribed manner to enhance mixing or induce separation for a variety of applications, including aeroacoustic noise reduction, drag reduction, and f1ight control. The active flow effectors were developed for noise reduction as an alternative to fixed-configuration effectors, such as static chevrons, that cannot be optimized for airframe installation effects or variable operating conditions and cannot be retracted for off-design or fail-safe conditions. Benefits include: Increased vehicle control, overall efficiency, and reduced noise throughout all f1ight regimes, Reduced flow noise, Reduced drag, Simplicity of design and fabrication, Simplicity of control through direct current stimulation, autonomous re sponse to environmental heating, fast re sponse, and a high degree of geometric stability. The concept involves embedding prestrained SMA actuators on one side of the chevron neutral axis in order to generate a thermal moment and def1ect the structure out of plane when heated. The force developed in the host structure during def1ection and the aerodynamic load is used for returning the structure to the retracted position. The chevron design is highly scalable and versatile, and easily affords active and/or autonomous (environmental) control. The technology offers wide-ranging market applications, including aerospace, automotive, and any application that requires flow separation or noise control.

Turner, Travis L.↗
NASA NTRS1982

High-intensity sound in air saturated fibrous bulk porous materials

The interaction high-intensity sound with bulk porous materials in porous materials including Kevlar 29 is reported. The nonlinear behavior of the materials was described by dc flow resistivity tests. Then acoustic propagation and reflection were measured and small signal broadband measurements of phase speed and attenuation were carried out. High-intensity tests were made with 1, 2, and 3 kHz tone bursts to measure harmonic generation and extra attenuation of the fundamental. Small signal standing wave tests measured impedence between 0.1 and 3.5 kHz. High level tests with single cycle tone bursts at 1 to 4 kHz show that impedance increases with intensity. A theoretical analysis is presented for high-porosity, rigid-frame, isothermal materials. One dimensional equations of motion are derived and solved by perturbation. The experiments show that there is excess attenuation of the fundamental component and in some cases a close approach to saturation. A separate theoretical model, developed to explain the excess attenuation, yields predictions that are in good agreement with the measurements. Impedance and attenuation at high intensities are modeled.

Kuntz, H. L., II↗
DOE OSTI2023

Quinones having high capacity retention for use as electrolytes in aqueous redox flow batteries

We disclose quinone compounds and related species (Formula I) that possess significant advantages when used as a redox active material in a battery, e.g., a redox flow battery. In particular, the compounds provide redox flow batteries (RFBs) with extremely high capacity retention. For example, RFBs of the invention can be cycled for 500 times with negligible loss of capacity, and such batteries could be employed for years of service. Thus, the invention provides a high efficiency, long cycle life redox flow battery with reasonable power cost, low energy cost, and all the energy scaling advantages of a flow battery.

Aziz, Michael J.↗
NASA NTRS1983

Crustal deformation, the earthquake cycle, and models of viscoelastic flow in the asthenosphere

The crustal deformation patterns associated with the earthquake cycle can depend strongly on the rheological properties of subcrustal material. Substantial deviations from the simple patterns for a uniformly elastic earth are expected when viscoelastic flow of subcrustal material is considered. The detailed description of the deformation pattern and in particular the surface displacements, displacement rates, strains, and strain rates depend on the structure and geometry of the material near the seismogenic zone. The origin of some of these differences are resolved by analyzing several different linear viscoelastic models with a common finite element computational technique. The models involve strike-slip faulting and include a thin channel asthenosphere model, a model with a varying thickness lithosphere, and a model with a viscoelastic inclusion below the brittle slip plane. The calculations reveal that the surface deformation pattern is most sensitive to the rheology of the material that lies below the slip plane in a volume whose extent is a few times the fault depth. If this material is viscoelastic, the surface deformation pattern resembles that of an elastic layer lying over a viscoelastic half-space. When the thickness or breath of the viscoelastic material is less than a few times the fault depth, then the surface deformation pattern is altered and geodetic measurements are potentially useful for studying the details of subsurface geometry and structure. Distinguishing among the various models is best accomplished by making geodetic measurements not only near the fault but out to distances equal to several times the fault depth. This is where the model differences are greatest; these differences will be most readily detected shortly after an earthquake when viscoelastic effects are most pronounced.

Cohen, S. C.↗
NASA NTRS1984

Crustal deformation, the earthquake cycle, and models of viscoelastic flow in the asthenosphere

The crustal deformation patterns associated with the earthquake cycle can depend strongly on the rheological properties of subcrustal material. Substantial deviations from the simple patterns for a uniformly elastic earth are expected when viscoelastic flow of subcrustal material is considered. The detailed description of the deformation pattern and in particular the surface displacements, displacement rates, strains, and strain rates depend on the structure and geometry of the material near the seismogenic zone. The origin of some of these differences are resolved by analyzing several different linear viscoelastic models with a common finite element computational technique. The models involve strike-slip faulting and include a thin channel asthenosphere model, a model with a varying thickness lithosphere, and a model with a viscoelastic inclusion below the brittle slip plane. The calculations reveal that the surface deformation pattern is most sensitive to the rheology of the material that lies below the slip plane in a volume whose extent is a few times the fault depth. If this material is viscoelastic, the surface deformation pattern resembles that of an elastic layer lying over a viscoelastic half-space. When the thickness or breath of the viscoelastic material is less than a few times the fault depth, then the surface deformation pattern is altered and geodetic measurements are potentially useful for studying the details of subsurface geometry and structure. Distinguishing among the various models is best accomplished by making geodetic measurements not only near the fault but out to distances equal to several times the fault depth. This is where the model differences are greatest; these differences will be most readily detected shortly after an earthquake when viscoelastic effects are most pronounced.

Cohen, S. C.↗
NASA NTRS2003

Isothermal Microcalorimetric Evaluation of Compatibility of Proposed Injector Materials with High-Test Hydrogen Peroxide Propellant

High-test hydrogen peroxide (HTP) is receiving renewed interest as a monopropellant and as the oxidizer for bipropellant systems. HTP is hydrogen peroxide in concentrations ranging from 70 to 98%. All surfaces wetted by HTP must be evaluated for compatibility with the fluid. In the case of tanks, lines and valves compatibility is required to preserve the HTP oxygen and energy content and to avoid overpressurization due to decomposition. With injectors and regenerative cooling passages shorter exposure time reduces these concerns. However, phase changes from fluid to gas impact heat transfer and become the dominant compatibility concern. Isothermal microcalorimetry (IMC) provides a convenient and reproducible means to observe the decomposition of HTP when exposed to structural materials and therefore the compatibility of those materials'. The instrument provides heat flow values in terms of watts that may be converted to a reaction rate given the heat of reaction for the decomposition of hydrogen peroxide. These values are then converted to percent active oxygen loss per week (%AOL/wk) to preserve an earlier convention for quantifying HTP compatibility. Additionally, qualitative designations of compatibility have been assigned to these values. This scheme consists of four classes with Class 1 being the most compatible. While historical compatibility data is available its current applicability is in question due to subtle changes in the compositions of both HTP and structural materials. Trace levels of molecules can have significant influence on compatibility. Therefore representative samples of materials must be evaluated with current HTP formulations. In this work seven materials were selected for their strength characteristics at high temperature as expected in a HTP injector. The materials were then evaluated by IMC for HTP compatibility.

Gostowski, Rudy↗
DOE OSTI2021

Recent progresses on thermal–hydraulics evaluations of accident tolerant fuel cladding materials

Thermal–hydraulics (T-H) experiments have been on the progress to evaluate boiling heat transfer characteristics of accident tolerant fuel (ATF) candidates for further supporting the core-loading of these advanced ATF concepts in light water reactors (LWRs). Here this study covers recent experimental studies of ATF claddings and summarizes some significant results. Recent T-H experimental results of ATF cladding candidates demonstrated that the material thermal–physical properties have pronounced effects on critical heat flux (CHF). Such effects have not been well resolved in the current physics-governing models. These effects of cladding materials on CHF could be potentially rationalized by the material-conjugated boiling heat transfer, where the material-dominated heat conduction competes with the flow boiling-dominated heat convection. As progressively increasing the mass flux and/or liquid subcooling, CHF differences between different materials gradually decrease, which is in agreement with the recent T-H experimental results of ATF claddings. This is because the dominance of heat convection over heat conduction is primarily improved by liquid subcooling and/or mass flow rate. It is noteworthy that surface oxidization of claddings may have unknown impacts on T-H performances because the formation of oxide layers on cladding surfaces introduces variations of material thermal–physical properties and then changes the surface morphological features, which results in some difficulties in evaluating the thermal safety margins of ATF claddings.

36 MATERIALS SCIENCE↗
DOE OSTI2023

SPH modeling of biomass granular flow: Theoretical implementation and experimental validation

The commercialization of biomass-derived energy is impeded by flowability challenges arising from the feeding and handling of granular biomass materials in full-scale biorefineries. To overcome these obstacles, a robust and accurate model to simulate the flow of granular biomass is indispensable. However, conventional mesh-based numerical codes are limited by inherent mesh distortion in simulating large deformation that commonly occurs in granular biomass handling. Here, in this study, we propose a graphics processing unit (GPU)-accelerated meshless Smoothed Particle Hydrodynamics (SPH) code to model the flow of granular biomass materials. A modified void ratio-based mass conversation, a hybrid particle-to-particle/surface frictional boundary treatment, and a hypoplastic constitutive model are implemented. Four numerical examples, an elastic block sliding on inclined planes, sand column collapse, Angle of Repose, and axial compression tests for pine chips, were simulated using the developed SPH code. The results demonstrate good agreement between numerical predictions and analytical and experimental data for all four examples, validating the SPH code and increasing confidence that it can be applied to simulate more complex granular biomass handling processes, such as hopper feeding or auger conveyance.

09 BIOMASS FUELS↗
NASA NTRS1999

Development of a hydraulic model of the human systemic circulation

Physical and numeric models of the human circulation are constructed for a number of objectives, including studies and training in physiologic control, interpretation of clinical observations, and testing of prosthetic cardiovascular devices. For many of these purposes it is important to quantitatively validate the dynamic response of the models in terms of the input impedance (Z = oscillatory pressure/oscillatory flow). To address this need, the authors developed an improved physical model. Using a computer study, the authors first identified the configuration of lumped parameter elements in a model of the systemic circulation; the result was a good match with human aortic input impedance with a minimum number of elements. Design, construction, and testing of a hydraulic model analogous to the computer model followed. Numeric results showed that a three element model with two resistors and one compliance produced reasonable matching without undue complication. The subsequent analogous hydraulic model included adjustable resistors incorporating a sliding plate to vary the flow area through a porous material and an adjustable compliance consisting of a variable-volume air chamber. The response of the hydraulic model compared favorably with other circulation models.

NASA Program Biomedical Research and Countermeasur↗