Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “mass diffusivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 955 records · Page 53

The Matter Beyond the Ring: The Recent Evolution of SN 1987A Observed by the Hubble Space Telescope

The nearby SN 1987A offers a spatially resolved view of the evolution of a young supernova (SN) remnant. Here we present recent Hubble Space Telescope imaging observations of SN 1987A, which we use to study the evolution of the ejecta, the circumstellar equatorial ring (ER), and the increasing emission from material outside the ER. We find that the inner ejecta have been brightening at a gradually slower rate and that the western side has been brighter than the eastern side since ∼7000 days. This is expected given that the X-rays from the ER are most likely powering the ejecta emission. At the same time, the optical emission from the ER continues to fade linearly with time. The ER is expanding at 680 ± 50 km s−1, which reflects the typical velocity of transmitted shocks in the dense hot spots. A dozen spots and a rim of diffuse Hα emission have appeared outside the ER since 9500 days. The new spots are more than an order of magnitude fainter than the spots in the ER and also fade faster. We show that the spots and diffuse emission outside the ER may be explained by fast ejecta interacting with high-latitude material that extends from the ER toward the outer rings. Further observations of this emission will make it possible to determine the detailed geometry of the high-latitude material and provide insight into the formation of the rings and the mass-loss history of the progenitor.

Core-collapse supernova↗

The cool DC white dwarf Stein 2051B

Visual scans from the Kitt-Peak 2.1-m telescope and UV spectra from the IUE satellite are combined in a spectroscopic study of the bright DC white dwarf, Stein 2051B. With a cooling age near 2 billion years, and a resulting atmospheric mass of hydrogen of the order of 6 x 10 to the 17th g, the accretion rate over the star's lifetime is less than 2 x 10 to the -25th solar masses/year. This is far below the predictions of standard accretion theories, and requires unreasonably strong suppression of hydrogen accretion in this star if the accretion-diffusion theory is to account for the carbon abundance found. It is suggested that the carbon may have been brought to the surface by convective mixing.

Wegner, G.↗

Lateral fluid forces acting on a whirling centrifugal impeller in vaneless and vaned diffuser

Fluid forces on a rotating centrifugal impeller in whirling motion were studied. A two dimensional impeller installed in a parallel-walled vaneless and vaned diffuser whirled on a circular orbit with various positive and negative angular velocities. It is shown that the fluid forces exert a damping effect on the rotor in most operating conditions, but become excitatory when the impeller operates at very low partial discharge while rotating far faster than the whirl speed. The fluid forces were expressed in terms of mass, damping and stiffness matrices. Impellers with the same geometry and whirl condition are calculated. Quantitative agreement is obtained especially in positive whirl.

Ohashi, H.↗

Production of isotopically heavy ozone by ultraviolet light photolysis of O2

Ozone was produced by UV photolysis (157-200 nm) of molecular oxygen. The product ozone is enriched in O-17 and O-18 on a mass-independent basis, similar to the fractionations observed in an electrical discharge. The magnitude of O-18 and O-17 enrichment decreases with decreasing pressure, suggesting the presence of two fractionation mechanisms with differing delta-O-17/delta-O-18 ratios. One of the end members would be mass-independent with delta-O-18 equal to delta-O-17 equal to about 90 percent, which is dominant above about 20 torr. The second process which is significant below about 6 torr produces O3 with delta-O-18 equals about -55 percent, delta-O-17 equals about -27.5, possibly due to isotopic selectivity in diffusion to the reaction systems wall. The delta-O-17 = delta-O-18 isotopic fractionation resembles that observed in stratospheric ozone, though the magnitude of fractionation is a factor of four less.

Thiemens, Mark H.↗

Magnetic reconnection in incompressible fluids

The paper investigates the dynamical relaxation of a disturbed X-type magnetic neutral point in a periodic geometry, with an ignorable coordinate, for an incompressible fluid. It is found that the properties of the current sheet cannot be understood in terms of steady state reconnection theory or more recent linear dynamical solutions. Accordingly, a new scaling law for magnetic reconnection is presented, consistent with fast energy dissipation (i.e., the dissipation rate at current maximum is approximately independent of magnetic diffusivity (eta)). The flux annihilation rate, however, scales at eta exp 1/4, faster than the Sweet-Parker rate of sq rt eta but asymptotically much slower than the dissipation rate. These results suggest a flux pile-up regime in which the bulk of the free magnetic energy is released as heat rather than as kinetic energy of mass motion. The implications of our results for reconnection in the solar atmosphere and interior are discussed.

Deluca, Edward E.↗

ROSAT-IUE observations of symbiotic stars. The x ray morphology of high latitude associations

The purposes of this grant included: to provide for continuing investigations of the x-ray properties of a class of interacting binaries known as symbiotic stars through analysis of their detection statistics in the ROSAT All-Sky Survey and simultaneous IUE observations; and to obtain and analyze ROSAT images of selected high latitude OB star associations, in order to permit multi-wavelength dissection of their contents and energetics. The first study is expected to result in enhanced information on mass transfer and accretion in such systems, and provide a more quantitative basis for interpretation of the spectra of these and similar stellar and extragalactic systems. This particular effort represents NASA support for an approved collaboration between the PI and the ROSAT Team at MPE Garching. In the second study, we seek to correlate the strength with which the diffuse clouds have been shocked and the recent star formation triggered, namely, the O and B stars of the Association, as well as nearby T Tauri stars. The large scale X-ray emission in deep ROSAT PSPC images will be compared with the optical, infrared, and radio topology of nearby supernova remnants, molecular clouds, and the distribution of massive stars in the regions. This should enable us to test whether the star formation triggering shocks originate from in the galactic plane (nearby supernovae) or from the collision of infalling matter with the disk material (galactic fountain dynamics).

Stencel, Robert E.↗

Mass Transfer Cooling Near The Stagnation Point

A simplified analysis is made of mass transfer cooling, that is, injection of a foreign gas, near the stagnation point for two-dimensional and axisymmetric bodies. The reduction in heat transfer is given in terms of the properties of the coolant gas and it is shown that the heat transfer may be reduced considerably by the introduction of a gas having appropriate thermal and diffusive properties. The mechanism by which heat transfer is reduced is discussed.

Roberts, Leonard↗

First Detection of Krypton and Xenon in a White Dwarf

We report on the first detection of the noble gases krypton (Z = 36) and xenon (54) in a white dwarf. About 20 KrVI-VII and Xe VI-VII lines were discovered in the ultraviolet spectrum of the hot DO-type white dwarf RE 0503-289. The observations, performed with the Far Ultraviolet Spectroscopic Explorer, also reveal highly ionized photospheric lines from other trans-iron group elements, namely Ga (31), Ge (32), As (33), Se (34), Mo (42), Sn (50), Te (52), and I (53), from which gallium and molybdenum are new discoveries in white dwarfs, too. For Kr and Xe, we performed an NLTE analysis and derived mass fractions of log Kr = -4.3 plus or minus 0.5 and log Xe = -4.2 plus or minus 0.6, corresponding to an enrichment by factors of 450 and 3800, respectively, relative to the Sun. The origin of the large overabundances is unclear. We discuss the roles of neutron-capture nucleosynthesis in the-precursor star and radiation-driven diffusion. It is possible that diffusion is insignificant and thaI the observed metal abundances constrain the evolutionary history of the star. Its hydrogen deficiency may be the consequence of a late helium-shell nash or a binary white dwarf merger.

Werner, Klaus↗

The Chemical Evolution of Cosmic Dust: From Gas-Phase Precursors to Solid Grains - Laboratory Studies with the COSmIC Facility

Cosmic dust in in its gas phase and solid phase components plays an essential role in the chemical and physical evolution of the universe. Our understanding of cosmic dust properties relies on a combination of astronomical observations, astrophysical modeling and laboratory studies of realistic analogs of cosmic dust being gas-phase molecules and/or solid grains. The COSmIC facility was developed at NASA Ames to study the evolution of cosmic carbon from circumstellar outflows to interstellar clouds to planetary atmospheres in the laboratory [1]. COSmIC stands for “Cosmic Simulation Chamber” and is dedicated to the study of neutral and ionized molecules and grain particles under the low temperature and density conditions that are required to simulate space environments. It integrates a variety of instruments that allow generating, processing, and monitoring simulated space conditions in the laboratory. It is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a plasma in a free supersonic jet expansion, coupled to high-sensitivity, complementary in situ diagnostic tools used for the detection and characterization of the species present in the expansion: Cavity Ring Down Spectroscopy (CRDS) and fluorescence spectroscopy systems for photonic detection and an orthogonal Reflectron Time-Of-Flight Mass Spectrometer (oReTOF-MS) for mass detection. Recent advances achieved using COSmIC’s laboratory data in synergy with observational data will be presented. These results include the formation of dust grains and aerosols from gas-phase molecular precursors in environments as varied as circumstellar outflows of late AGB stars [2, 3] and planetary atmospheres [4] and the evolution of our understanding of the diffuse interstellar bands (DIBs) with applications to the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES [5, 6]). Plans for future laboratory developments and techniques to study the evolution of cosmic carbon molecules and grains (including NIR-MIR CRDS, laser induced fluorescence (LIF) and incandescence (LII)) will also be addressed as well as their astronomical applications.

Planetary↗

OSO-7 hard X-ray observations of 3U 0352+30 = X Persei

Results are reported for OSO 7 observations of 3U 0352+30 (X Per) over the energy range from 7 to 110 keV. It is found that this source has either a hard power-law spectrum or a thermal bremsstrahlung spectrum over the observed energy range, indicating that X Per may be the prototype of a new class of weak galactic hard X-ray sources. The data are shown to be consistent with spectra calculated for accretion onto a degenerate dwarf of at least 1 solar mass. Geometrical and dynamical constraints are considered for a model in which an accreting degenerate dwarf is in a close orbit about the primary of X Per, and it is concluded that such a model is not ruled out at present. It is suggested that X-ray sources associated with Be stars may make a significant contribution to the diffuse hard X-ray background in the galactic plane.

Mushotzky, R. F.↗

Grain alignment by ferromagnetic impurities

The observed wavelength dependence of linear polarization, and its variation from region to region can be explained by the following assumptions. Interstellar grains resemble interplanetary grains, in that they are composed of collections of small particles coagulated together into elongated masses. A fraction of the small particles are ferromagnetic. Presumably these are either metallic Fe or magnetite, Fe3O4. If and only if a large grain contains one or more magnetic particles is the grain aligned in the galactic magnetic field. The magnetic particles stick only to silicate grains because of chemical similarities, or (equivalently) any pure carbon grains in the diffuse interstellar medium (ISM) are too spherical to produce polarization. Grains in dense regions, such as the outer parts of molecular clouds, are larger than those in the diffuse ISM because of coagulation of the grains rather than accretion of icy mantles. These regions are known to have larger than normal values of lambda (max), the wavelength of the maximum of linear polarization. The above assumptions are sufficient to allow the calculation of the wavelength dependence of the polarization.

Mathis, J. S.↗

Solar wind noble gases and nitrogen in metal from lunar soil 68501

Noble gases and N were analyzed in handpicked metal separates from lunar soil 68501 by a combination of step-wise combustions and pyrolyses. Helium and Ne were found to be unfractionated with respect to one another when normalized to solar abundances, for both the bulk sample and for all but the highest temperature steps. However, they are depleted relative to Ar, Kr and Xe by at least a factor of 5. The heavier gases exhibit mass-dependent fractionation relative to solar system abundance ratios but appear unfractionated, both in the bulk metal and in early temperature steps, when compared to relative abundances derived from lunar ilmenite 71501 by chemical etching, recently put forward as representing the abundance ratios in solar wind. Estimates of the contribution of solar energetic particles (SEP) to the originally implanted solar gases, derived from a basic interpretation of He and Ne isotopes, yield values of about 10%. Analysis of the Ar isotopes requires a minimum of 20% SEP, and Kr isotopes, using our preferred composition for solar wind Kr, yield a result that overlaps both these values. It is possible to reconcile the data from these gases if significant loss of solar wind Ar, Kr and presumably Xe has occurred relative to the SEP component, most likely by erosive processes that are mass independent, although mass-dependent losses (Ar greater than Kr greater than Xe) cannot be excluded. If such losses did occur, the SEP contribution to the solar implanted gases must have been no more than a few percent. Nitrogen is a mixture of indigenous meteoritic N, whose isotopic composition is inferred to be relatively light, and implanted solar N, which has probably undergone diffusive redistribution and fractionation. If the heavy noble gases have not undergone diffusive loss, then N/Ar in the solar wind can be inferred to be at least several times the accepted solar ratio. The solar wind N appears, even after correction for fractionation effects, to have a minimum delta N-15 value equal to or greater than +150% and a more probable value equal to or greater than +200%.

Becker, Richard H.↗

Influence of Solutocapillary Convection on Macrovoid Defect Formation in Polymeric Membranes

Macrovoids (MVs) are large (10-50 micrometers) pores often found in polymeric membranes prepared via phase-inversion techniques. They are generally considered undesirable, as they adversely affect the permeability properties and performance of polymeric membranes for microfiltration, ultrafiltration, and reverse osmosis. However, MVs can be useful in certain thin-film applications in which vapor transmission is necessary, or for use as reservoirs for enzymes or liquid membrane material. If more could be learned about the nature and causes of MV formation, it might be possible to devise techniques to control and/or prevent MV formation that are more effective than those currently employed. Two hypotheses for the MV growth mechanism have been advanced. Reuvers proposed that once initiated, MV growth can be attributed to diffusion of (primarily) solvent to the MV nuclei. Because this mechanism does not involve gross movement of the MV, the presence or absence of body forces such as buoyancy should not significantly affect MV growth. On the other hand, Shojaie et al. proposed that solutocapillary convection induced by a steep surface-tension gradient along the MV/bulk solution interface enhances mass transfer to the growing MV. This interfacial convection exerts a force that pulls the growing MV downward into the casting solution. Both buoyancy and viscous drag hinder MV growth by inhibiting this motion. Thus, removing the buoyancy force by casting in microgravity should augment MV growth according to this hypothesis. Whereas neither surface tension nor gravity has a significant effect on MV growth according to the first hypothesis, buoyancy forces should be important if the second hypothesis is correct. The overall goal of this research is to test these two hypotheses in order to improve our understanding of the MV growth processing solvent-cast polymeric membranes. Studying MV growth in low-gravity conditions is pivotal to our ability to discriminate between these two hypotheses.

Pekny, M. R.↗

A Burning Rate Emulator (BRE) for Study in Microgravity

A gas-fueled burner, the Burning Rate Emulator (BRE), is used to emulate condensed-phase fuel flames. The design has been validated to easily measure the burning behavior of condensed-phase fuels by igniting a controlled stream of gas fuel and diluent. Four properties, including the heat of combustion, the heat of gasification, the surface temperature, and the laminar smoke point, are assumed to be sufficient to define the steady burning rate of a condensed-phase fuel. The heat of gasification of the fuel is determined by measuring the heat flux and the fuel flow rate. Microgravity BRE tests in the NASA 5.2 s drop facility have examined the burning of pure methane and ethylene (pure and 50 in N2 balance). Fuel flow rates, chamber oxygen concentration and initial pressure have been varied. Two burner sizes, 25 and 50 mm respectively, are chosen to examine the nature of initial microgravity burning. The tests reveal bubble-like flames that increase within the 5.2s drop but the heat flux received from the flame appears to asymptotically approach steady state. Portions of the methane flames appear to locally detach and extinguish at center, while its shape remains fixed, but growing. The effective heat of gasification is computed from the final measured net heat flux and the fuel flow rate under the assumption of an achieved steady burning. Heat flux (or mass flux) and flame position are compared with stagnant layer burning theory. The analysis offers the prospect of more complete findings from future longer duration ISS experiments.

diffusion flames↗

Implementation of Charged Particle Behavior in Discrete Element Method (DEM) Simulations

Lunar landers will agitate the surface of the Moon with an exhaust plume during descent which will, due to the particulate nature of the lunar regolith, loosen and eject grains from the surface. This ejection is not only coupled with the charged plume gas, but also results in significant particle-particle interactions. Settling of these grains after plume effects have subsided takes much longer than expected in a ballistic trajectory. The prevailing hypothesis attributes this behavior to the accumulated charge on the particles. We are thus developing a discrete element method (DEM) approach to explore these charged particle interactions on the lunar surface. The Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) Improved for General Granular and Granular Heat Transfer Simulations (LIGGGHTS) software package provides a DEM modeling framework for granular interactions. It includes many complexities such as non-spherical particle shapes, cohesion and frictional forces, and heat transfer, but has no provision for inter-particle electrostatic forces and charge transfer that are important to examine in the lunar environment. In this work, a standard Coulomb potential and a Yukawa potential are integrated into the LIGGGHTS framework to provide a basis for particle-particle electrostatic interactions, as well as a gravitational potential to enable inter-grain gravitational interactions. A preliminary approach to charge transfer between grains incorporating properties such as work function and electrical conductivity to the library of available material characteristics will be presented. Several scenarios have been simulated that include charged particle interactions within a diffuse granular gas, settling of charged grains into a regolith bed, sliding of granular material along an incline, and vibration of settled grains to produce a behavior similar to fluidization. There are numerous challenges to incorporate realistic interactions between complex lunar particles. Currently, grains are modeled to behave as if the entirety of the charge acts at the center of mass, such as conductors with spherical symmetry and insulators with homogeneously distributed charge. We are developing improvements that will include the use of non-spherical particle geometries, as well as reasonable approximations of insulating/dielectric materials that have non-uniform charge distributions. The cases simulated thus far will be examined in a relevant environment within a vacuum chamber to validate the simulations. These simulations will be bounded by experiments utilizing high-speed camera observations of the motion for validation. The grains in the experiment will exchange charge during their motion and this can be quantified by collection within a charge measurement device such as a Faraday cup. Such a device may be modeled within the software by defining an integration region and computing the contained charge as a function of simulation time, allowing for side-by-side comparison of simulated and measured bulk charging results. Any differences will be reconciled by updating the mathematical mechanisms described within the simulation suite. Successfully combining results from experiments within a relevant environment into the LIGGGHTS framework will improve modeling of the charged grain dynamics experienced on the Moon to provide insights into dust behavior for future lunar exploration missions.

Electrostatics↗

Pressure dependence of the oxygen reduction reaction at the platinum microelectrode/nafion interface - Electrode kinetics and mass transport

The investigation of oxygen reduction kinetics at the platinum/Nafion interface is of great importance in the advancement of proton-exchange-membrane (PEM) fuel-cell technology. This study focuses on the dependence of the oxygen reduction kinetics on oxygen pressure. Conventional Tafel analysis of the data shows that the reaction order with respect to oxygen is unity at both high and low current densities. Chronoamperometric measurements of the transport parameters for oxygen in Nafion show that oxygen dissolution follows Henry's isotherm. The diffusion coefficient of oxygen is invariant with pressure; however, the diffusion coefficient for oxygen is lower when air is used as the equilibrating gas as compared to when oxygen is used for equilibration. These results are of value in understanding the influence of O2 partial pressure on the performance of PEM fuel cells and also in elucidating the mechanism of oxygen reduction at the platinum/Nafion interface.

Parthasarathy, Arvind↗

Numerical modeling of diffusive-convective physical vapor transport in cylindrical vertical ampoules

Diffusive-convective physical vapor transport (PVT) in cylindrical, vertical ampoules of aspect ratio (length/radius) between 0.5 and 10 was modeled numerically. The transport of a crystal forming component through an inert component that undergoes zero net transport was considered. Systems were treated in which: (1) with unequal molecular weight of the components and with temperature gradients typically employed in PVT, convective flow arises dominantly from solutal density gradients; and (2) with equal molecular weight of the components, convective flow can arise only from thermal expansion. It was found that, due to the diffusion-induced horizontal density gradients, buoyancy-driven convective flows are superimposed on the diffusive-advective fluxes without threshold. Net recirculation sets in adjacent to the growing interface, in contrast to the corresponding monocomponent situation where marginally stable convective modes fill the whole fluid space. Depending on the orientation of the main transport direction with respect to gravity, convection can either reduce or enhance the diffusion-induced radial concentration gradients. Significant enhancement of the net transport rate was found to occur only when the whole vapor space between source and growing crystal is filled by a convective recirculation roll. Solutal and thermal convection results are similar; yet for quantitative discussions, thermal and solutal Rayleigh numbers are not interchangeable in contrast to convective situations that lack net mass transport across the fluid space.

Markham, B. L.↗

Mass and energy balance of the cold Io torus

A new model of the cold Io torus is described. Ions and energy are injected into the system by independent processes so that the mass balance is isolated from the energy balance. The primary source of energy is local ionization and acceleration of hot pickup ions resulting from charge exchange between thermal ions and an extended cloud of Iogenic sulfur and oxygen atoms. The primary energy loss mechanism of the plasma is collisionally excited line emission at optical wavelengths. The primary ion source is radial diffusion inward from the hot torus on a time scale of 140-710 days. The primary ion loss mechanism is a novel two-step enhanced recombination mechanism involving charge exchange between thermal ions and an extended cloud of neutral SO2 molecules, followed by rapid dissociative recombination of the resultant molecular ion. The model provides a self-consistent solution which reconciles a number of diverse observations with known physical processes.

Moreno, M. A.↗