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At least 955 records · Page 53

Nuclear Safeguards: Feature Extraction for Machine Learning Enrichment Analysis of UF 6 Cylinders

With the increasing international interest in using nuclear material as sources of energy, comes the growing concern that we may see an increase in proliferation threats. Uranium hexafluoride (UF 6 ) is used in the nuclear fuel cycle for uranium enrichment. Inspectors from the International Atomic Energy Agency (IAEA) monitor the enrichment levels of UF 6 stored in transportation cylinders, to ensure the enrichments match that of a facility operator’s declarations. However, only a characteristic subset of UF 6 cylinders can be measured by inspectors from the IAEA during these inspections. In turn, the inspector may not identify a cylinder whose enrichment levels do not match the facility declarations. Therefore, our team attempts to develop a machine learning network that could determine the enrichment percentage of cylinders as they enter and exit facilities. The machine learning model must be robust against spectral variations due to factors that are internal and external to the UF 6 cylinder. Such factors include but are not limited to the speed and distance of the moving vehicle, cylinder type, cylinder orientation, and fill level. Many features in the spectral continuum can be used to identify and correct for some of these variations. As a consequence, the model must extract numerous features in the continuum. We investigate new approaches in continuum subtraction to verify enrichment percentage: interpolation and extrapolation of lines at the notable characteristic spectral peaks. It was determined that there was no clear answer on which method proved superior, therefore the decision was made to implement both new methods into the current codebase. We currently rely on synthetic training and testing data to analyze the results and fine tune our models but hope to test the system on measured data soon.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Improved Light Extraction by Engineering Molecular Properties of Square Planar Phosphorescent Emissive Materials

The ultimate objective of this project was to develop a cost-effective technology which could significantly improve the light outcoupling efficiency up to 70% and higher and the key tasks were listed as follows: (i) improving light extraction efficiency through a better control of horizontally aligned emitting dipoles of square planar phosphorescent emitters; (ii) fabricating high-efficiency monochromic and amber OLED in the device settings; (iii) fabricating high-efficiency white OLED in the device settings. With both materials innovation and device structure optimization, we realized OLEDs with an EQE of 66% with a LT 95 lifetime of over 100 khrs at a brightness of 1,000 cd/m 2 . This proposed research is a high impact project which could potentially revolutionize OLED lighting technology and expedite the commercialization process of OLED technology for solid state lighting. This project outcomes contributed to meet the targeted performance of organic solid state lighting set in the DOE MYPP.

36 MATERIALS SCIENCE↗

Scoping Study for Direct Power Extraction (DPE) Systems (Final Report)

NETL led a detailed scoping study of various direct power extraction systems and concepts for utility power generation. The study consisted of qualitative analysis along with quantitative techno-economic analysis of selected systems which use magnetohydrodynamic (MHD) power generators.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Performance of Microreactor Test Article with Embedded Sensors During Testing in The Single Primary Heat Extraction and Removal Emulator

The nuclear industry is pursuing microreactors that can be factory assembled and deployed to remote regions for reliable power generation. One class of microreactors uses a monolithic metal core block coupled to heat pipes that use passive heat flow, increasing the surface area for heat transfer without requiring active coolant flow through the reactor core. Additional experimental testing is required to understand the heat rejection limitations of heat pipes and thermal stresses in the monolithic core block due to significant temperature gradients. This report describes the initial characterization and testing of a stainless-steel test article that was fabricated with embedded sensors to measure heat pipe performance limits, as well as spatially distributed temperatures and strains during electrically heated thermal testing to simulate nuclear heating. The electrically heated testing was performed in the Single Primary Heat Extraction and Removal Emulator facility located at Idaho National Laboratory. The ultimate goals of this work are to (1) accurately monitor temperature and strain distributions that result from differential thermal expansion in the test articles and (2) quantify the heat rejection limits of heat pipes as a function of operating temperature and working fluid during steady-state and transient operations. Initial tests focused on the feasibility of using advanced fiber-optic sensors and other sensor technologies to improve the understanding of temperature and strain distributions within the electrically heated experiments. However, these sensing capabilities could benefit the broader microreactor community if the sensors could be used to monitor component and system health during nuclear operations to inform a limited number of microreactor operators, ultimately reducing operation and maintenance costs and moving toward semiautonomous operation.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Strain gauge for testing microreactor hexagonal core blocks in the Single Primary Heat Extraction and Removal Emulator

To support the development and deployment of microreactor technologies, experiments that help verify and validate reactor systems and components are performed at non-nuclear test facilities. The Single Primary Heat Extraction Removal Emulator at Idaho National Laboratory is one of these test facilities and was used to monitor a test article that has a prototypic geometry of a heat-pipe cooled microreactor core block. To collect crucial temperature and strain data during testing, temperature and strain sensing fiber optics were embedded to the surface of the test article using an ultrasonic additive manufacturing technique. To support and provide benchmark strain data for the embedded sensors, a commercial resistive strain gauge was attached. This report will discuss the results from the deployment of the commercial strain gauge which includes the setup/attachment strategies, data acquisition, and analysis of the strain data.

36 MATERIALS SCIENCE↗

A Non-Invasive Approach for Elucidating the Spatial Distribution of In Situ Stress in Deep Subsurface Geologic Formations Considered for CO 2 Storage (Task 2 Report Extracting Stress Data from Seismic Data)

This report describes research accomplishments achieved with funding provided through Department of Energy (DOE) Contract DE-FE0031686. The purpose of this DOE funding is to develop methods that can provide key information about stress fields that act on deep rocks without invading the earth to acquire that information. The research objective was to demonstrate methods that extract the azimuth directions of SHmax and SHmin stress in deep rocks from traditional seismic reflection data like the data that are used to explore for deep oil and gas reservoirs. Battelle performed two seismic investigations and achieved estimates of SHmax and SHmin azimuths in both efforts that agreed with local, non-seismic, ground-truth measurements of SHmax orientation. The first procedure utilized vertical seismic profiling (VSP) data; the second effort utilized three-dimensional (3D) seismic data.

58 GEOSCIENCES↗

Systematic Extraction of Pion Parton Distributions Using Threshold Resummation and Applications to Pion TMDs

Following our recent Monte Carlo determination of the pion?s PDFs from Drell-Yan (DY) and leading neutron electroproduction data from the Jefferson Lab Angular Momentum (JAM) collaboration, we extend the analysis by including effects from threshold resummation. At higher orders in the strong coupling, ?S, soft gluon emissions cause large logarithmic corrections, which become important in the qq¯ channel of the DY partonic cross section near threshold. These corrections can be summed over all orders of ?S. However, different prescriptions exist for how the threshold resummation is implemented, for instance, using varying levels of approximation in the Minimal Prescription with cosine, expansion, and double Mellin methods. We present the Monte Carlo results of the first simultaneous fit of the valence, sea, and gluon distributions in the pion taking into account the ambiguities in the resummation calculations. The wide ranges of valence distributions at large x and the effective behavior of the valence distribution as x approaches 1 is discussed. While the PDFs are extracted through collinear factorization, we additionally present a dedicated study to the low and large lepton pair transverse momentum distributions (TMDs) in the same DY experimental data. By adjusting the nonperturbative TMD components, we analyze the degree of compatibility between data and theory across all regions of transverse momentum dependence. We attempt to match the description of the low transverse momentum region using Collins-Soper-Sterman (CSS) formalism and the large transverse momentum region, which is best described using collinear factorization.

Sato, Nobuo↗

Multi material/functionally graded wire arc additive manufacturing of high strength steel valves clad with nickel alloy 625 used for oil extraction

This Phase 1 technical collaboration project (ORNL/TM-2022/2683) began on August 1st, 2020 and concluded on July 31st, 2022. The collaboration partner Schlumberger is a large business enterprise assisting oil companies to extract oil from land and subsea cost competitively and safely. It is based in Houston, Texas USA. In this work as study of additive deposition of AWS EF100S-G and AWS ERNiCrMo-3 wires via wire-arc process was conducted.

36 MATERIALS SCIENCE↗

The Compatibility of Tefzel™ and Viton™ B with Caustic-Side Solvent Extraction Solvents

The Salt Waste Processing Facility (SWPF) plans to switch from the current Caustic-Side Solvent Extraction (CSSX) solvent to the Next Generation Solvent-Phase II (NGS-Phase II). SRNL was requested to evaluate the compatibility between polymeric materials of construction at SWPF and NGS-Phase II solvent. The work presented here concentrated on two materials of interest: Tefzel™ and Viton™ B.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Multifidelity and Multimodal Machine Learning Approach for Extracting Bonding Environments of Impurities and Dopants from X-ray Spectroscopies

Extended X-ray absorption fine structure (EXAFS) spectroscopy is crucial for determining the coordination environment of impurities and dopants; however, it requires difficult measurements. X-ray absorption near edge structure (XANES) spectroscopy and X-ray emission spectroscopy (XES) can be obtained easily but cannot be converted to determine structures. In this work we develop tools to map measured XANES to the EXAFS signal through machine learning, thereby facilitating the use of EXAFS structural-determination analyses on XANES data. Through the use of Deep Operator Networks (DeepONets), we are able to accurately predict the EXAFS spectrum between 6 and 14 Å -1 from the first 6 Å -1 (~100 eV) of the absorption spectrum of Cu 2+ substitutional defects in the Fe 3+ mineral hematite (a-Fe 2 O 3 ). This surprising finding implies that theoretical analyses of X-ray absorption spectra could be implemented that extract the same conclusions as high-quality EXAFS studies from spectra collected over a much smaller range of photon energies. To encourage similar efforts, the simulated x-ray spectra, machine learning, and fitting code is made publicly available.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

MR&R Strategic Investments Review: OREATE (Oxide Reduction by Electrochemical Amalgamation and Thermal Extraction) [Slides]

The goal of this project is to develop a new process for metal recovery and recycle based on OREATE (Oxide Reduction by Electrochemical Amalgamation and Thermal Extraction). OREATE will be able to efficiently transform PuO 2 into metal (e.g., Pu-242) as well as recover and recycle actinide and rare earth metals after chlorination. The main objectives for FY24 are to complete the TRL assessment of the OREATE process and to achieve a throughput increase, transitioning from mg to gram quantities of metal.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Active Reservoir Management Engineering and Evaluation Summary – Brine Extraction and Storage Test Phase II Final Report – Volumes 1-3

The Energy & Environmental Research Center (EERC) conducted a multiyear program over two phases to perform a field study of the potential efficacy of formation water extraction during carbon dioxide (CO 2 ) injection for CO 2 storage as a means of improving efficiency and/or effectiveness. Phase I was a 2-year study on potential methodologies for a field study of pressure management, culminating in site selection and experimental and site design. Phase II was a 7-year effort that involved constructing site facilities, conducting experiments, and evaluating collected field data. The experimental portion was split into two collaborative components, one for the active reservoir management (ARM) experiment and a second component to host and demonstrate potential water treatment technologies appropriate for high-saline brine at the project site. The results of the overall project are expected to benefit future saline storage projects through validation of techniques that may reduce stress on sealing formations, increase storage capacity, and reduce area of review. The following report focuses on the Phase II ARM experimental implementation and results. A second companion report summarizes the results of the high-saline brine demonstrations.

54 ENVIRONMENTAL SCIENCES↗

Tritium Extraction from FLiBe using a Permeation Against Vacuum (PAV): Impact of Surface Potentials, Currents, and Coupling PAV to Sacrificial Anodes

Savannah River National Laboratory (SRNL) is exploring a concept of pairing a LiF-BeF2 (FLiBe) immersed Permeation Against Vacuum (PAV) tritium extraction system with a sacrificial anode. Several fusion concepts utilize FLiBe for tritium breeding, and breeding of tritium would occur from neutron interactions with the Li component, creating corrosive TF and/or T2. In absence of a redox buffered system, the TF would be able to attack containment materials until neutralized. One way to neutralize TF is to contact it with an active metal such as Be or Li which would preferentially combine with the fluorine in the TF to form BeF2 or LiF, respectively, and resulting in T2. When the active metal (e.g., Be) is oxidized, it will provide electrons, when T in TF is reduced and forms T2, it needs electrons. SRNL proposes to electrically link these two reactions and with the PAV to help drive the reactions faster than on their own and potentially increase T2 dissociation. In a soluble redox salt buffered system, it is expected that with sufficient buffering, T2, may form more rapidly and the core components would be more protected, but the soluble redox salt buffer would need to be occasionally regenerated, which could be accomplished by again contacting the salt with an active metal such as Be or Li, although in this case the cathodic reaction would be electrons coming from the shift in oxidative state of the redox buffer. The exploration of potential and current effects on the PAV and impacts of redox agents will be discussed.

Olson, Luke C.↗

Quantification of the Crack Evolution Process by Extracting Relevant Signal Components from Wave Propagation and Diffusive Transport Front Measurements

Wave propagation and diffusive transport phenomena in a geological rock sample undergoing crack evolution process are expected to interact with the mechanical discontinuities in the medium. The measurements of the signals associated with these phenomena can be used to assess and monitor the crack-driven micromechanical alterations in the rock. Different wave/diffusion phenomena, such as sonic propagation, pressure diffusion, and acoustic emission (AE), are sensitive to different elements of the mechanical discontinuities generated during the evolution of the crack clusters from initiation to coalescence. Sonic propagation, AE, and pressure diffusion monitoring have the potential to map the crack evolution because the transmitter-receiver arrays can be designed, arranged and tuned to (1) achieve maximum recovery of the scattered waveforms and travel times, (2) capture the later arrivals and multiple reflections, and (3) illuminate large rock volume. However, the structural/topological complexities of the mechanical discontinuities, complex distribution of the stress fields, complex mechanical alterations in media, and fluid redistribution in the crack system pose serious challenges for the detection and modeling of the crack evolution process (from here on, we will use the term ‘crack evolution process’ to mean that the crack evolution occurred under shallow crustal conditions). For purposes of accurately accounting such complexities and heterogeneities in the absence of reliable physical laws, simulation methods, and signal processing techniques, my early-career research proposal will develop and apply novel data-driven machine learning methods to: (1) extract signal components relevant to the various phases of crack evolution and (2) generate a 2D visual map of the crack evolution process.

58 GEOSCIENCES↗

Application of Ion Sieve Sorbent Prepared from Mineral Stream Associated with Critical Minerals in Direct Lithium Extraction

In this presentation, the speaker discusses the research that has been carried out at NETL regarding direct lithium extraction. The three main discussing points are as follows: developing high-capacity lithium-ion sieve sorbent using mineral streams associated with critical minerals; demonstrating the sorbent ability to recover lithium from oil/gas produced waters and geothermal brines; and assessing the feasibility of large-scale implementation through technoeconomic analysis.

Cheng, Chin-Min [NETL Site Support Contractor, Nat↗