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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 955 records · Page 53
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Petrographic Evidence for Rapid Heating and Cooling During Chrondrule Formation

The chondrule cooling rates used in most chondrule-formation models appear to be too low. Recent petrographic evidence indicates that the amount of crystal (especially olivine) growth that occurred after the last melting event was about 30 smaller than the grain sizes simulated in order to estimate cooling rates. The smaller amount of growth leads to an upwards revision of cooling rates by about a factor of 1000. Most chondrules are porphyritic. They consist of large and small crystals of olivine and, less commonly, pyroxene immersed in a mesostasis having a plagioclase-rich composition. In the most primitive chondrites the mesostasis is often vitreous. Because the large majority of chondrules contain FeS, it is clear that the nebula had cooled below the FeS condensation temperature (ca. 650 K) before chondrule formation occurred. The high FeO/(FeO+MgO) ratios of some chondrules require still lower nebular temperatures (less than 500 K). The traditional view has been that porphyritic chondrules formed in a single heating/cooling event and many laboratory experiments have been carried out in various kinds of kinds of furnaces to try to simulate the formation of chondrules textures in a single heating/cooling cycle. These furnace experiments have been used to infer the cooling rates of chondrules during the temperature range at which olivine crystallized from the melt. Most of these inferred values are in the range 0.01-1 K per second. These low cooling rates are problematical because there is no long-term nebular environment that yields such values. In transparent regions chondrules would cool at rates orders of magnitude higher, whereas in an opaque nebular disk the cooling rates would be many orders of magnitude lower. And these latter conditions are not suitable locations for chondrule formation because such high temperatures would cause the complete evaporation of chondrules (which have melting temperatures about 600 K higher than their evaporation temperatures). During the last several years several kinds of petrographic evidence indicating rapid chondrule cooling have been recognized. These include thin overgrowths on relict grains, clusters of small crystals that grew following the most recent melting event, and fragments preserving shardlike shapes that would have been hidden had several tens of micrometers of new growth occurred following the last melting event. And there are other indications of rapid cooling including the preservation of volatiles such as FeS and one case where the modeling of O-isotopic and FeO/(FeO+MgO) gradients indicated a high cooling rate.

Wasson, J. T.↗
DOE OSTI2019

Laser-wakefield accelerators for high-resolution X-ray imaging of complex microstructures

Laser-wakefeld accelerators (LWFAs) are high acceleration-gradient plasma-based particle accelerators capable of producing ultra-relativistic electron beams. Within the strong focusing felds of the wakefeld, accelerated electrons undergo betatron oscillations, emitting a bright pulse of X-rays with a micrometer-scale source size that may be used for imaging applications. Non-destructive X-ray phase contrast imaging and tomography of heterogeneous materials can provide insight into their processing, structure, and performance. To demonstrate the imaging capability of X-rays from an LWFA we have examined an irregular eutectic in the aluminum-silicon (Al-Si) system. The lamellar spacing of the Al-Si eutectic microstructure is on the order of a few micrometers, thus requiring high spatial resolution. We present comparisons between the sharpness and spatial resolution in phase contrast images of this eutectic alloy obtained via X-ray phase contrast imaging at the Swiss Light Source (SLS) synchrotron and X-ray projection microscopy via an LWFA source. An upper bound on the resolving power of 2.7±0.3μm of the LWFA source in this experiment was measured. These results indicate that betatron X-rays from laser wakefeld acceleration can provide an alternative to conventional synchrotron sources for high resolution imaging of eutectics and, more broadly, complex microstructures.

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

Interpretation of electromagnetic modes in the sub-TAE frequency range in JET plasmas with elevated monotonic q-profiles

Recent JET deuterium experiments with an advanced tokamak scenario using an internal transport barrier (ITB) have been performed to clearly observe destabilized toroidicity-induced Alfvén eigenmodes (TAEs) by fast ions; interestingly, these also exhibit unstable electromagnetic (EM) perturbations in the sub-TAE frequency range. We identify such EM perturbations to be beta-induced ion temperature gradient (BTG) eigenmodes and not beta-induced Alfvén eigenmodes nor beta-induced Alfvén acoustic eigenmodes, which are often unstable in such high-beta plasmas with high-power neutral beam injection (NBI). The BTG modes are the most unstable modes due to the high thermal ion temperature gradient related to the ITB, high thermal ion temperature compared to thermal electron temperature (high T i /T⁠ e ), and a high ion beta regime. BTG mode experimental characteristics match the analytical theory, i.e., location in the vicinity of a rational magnetic surface with a low magnetic shear, mode frequency scaling with the ion diamagnetic frequency (⁠ω$^*_i$⁠), and a coupling among Alfvén and drift waves. We also perform linear gyrokinetic simulations with validated plasma profiles and equilibrium, and find a mode kinetically driven by thermal ions with similar characteristics as the experimental BTG modes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1993

Conjugate-Gradient Neural Networks in Classification of Multisource and Very-High-Dimensional Remote Sensing Data

Application of neural networks to classification of remote sensing data is discussed. Conventional two-layer backpropagation is found to give good results in classification of remote sensing data but is not efficient in training. A more efficient variant, based on conjugate-gradient optimization, is used for classification of multisource remote sensing and geographic data and very-high-dimensional data. The conjugate-gradient neural networks give excellent performance in classification of multisource data, but do not compare as well with statistical methods in classification of very-high-dimentional data.

Benediktsson, J. A.↗
DOE OSTI2017

Liquid Metals as Plasma-facing Materials for Fusion Energy Systems: From Atoms to Tokamaks

The objective of our studies was to advance our fundamental understanding of liquid metals as plasma-facing materials for fusion energy systems, with a broad scope: from atoms to tokamaks. The flow of liquid metals offers solutions to significant problems of the plasma-facing materials for fusion energy systems. Candidate metals include lithium, tin, gallium, and their eutectic combinations. However, such liquid metal solutions can only be designed efficiently if a range of scientific and engineering issues are resolved that require advances in fundamental fluid dynamics, materials science and surface science. In our research we investigated a range of significant and timely problems relevant to current and proposed engineering designs for fusion reactors, including high-heat flux configurations that are being considered by leading fusion energy groups world-wide. Using experimental and theoretical tools spanning atomistic to continuum descriptions of liquid metals, and bridging surface chemistry, wetting/dewetting and flow, our research has advanced the science and engineering of fusion energy materials and systems. Specifically, we developed a combined experimental and theoretical program to investigate flows of liquid metals in fusion-relevant geometries, including equilibrium and stability of thin-film flows, e.g. wetting and dewetting, effects of electromagnetic and thermocapillary fields on liquid metal thin-film flows, and how chemical interactions and the properties of the surface are influenced by impurities and in turn affect the surface wetting characteristics, the surface tension, and its gradients. Because high-heat flux configurations produce evaporation and sputtering, which forces rearrangement of the liquid, and any dewetting exposes the substrate to damage from the plasma, our studies addressed such evaporatively driven liquid flows and measured and simulated properties of the different bulk phases and material interfaces. The range of our studies included (i) quantum mechanical calculations that allow inclusion of many thousands of atoms for the characterization of the interface of liquid metals exposed to continuous bombardment by deuterium and tritium as expected in fusion, (ii) molecular dynamics studies of the phase behavior of liquid metals, which (a) utilize thermodynamic properties computed using our quantum mechanical calculations and (b) establish material and wetting properties of the liquid metals, including relevant eutectics, (iii) experimental investigations of the surface science of liquid metals, interacting both with the solid substrate as well as gaseous species, and (iv) fluid dynamical studies that incorporate the material and surface science results of (ii) and (iii) in order to characterize flow in capillary porous materials and the thin-film flow along curved boundaries, both of which are potentially major components of plasma-facing materials. The outcome of these integrated studies was new understanding that enables developing design rules useful for future developments of the plasma-facing components critical to the success of fusion energy systems.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Algorithms for high aspect ratio oriented triangulations

Grid generation plays an integral part in the solution of computational fluid dynamics problems for aerodynamics applications. A major difficulty with standard structured grid generation, which produces quadrilateral (or hexahedral) elements with implicit connectivity, has been the requirement for a great deal of human intervention in developing grids around complex configurations. This has led to investigations into unstructured grids with explicit connectivities, which are primarily composed of triangular (or tetrahedral) elements, although other subdivisions of convex cells may be used. The existence of large gradients in the solution of aerodynamic problems may be exploited to reduce the computational effort by using high aspect ratio elements in high gradient regions. However, the heuristic approaches currently in use do not adequately address this need for high aspect ratio unstructured grids. High aspect ratio triangulations very often produce the large angles that are to be avoided. Point generation techniques based on contour or front generation are judged to be the most promising in terms of being able to handle complicated multiple body objects, with this technique lending itself well to adaptivity. The eventual goal encompasses several phases: first, a partitioning phase, in which the Voronoi diagram of a set of points and line segments (the input set) will be generated to partition the input domain; second, a contour generation phase in which body-conforming contours are used to subdivide the partition further as well as introduce the foundation for aspect ratio control, and; third, a Steiner triangulation phase in which points are added to the partition to enable triangulation while controlling angle bounds and aspect ratio. This provides a combination of the advancing front/contour techniques and refinement. By using a front, aspect ratio can be better controlled. By using refinement, bounds on angles can be maintained, while attempting to minimize the number of Steiner points.

Posenau, Mary-Anne K.↗
DOE OSTI2013

Phonon thermal transport outside of local equilibrium in nanowires via molecular dynamics

We study thermal transport through Pt nanowires that bridge planar contacts as a function of wire length and vibrational frequency of the contacts. When phonons in the contacts have lower average frequencies than those in the wires thermal transport occurs under conditions away from local equilibrium with low-frequency phonons experiencing a higher thermal gradient than high-frequency ones. This results in a size-dependent increase in the effective thermal conductivity of the wire with decreasing vibrational frequencies of the contacts. The interfacial resistivity when heat flows from the wire to the contact is also size-dependent and has the same physical origin in the lack of full equilibration in short nanowires. We develop a model based on a 1D atomic chain that captures the salient physics of the MD results.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Chemoattractant receptors activate, recruit and capture G proteins for wide range chemotaxis

Highlights: • Chemotactic GPCR forms an unconventional complex with the activated Gα. • Receptors activate, recruit and capture G proteins at different cAMP concentrations. • Capture of Gα can contribute to gradient sensing at high cAMP concentrations. The wide range sensing of extracellular signals is a common feature of various sensory cells. Eukaryotic chemotactic cells driven by GPCRs and their cognate G proteins are one example. This system endows the cells directional motility towards their destination over long distances. There are several mechanisms to achieve the long dynamic range, including negative regulation of the receptors upon ligand interaction and spatial regulation of G proteins, as we found recently. However, these mechanisms are insufficient to explain the 10{sup 5}-fold range of chemotaxis seen in Dictyostelium. Here, we reveal that the receptor-mediated activation, recruitment, and capturing of G proteins mediate chemotactic signaling at the lower, middle and higher concentration ranges, respectively. These multiple mechanisms of G protein dynamics can successfully cover distinct ranges of ligand concentrations, resulting in seamless and broad chemotaxis. Furthermore, single-molecule imaging analysis showed that the activated Gα subunit forms an unconventional complex with the agonist-bound receptor. This complex formation of GPCR-Gα increased the membrane-binding time of individual Gα molecules and therefore resulted in the local accumulation of Gα. Our findings provide an additional chemotactic dynamic range mechanism in which multiple G protein dynamics positively contribute to the production of gradient information.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

Innovative compact braze-free accelerating cavity

We report that high energy physics experiments using particle accelerators as well as industrial and medical applications are continuously seeking more compact, robust and cheaper accelerating structures. As of today, stable operating gradients, exceeding 100 MV/m, have been demonstrated by the SLAC group in the X-Band (11.424 GHz). These experiments show that hard structures, fabricated without high-temperature processes, achieve a better high gradient performance in terms of accelerating gradients. Therefore, we present an innovative and compact type of accelerating cavity that avoids any high-temperature processes like brazing or diffusion bonding. All cells are joined together by means of specifically designed and proprietary screws which ensure good vacuum and RF contacts. Two three-cell standing-wave accelerating structures, designed to operate in the pi-mode at 11.424 GHz, have been successfully built and cold tested. In order to guarantee a vacuum envelope and mechanically robust assembly, we used the Electron Beam Welding (EBW) and the Tungsten Inert Gas (TIG) processes. Lastly, this work has been carried out in the framework of a funded project by the Vth Committee of the INFN for the Laboratori Nazionali di Frascati (LNF), within a large international collaboration between LNF, SLAC and KEK for the development of X-Band accelerating cavities using "hard structure" technology.

43 PARTICLE ACCELERATORS↗
DOE OSTI2018

Processing Parameter Effects on Residual Stress and Mechanical Properties of Selective Laser Melted Ti6Al4V

Selective laser melting (SLM) process is characterized by large temperature gradients resulting in high levels of residual stress within the additively manufactured metallic structure. SLM-processed Ti6Al4V yields a martensitic microstructure due to the rapid solidification and results in a ductility generally lower than a hot working equivalent. Post-process heat treatments can be applied to SLM components to remove in-built residual stress and improve ductility. Residual stress buildup and the mechanical properties of SLM parts can be controlled by varying the SLM process parameters. This investigation studies the effect of layer thickness on residual stress and mechanical properties of SLM Ti6Al4V parts. This is the first-of-its kind study on the effect of varying power and exposure in conjunction with keeping the energy density constant on residual stress and mechanical properties of SLM Ti6Al4V components. It was found that decreasing power and increasing exposure for the same energy density lowered the residual stress and improved the % elongation of SLM Ti6Al4V parts. Increasing layer thickness resulted in lowering the residual stress at the detriment of mechanical properties. The study is based on detailed experimental analysis along with finite element simulation of the process using ABAQUS to understand the underlying physics of the process.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Along the Channel Gradients Impact on the Spatioactivity of Gas Diffusion Electrodes at High Conversions during CO 2 Electroreduction

Results of a 2-D transport model for a gas diffusion electrode performing CO 2 reduction to CO with a flowing catholyte are presented, including the concentration gradients along the flow cell, spatial distribution of the current density and local pH in the catalyst layer. The model predicts that both the concentration of CO 2 and the buffer electrolyte gradually diminish along the channels for a parallel flow of gas and electrolyte as a result of electrochemical conversion and nonelectrochemical consumption. At high single-pass conversions, significant concentration gradients exist along the flow channels leading to large local variations in the current density (>150 mA/cm 2 ), which becomes prominent when compared to ohmic losses. In addition, concentration overpotentials change dramatically with CO 2 flow rate, which results in significant differences in outlet concentrations at high conversions. The outlet concentration of CO attains a maximum of 80% along with 5% CO 2 and 15% H 2 , although the maximum single-pass conversion is limited to below 60% due to homogeneous consumption by the electrolyte. Fundamental and practical implications of our findings on electrochemical CO 2 reduction are discussed with a focus on the trade-off between high current density operation and high single-pass conversion efficiency.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Crystalline Bilayer Graphene with Preferential Stacking from Ni–Cu Gradient Alloy

We developed a high-yield synthesis of highly crystalline bilayer graphene (BLG) with two preferential stacking modes using a Ni–Cu gradient alloy growth substrate. Previously reported approaches for BLG growth include flat growth substrates of Cu or Ni–Cu uniform alloys and “copper pocket” structures. Use of flat substrates has the advantage of being scalable, but the growth mechanism is either “surface limited” (for Cu) or carbon precipitation (for uniform Ni–Cu), which results in multicrystalline BLG grains. For copper pockets, growth proceeds through a carbon back-diffusion mechanism, which leads to the formation of highly crystalline BLG, but scaling of the copper pocket structure is expected to be difficult. Here we demonstrate a Ni–Cu gradient alloy that combines the advantages of these earlier methods: the substrate is flat, so easy to scale, while growth proceeds by a carbon back-diffusion mechanism leading to high-yield growth of BLG with high crystallinity. Here, the BLG layer stacking was almost exclusively Bernal or twisted with an angle of 30°, consistent with first-principles calculations we conducted. Furthermore, we demonstrated scalable production of transistor arrays based crystalline Bernal-stacked BLG with a band gap that was tunable at room temperature.

36 MATERIALS SCIENCE↗
NASA NTRS1974

Determination of the radial gradient in the region 0.81-1.0 AU using both high- and low-energy /more than 10-GeV and more than 52-MeV/ detectors for the 1-AU monitor

A determination of the radial gradient for alpha particles (31-46 MeV/nuc) and protons with energies above 7.5 MeV and 44-77 MeV in the region 1.0-0.81 AU is presented for the solar-quiet year 1966. The determinations are based on data from the Pioneer 6 space probe. Two different detectors are used: the Deep River neutron monitor and measurements of low energy protons made on the IMP-C satellite. The average energy response of the Deep River monitor is 16 GeV, whereas the IMP-C data is for protons with energies above 50 MeV. The resulting radial gradient is found to be nearly zero for the alpha particles and slightly negative for the protons. The same qualitative results were found using the IMP-C data and the Deep River neutron monitor to measure the temporal variation in the cosmic ray intensity. The present analysis indicates that detectors over a wide range of energies are suitable for measuring the radial gradient, providing sufficient statistical precision is obtained to evaluate short-term modulation and the azimuthal separation of the detectors is not great.

Sheldon, W. R.↗
DOE OSTI2015

RACORO continental boundary layer cloud investigations. Part I: Case study development and ensemble large-scale forcings

Observation-based modeling case studies of continental boundary layer clouds have been developed to study cloudy boundary layers, aerosol influences upon them, and their representation in cloud- and global-scale models. Three 60-hour case study periods span the temporal evolution of cumulus, stratiform, and drizzling boundary layer cloud systems, representing mixed and transitional states rather than idealized or canonical cases. Based on in-situ measurements from the RACORO field campaign and remote-sensing observations, the cases are designed with a modular configuration to simplify use in large-eddy simulations (LES) and single-column models. Aircraft measurements of aerosol number size distribution are fit to lognormal functions for concise representation in models. Values of the aerosol hygroscopicity parameter, κ, are derived from observations to be ~0.10, which are lower than the 0.3 typical over continents and suggestive of a large aerosol organic fraction. Ensemble large-scale forcing datasets are derived from the ARM variational analysis, ECMWF forecasts, and a multi-scale data assimilation system. The forcings are assessed through comparison of measured bulk atmospheric and cloud properties to those computed in 'trial' large-eddy simulations, where more efficient run times are enabled through modest reductions in grid resolution and domain size compared to the full-sized LES grid. Simulations capture many of the general features observed, but the state-of-the-art forcings were limited at representing details of cloud onset, and tight gradients and high-resolution transients of importance. Methods for improving the initial conditions and forcings are discussed. The cases developed are available to the general modeling community for studying continental boundary clouds.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

On the formation and origin of substorm growth phase/onset auroral arcs inferred from conjugate space-ground observations

In this study, magnetotail processes and structures related to substorm growth phase/onset auroral arcs remain poorly understood mostly due to the lack of adequate observations. In this study we make a comparison between ground-based optical measurements of the premidnight growth phase/onset arcs at subauroral latitudes and magnetically conjugate measurements made by the Active Magnetosphere and Planetary Electrodynamics Response Experiment (AMPERE) at ~780 km in altitude and by the Van Allen Probe B (RBSP-B) spacecraft crossing L values of ~5.0–5.6 in the premidnight inner tail region. The conjugate observations offer a unique opportunity to examine the detailed features of the arc location relative to large-scale Birkeland currents and of the magnetospheric counterpart. Our main findings include (1) at the early stage of the growth phase the quiet auroral arc emerged ~4.3° equatorward of the boundary between the downward Region 2 (R2) and upward Region 1 (R1) currents; (2) shortly before the auroral breakup (poleward auroral expansion) the latitudinal separation between the arc and the R1/R2 demarcation narrowed to ~1.0°; (3) RBSP-B observed a magnetic field signature of a local upward field-aligned current (FAC) connecting the arc with the near-Earth tail when the spacecraft footprint was very close to the arc; and (4) the upward FAC signature was located on the tailward side of a local plasma pressure increase confined near L ~5.2–5.4. These findings strongly suggest that the premidnight arc is connected to highly localized pressure gradients embedded in the near-tail R2 source region via the local upward FAC.

58 GEOSCIENCES↗
DOE OSTI2017

Van Allen Probes observations of structured whistler mode activity and coincident electron Landau acceleration inside a remnant plasmaspheric plume

We present observations from the Van Allen Probes spacecraft that identify a region of intense whistler mode activity within a large density enhancement outside of the plasmasphere. We speculate that this density enhancement is part of a remnant plasmaspheric plume, with the observed wave being driven by a weakly anisotropic electron injection that drifted into the plume and became nonlinearly unstable to whistler emission. Particle measurements indicate that a significant fraction of thermal (<100 eV) electrons within the plume were subject to Landau acceleration by these waves, an effect that is naturally explained by whistler emission within a gradient and high-density ducting inside a density enhancement.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

A convection-permitting dynamically downscaled dataset over the Midwestern United States

Climate change is expected to have far-reaching effects at both the global and regional scale, but local effects are difficult to determine from coarse-resolution climate studies. Dynamical downscaling can provide insight into future climate projections on local scales. Here, we present a new dynamically downscaled dataset for Indiana and the surrounding regions. Output from the Community Earth System Model (CESM) version 1 is downscaled using the Weather Research and Forecasting model (WRF). Simulations are run with a 24-hr reinitialization strategy and a 12-hr spin-up window. WRF output is bias corrected to the National Centers for Environmental Protection/National Center for Atmospheric Research 40-year Reanalysis project (NCEP) using a modified quantile mapping method. Bias-corrected 2-m air temperature and accumulated precipitation are the initial focus, with additional variables planned for future releases. Regional climate change signals agree well with larger global studies, and local fine-scaled features are visible in the resulting dataset, such as urban heat islands, frontal passages, and orographic temperature gradients. This high-resolution climate dataset could be used for down-stream applications focused on impacts across the domain, such as urban planning, energy usage, water resources, agriculture and public health.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Object-space optimization of tomographic reconstructions for additive manufacturing

Volumetric 3D printing motivated by computed axial lithography enables rapid printing of homogeneous parts but requires a high dimensionality gradient-descent optimization to calculate image sets. Here we introduce a new, simpler approach to image-computation that algebraically optimizes a model of the printed object, significantly improving print accuracy of complex parts under imperfect material and optical precision by improving optical dose contrast between the target and surrounding regions. Quality metrics for volumetric printing are defined and shown to be significantly improved by the new algorithm. The approach is extended beyond binary printing to grayscale control of conversion to enable functionally graded materials. The flexibility of the technique is digitally demonstrated with realistic projector point spread functions, printing around occluding structures, printing with restricted angular range, and incorporation of materials chemistry such as inhibition. Finally, simulations show that the method facilitates new printing modalities such as printing into flat, rather than cylindrical packages to extend the applications of volumetric printing.

36 MATERIALS SCIENCE↗