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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 955 records · Page 53
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Characteristics of laminar gas jet diffusion flames under the influence of elevated gravity

Laminar gas jet diffusion flames of hydrogen, methane, ethane, and propane, stabilized on small cylindrical burners, were studied at elevated gravity in a centrifuge to investigate the role of buoyancy in such flames. Photographic observation of the hydrocarbon flames indicated that length and carbon luminosity decreased with increasing buoyancy. These flames eventually separated from the burner rim and finally extinguished as gravity increased. Hydrogen flames, however, did not separate or extinguish up to about 31 times earth normal gravity. Length data are reported and interpreted with the aid of a simplified model which describes the flame as a heated vertical cylindrical sheet to which oxygen is supplied by a free convection boundary layer.

Altenkirch, R. A.↗
NASA NTRS1981

Seismic codas on the earth and the moon - A comparison

The seismic codas, representing that part of the seismogram following the arrival of the surface waves or the direct S waves, characteristic of the earth and moon are compared with regard to the implications of coda characteristics for scattering and attenuation. Scattering models based on single S-S scatter theory, in which seismic energy in the coda is assumed to be S waves that have undergone only one scattering without conversion, and on diffusion theory, which assumed that energy in the coda has been scattered many times, are examined, and situations where the single-scattering and multiple-scattering theories are applicable are distinguished by the ratio of attenuation distance to the scattering mean free path. Values of the attenuation distance and the mean free path derived from coda studies for the earth and moon are compared, and it is found that for the frequency range 0.5-10 Hz, diffusion scattering is important in lunar codas, while at frequencies from 1 to 25 Hz single scattering is important in terrestrial codas. It is pointed out that attenuation acts to eliminate scattering paths much longer than the attenuation length. The observed differences between terrestrial and lunar codas are thus attributed to lesser attenuation and greater scattering on the moon.

Dainty, A. M.↗
NASA NTRS1985

Pitch Angle Distributions of Solar Energetic Particles and the Local Scattering Properties of the Interplanetary Magnetic Field

An approximate solution of the Fokker-Planck equation containing pitch angle scattering and adiabatic focusing is discussed. For modest focusing effects the omnidirectional density obeys an ordinary diffusion equation with a modified diffusion coefficient. The anisotropic part of the distribution function is properly normalized and split into an even and an odd part. The even part is determined by the ratio between the scattering mean free path and the focusing length and by the degree of polarization of the magnetic field fluctuations. The odd part is determined by the deviation of the pitch angle scattering from isotropic scattering. The method supplies a powerful tool to obtain the local characteristics of pitch angle scattering. It is insensitive to long lasting solar injections and to moderate radial variations of the mean free path. The method is applied to solar particle events observed on Helio-1 and -2.

Beeck, J.↗
DOE OSTI2022

Confinement-Driven Heterogeneous Benzene Crystallization in Silica Nanopores

Nanoconfinement alters the thermodynamics, dynamics, and kinetics of fluids hosted in nanoscale solid nanopores to an extent that depends on the characteristics of the confining space and the chemistry of the confined fluids. Confinement-induced alterations in the phase behavior of confined energetic fluids under high pressure or low temperature are highly relevant to subsurface and subsea phenomena such as fluid flow in porous media, hydrate formation and dissociation, and gas storage capacity. Although extensive efforts have been directed toward understanding the phase behavior of confined fluids, the role of solid-liquid interfaces in the phase transitions of organic liquids has not been resolved yet. Here, we explore the onset and growth of benzene crystallization confined in 6 nm sized SBA-15 silica nanopores in the temperature range 300-200 K using in situ extended range small-angle and wide-angle X-ray scattering (SAXS/WAXS) measurements and atomistic classical molecular dynamics (MD) simulations. The crystallization onset of confined benzene depresses to 265 K compared to the freezing point of bulk benzene ( ~278 K), followed by the continuous growth of the emerged crystals in the pore space with complete crystallization at 200 K. The orientation of the emerged benzene crystals is dominated by parallel (π-π stacking) and perpendicular (T-shape stacking) orientations along the cylindrical pore radius and pore length, respectively. The onset of benzene crystals occurs heterogeneously on the pore surface and grows continuously toward the pore center. Further, confined benzene undergoes a dynamical crossover from fragile to strong dynamics behavior, inferred from the rotational and translational diffusion. The insights provided by this study have significant implications for the phase transitions of confined organic liquids that are relevant to a wide range of applications in the biological, geological, environmental, and chemical fields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1986

Time-dependent coronal shock acceleration of energetic solar flare particles

A global time-dependent model is presented for the coronal and interplanetary shock acceleration and propagation of energetic solar flare particles. The calculations are carried out to help prove that coronal shock acceleration of solar flare particles is responsible for energetic solar flare event data gathered in interplanetary space. The model is based on the theory of diffusive shock acceleration, and requires particle speeds to be much greater than bulk velocities. Also, sufficient scattering must occur upstream and downstream of the shock for the particle scattering mean free path to be smaller than the characteristic scale lengths, which causes the same particles to encounter the shock repeatedly. A spherically symmetric shock wave is assumed, which leads to the same emission configuration for impulsively and monoenergetically emitted particles. Consideration is given to acceleration by compression at the shock front, adiabatic deceleration in the divergent downstream flow, the temporal evolution of the shock and the three-dimensional geometry of the corona. The model is used to generate normalized proton omnidirectional distributions at 1 AU and at the shock front. The spectral exhibit trends similar to those in observational data, especially proton acceleration times and the proton distribution profiles at 1 AU.

Lee, M. A.↗
NASA NTRS1986

Cascade model of coronal heating

It is suggested that the quasi-static evolution of coronal magnetic structures is characterized by a cascade of magnetic energy to smaller length scales. This cascade process takes place on a time scale t sub b determined entirely by the photospheric motions. The Ohmic heating rate E sub H in the statistically stationary state was estimated using observational data on the diffusivity of photospheric motions; E sub H turned out to be too small by a factor of 40 when compared with observed coronal energy losses. However, given the fact that the theoretical estimate is based on a rather uncertain extrapolation to the diffusive regime, current heating cannot be ruled out as a viable mechanism of coronal heating.

Vanballegooijen, A. A.↗
NASA NTRS1993

Chemical Dosimeter Tube With Coaxial Sensing Rod

Improved length-of-stain (LOS) chemical dosimeter indicates total dose of chemical vapor in air. Made with rods and tubes of various diameters to obtain various sensitivities and dynamic ranges. Sensitivity larger and dose range smaller when more room for diffusion in gap between tube and rod. Offers greater resistance to changing of color of exposed dye back to color of unexposed condition, greater sensitivity, and higher degree of repeatability. Developed to measure doses of gaseous HCI, dosimeter modified by use of other dyes to indicate doses of other chemical vapors.

Lueck, Dale E.↗
NASA NTRS1993

Simulation of the early startup period of high-temperature heat pipes from the frozen state by a rarefied vapor self-diffusion model

The heat pipe startup process is described physically and is divided into five periods for convenience of analysis. The literature survey revealed that none of the previous attempts to simulate the heat pipe startup process numerically were successful, since the rarefied vapor flow in the heat pipe was not considered. Therefore, a rarefied vapor self-diffusion model is proposed, and the early startup periods, in which the rarefied vapor flow is dominant within the heat pipe, are first simulated numerically. The numerical results show that large vapor density gradients existed along the heat pipe length, and the vapor flow reaches supersonic velocities when the density is extremely low. The numerical results are compared with the experimental data of the early startup period with good agreement.

Cao, Y.↗
NASA NTRS1993

Perpendicular blade vortex interaction and its implications for helicopter noise prediction: Wave-number frequency spectra in a trailing vortex for BWI noise prediction

Perpendicular blade vortex interactions are a common occurrence in helicopter rotor flows. Under certain conditions they produce a substantial proportion of the acoustic noise. However, the mechanism of noise generation is not well understood. Specifically, turbulence associated with the trailing vortices shed from the blade tips appears insufficient to account for the noise generated. The hypothesis that the first perpendicular interaction experienced by a trailing vortex alters its turbulence structure in such a way as to increase the acoustic noise generated by subsequent interactions is examined. To investigate this hypothesis a two-part investigation was carried out. In the first part, experiments were performed to examine the behavior of a streamwise vortex as it passed over and downstream of a spanwise blade in incompressible flow. Blade vortex separations between +/- one eighth chord were studied for at a chord Reynolds number of 200,000. Three-component velocity and turbulence measurements were made in the flow from 4 chord lengths upstream to 15 chordlengths downstream of the blade using miniature 4-sensor hot wire probes. These measurements show that the interaction of the vortex with the blade and its wake causes the vortex core to loose circulation and diffuse much more rapidly than it otherwise would. Core radius increases and peak tangential velocity decreases with distance downstream of the blade. True turbulence levels within the core are much larger downstream than upstream of the blade. The net result is a much larger and more intense region of turbulent flow than that presented by the original vortex and thus, by implication, a greater potential for generating acoustic noise. In the second part, the turbulence measurements described above were used to derive the necessary inputs to a Blade Wake Interaction (BWI) noise prediction scheme. This resulted in significantly improved agreement between measurements and calculations of the BWI noise spectrum especially for the spectral peak at low frequencies, which previously was poorly predicted.

Devenport, William J.↗
NASA NTRS2003

X-ray single Photon Spectrometers

The research at Yale on superconducting tunnel junctions (STJs) focussed on x-ray detectors, using a 5.9 keV x-ray source. All the Yale tests were carried out at 0.21 K, in a two-stage helium 3 dewar. Careful attention was given to grounding and shielding. All current waveforms were digitially recorded and analyzed subsequently on computer. The imaging device geometry was studied. This allows imaging along the length of the tantalum (Ta) absorber, which is 600 nm thick to provide good x-ray absorption. The quasiparticles produced by single photon absorption rapidly cool to the Ta gap, E(sub g_Ta) = 1.4 meV, and then diffuse. They are trapped in the A1 traps at the two ends (E(sub g_A1) = 0.4 meV), to give two charges that tunnel out of the A1 traps, Q(sub 1) and Q(sub 2). The total charge is Q = Q(sub 1) + Q(sub 2). This lateral trapping is what allows imaging.

Prober, Daniel↗
DOE OSTI2021

Prediction of Bi 2 Te 3 -Sb 2 Te 3 Interfacial Conductance and Superlattice Thermal Conductivity Using Molecular Dynamics Simulations

Bismuth telluride (Bi 2 Te 3 ) and its alloys with antimony telluride (Sb 2 Te 3 ) have long been considered to be the best room-temperature bulk thermoelectric (TE) materials. In recent decades, proof-of-concept demonstrations on Bi 2 Te 3 -Sb 2 Te 3 nanostructures have shown high TE performance due to reduction in lattice thermal conductivities. Particularly, ultra-low thermal conductivities have been observed in Bi 2 Te 3 -Sb 2 Te 3 1D superlattices, leading to thermoelectric figures of merit (ZT) as high as 2.4. In contrast, very few computational studies have been performed to provide insight into the phonon transport across these nanostructures. In this work, we use non-equilibrium molecular dynamics simulations with previously developed force fields to simulate thermal transport across Bi 2 Te 3 -Sb 2 Te 3 interfaces and superlattices. We first calculate the thermal conductance associated with a Bi 2 Te 3 -Sb 2 Te 3 interface across a temperature range of 200–400 K. Furthermore, the values are also compared with thermal conductances calculated by a modified Landauer transport formalism using phonon transmission coefficients obtained from the diffuse mismatch model. Our results show that inelastic scattering processes contribute to an increase in interfacial thermal conductance at higher temperatures. Finally, we calculate the thermal conductivities of Bi 2 Te 3 -Sb 2 Te 3 superlattices with varying period lengths from 2 to 18 nm. A minimum thermal conductivity of 0.27 W/mK is observed at a period length of 4 nm, which is attributed to the competition between incoherent and coherent phonon transport regimes. In comparison with previous experimental measurements in the literature, our results show good agreement with respect to the range of thermal conductivity values and the period length corresponding to the minimum superlattice thermal conductivity.

42 ENGINEERING↗
NASA NTRS1990

On the possibility of an alpha-sq omega-type dynamo in a thin layer inside the sun

If the solar dynamo operates in a thin layer of 10,000-km thickness at the interface between the convection zone and the radiative core, using the facts that the dynamo should have a period of 22 years and a half-wavelength of 40 deg in the theta-direction, it is possible to impose restrictions on the values which various dynamo parameters are allowed to have. It is pointed out that the dynamo should be of alpha-sq omega nature, and kinematical calculations are presented for free dynamo waves and for dynamos in thin rectangular slabs with appropriate boundary conditions. An alpha-sq omega dynamo is expected to produce a significant poloidal field which does not leak to the solar surface. It is found that the turbulent diffusity eta and alpha-coefficient are restricted to values within about a factor of 10, the median values being eta of about 10 to the 10th sq cm/sec and alpha of about 10 cm/sec. On the basis of mixing length theory, it is pointed out that such values imply a reasonable turbulent velocity of the order 30 m/s, but rather small turbulent length scales like 300 km.

Choudhuri, Arnab Rai↗
NASA NTRS1993

Wind tunnel investigation of three axisymmetric cowls of different lengths at Mach numbers from 0.60 to 0.92

Pressure distributions on three inlets having different cowl lengths were obtained in the Langley 16-Foot Transonic Tunnel. The cowl diameter ratio (highlight diameter to maximum diameter) was 0.85 and the cowl length ratios (cowl length to maximum diameter) were 0.337, 0.439, and 0.547. The cowls had identical nondimensionalized (with respect to cowl length) external geometry and identical internal geometry. The internal contraction ratio (highlight area to throat area) was 1.250. The inlets had longitudinal rows of static pressure orifices on the top and bottom (external) surfaces and on the contraction (internal) and diffuser surfaces. The afterbody was cylindrical in shape, and its diameter was equal to the maximum diameter of the cowl. Depending on the cowl configuration and free-stream Mach number, the mass-flow ratio varied between 0.27 and 0.87 during the tests. Angle of attack varied from 0 to 4.1 deg at selected Mach numbers and mass-flow ratios, and the Reynolds number varied with the Mach number from 3.2x10(exp 6) to 4.2x10(exp 6) per foot.

Re, Richard J.↗
DOE OSTI2022

Models to Incorporate Reaction Mechanisms into DG-OSPREY: Fixed-Bed Simulations for Organic Iodides Capture Using Ag 0 Z

As one of the most potent radioisotopes released during spent nuclear fuel reprocessing, 129 I is strictly regulated and must be removed before discharge. Organic iodides (primarily alkyl iodides with different chain lengths, i.e., CH 3 I, C 4 H 9 I, and C 12 H 25 I) comprise ~2% of the total iodine in the reprocessing off-gases and are primarily present in vessel off-gas (VOG). Reduced silver mordenite (Ag 0 Z) is predominantly considered for the removal of radioiodine; however, its capture performance and underlying interaction processes with long-chain organic iodides are not fully understood. Two major tasks were accomplished in this study. First, to improve upon the previous experimental studies where Ag 0 Z was used to capture CH 3 I, C 4 H 9 I, and C 12 H 25 I at different concentrations, we comprehensively investigated the corresponding capture mechanisms by characterizing fully loaded Ag 0 Z samples. Second, computational codes were implemented to perform fixed-bed simulations that account for transport and reaction mechanisms. Scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), powder X-ray diffraction (PXRD), UV-visible diffuse reflectance spectroscopy (UV-vis DRS), and thermogravimetric analysis (TGA) were conducted on Ag 0 Z samples that are saturated with I 2 , CH 3 I, C 4 H 9 I, and C 12 H 25 I), respectively. Results indicate that AgI is the predominant adsorption product regardless of the adsorbed iodine species, yet alkyl iodides with different carbon chain lengths may have different compositions of α- and γ-AgI. Synchrotron pair distribution function (PDF) measurements and TGA coupled with a Fourier transformed infrared detector (TGA FTIR) have been performed, and experimental data are currently analyzed. Results are expected to provide further insights into the adsorption mechanisms. The fixed-bed capture performance for CH 3 I was successfully simulated by solving mathematical equations that describe the underlying transport processes and adsorption reactions. The computational framework, Catalytic After Treatment System (CATS), that was originated in our research group, was used to solve the governing equations. Kinetic parameters, including the pore diffusivity and reaction rate constant were obtained by optimization techniques using data from thin-bed experiments performed at Oak Ridge National Laboratory. The performance of a deep bed predicted using the optimized parameters showed promising agreement with the experimental data.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1999

Experimental Observations on a Low Strain Counter-Flow Diffusion Flame: Flow and Bouyancy Effects

Diffusion flames are of great interest in fire safety and many industrial processes. The counter-flow configuration provides a constant strain flow, and therefore is ideal to study the structure of diffusion flames. Most studies have concentrated on the high velocity, high strain limit, since buoyantly induced instabilities will disintegrate the planar flame as the velocity decreases. Only recently, experimental studies in microgravity conditions have begun to explore the low strain regimes. Numerical work has shown the coupling between gas phase reaction rates, soot reaction rates, and radiation. For these programs, size, geometry and experimental conditions have been chosen to keep the flame unaffected by the physical boundaries. When the physical boundaries can not be considered infinitely far from the reaction zone discrepancies arise. A computational study that includes boundary effects and accounts for the deviations occurring when the major potential flow assumptions are relaxed was presented by Borlik et al. This development properly incorporates all heat loss terms and shows the possibility of extinction in the low strain regime. A major constraint of studying the low strain regime is buoyancy. Buoyant instabilities have been shown to have a significant effect on the nature of reactants and heat transport, and can introduce instabilities on the flow that result in phenomena such as flickering or fingering. The counter-flow configuration has been shown to provide a flame with no symmetry disrupting instabilities for inlet velocities greater than 50 mm/s. As the velocity approaches this limit, the characteristic length of the experiment has to be reduced to a few millimetres so as to keep the Rayleigh number (Ra L = (β g 0 L 3 ∆T)/(𝑎v)) below 2000. In this work, a rectangular counter-flow burner was used to study a two-dimensional counter-flow diffusion flame. Flow visualisation and Particle Image Velocimetry served to describe the nature of the stagnation plane for strain rates smaller than 100 (1/s). These experiments were conducted with a non-reacting flow. Video images of a propane air diffusion flame were used to describe the behaviour of a diffusion flame in this regime. Flame geometry and pulsation frequency are described.

J. A. Sutula↗
DOE OSTI2024

A Pseudo‐Surfactant Chemical Permeation Enhancer to Treat Otitis Media via Sustained Transtympanic Delivery of Antibiotics

Abstract Chemical permeation enhancers (CPEs) represent a prevalent and safe strategy to enable noninvasive drug delivery across skin‐like biological barriers such as the tympanic membrane (TM). While most existing CPEs interact strongly with the lipid bilayers in the stratum corneum to create defects as diffusion paths, their interactions with the delivery system, such as polymers forming a hydrogel, can compromise gelation, formulation stability, and drug diffusion. To overcome this challenge, differing interactions between CPEs and the hydrogel system are explored, especially those with sodium dodecyl sulfate (SDS), an ionic surfactant and a common CPE, and those with methyl laurate (ML), a nonionic counterpart with a similar length alkyl chain. Notably, the use of ML effectively decouples permeation enhancement from gelation, enabling sustained delivery across TMs to treat acute otitis media (AOM), which is not possible with the use of SDS. Ciprofloxacin and ML are shown to form a pseudo‐surfactant that significantly boosts transtympanic permeation. The middle ear ciprofloxacin concentration is increased by 70‐fold in vivo in a chinchilla AOM model, yielding superior efficacy and biocompatibility than the previous highest‐performing formulation. Beyond improved efficacy and biocompatibility, this single‐CPE formulation significantly accelerates its progression toward clinical deployment.

Engineering↗
NASA NTRS1963

Heat Transfer in Annular Passages - Hydrodynamically Developed Turbulent Flow with Arbitrarily Prescribed Heat Flux

The problem of turbulent flow heat transfer in a concentric circular tube annulus with fully developed velocity profile and constant heat rate per unit of length is considered. Experimentally obtained solutions are presented for the thermal entry length for a fluid with P(sub r) = 0·7. Asymptotic solutions (fully developed velocity and temperature profiles) are developed for a wide range of radius ratio, Reynolds number, and Prandtl number. The solutions are based on empirical velocity and eddy diffusivity profiles, and the validity of the solutions is demonstrated experimentally for P(sub r) = 0·7. A superposition method is demonstrated for solving the problem of asymmetric heating from the two surfaces of an annulus, and experimental data on asymmetric heating are presented which are in excellent agreement with the analysis. This paper is the third in a series (1, 2) culminating a four year study of heat transfer in annular passages.

Kays, W. M.↗
DOE OSTI2025

Chromium-doped uranium dioxide fuels: A review

UO 2 doped with parts per million CR 2 O 3 powder is considered a potential near term accident tolerant fuel candidate. Here, the results of decades of industry and academic research into Cr-doped UO 2 are analyzed and their shortcomings are critiqued. Focusing on the incorporation mechanisms of Cr into the fuel matrix, we explore a mechanistic understanding of the characteristic properties of Cr-doped UO 2 , notably, enhanced fission gas retention attributed to enlarged grain sizes following sintering, along with marginal improvements in the thermophysical properties. The findings of recent X-ray Adsorption Near Edge Spectroscopy studies were compared and put into conversation with historic data regarding the incorporation of Cr in UO 2 . On the basis of defect mechanisms, the case is made for the substitutional incorporation of Cr governing the lattice solubility but not the enhanced U diffusivity. Instead, Cr/CR 2 O 3 redox chemistry in a well-defined oxygen potential explains the differences in the U diffusivity and O/M ratio. The primary mechanism of doping enhanced grain growth is found to be liquid assisted sintering due to a CRO (1) eutectic phase at the grain boundaries. The role of inhomogeneities in Cr concentration in UO 2 at various length scales across the materials microstructure is highlighted and connected to promising experimental and modeling work to fill in the gaps in the current understanding of Cr-doped UO 2 . The review considers both the open scientific questions and engineering applications to illustrate the deep connections between the practice and theory in the design of accident tolerant nuclear fuels. In conclusion, the review ends with an outline of future works that combine meticulous irradiation studies and high resolution experiments with next generation modeling and simulations techniques empowered by machine learning advances to accelerate the fabrication and adoption of Cr-doped UO 2 light water reactors.

Cleveland, Mack Wesley [Massachusetts Inst. of Tec↗