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DOE OSTI2020

Iodine Speciation Effects in LAW Feeds

Tests were conducted on a DM10 vitrification system with prototypical off-gas treatment system, which includes an SBS, WESP, and evaporator based on the design of the evaporator to be installed at the WTP for concentration of the liquid effluents. This allowed determination of the partitioning and speciation of iodine between the melter and the off gas system components, including liquid effluents from the SBS and WESP as well as in the evaporator condensate and concentrate. Evaporator testing was decoupled from melter testing to permit filtration and pH adjustments of process solutions prior to evaporation. In addition, a slip stream was pulled from the exhaust downstream of the WESP and High-Efficiency Particulate Air (HEPA) filters and passed through a caustic scrubber simulating the WTP caustic scrubber to assess iodine partitioning to the caustic scrubber liquid effluent. The tests were conducted using simulated Hanford LAW from tank AP-107, which is the planned first feed for Direct Feed LAW (DFLAW) operations, at a nominal feed concentration of 5.6 molar Na over about 120 hours of testing.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2026

Xanthos-Lake Model Source Code

This repository contains the source code for Xanthos-Lake, a lake-modeling extension of the Xanthos framework that introduces a coupled lake component comprising the Xanthos-Lake Snow and Ice Model (xLSIM) and the Xanthos-Lake Water Balance Model (xLWBM). xLSIM is a basin-aware machine-learning model for lake snow, ice, and thermal conditions. It predicts monthly lake ice thickness, snow depth, snow-cover fraction, mixing-layer temperature, and lake ice fraction from meteorological forcing and lake surface-area information. It uses sequence-based deep-learning architectures, including Transformer and hybrid Long Short-Term Memory–Transformer (LSTM–Transformer) models, together with seasonal encoding, multi-lake learning, physical masking, and basin-level cryospheric and non-cryospheric classification. The training workflow uses Ray for scalable execution and includes optional Ray Tune hyperparameter optimization. Model predictions, observations, diagnostics, and feature-importance outputs are written in NetCDF. xLWBM is the water-balance component of the new lake framework. It simulates monthly lake storage, surface area, evaporation, inflow, outflow, and lake–groundwater exchange. It combines physical water-balance equations with calibrated bathymetric relationships, weir-based outlet flow, modified Penman open-water evaporation, groundwater head relaxation, Penman–Monteith snow and ice sublimation, and snow, ice, and thermal conditions supplied by xLSIM. The model calibrates lake parameters against satellite-derived surface-area data, using evaporation-based calibration where surface-area data are unavailable, and supports small, medium, and large lake classes. For large lakes, xLWBM is integrated with the managed-routing workflow so that lake storage and outflow interact directly with downstream river routing and reservoir operations. Together, xLSIM and xLWBM provide Xanthos with a coupled lake-modeling capability. xLSIM supplies the snow, ice, and thermal conditions that affect lake evaporation and snow- and ice-related water exchanges, while xLWBM translates those conditions into dynamic lake storage, surface area, evaporation, and discharge. In return, xLWBM supplies evolving lake surface area to xLSIM. This coupling enables Xanthos to represent lakes as active hydrologic components within basin-scale water-availability and routing simulations.

Machine Learning↗

NASA NTRS1973

Segregation effects during solidification in weightless melts

Two types of melt segregation effects were studied: (1) evaporative segregation, or segregation due to surface evaporation; and (2) freezing segregation, or segregation due to liquid-solid phase transformation. These segregation effects are closely related. In fact, evaporative segregation always precedes freezing segregation to some degree and must often be studied prior to performing meaningful solidification experiments. This is particularly true since evaporation may cause the melt composition, at least at the critical surface regions or layers to be affected manyfold within seconds so that the surface region or layer melting point and other thermophysical properties, nucleation characteristics, base for undercooling, and critical velocity to avoid constitutional supercooling, may be completely unexpected. An important objective was, therefore, to develop the necessary normal evaporation equations for predicting the compositional changes within specified times at temperature and to correlate these equations with actual experimental data collected from the literature.

Li, C.↗

NASA NTRS1988

A high power spacecraft thermal management system

This paper describes the design and test results of an ammonia hybrid capillary pumped loop thermal control system. As a hytbrid, the system can operate as either a passive, capillary pumped loop, or, as a mechanically pumped system. The system is comprised of an evaporator section, a condenser section, 10 meters of liquid and vapor transport lines, a mechanical pump, and a reservoir. In the evaporator section, four capillary pumps are each integrated into three cold plates. The mechanical pump is installed in the liquid line and is in series with the capillary pumps. Testing has demonstrated that in the capillary pumped mode, the HPSTM can acquire and transport a total heat load of between 120 W and 24 kW, with a maximum heat flux density of 4.3 W/sq cm in the evaporator section. In the mechanically pumped configuration, a heat acquisition potential of 50 kW (9 W/sq cm heat flux density) has been demonstrated. The hybrid system still retains the proven capillary capabilities of temperature control, heat load sharing and fluid flow control between evaporator plates, rapid power cycling, and pressure priming recovery of deprimed evaporators.

Ku, J.↗

NASA NTRS1990

Space Station heat pipe advanced radiator element (SHARE) flight test results and analysis

The SHARE experiment, which consisted of a single 51 ft long by 1 ft wide prototypical Space Station heat pipe radiator panel, was flown aboard STS-29 in March 1989. Several problems were uncovered during the flight which limited performance. Extensive post-flight analysis has revealed that the manifold connecting the evaporator and condenser sections did not prime properly in 0-g, and that a mismatch in hydraulic diameters between the evaporator and condenser caused large bubbles to be present in the liquid channel at startup. These bubbles subsequently became trapped at the evaporator entrance, halting liquid flow and causing premature dryout of the evaporator wall grooves. The experiment did demonstrate heat pipe transport capability of up to 1572 W with near isothermality in both the evaporator and condenser for short periods of time.

Kosson, Robert↗

NASA NTRS1993

Large-scale effects on the regulation of tropical sea surface temperature

The dominant terms in the surface energy budget of the tropical oceans are absorption of solar radiation and evaporative cooling. If it is assumed that relative humidity in the boundary layer remains constant, evaporative cooling will increase rapidly with sea surface temperature (SST) because of the strong temperature dependence of saturation water vapor pressure. The resulting stabilization of SST provided by evaporative cooling is sufficient to overcome positive feedback contributed by the decrease of surface net longwave cooling with increasing SST. Evaporative cooling is sensitive to small changes in boundary-layer relative humidity. Large and negative shortwave cloud forcing in the regions of highest SST are supported by the moisture convergence associated with largescale circulations. In the descending portions of these circulations the shortwave cloud forcing is suppressed. When the effect of these circulations is taken into account by spatial averaging, the area-averaged cloud forcing shows no sensitivity to area-averaged SST changes associated with the 1987 warming event in the tropical Pacific. While the shortwave cloud forcing is large and important in the convective regions, the importance of its role in regulating the average temperature of the tropics and in modulating temperature gradients within the tropics is less clear. A heuristic model of SST is used to illustrate the possible role of large-scale atmospheric circulations on SST in the tropics and the coupling between SST gradients and mean tropical SST. The intensity of large-scale circulations responds sensitivity to SST gradients and affects the mean tropical SST by supplying dry air to the planetary boundary layer. Large SST gradients generate vigorous circulations that increase evaporation and reduce the mean SST.

Hartmann, Dennis L.↗

NASA NTRS2001

Water Vapor Tracers as Diagnostics of the Regional Hydrologic Cycle

Numerous studies suggest that local feedback of surface evaporation on precipitation, or recycling, is a significant source of water for precipitation. Quantitative results on the exact amount of recycling have been difficult to obtain in view of the inherent limitations of diagnostic recycling calculations. The current study describes a calculation of the amount of local and remote geographic sources of surface evaporation for precipitation, based on the implementation of three-dimensional constituent tracers of regional water vapor sources (termed water vapor tracers, WVT) in a general circulation model. The major limitation on the accuracy of the recycling estimates is the veracity of the numerically simulated hydrological cycle, though we note that this approach can also be implemented within the context of a data assimilation system. In the WVT approach, each tracer is associated with an evaporative source region for a prognostic three-dimensional variable that represents a partial amount of the total atmospheric water vapor. The physical processes that act on a WVT are determined in proportion to those that act on the model's prognostic water vapor. In this way, the local and remote sources of water for precipitation can be predicted within the model simulation, and can be validated against the model's prognostic water vapor. As a demonstration of the method, the regional hydrologic cycles for North America and India are evaluated for six summers (June, July and August) of model simulation. More than 50% of the precipitation in the Midwestern United States came from continental regional sources, and the local source was the largest of the regional tracers (14%). The Gulf of Mexico and Atlantic regions contributed 18% of the water for Midwestern precipitation, but further analysis suggests that the greater region of the Tropical Atlantic Ocean may also contribute significantly. In most North American continental regions, the local source of precipitation is correlated with total precipitation. There is a general positive correlation between local evaporation and local precipitation, but it can be weaker because large evaporation can occur when precipitation is inhibited. In India, the local source of precipitation is a small percentage of the precipitation owing to the dominance of the atmospheric transport of oceanic water. The southern Indian Ocean provides a key source of water for both the Indian continent and the Sahelian region.

Bosilovich, Michael G.↗

NASA NTRS2003

High Frequency Low Amplitude Temperature Oscillations in Loop Heat Pipe Operation

The operating temperature of a loop heat pipe (LHP) with a single evaporator is governed by the compensation chamber (CC) temperature, which in turn is a finction of the evaporator power, condenser sink temperature, and ambient temperature. As the operating condition changes, the CC temperature will change during the transient but eventually reach a new steady temperature. Under certain conditions, however, the LHP never really reaches a true steady state, but instead displays an oscillatory behavior. This paper presents a study on the oscillation of the loop operating temperature with amplitudes on the order of one degree Kelvin and frequencies on the order of 10(exp -1) to 10(exp -2) Hertz. The source of the high frequency temperature oscillation is the fast movement of the vapor front in the condenser section, which usually occurs when the vapor front is near the condenser inlet or the condenser outlet. At these locations, the vapor front is unable to find a stable position for the given operating conditions, and will move back and forth. The movement of the vapor front causes the movement of the liquid in the condenser and the liquid line, leading to oscillations of the CC and the loop temperatures. Factors that affect the vapor front movement include evaporator power, condenser sink temperature, body forces and whether or the CC temperature is actively controlled. As long as there are no large thermal masses attached to the evaporator, the loop can self adjust rather quickly and the vapor front will move rapidly around the condenser inlet or outlet, leading to high frequency temperature oscillations. The amplitude of temperature oscillation is usually the largest in the liquid line, up to 20 degrees Kelvin in many cases, but diminishes to less than one degree Kelvin in the CC. Furthermore, the high frequency temperature oscillation can occur at any CC temperature when the right combination of the evaporator power and condenser sink temperature prevails.

Ku, Jentung↗

NASA NTRS2003

Low Frequency High Amplitude Temperature Oscillations in Loop Heat Pipe Operation

This paper presents a theory that explains low frequency, high amplitude temperature oscillations in loop heat pipe (LHP) operation. Oscillations of the CC temperature with amplitudes on the order of tens of degrees Kelvin and periods on the order of hours have been observed in some LHPs during ambient testing. There are presently no satisfactory explanations for such a phenomenon in the literature. It is well-known that the operating temperature of an LHP with a single evaporator is governed by the compensation chamber (CC) temperature, which in turn is a function of the evaporator heat load, sink temperature, and ambient temperature. As the operating condition changes, the CC temperature will change during the transient but eventually reach a new steady temperature. Under certain conditions, however, the LHP never really reaches a true steady state, but instead displays an oscillatory behavior. The proposed new theory describes why low frequency, high amplitude oscillations may occur when the LHP has a low evaporator power, a low heat sink temperature (below ambient temperature), and a large thermal mass attached to the evaporator. When this condition prevails, there are some complex interactions between the CC, condenser, thermal mass and ambient. The temperature oscillation is a result of the large movement of the vapor front inside the condenser, which is caused by a change in the net evaporator power modulated by the large thermal mass through its interaction with the sink and CC. The theory agrees very well with previously published test data. Effects of various parameters on the amplitude and frequency of the temperature oscillation are also discussed.

Ku, Jentung↗

NASA NTRS2003

Estimation of Transpiration and Water Use Efficiency Using Satellite and Field Observations

Structure and function of terrestrial plant communities bring about intimate relations between water, energy, and carbon exchange between land surface and atmosphere. Total evaporation, which is the sum of transpiration, soil evaporation and evaporation of intercepted water, couples water and energy balance equations. The rate of transpiration, which is the major fraction of total evaporation over most of the terrestrial land surface, is linked to the rate of carbon accumulation because functioning of stomata is optimized by both of these processes. Thus, quantifying the spatial and temporal variations of the transpiration efficiency (which is defined as the ratio of the rate of carbon accumulation and transpiration), and water use efficiency (defined as the ratio of the rate of carbon accumulation and total evaporation), and evaluation of modeling results against observations, are of significant importance in developing a better understanding of land surface processes. An approach has been developed for quantifying spatial and temporal variations of transpiration, and water-use efficiency based on biophysical process-based models, satellite and field observations. Calculations have been done using concurrent meteorological data derived from satellite observations and four dimensional data assimilation for four consecutive years (1987-1990) over an agricultural area in the Northern Great Plains of the US, and compared with field observations within and outside the study area. The paper provides substantive new information about interannual variation, particularly the effect of drought, on the efficiency values at a regional scale.

Choudhury, Bhaskar J.↗

NASA NTRS2002

Satellite-Based Surface Heat Budgets and Sea Surface Temperature Tendency in the Tropical Eastern Indian and Western Pacific Oceans for the 1997/98 El Nino and 1998/99 La Nina

The 1997/98 is a strong El Nino warm event, while the 1998/99 is a moderate La Nina cold event. We have investigated surface heat budgets and sea surface temperature (SST) tendency for these two events in the tropical western Pacific and eastern Indian Oceans using satellite-retrieved surface radiative and turbulent fluxes. The radiative fluxes are taken from the Goddard Satellite-retrieved Surface Radiation Budget (GSSRB), derived from radiance measurements of the Japanese Geostationary Meteorological Satellite 5. The GSSRB covers the domain 40 deg S - 4 deg N, 90 deg E-17 deg W and a period from October 1997 to December 2000. The spatial resolution is 0.5 deg x 0.5 deg lat-long and the temporal resolution is 1 day. The turbulent fluxes are taken from Version 2 of the Goddard Satellite-based Surface Turbulent Fluxes (GSSTF-2). The GSSTF-2 has a spatial resolution of 1 deg x 1 deg lat-long over global Oceans and a temporal resolution of 1 day covering the period July 1987-December 2000. Daily turbulent fluxes are derived from the S S M (Special Sensor Microwave/Imager) surface wind and surface air humidity, and the SST and 2-m air temperature of the NCEP/NCAR reanalysis, using a stability-dependent bulk flux algorithm. The changes of surface heat budgets, SST and tendency, cloudiness, wind speed, and zonal wind stress of the 1997/98 El Nino relative to the1998/99 La Nina for the northern winter and spring seasons are analyzed. The relative changes of surface heat budgets and SST tendency of the two events are quite different between the tropical eastern Indian and western Pacific Oceans. For the tropical western Pacific, reduced solar heating (more clouds) is generally associated with decreased evaporative cooling (weaker winds), and vise versa. The changes in evaporative cooling over-compensate that of solar heating and dominate the spatial variability of the changes in net surface heating. Both solar heating and evaporative cooling offset each other to reduce interannual variability of net surface heating. In addition, the area of increased SST tendency is larger than that of increased net surface heating, due to less solar radiation penetration through the bottom of deeper ocean mixed layer (stronger winds). For the tropical eastern Indian Ocean, enhanced solar heating (less clouds) is generally associated with reduced evaporative cooling (weaker winds). Both solar heating and evaporative cooling reinforce each other to increase interannual variability of net surface heating. In addition, the area of increased SST tendency is smaller than that of increased net surface heating in the southern domain. The relative changes in wind and zonal wind stress indicate more solar radiation penetration through the ocean mixed layer and more northward heat transport by Ocean current from the south to the north Indian Ocean for the El Nino than for the La Nina.

Chou, Shu-Hsien↗

NASA NTRS2004

Aqueous Chemical Modeling of Sedimentation on Early Mars with Application to Surface-Atmosphere Evolution

This project was to investigate models for aqueous sedimentation on early Mars from fluid evaporation. Results focused on three specific areas: (1) First, a fluid evaporation model incorporating iron minerals was developed to compute the evaporation of a likely solution on early Mars derived from the weathering of mafic rock. (2) Second, the fluid evaporation model was applied to salts within Martian meteorites, specifically salts in the nakhlites and ALH84001. Evaporation models were found to be consistent with the mineralogy of salt assemblages-anhydrite, gypsum, Fe-Mg-Ca carbonates, halite, clays-- and the concentric chemical fractionation of Ca-to Mg-rich carbonate rosettes in ALH84001. We made progress in further developing our models of fluid concentration by contributing to updating the FREZCHEM model. (3) Third, theoretical investigation was done to determine the thermodynamics and kinetics involved in the formation of gray, crystalline hematite. This mineral, of probable ancient aqueous origin, has been observed in several areas on the surface of Mars by the Thermal Emission Spectrometer on Mars Global Surveyor. The "Opportunity" Mars Exploration Rover has also detected gray hematite at its landing site in Meridiani Planum. We investigated how gray hematite can be formed via atmospheric oxidation, aqueous precipitation and subsequent diagenesis, or hydrothermal processes. We also studied the geomorphology of the Aram Chaos hematite region using Mars Orbiter Camera (MOC) images.

Catling, David C.↗

NASA NTRS2005

Simulation of Water Sources and Precipitation Recycling for the MacKenzie, Mississippi and Amazon River Basins

An atmospheric general circulation model simulation for 1948-1997 of the water budgets for the MacKenzie, Mississippi and Amazon River basins is presented. In addition to the water budget, we include passive tracers to identify the geographic sources of water for the basins, and the analysis focuses on the mechanisms contributing to precipitation recycling in each basin. While each basin s precipitation recycling has a strong dependency on evaporation during the mean annual cycle, the interannual variability of the recycling shows important relationships with the atmospheric circulation. The MacKenzie River basin has only a weak interannual dependency on evaporation, where the variations in zonal moisture transport from the Pacific Ocean can affect the basin water cycle. On the other hand, the Mississippi River basin has strong interannual dependencies on evaporation. While the precipitation recycling weakens with increased low level jet intensity, the evaporation variations exert stronger influence in providing water vapor for convective precipitation at the convective cloud base. High precipitation recycling is also found to be partly connected to warm SSTs in the tropical Pacific Ocean. The Amazon River basin evaporation exhibits small interannual variations, so that the interannual variations of precipitation recycling are related to atmospheric moisture transport from the tropical south Atlantic Ocean. Increasing SSTs over the 50-year period are causing increased easterly transport across the basin. As moisture transport increases, the Amazon precipitation recycling decreases (without real time varying vegetation changes). In addition, precipitation recycling from a bulk diagnostic method is compared to the passive tracer method used in the analysis. While the mean values are different, the interannual variations are comparable between each method. The methods also exhibit similar relationships to the terms of the basin scale water budgets.

Bosilovich, Michael G.↗

NASA NTRS2002

New Method Developed to Measure Contact Angles of a Sessile Drop

The spreading of an evaporating liquid on a solid surface occurs in many practical processes and is of importance in a number of practical situations such as painting, textile dyeing, coating, gluing, and thermal engineering. Typical processes involving heat transfer where the contact angle plays an important role are film cooling, boiling, and the heat transfer through heat pipes. The biological phenomenon of cell spreading also is analogous to a drop spreading (ref. 1). In the study of spreading, the dynamic contact angle describes the interfacial properties on solid substrates and, therefore, has been studied by physicists and fluid mechanics investigators. The dynamic contact angle of a spreading nonvolatile liquid drop provides a simple tool in the study of the free-boundary problem, but the study of the spreading of a volatile liquid drop is of more practical interest because the evaporation of common liquids is inevitable in practical processes. The most common method to measure the contact angle, the contact radius, and the height of a sessile drop on a solid surface is to view the drop from its edge through an optical microscope. However, this method gives only local information in the view direction. Zhang and Yang (ref. 2) developed a laser shadowgraphy method to investigate the evaporation of sessile drop on a glass plate. As described here, Zhang and Chao (refs. 3 and 4) improved the method and suggested a new optical arrangement to measure the dynamic contact angle and the instant evaporation rate of a sessile drop with much higher accuracy (less than 1 percent). With this method, any fluid motion in the evaporating drop can be visualized through shadowgraphy without using a tracer, which often affects the field under investigation.

Chao, David F.↗

NASA NTRS2007

Loop Heat Pipe Operation with Thermoelectric Converters and Coupling Blocks

This paper presents theoretical and experimental studies on using thermoelectric converters (TECs) and coupling blocks to control the operating temperature of a miniature loop heat pipes (MLHP). The MLHP has two parallel evaporators and two parallel condensers, and each evaporator has its own integral compensation chamber (CC). A TEC is attached to each CC, and connected to the evaporator via a copper thermal strap. The TEC can provide both heating and cooling to the CC, therefore extending the LHP operating temperature over a larger range of the evaporator heat load. A bi-polar power supply is used for the TEC operation. The bipolar power supply automatically changes the direction of the current to the TEC, depending on whether the CC requires heating or cooling, to maintain the CC temperature at the desired set point. The TEC can also enhance the startup success by maintaining a constant CC temperature during the start-up transient. Several aluminum coupling blocks are installed between the vapor line and liquid line. The coupling blocks serve as a heat exchanger which preheats the cold returning liquid so as to reduce the amount of liquid subcooling, and hence the power required to maintain the CC at the desired set point temperature. This paper focuses on the savings of the CC control heater power afforded by the TECs when compared to traditional electric heaters. Tests were conducted by varying the evaporator power, the condenser sink temperature, the CC set point temperature, the number of coupling blocks, and the thermal conductance of the thermal strap. Test results show that the TECs are able to control the CC temperature within k0.5K under all test conditions, and the required TEC heater power is only a fraction of the required electric heater power.

Ku, Jentung↗

NASA NTRS2006

Using Thermoelectric Converters for Loop Heat Pipe Operating Temperature Control

This paper describes an experimental study to investigate the effectiveness of using thermoelectric converters (TECs) to control the loop heat pipe (LHP) operating temperature. Tests were conducted on an LHP having two evaporators and two condensers. Each evaporator has its own integral compensation chamber (CC). One side of the TEC is attached to the CC, and the other side is connected to the evaporator through a copper thermal strap. A bi-polar power supply is used to provide the power for the operation of each TEC. The bipolar supply will automatic change the direction of the current to the TEC depending on whether the CC requires heating or cooling in order to maintain its temperature at the desired set point. When cooling the CC, the heat pumped by the TEC plus the power needed to operate the TEC is dissipated to the evaporator, and is ultimately transmitted to the condenser. When heating the CC, the TEC can draw heat from the evaporator to supplement the required control heater power. Test results showed that the TEC could control the LHP operating temperature within h1K of the set point temperature. The control heater power required for TEC operation was also much less than that of using electrical heaters.

Ku, Jentung↗

NASA NTRS2009

Thermal Interface Evaluation of Heat Transfer from a Pumped Loop to Titanium-Water Thermosyphons

Titanium-water thermosyphons are being considered for use in the heat rejection system for lunar outpost fission surface power. Key to their use is heat transfer between a closed loop heat source and the heat pipe evaporators. This work describes laboratory testing of several interfaces that were evaluated for their thermal performance characteristics, in the temperature range of 350 to 400 K, utilizing a water closed loop heat source and multiple thermosyphon evaporator geometries. A gas gap calorimeter was used to measure heat flow at steady state. Thermocouples in the closed loop heat source and on the evaporator were used to measure thermal conductance. The interfaces were in two generic categories, those immersed in the water closed loop heat source and those clamped to the water closed loop heat source with differing thermal conductive agents. In general, immersed evaporators showed better overall performance than their clamped counterparts. Selected clamped evaporator geometries offered promise.

Jaworske, Donald A.↗

NASA NTRS2011

Venting of a Water/Inhibited Propylene Glycol Mixture in a Vacuum Environment-Characterization and Representative Test Results

A planned use of the Orion space vehicle involves its residence at the International Space Station for six months at a time. One concept of operations involves temporarily venting portions of the idle Orion active thermal control system (ATCS) during the docked phase, preventing freezing. The venting would have to be reasonably complete with few, if any, completely filled pockets of frozen liquid. Even if pockets of frozen liquid did not damage the hardware during the freezing process, they could prevent the system from filling completely prior to its reactivation. The venting of single component systems in a space environment has been performed numerous times and is well understood. Local nucleation occurs at warm, relatively massive parts of the system, which creates vapor and forces the bulk liquid out of the system. The remnants of the liquid will freeze, then evaporate over time through local heating. Because the Orion ATCS working fluid is a 50/50 mixture of water and inhibited propylene glycol, its boiling behavior was expected to differ from that of a pure fluid. It was thought that the relatively high vapor pressure water might evaporate preferentially, leaving behind a mixture enriched with the low vapor pressure propylene glycol, which would be vaporization ]resistant. Owing to this concern, a test was developed to compare the evaporation behavior of pure water, a 50/50 mixture of water and inhibited propylene glycol, and inhibited propylene glycol. The test was performed using room temperature fluids in an instrumented thin walled stainless steel vertical tube. The 1 in x 0.035 in wall tube was instrumented with surface thermocouples and encased in closed cell polyurethane foam. Reticulated polyurethane foam was placed inside the tube to reduce the convection currents. A vacuum system connected to the top of the tube set the pressure boundary condition. Tests were run for the three fluids at back pressures ranging from 1 to 18 torr. During each test, the mass of the test article was measured as it changed over time, as was its temperature and backpressure. The tests were successful. Somewhat surprisingly, the results showed that the evaporation behavior of the three fluids had more similarities than differences. The 50/50 mixture evaporated similarly to the pure water - albeit at a slower rate. The test results indicate that our extensive space - based experience with venting of single component fluids can be applied to the problem of Orion ATCS venting as long as the appropriate puts, takes, and caveats are applied.

Ungar, Eugene K.↗