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NASA NTRS1999

Geochemical Evidence for a Terrestrial Magma Ocean

The aftermath of phase separation and crystal-liquid fractionation in a magma ocean should leave a planet geochemically differentiated. Subsequent convective and other mixing processes may operate over time to obscure geochemical evidence of magma ocean differentiation. On the other hand, core formation is probably the most permanent, irreversible part of planetary differentiation. Hence the geochemical traces of core separation should be the most distinct remnants left behind in the mantle and crust, In the case of the Earth, core formation apparently coincided with a magma ocean that extended to a depth of approximately 1000 km. Evidence for this is found in high pressure element partitioning behavior of Ni and Co between liquid silicate and liquid iron alloy, and with the Ni-Co ratio and the abundance of Ni and Co in the Earth's upper mantle. A terrestrial magma ocean with a depth of 1000 km will solidify from the bottom up and first crystallize in the perovskite stability field. The largest effect of perovskite fractionation on major element distribution is to decrease the Si-Mg ratio in the silicate liquid and increase the Si-Mg ratio in the crystalline cumulate. Therefore, if a magma ocean with perovskite fractionation existed, then one could expect to observe an upper mantle with a lower than chondritic Si-Mg ratio. This is indeed observed in modern upper mantle peridotites. Although more experimental work is needed to fully understand the high-pressure behavior of trace element partitioning, it is likely that Hf is more compatible than Lu in perovskite-silicate liquid pairs. Thus, perovskite fractionation produces a molten mantle with a higher than chondritic Lu-Hf ratio. Arndt and Blichert-Toft measured Hf isotope compositions of Barberton komatiites that seem to require a source region with a long-lived, high Lu-Hf ratio. It is plausible that that these Barberton komatiites were generated within the majorite stability field by remelting a perovskite-depleted part of the upper mantle transition zone.

Agee, Carl B.↗
NASA NTRS1998

A Multiplicity Survey of Chromospherically Active and Inactive Stars

Surveys of the three samples of solar-type stars, segregated by chromospheric emission level, were made to determine their multiplicity fractions and to investigate the evolution of multiplicity with age. In total, 245 stars were searched for companions with DeltaV <= 3.0 and separations of 0.035" to 1.08" using optical speckle interferometry, By incorporating the visual micrometer survey for duplicity of the LamontHussey Observatory, the angular coverage was extended to 5.0" with no change in in the DeltaV limit. This magnitude difference allows mass ratios of 0.63 and larger to be detected throughout a search region of 2-127 AU for the stars observed. The 84 primaries observed in the chromospherically active sample are presumably part of a young population and are found to have a multiplicity fraction of 17.9% +/- 4.6%. The sample of 118 inactive, presumably older, primaries were selected and observed using identical methods and are found to have a multiplicity fraction of only 8.5% +/- 2.7%. Given the known link between chromospheric activity and age, these results tentatively imply a decreasing stellar multiplicity fraction from 1 to 4 Gyr, the approximate ages of the two samples. Finally, only two of the 14 very active primaries observed were found to have a companion meeting the survey detection parameters. In this case, many of the systems are either very young, or close, RS CVn type multiples that are unresolvable using techniques employed here.

Mason, Brian D.↗
NASA NTRS2000

Application of Statistical Methods of Rain Rate Estimation to Data From The TRMM Precipitation Radar

The TRMM Precipitation Radar is well suited to statistical methods in that the measurements over any given region are sparsely sampled in time. Moreover, the instantaneous rain rate estimates are often of limited accuracy at high rain rates because of attenuation effects and at light rain rates because of receiver sensitivity. For the estimation of the time-averaged rain characteristics over an area both errors are relevant. By enlarging the space-time region over which the data are collected, the sampling error can be reduced. However. the bias and distortion of the estimated rain distribution generally will remain if estimates at the high and low rain rates are not corrected. In this paper we use the TRMM PR data to investigate the behavior of 2 statistical methods the purpose of which is to estimate the rain rate over large space-time domains. Examination of large-scale rain characteristics provides a useful starting point. The high correlation between the mean and standard deviation of rain rate implies that the conditional distribution of this quantity can be approximated by a one-parameter distribution. This property is used to explore the behavior of the area-time-integral (ATI) methods where fractional area above a threshold is related to the mean rain rate. In the usual application of the ATI method a correlation is established between these quantities. However, if a particular form of the rain rate distribution is assumed and if the ratio of the mean to standard deviation is known, then not only the mean but the full distribution can be extracted from a measurement of fractional area above a threshold. The second method is an extension of this idea where the distribution is estimated from data over a range of rain rates chosen in an intermediate range where the effects of attenuation and poor sensitivity can be neglected. The advantage of estimating the distribution itself rather than the mean value is that it yields the fraction of rain contributed by the light and heavy rain rates. This is useful in estimating the fraction of rainfall contributed by the rain rates that go undetected by the radar. The results at high rain rates provide a cross-check on the usual attenuation correction methods that are applied at the highest resolution of the instrument.

Meneghini, R.↗
NASA NTRS2000

A Texture-Polarization Method for Estimating Convective/Stratiform Precipitation Area Coverage from Passive Microwave Radiometer Data

Observational and modeling studies have described the relationships between convective/stratiform rain proportion and the vertical distributions of vertical motion, latent heating, and moistening in mesoscale convective systems. Therefore, remote sensing techniques which can quantify the relative areal proportion of convective and stratiform, rainfall can provide useful information regarding the dynamic and thermodynamic processes in these systems. In the present study, two methods for deducing the convective/stratiform areal extent of precipitation from satellite passive microwave radiometer measurements are combined to yield an improved method. If sufficient microwave scattering by ice-phase precipitating hydrometeors is detected, the method relies mainly on the degree of polarization in oblique-view, 85.5 GHz radiances to estimate the area fraction of convective rain within the radiometer footprint. In situations where ice scattering is minimal, the method draws mostly on texture information in radiometer imagery at lower microwave frequencies to estimate the convective area fraction. Based upon observations of ten convective systems over ocean and nine systems over land, instantaneous 0.5 degree resolution estimates of convective area fraction from the Tropical Rainfall Measuring Mission Microwave Imager (TRMM TMI) are compared to nearly coincident estimates from the TRMM Precipitation Radar (TRMM PR). The TMI convective area fraction estimates are slightly low-biased with respect to the PR, with TMI-PR correlations of 0.78 and 0.84 over ocean and land backgrounds, respectively. TMI monthly-average convective area percentages in the tropics and subtropics from February 1998 exhibit the greatest values along the ITCZ and in continental regions of the summer (southern) hemisphere. Although convective area percentages. from the TMI are systematically lower than those from the PR, monthly rain patterns derived from the TMI and PR rain algorithms are very similar. TMI rain depths are significantly higher than corresponding rain depths from the PR in the ITCZ, but are similar in magnitude elsewhere.

Olson, William S.↗
NASA NTRS1999

Dynamics of Single Chains of Suspended Ferrofluid Particles

We present an experimental study of the dynamics of isolated chains made of super-paramagnetic particles under the influence of a magnetic field. The motivation of this work is to understand if the chain fluctuations exist and, if it does, how does the fluctuation affect chain aggregation. We find that single chains strongly fluctuate and that the characteristic frequency of their fluctuations is inversely proportional to the magnetic field strength. The higher the field the lower the characteristic frequency of the chain fluctuations. In the high magnetic field limit, chains behave like rigid rods without any internal motions. In this work, we used ferrofluid particles suspended in water. These particles do not have any intrinsic magnetization. Once a magnetic field is applied, a dipole moment is induced in each particle, proportional to the magnetic field. A dipolar magnetic interaction then occurs between particles. If dipole-dipole magnetic energy is higher than the thermal energy, the result is a structure change inside the dipolar fluid. The ratio of these two energies is expressed by a coupling constant lambda as: lambda = (pi(a(exp 3))(chi(exp 2))(mu(sub 0))(H(sub 0))(exp 2))/18kT Where a is the particle radius, mu(sub 0) is the vacuum magnetic permeability, H(sub 0) the applied magnetic field, k the Boltzmann constant and T the absolute temperature. If lambda > 1, magnetic particles form chains along the field direction. The lateral coalescence of several chains may form bigger aggregates especially if the particle volume fraction is high. While many studies and applications deal with the rheological properties and the structural changes of these dipolar fluids, this work focuses on the understanding of the chain dynamics. In order to probe the chain dynamics, we used dynamic light scattering (DLS) in self-beating mode as our experimental technique. The experimental geometry is such that the scattering plane is perpendicular to the magnetic field. Therefore, only motions in this plane are probed. A very dilute sample of a ferrofluid emulsion with a particle volume fraction of 10(exp -5) is used in this experiment. We chose such a low volume fraction to avoid multiple light scattering as well as lateral chain-chain aggregation. DLS measures the dynamic structure factor S(q,t) of the sample (q is the scattering wave vector, t is the time). In the absence of the magnetic field, identical particles of ferrofluid droplets are randomly distributed and S(q,t) reduces to exp(-q(exp 2)2D(sub 0)t). D(sub 0)=(kT/(6(pi)(eta)(a)) is the diffusion coefficient of Brownian particles (where Xi = (6(pi)(eta)(a)) is the Stokes frictional coefficient of a spherical particle in a fluid of viscosity eta). If interactions or polydispersity can not be ignored, an effective diffusion coefficient is introduced. Formally, D(sub eff) is defined as: D(sub eff) = - q(exp -2) partial derivative of (ln(S(q,t)) with respect to time, as t goes to 0. D(sub eff) reduces to D(sub 0) if no interactions and only a few particles size are present. Therefore, we can use DLS to measure particle size. The particle radius was found to be a=0.23 mu m with 7% of polydispersity. In this case, if we vary the scattering angle theta (and so q) we do not have any change in the measured diffusion coefficient: it is q-independent. When a magnetic field is applied, particles aggregate into chains if lambda > 1. We first studied the kinetics of the chain formation when lambda = 406. At a fixed scattering angle, we measured diffusion coefficient D(sub eff) as a function of time. Experimentally, we find that D(sub eff) decreases monotonously with time. Physically, this means that chains are becoming longer and longer. Since we are only sensitive to motions in the scattering plane and since chains have their main axis perpendicular to this plane, the measured diffusion coefficient is the trans-verse diffusion coefficient. We can relate D(sub eff) to the mean number of particles per chain N(t) at a given time and to the diffusion coefficient of an isolated particle D(sub 0) as D(sub eff)=f(N(t))D(sub 0). Since f(N) is known from other recent work, N can be expressed as a function of the time. We found a square root dependency: N(t) proportional to the square root of t. As expected for very low volume fraction, this behavior is characteristic of a diffusion-limited aggregation as suggested by several authors and by our previous work. In this study, we focus on the dependence of the effective diffusion coefficient on the scattering angle and the magnetic field strength. After the magnetic field is applied (lambda = 406) for a long time, typically 6 hours, kinetics of chain formation becomes very slow. Chain size does not vary much over the next hour period. Thus, we can perform different interesting experiments. First, at a fixed magnetic field, we measure the effective diffusion coefficient as a function of the scattering angle (from 5 to 130 deg). Our results show that the measured diffusion coefficient increases linearly with the scattering angle: D(sub eff) proportional to q. If we do the same experiment for different lambda values, D(sub eff) depends on lambda as D(sub eff) proportional to lambda(exp -1/2). We also find for different lambda values that the same asymptotic D(sub eff) value is obtained when q approaches zero. The angle dependency of D(sub eff) suggests that an additional motion exists besides chain drifting. Chain size is constant during experiment, which was verified by measuring the same diffusion coefficient at the beginning and at the end of the angle switching. If chains are rigid, D(sub eff) is independent of q. Therefore, we found that D(sub eff) not only measures the motion of the entire chain but also its internal fluctuations. These internal motions are the fluctuations of the particles in the chain. To understand the q dependency of D(sub eff), let us look at the probing length used. In our study, the characteristic length scale probed is l=2pi/q which is in the range of 0.9<l/a<20. When l is much larger than the particle radius (l/a going to infinity) we are mainly sensitive to the center of mass diffusion of the chain. D(sub eff) is then the diffusion of the entire chain and depends only on N but not on q and lambda. The value D(sub eff) allows us to obtain the number of particles per chain N. In the opposite limit (i.e. l/a < 1), we are sensitive to motions on the size of individual particles. The main contributions to the measured diffusion coefficient come from internal motions of the chains (i.e. particles' fluctuations inside the chain). We investigated also the effect of the chain size on D(sub eff). For the same value of the magnetic interaction lambda and different chain sizes, we found that the slope of D(sub eff) versus q decreases when N increases as a power law D(sub eff) proportional to N(exp -0.7). This is an important behavior because this means that the longer the chain the slower its internal fluctuations besides the whole chain motion.

Cutillas, S.↗
NASA NTRS2001

Evolution of Local Microstructures: Spatial Instabilities of Coarsening Clusters

This work examines the diffusional growth of discrete phase particles dispersed within a matrix. Engineering materials are often microstructurally heterogeneous, and the details of the microstructure determine how well that material performs in a given application. Critical to the development of designing multiphase microstructures with long-term stability is the process of Ostwald ripening. Ripening, or phase coarsening, is diffusion-limited and arises in polydisperse multiphase materials. Growth and dissolution occur because fluxes of solute, driven by chemical potential gradients at the interfaces of the dispersed phase material, depend on particle size. Competitive kinetics of these processes dictates that larger particles grow at the expense of smaller ones, overall leading to an increase of the average particle size. The classical treatment of phase coarsening was done by Todes, Lifshitz, and Slyozov, (TLS) in the limit of zero volume fraction, V(sub V)=0 of the dispersed phase. Since the publication of TLS theory, there have been numerous investigations, many of which sought to describe the kinetic scaling behavior over a range of volume fractions. Some studies in the literature report that the relative increase in coarsening rate at low (but not zero) volume fractions compared to that predicted by TLS is proportional to V(exp 1/2)(sub v) whereas others suggest V(exp 1/3)(sub v).This issue has been addressed recently by simulation studies at low volume fractions in three dimensions by members of the Rensselaer/MSFC team.

Glicksman, Martin E.↗
NASA NTRS1999

Iron Meteorites from Antarctica: More Specimens, Still 40% Ungrouped

Clarke was the first to recognize that ungrouped irons are more common in Antarctica than in the regions where most irons have been collected; his conclusion was based on the first 21 irons collected in Antarctica. Wasson et al. reported compositional data for 24 Antarctic irons and reported that eight were ungrouped; the ungrouped fraction of 0.33 was found to be about twice that (0.153) observed in irons from the remainder of the world. Wasson reported data for seven additional Antarctic irons, and reported that 12 of 31 were ungrouped, a fraction of 0.39. I summarize the data obtained to date on independent Antarctic iron meteorites by our UCLA neutron-activation laboratory. With about five exceptions, the listed values are the means of duplicate determinations. We have now analyzed 40 independent iron meteorites; I list eight other irons that proved to be paired with meteorites listed. Because of the close relationship between pallasites and iron meteorites, I also list our data for two Antarctic pallasites that were studied at UCLA. Our new results confirm the previously reached conclusion about the abundance of ungrouped irons. In fact, the ungrouped fraction has increased slightly; of the 40 irons 16 are ungrouped, a fraction of 0.40. The two meteorites with pallasite structures are both small (= 50 g); one is ungrouped, the other a high-Ir anomalous member of the main-group pallasites (PMG).

Wasson, J. T.↗
NASA NTRS2001

Sooting Limits Of Microgravity Spherical Diffusion Flames

Limiting conditions for soot-particle inception were studied in microgravity spherical diffusion flames burning ethylene at atmospheric pressure. Nitrogen was supplied in the fuel and/or oxidizer to obtain the broadest range of stoichiometric mixture fraction. Both normal flames (oxygen in ambience) and inverted flames (fuel in ambience) were considered. Microgravity was obtained in the NASA Glenn 2.2-second drop tower. The flames were observed with a color video camera and sooting conditions were defined as conditions for which yellow emission was present throughout the duration of the drop. Sooting limit results were successfully correlated in terms of adiabatic flame temperature and stoichiometric mixture fraction. Soot free conditions were favored by increased stoichiometric mixture fractions. No statistically significant effect of convection direction on sooting limits was observed. The relationship between adiabatic flame temperature and stoichiometric mixture fraction at the sooting limits was found to be in qualitative agreement with a simple theory based on the assumption that soot inception can occur only where temperature and local C/O ratio exceed threshold values (circa 1250 K and 1, respectively).

Sunderland, P. B.↗
NASA NTRS2001

Estimating Net Primary Productivity Using Satellite and Ancillary Data

The net primary productivity (C) or annual rate of carbon accumulation per unit ground area by terrestrial plant communities is the difference of the rate of gross photosynthesis (A(sub g)) and autotrophic respiration (R) per unit ground area. Although available observations show that R is a large and variable fraction of A(sub g), viz., 0.3 to 0.7, it is generally recognized that much uncertainties exist in this fraction due to difficulties associated with the needed measurements. Additional uncertainties arise when these measurements are extrapolated to regional or global land surface using empirical equations, for example, using regression equations relating C to mean annual precipitation and air temperature. Here, a process-based approach has been taken to calculate A(sub g) and R using satellite and ancillary data. A(sub g) has been expressed as a product of radiation use efficiency, magnitude of intercepted photosynthetically active radiation (PAR), and normalized by stresses due to soil water shortage and air temperature away from the optimum range. A biophysical model has been used to determine the radiation use efficiency from the maximum rate of carbon assimilation by a leaf, foliage temperature, and the fraction of diffuse PAR incident on a canopy. All meteorological data (PAR, air temperature, precipitation, etc.) needed for the calculation are derived from satellite observations, while a land use, land cover data (based on satellite and ground measurements) have been used to assess the maximum rate of carbon assimilation by a leaf of varied cover type based on field measurements. R has been calculated as the sum of maintenance and growth components. The maintenance respiration of foliage and live fine roots at a standard temperature of different land cover has been determined from their nitrogen content using field and satellite measurements, while that of living fraction of woody stem (viz., sapwood) from the seasonal maximum leaf area index as determined from satellite observations. These maintenance respiration values were then adjusted to that corresponding to air temperature according to a prescribed non-linear variation of respiration with temperature. The growth respiration has been calculated from the difference of Ag and maintenance respiration, according to the two-compartment model. The results of calculations will be reported for 36 consecutive months (1987-1989) over large contiguous areas (ca. 10(exp 5) sq km) Of agricultural land and tropical humid evergreen forests, and compared with available field data.

Choudhury, B. J.↗
NASA NTRS2002

Use of TRMM Data to Test an Improved Parameterization of Stratiform Precipitation

We successfully implemented our EAUcup parameterization of convection in our most recent geodesic-grid version of the Colorado State University General Circulation Model (CSU GCM). Tendencies due to convection and large-scale cloud microphysics are computed using the same time-step, allowing smoother interactions between convective and large-scale moist processes. Figures illustrate our most recent progress on the simulation of convective and stratiform precipitations for January. Comparisons against TRMM precipitation radar (PR) data would reveal a systematic overestimation of the simulated monthly-mean convective rainfall over well-known areas of deep convection. One major deficiency in the global distribution of stratiform precipitation simulated in the CSU GCM is the lack of stratiform precipitation over land in the tropics. This result strongly disagree with Fowler and Randall who show that convective and stratiform precipitations always coexist and that their ratio to the total precipitation is about 0.5. We believe that stratiform precipitation over land evaporates before reaching the ground because the lower troposphere remains too dry in response to the lack of convective detrainment occurring immediately above the Planetary Boundary Layer (PBL). This issue is further investigated at present. We made significant progress in the development of our parameterization of fractional cloudiness. As an example of our ongoing research effort, a figure shows the global distribution of the cloud ice mixing ratio and corresponding fractional area of ice clouds at 250 hPa. These results were obtained using our latitude-longitude grid version of the CSU GCM. There is a nice correspondence between areas of high (low) values of the cloud ice mixing ratio and the cloud fraction. A nice correspondence between the global distribution of the cloud water mixing ratio and fraction of water clouds in the lower troposphere can also be found. We are pursuing this effort, but in the geodesic version of the GCM. We hope to be able to make comparison of the simulated precipitation against TRMM precipitation data in the near future.

Randall, David A.↗
NASA NTRS1999

Blood Collection

The method that is used for the collection, storage and real-time analysis of blood and other bodily fluids has been licensed to DBCD, Inc. by NASA. The result of this patent licensing agreement has been the development of a commercial product that can provide serum or plasma from whole blood volumes of 20 microliters to 4 milliliters. The device has a fibrous filter with a pore size of less than about 3 microns, and is coated with a mixture of mannitol and plasma fraction protein. The coating causes the cellular fraction to be trapped by the small pores, leaving the cellular fraction intact on the fibrous filter while the acellular fraction passes through the filter for collection in unaltered form from the serum sample collection chamber. The method used by this product is useful to NASA for blood analysis on manned space missions.

Source record↗
NASA NTRS1998

What Determines the Response: Test or Reference?

The stability of sensory memory has been studied by presenting a reference stimulus, a delay, and a test stimulus. As has been pointed out by Lages and Treisman (1998 Vision Research 38 557-572), the usual measure of performance depends only on the effect of test variations on the responses. The Weber fraction characterizing performance is more properly called the test stimulus Weber fraction. We measure the relative contribution of the test and reference to the response by the ratio of the test Weber fraction to the reference Weber fraction. The stimuli were two dark lines on a bright background. Seven reference separations, varying from 9.5 to 16.7 arc min, were intermixed in each run. Interstimulus intervals (ISI) of 50, 200 and 2000 msec and intertrial intervals (ITI) of 500 and 2500 msec were investigated. When the ISI was short (50 or 200 msec), for both ITIs, responses were determined equally by the test and reference. For the long ISI (2000 msec), the reference stimulus contributed less. However, only for the 500 msec ITI (and not for all observers) was the contribution of the reference stimulus negligible, as Treisman's criterion setting theory might suggest.

Chukova, S. V.↗
NASA NTRS2002

Microstructural Studies of Space Weathering Effects in Lunar Materials

Space weathering is a term used to include all of the processes which act on material exposed at the surface of a planetary or small body. In the case of the moon, it includes a variety of processes which have formed the lunar regolith, caused the maturation of lunar soils, and formed patina on rock surfaces. The processes include micrometeorite impact and reworking, implantation of solar wind and flare particles, radiation damage and chemical effects from solar particles and cosmic rays, interactions with the lunar atmosphere, and sputtering erosion and deposition. Space weathering effects collectively result in a reddened continuum slope, lowered albedo, and attenuated absorption features in reflectance spectra of lunar soils as compared to finely comminuted rocks from the same Apollo sites. However, the regolith processes that cause these effects are not well known, nor is the petrographic setting of the products of these processes fully understood. An interesting confluence of events occurred in the early 1990s. First, came the discovery of vapor deposited coatings on lunar regolith grains by Keller and McKay, who showed that amorphous coatings from 50-100 nm thick containing fine-grained Fe metal (1-10 nm in diameter) were common in the fine size fraction of several mature lunar soils. The other discovery was the recognition that the optical properties of lunar soils were dominated by fine grain sized material (less than 45 micrometer fraction) by Pieters and coworkers. These discoveries led to coordinated studies that looked at the mineralogy, chemistry, and optical properties of lunar soils as function of composition, maturity, and grain size fraction. One of the major revelations from these studies was the recognition that much of the nanophase Fe metal is surface-correlated especially in the finest size fractions, and that it was this nanophase Fe that dominated the optical properties of the soil.

Keller, L. P.↗
NASA NTRS2002

3D Finite Element Analysis of Particle-Reinforced Aluminum

Deformation in particle-reinforced aluminum has been simulated using three distinct types of finite element model: a three-dimensional repeating unit cell, a three-dimensional multi-particle model, and two-dimensional multi-particle models. The repeating unit cell model represents a fictitious periodic cubic array of particles. The 3D multi-particle (3D-MP) model represents randomly placed and oriented particles. The 2D generalized plane strain multi-particle models were obtained from planar sections through the 3D-MP model. These models were used to study the tensile macroscopic stress-strain response and the associated stress and strain distributions in an elastoplastic matrix. The results indicate that the 2D model having a particle area fraction equal to the particle representative volume fraction of the 3D models predicted the same macroscopic stress-strain response as the 3D models. However, there are fluctuations in the particle area fraction in a representative volume element. As expected, predictions from 2D models having different particle area fractions do not agree with predictions from 3D models. More importantly, it was found that the microscopic stress and strain distributions from the 2D models do not agree with those from the 3D-MP model. Specifically, the plastic strain distribution predicted by the 2D model is banded along lines inclined at 45 deg from the loading axis while the 3D model prediction is not. Additionally, the triaxial stress and maximum principal stress distributions predicted by 2D and 3D models do not agree. Thus, it appears necessary to use a multi-particle 3D model to accurately predict material responses that depend on local effects, such as strain-to-failure, fracture toughness, and fatigue life.

Shen, H.↗
NASA NTRS2003

Gravitational Effects on Distortion in Sintering

During sintering a powder compact gains strength through low-temperature interparticle bonding, usually induced by solid-state surface diffusion, followed by further strength contributions from high-temperature densification. In cases where a liquid phase forms, sintering densification is accelerated and shape retention is sustained while open pores remain and contribute capillary forces. Unfortunately, sintering densification requires the compact become thermally softened to a point where creep strain rates reach levels near 10(exp -2)/s when the liquid forms. On the other hand, thermal softening of the powder compact substantially reduces the strength at high temperatures. Therefore, the in situ strength evolution during sintering is a primary focus to separate compact densification (as required for high performance) with minimized distortion (as required for net-shaping). With respect to gravitation effects on distortion during sintering there are two points of substantial weakness - prior to significant interparticle bonding and during final pore closure. This research is focused on understanding the competition among interparticle neck growth, densification, thermal softening, grain boundary wetting, capillary effects associated with liquid wetting and residual porosity, and gravity. Most surprising is the apparent role of gravity, where the deviatoric stress acting on the powder structure induces skeletal formation that reduces distortion. In contrast with theory, microgravity samples exhibit more distortion yet fail to fully densify. Results are presented on the experimental concepts supporting an emerging model of sintering strength evolution that enables understanding of both distortion and densification. The experiments have relied on tungsten heavy alloys, various combinations of dihedral angle, pore size, initial porosity, liquid:solid ratio, and heating rates. On Earth, the dominant factor with respect to distortion is the starting body heterogeneity. Current modeling efforts are seeking some means to uniformly predict the distortion based on a starting pore structure heterogeneity parameter. Densification is largely unaffected by the initial pore structure, but distortion is highly variable, suggesting that nonuniform pore closure might be a significant parameter during sintering. With respect to flight experiments, plans include removal of the solid body forces acting on the solid grains, allowing stabilization of the pore structure and examination of the buoyancy effects with regard to distortion. In microgravity there is the surprising result that compacts do not densify, yet distort a factor that is contrary to all current sintering models. Densification without distortion during liquid phase sintering was achieved by manipulating microstructure and its evolution during sintering. Microstructure parameters such as the solid volume fraction, dihedral angle, initial porosity, and pore size were varied to measure densification and distortion behavior during LPS using W-Ni-Cu alloys. Green compacts were formed using ethylene-bis-stearamide as a pore-forming agent with the amount of polymer controlling the initial porosity. Different initial pore sizes were generated by varying the polymer particle size. Dihedral angle was varied by changing the Ni:Cu ratio in the alloys. Finally, the solid volume fraction was adjusted via the tungsten content. Distortion was quantified using profiles determined with a coordinate measuring machine to calculate a distortion parameter. Sintering results showed that solid volume fraction and dihedral angle are the dominant factors on densification and distortion during liquid phase sintering. Distortion decreases with increasing solid volume fraction and dihedral angle, while initial porosity and pore size have no observable effect on distortion at nearly full densification. Various strategies emerge to improve distortion control in liquid phase sintering.

German, Randall M.↗
NASA NTRS2003

Boundary Layer Aerosol Composition over Sierra Nevada Mountains using 9.11- and 10.59-micron CW Lidars and Modeled Backscatter from Size Distribution Data

An inversion technique has been developed to determine volume fractions of an atmospheric aerosol composed primarily of ammonium sulfate and ammonium nitrate and water combined with fixed concentration of elemental and organic carbon. It is based on measured aerosol backscatter obtained with 9.11 - and 10.59-micron wavelength continuous wave CO2 lidars and modeled backscatter from aerosol size distribution data. The technique is demonstrated during a flight of the NASA DC-8 aircraft over the Sierra Nevada Mountain Range, California on 19 September, 1995. Volume fraction of each component and effective complex refractive index of the composite particle were determined assuming an internally mixed composite aerosol model. The volume fractions were also used to re-compute aerosol backscatter, providing good agreement with the lidar-measured data. The robustness of the technique for determining volume fractions was extended with a comparison of calculated 2.1,-micron backscatter from size distribution data with the measured lidar data converted to 2.1,-micron backscatter using an earlier derived algorithm, verifying the algorithm as well as the backscatter calculations.

Cutten, D. R.↗
NASA NTRS2003

Ice-Accretion Scaling Using Water-Film Thickness Parameters

Studies were performed at INTA in Spain to determine water-film thickness on a stagnation-point probe inserted in a simulated cloud. The measurements were correlated with non-dimensional parameters describing the flow and the cloud conditions. Icing scaling tests in the NASA Glenn Icing Research Tunnel were then conducted using the Ruff scaling method with the scale velocity found by matching scale and reference values of either the INTA non-dimensional water-film thickness or a Weber number based on that film thickness. For comparison, tests were also performed using the constant drop-size Weber number and the average-velocity methods. The reference and scale models were both aluminum, 61-cm-span, NACA 0012 airfoil sections at 0 deg. AOA. The reference had a 53-cm-chord and the scale, 27 cm (1/2 size). Both models were mounted vertically in the center of the IRT test section. Tests covered a freezing fraction range of 0.28 to 1.0. Rime ice (n = 1.0) tests showed the consistency of the IRT calibration over a range of velocities. At a freezing fraction of 0.76, there was no significant difference in the scale ice shapes produced by the different methods. For freezing fractions of 0.40, 0.52 and 0.61, somewhat better agreement with the reference horn angles was typically achieved with the average-velocity and constant-film thickness methods than when either of the two Weber numbers was matched to the reference value. At a freezing fraction of 0.28, the four methods were judged equal in providing simulations of the reference shape.

Anderson, David N.↗
NASA NTRS1961

Estimates of Minimum Energy Requirements for Range-Controlled Return of a Nonlifting Satellite from a Circular Orbit

Existing expressions are used to obtain the minimum propellant fraction required for return from a circular orbit as a function of vacuum trajectory range. trajectory are matched to those of the atmospheric trajectory to obtain a complete return from orbit to earth. The results are restricted by the assumptions of (1) impulsive velocity change, (2) nearly circular transfer trajectory, ( 3) spherical earth, atmosphere, and gravitational field, (4) exponential atmospheric density variation with attitude, and (5) a nonrotating atmosphere. The solutions for the parameters of the vacuum Calculations are made t o determine the effects of longitudinal and lateral range on required propeUant fraction and reentry loading for a nonrotating earth and for several orbital altitudes. the single- and two-impulse method of return is made and the results indicate a "trade off" between propellant fraction required and landing- position accuracy. A comparison of An example of a return mission from a polar orbit is discussed where the initial deorbit point is the intersection of the North Pole horizon with the satellite orbit. Some effects of a rotating earth are also considered. It is found that, for each target-orbital-plane longitudinal difference, there exists a target latitude for which the required propellant fraction is a minimum.

Jackson, Charlie M., Jr.↗