Tuning metal-insulator behavior in LaTiO 3 /SrTiO 3 heterostructures integrated directly on Si(100) through control of atomic layer thickness
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Various electronic phases displayed by cuprates that exhibit high temperature superconductivity continue to attract much interest. We provide a short review of several experiments that we have performed aimed at investigating the superconducting state in these compounds. Measurements on single-phase films, bilayers, and superlattices all point to the conclusion that the high-temperature superconductivity in these materials is an essentially quasi-two dimensional phenomenon. With proper control over the film growth, high-temperature superconductivity can exist in a single copper oxide plane with the critical temperatures as high as that achieved in the bulk samples.
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We have investigated unusual phase transitions that were triggered by chemical doping in Ca 3 Ru 2 O 7 . Our experiments showed that doping with a few percent of Mn (>4%) can change the quasi-two-dimensional metallic state of Ca 3 Ru 2 O 7 into a Mott insulating state with a G-type antiferromagnetic order, but this Mott state cannot be induced by Fe doping. By combining these results with first-principles calculations, we show that lattice-orbital coupling (LOC) plays an important role in the Mott transition. Interestingly, the transition temperature T MIT is found to be predetermined by a structural parameter denoted by c/√ab at temperatures far above Néel temperature T N . This LOC-assisted Mott transition clearly contrasts with the band-filling picture. It is addressed that this type of Mott transition originates in the strong scattering centers formed by specific 3d dopants. The dopant-scattering picture is then applied to explain the puzzling doping effects that occur in other ruthenates and 3d oxides. As a result, our findings will advance the general understanding of how the unusual properties of 4d correlated systems are governed by the complex interplay that occurs among the charge, spin, lattice, and orbital degrees of freedom.
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