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At least 955 records · Page 53

Long Life Molten Salt Battery for NASA Venus Application

A development program is being conducted at Advanced Thermal Batteries (ATB) to create a low discharge rate, long life, molten salt battery for a NASA Venus surface probe. Battery goals are 60 days continuous operation at +25V +0/-6 volts and -25V +6/-0 Volts under severe environments of 465°C, 92 atm pressure, and corrosive sulfur dioxide in a super critical carbon dioxide atmosphere. Conveniently, molten salt thermal battery electrochemistry starts to operate efficiently at 330°C. However, a major barrier to direct application of existing thermal battery technology is the high self-discharge rate, resulting in lifetimes in only minutes, not days. The best performance to date, which meets the required voltage regulation, has been a lithium silicon (LiSi) alloy anode discharging through all three voltage plateau versus an iron monosulfide (FeS) cathode. In order to perform reproducibly, additional engineering controls within the battery design are required to limit cell–to–cell parasitic discharge mechanisms. Results of these trials have improved the efficiency and manufacturability of the design.

Thermal Battery↗

Review of the findings of the Ignik Sikumi CO2-CH4 gas hydrate exchange field trial

The Ignik Sikumi Gas Hydrate Exchange Field Trial was conducted by ConocoPhillips in partnership with the U.S. Department of Energy, the Japan Oil, Gas, and Metals National Corporation, and the U.S. Geological Survey within the Prudhoe Bay Unit on the Alaska North Slope (ANS) during 2011 and 2012. The 2011 field program included drilling the vertical test well and performing extensive wireline logging through a thick section of gas-hydrate-bearing sand reservoirs that provided substantial new insight into the nature of ANS gas hydrate occurrences. The 2012 field program involved an extended, scientific field trial conducted within a single vertical well (“huff-and-puff” design) through three primary operational phases: 1) injection of a gaseous phase mixture of CO2, N2, and chemical tracers; 2) flowback conducted at down-hole pressures above the stability threshold for native CH4-hydrate, and 3) extended (30-days) flowback at pressures below the stability threshold of native CH4-hydrate. Ignik Sikumi represents the first field investigation of gas hydrate response to chemical injection, and the longest-duration field reservoir response experiment yet conducted. Full descriptions of the operations and data collected have been fully reported by ConocoPhillips and are available to the science community. The 2011 field program indicated the presence of free water within the gas hydrate reservoir, a finding with significant implications to the design of the exchange trial – most notably the use of a mixed gas injectant. While this decision resulted in a complex chemical environment within the reservoir that greatly tests current experimental and modeling capabilities – without such a mixture, it is apparent that injection could not have been achieved. While interpretation of the field data are continuing, the primary scientific findings and implications of the program are: 1) gas hydrate destabilizing is self-limiting, dispelling any notion of the potential for uncontrolled destabilization; 2) wells must be carefully designed to enable rapid remediation of well-bore blockages that will occur during any cessation in operations; 3) appropriate gas mixes can be successfully injected into hydrate-bearing reservoirs; 4) sand production can be well-managed through standard engineering controls; 5) reservoir heat exchange during depressurization was much more favorable than expected – mitigating concerns for near-well-bore freezing and enabling consideration of more aggressive pressure reduction and; 6) CO2-CH4 exchange can be accomplished in natural reservoirs. The next steps in evaluation of exchange technology should feature multiple well applications; however such field programs will require extensive preparatory experimental and numerical modeling studies and will likely be a secondary priority to further field testing of production through depressurization.

Alaska↗

Bench Scale Process for Low Cost CO2 Capture Using a Phase-Changing Absorbent: Topical Report EH&S Risk Assessment

GE Global Research was contracted by the Department of Energy to design and build a bench-scale process for a novel phase-changing aminosilicone-based CO2 capture solvent (award number DEFE0013687). As part of this program, a technology EH&S assessment (Subtask 5.1) has been completed for a CO2 capture system for a 550 MW coal-fired power plant. The assessment focuses on two chemicals used in the process, the aminosilicone solvent, GAP-0, and dodecylbenzenesulfonic acid (DDBSA), the GAP-0 carbamate formed upon reaction of the GAP-0 with CO2, and two potential byproducts formed in the process, GAP-0/SOx salts and amine-terminated, urea-containing silicone (also referred to as “ureas” in this report). The EH&S assessment identifies and estimates the magnitude of the potential air and water emissions and solid waste generated by the process and reviews the toxicological profiles of the chemicals associated with the process. Details regarding regulatory requirements, engineering controls, and storage and handling procedures are also provided in the following sections.

20 FOSSIL-FUELED POWER PLANTS↗

Fast GDCI heated air intake system

A GDCI engine control system includes a fast electric heater located within a pocket in a cylinder head. The pocket is in fluid communication with multiple intake ports. A heater control system includes a capacitor that is configured to provide a voltage that is greater than battery voltage to more quickly heat the intake air during a cold start. Subsequently a lower voltage can be supplied to the heater.

Sellnau, Mark C.↗

GDCI cold start misfire prevention

A GDCI engine control system determines if in-cylinder conditions are sufficient to achieve combustion in a given cylinder or if a misfire is likely. Fuel is delivered to that cylinder if combustion is probable, but fuel is disabled to that cylinder if a misfire is probable.

Roth, Gregory T.↗

An automated approach to the alignment of compound refractive lenses

Compound refractive lenses (CRLs) are established X-ray focusing optics, and are thus a key element of many beamlines at X-ray facilities, used to either to focus a beam or image a sample. While CRLs are quite established, the stack of single lens elements affords a very small numerical aperture because of the thick lens profile, making them far more difficult to align than classical optical lenses that obey the thin-lens approximation. This means that the alignment must be very precise and is highly sensitive to changes to the incident beam; aligning CRLs is thus typically treated as a time-consuming manual process. Many groups circumvent day-to-day realignment by using engineering controls (e.g. mounting optics) that sacrifice some of the beam’s focusing characteristics, i.e. spot size, or resolution. While these choices minimize setup time, there are clear disadvantages. This work presents a new automated approach to align CRLs using a simple alignment apparatus that is easy to adapt and install at different types of X-ray experiments or facilities. Our approach builds on recent CRL modeling efforts, using an approach based on the Stochastic Nelder-Mead (SNM) simplex method. We demonstrate the efficacy of this method by numerical simulation and then extend this test to real experiments conducted at the Advanced Photon Source to confirm its performance with a synchrotron X-ray beam. This work provides an opportunity to automate key instrumentation at X-ray facilities.

97 MATHEMATICS AND COMPUTING↗

Facile clay exfoliation using polymer silicone surfactants

The present invention is directed to processes for preparing a silicone surfactant intercalated clay and a polymer-clay nanocomposite. The processes use silicone surfactants having a molecular weight in the range of 10,000 to 100,000 Dalton to achieve fully exfoliating clay structures. Using these macromolecular silicone surfactants, along with the engineered control of the processing pH and drying stress conditions, this invention provides simple and low-cost methods of making a fully-exfoliated polymer-clay nanocomposite.

Yang, Arthur Jin-Ming↗

Management of technetium contaminated demolition debris from the gaseous diffusion plants at the east Tennessee Technology Park - 15422

The demolition of the final section of the gaseous diffusion plant (GDP) facility formerly known as K-25 at the East Tennessee Technology Park was completed in December of 2013, with the final shipment of waste completed only six months later in June 2014. While most of the radioactive waste shipments would be considered 'routine' by today's standards (lower activity waste was disposed onsite at the Environmental Management Waste Management Facility [EMWMF] and at some offsite commercial disposal facilities with higher activity waste making its way across country to the Nevada National Security Site [NNSS] disposal facility) the final section of K-25, consisting of six cascade 'units', presented some unique technical and stakeholder challenges. Portions of this final section of K-25 were presumed to be heavily contaminated with Technetium-99 (Tc-99) based on sampling and analysis activities conducted during facility deactivation. Tc-99 is known to be highly mobile under a variety of environmental conditions, and is suspected to be potentially mobile in unmitigated landfill conditions, resulting in the need to implement additional engineered controls during facility demolition as well as throughout the management of the resultant waste. A variety of controls were implemented to ensure Tc-99 mobility was controlled and possible consequences mitigated, including isolation and offsite shipment of highest Tc-99 concentration components, as well as construction of a 'cell within a cell' at the EMWMF. This paper will examine the process utilized to develop the controls for management of Tc-99 contaminated waste and will describe those controls. Additionally, it will describe the stakeholder involvement and approval process as well as examining and documenting the efficacy of the controls that were implemented. Finally, this paper will discuss lessons learned from this first of a kind demolition effort and how this experience can be utilized to further refine the Tc-99 waste management approach for the remaining GDPs at ETTP. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

An approach to evaluating and monitoring ecological resources for sustainability on DOE remediation sites: Hanford as a case study - 15524

Protecting ecological and environmental resources is a worthy aspect of the Department of Energy's site missions, for each of its sites, during and after remediation. Ecological resources are important to a range of stakeholders, including regulatory agencies, resource agencies, natural resource trustees, Tribal governments, and the public, and may be an essential component of Native American cultural resources. Because the nature and value of ecological resources can change over time as a result of remediation, succession, and global climate change, it is imperative for DOE to have instituted an acceptable method of evaluating resources before initiation of active remediation, over the ensuing century when institutional and engineering controls are considered to be in effect. Having such a methodology in place also would be key to resource sustainability. Department of Energy sites generally have environmental programs, so instituting specific unified practices for evaluating resources should not be difficult to implement. Instituting these practices would assure the public that ecological resources, as well as human and cultural resources, are being protected now, and can be protected into the future. Key ecological species and/or unique habitats have been preserved at Department of Energy sites since the mid-20. century because of federal government stewardship. Such preservation is particularly true for the sites with larger land areas, including the Hanford Reservation, the Idaho National Laboratory and the Savannah River Site. Individual sites typically have extensive studies of site biodiversity, but site resources are not routinely examined within a regional or national context (Eco-region). The evaluation of the on-site resources with those resources in the appropriate Eco-region provides a context for 'valuing' on- site resources. On-site resources should also be evaluated in terms of federal and state legislation where species may have legal protection and require legal consideration during remediation if present or adjacent to the remediation site. A method is needed in this study for evaluating ecological resources prior to remediation and during remediation, and a paradigm is proposed that will ensure sustainability. Finally, in a period of climate change and instability, developing methods of evaluating ecological resources is essential to successful protection, enhancement, and sustainability. The ecological methodology is part of a Hanford site-wide Risk Review Project, conducted by the Consortium for Risk Evaluation with Stakeholder Participation (CRESP). Our method adapts an existing methodology that includes using established levels for evaluating ecological resources by expanding the existing methodology to include field work for validating previous resource level designations, to assess the occurrence of invasive/exotic species, and to identify landscape scale features (patch size, connectivity). Evaluations should be conducted in the remediation unit itself, and in a buffer zone surrounding the remediation site. The methodology described has been applied to several remediation areas at Hanford, and issues that emerged during its application are discussed. The methodology can be applied at the major sites. Application of the Eco-region analysis will provide regulators and the public with an understanding of the value of the ecological resources in relation to the region, as well as an appreciation for the stewardship role the Department of Energy has played in protecting these resources since the beginning of the Cold War Era and can continue to do so sustainably. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Fit for Purpose Remote Technology Decommissioning Solutions - 18630

The Magnox Decommissioning Project is actively progressing clean-up and decommissioning of 12 reactor sites across England, Scotland and Wales. Funded and directed by the United Kingdom's Nuclear Decommissioning Authority (NDA) and managed by the Cavendish Fluor Partnership (CFP), the Magnox Decommissioning Project introduces a wide range of radiological and industrial hazards warranting deployment of remote technologies to safely de-inventory, decontaminate and decommission a vast array of nuclear facilities. The Magnox Decommissioning Project encompasses 22 former Magnox nuclear power production reactors across 10 reactor sites and five research/test reactors at two former research sites. Decommissioning activities have been underway at some sites for nearly 20 years with early focus on retrieving and stabilising wastes and draining and stabilising spent fuel ponds. The Magnox decommissioning strategy invokes a programme perspective to drive consistency in tackling similar decommissioning and waste challenges across multiple sites. Programme central teams have worked with technology suppliers to foster learning from industry experience to develop and deploy tooling and robotics. The programme approach has also facilitated learning from one site to the next. In many cases, this central programme approach has promoted an evolution of technologies resulting in optimisation of simple remote tooling. In other instances, collaboration with suppliers is producing state-of-the-art technologies to tackle more unique challenges including, most recently, early demonstration of laser cutting for reactor vessel dismantling. This paper will outline the programme management approach and the scalable optioneering process Magnox employs to select the engineered controls and technologies used in decommissioning and waste management activities. It will provide an overview of the broad range of remote tooling and robotics deployed across the 12 Magnox sites by exploring some specific examples. Lastly, the paper will summarise key lessons learned in the now extensive history of selecting and using remote technologies to decommission Magnox nuclear facilities. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Developing a Supply Chain Security Program

Amid growing concerns over foreign manufacturing for components and devices deployed in critical energy infrastructure, this research from the national labs will highlight best practices for developing and maintaining a supply chain security program. Tools for asset inventory, tips for developing and maintaining software- and hardware-bills-of-materials (SBOMs and HBOMs), recommended contractual language for vendor agreements, and identification of responsibilities will be shared. We discuss the one-time requirements to enable a successful supply chain security program and the best ways to operationalize this program for maximum impact, including development of robust practices for vulnerability tracking, patch management, and workarounds, with understanding of the reliability and uptime requirements for utilities. The recommendations shared are based on a cyber-informed engineering approach to identification of high-consequence impacts and the engineering controls related to supply chain management that can best mitigate these impacts. This approach allows for prioritization of resources. Additionally, we highlight relative up-front and ongoing costs associated with recommended controls. Viewers will leave with an understanding what a supply chain security program is, and what steps, prioritized for resource-constrained organizations, can build a robust program.

14 SOLAR ENERGY↗

Lessons learned from the development and implementation of a workforce training curriculum for advanced controls for high performance HVAC systems

Over the past decade, academic research on advanced controls has slowly transitioned into new software platforms, giving rise to various companies developing and deploying these innovative products, including solutions for light commercial HVAC systems. However, the current workforce remains widely unprepared to install, maintain and operate these systems, particularly complex software-based control platforms, as most workforce training programs still focus on traditional building automation for large commercial buildings. This paper presents the development and piloting of curriculum for three key types of professionals: ● Technicians (trade-level): installing and maintaining modern high-performance HVAC systems and controls ● Programmers (undergrad-level): developing and implementing advanced controls ● Engineers and energy professionals (undergrad/grad-level): managing and evaluating system performance We share details of the material developed including training videos, open-source software, instruction manuals. We also present the results of a pilot implementation of the training materials with real students.

Casillas, Armando↗

Hydrogen Recombiner Catalyst Evaluations for Waste Storage

Radiolysis of water in nuclear waste storage generates hydrogen gas that can accumulate within sludge style waste and be rapidly released during agitation events, creating a significant flammability hazard. Engineering controls are therefore required to limit hydrogen concentrations during both quiescent storage and transient disturbances. Catalytic recombination of hydrogen in waste storage offgas is a proven mitigation strategy, maintaining hydrogen levels below flammability limits and managing sudden concentration spikes. Conventional recombiners rely on platinum and/or palladium catalysts, with development efforts focused on extending service life, increasing active surface area, and ensuring safe deployment in radioactive environments. Savannah River National Laboratory (SRNL) is evaluating a newly developed hydrogen recombiner catalyst from Canadian Nuclear Laboratories as a cost-effective and durable alternative for nuclear waste applications. Testing was conducted in SRNL’s Shielded Cells facility, which enables reduced-scale experimental modeling under radiation fields and near-use-case conditions relevant to radioactive waste storage. Catalyst performance was evaluated using a custom offgas characterization system designed for near-zero flow conditions. The experimental apparatus consisted of a gas-tight 2.7 L PTFE vessel equipped with temperature monitoring, gas flow controls, and a variable-speed mixer to simulate sludge agitation. Offgas composition was monitored using a dedicated gas chromatograph with argon carrier gas and a krypton internal standard. Measurements were obtained for an empty vessel, the vessel containing a well characterized radioactive tank waste sample, and the same configuration with the candidate catalyst installed. Results demonstrate that the new catalyst effectively reduced hydrogen concentrations in the offgas within the constraints of the experimental design. In addition to confirming catalytic activity, the testing provided valuable insights into experimental optimization and considerations for future performance evaluations. These findings support the potential scalability of the technology and highlight its applicability to broader nuclear waste management operations, offering improved safety and reduced operational costs through enhanced catalyst durability and lower replacement frequency.

Tener, Zachary P. [Savannah River National Laborat↗

Evaluation of engineering foods for Controlled Ecological Life Support Systems (CELSS)

The feasibility of developing acceptable and reliable engineered foods for use in controlled ecological support systems (CELSS) was evaluated. Food resupply and regeneration are calculated, flow charts of food processes in a multipurpose food pilot plant are presented, and equipment for a multipurpose food pilot plant and potential simplification of processes are discussed. Food-waste treatment and water usage in food processing and preparation are also considered.

Karel, M.↗

Application of polynomial techniques to multivariable control of jet engines

This paper describes a complete case study of the application of the theory of minimal design to multivariable control of jet engines. The minimal-design problem is approached from the viewpoint of polynomial modules, and computational experience with PL/I and FORMAC-PL/I software is discussed. The complete minimal-design solution exhibits flexibilities not apparent in early industry studies, and a matrix approach to pole assignment can be used to advantage in this situation.

Gejji, R. R.↗

Evaluation of an F100 multivariable control using a real-time engine simulation

The control evaluated has been designed for the F100-PW-100 turbofan engine. The F100 engine represents the current state-of-the-art in aircraft gas turbine technology. The control makes use of a multivariable, linear quadratic regulator. The evaluation procedure employed utilized a real-time hybrid computer simulation of the F100 engine and an implementation of the control logic on the NASA LeRC digital computer/controller. The results of the evaluation indicated that the control logic and its implementation will be capable of controlling the engine throughout its operating range.

Szuch, J. R.↗

Grain engineering: How nanoscale inhomogeneities can control charge collection in solar cells

Statistical and correlative analysis are increasingly important in the design and study of new materials, from semiconductors to metals. Non-destructive measurement techniques, with high spatial resolution, capable of correlating composition and/or structure with device properties, are few and far between. For the case of polycrystalline and inhomogeneous materials, the added challenge is that nanoscale resolution is in general not compatible with the large sampling areas necessary to have a statistical representation of the specimen under study. For the study of grain cores and grain boundaries in polycrystalline solar absorbers this is of particular importance since their dissimilar behavior and variability throughout the samples makes it difficult to draw conclusions and ultimately optimize the material. In this study, we present a nanoscale in-operando approach based on the multimodal utilization of synchrotron nano x-ray fluorescence and x-ray beam induced current collected for grain core and grain boundary areas and correlated pixel-by-pixel in fully operational Cu(In(1-x)Gax)Se2Cu(In(1-x)Gax)Se2 solar cells. We observe that low gallium cells have grain boundaries that over perform compared to the grain cores and high gallium cells have boundaries that under perform. These results demonstrate how nanoscale correlative X-ray microscopy can guide research pathways towards grain engineering low cost, high efficiency solar cells.

14 SOLAR ENERGY↗