Using all energy in a battery
Controlled electrode structure improves energy utilization [Also see Report by Kirshenbaum et al. ]
25 ENERGY STORAGE↗
SEARCH · Engineering Papers
Results for “control structures”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites
Maximizing the power conversion efficiency (PCE) of perovskite/silicon tandem solar cells that can exceed the Shockley-Queisser single-cell limit requires a high-performing, stable perovskite top cell with a wide bandgap. We developed a stable perovskite solar cell with a bandgap of ~1.7 electron volts that retained more than 80% of its initial PCE of 20.7% after 1000 hours of continuous illumination. Anion engineering of phenethylammonium-based two-dimensional (2D) additives was critical for controlling the structural and electrical properties of the 2D passivation layers based on a lead iodide framework. The high PCE of 26.7% of a monolithic two-terminal wide-bandgap perovskite/silicon tandem solar cell was made possible by the ideal combination of spectral responses of the top and bottom cells.
14 SOLAR ENERGY↗
The role of CenKR in the coordination of Rhodobacter sphaeroides cell elongation and division
ABSTRACT Cell elongation and division are essential aspects of the bacterial life cycle that must be coordinated for viability and replication. The impact of misregulation of these processes is not well understood as these systems are often not amenable to traditional genetic manipulation. Recently, we reported on the CenKR two-component system (TCS) in the Gram-negative bacterium Rhodobacter sphaeroides that is genetically tractable, widely conserved in α-proteobacteria, and directly regulates the expression of components crucial for cell elongation and division, including genes encoding subunit of the Tol-Pal complex. In this work, we show that overexpression of cenK results in cell filamentation and chaining. Using cryo-electron microscopy (cryo-EM) and cryo-electron tomography (cryo-ET), we generated high-resolution two-dimensional (2D) images and three-dimensional (3D) volumes of the cell envelope and division septum of wild-type cells and a cenK overexpression strain finding that these morphological changes stem from defects in outer membrane (OM) and peptidoglycan (PG) constriction. By monitoring the localization of Pal, PG biosynthesis, and the bacterial cytoskeletal proteins MreB and FtsZ, we developed a model for how increased CenKR activity leads to changes in cell elongation and division. This model predicts that increased CenKR activity decreases the mobility of Pal, delaying OM constriction, and ultimately disrupting the midcell positioning of MreB and FtsZ and interfering with the spatial regulation of PG synthesis and remodeling. IMPORTANCE By coordinating cell elongation and division, bacteria maintain their shape, support critical envelope functions, and orchestrate division. Regulatory and assembly systems have been implicated in these processes in some well-studied Gram-negative bacteria. However, we lack information on these processes and their conservation across the bacterial phylogeny. In R. sphaeroides and other α-proteobacteria, CenKR is an essential two-component system (TCS) that regulates the expression of genes known or predicted to function in cell envelope biosynthesis, elongation, and/or division. Here, we leverage unique features of CenKR to understand how increasing its activity impacts cell elongation/division and use antibiotics to identify how modulating the activity of this TCS leads to changes in cell morphology. Our results provide new insight into how CenKR activity controls the structure and function of the bacterial envelope, the localization of cell elongation and division machinery, and cellular processes in organisms with importance in health, host-microbe interactions, and biotechnology.
59 BASIC BIOLOGICAL SCIENCES↗
Transport, Magnetic, and Memristive Properties of a Nanogranular (CoFeB){sub x}(LiNbO{sub y}){sub 100–x} Composite Material
The properties of (CoFeB){sub x}(LiNbO{sub y}){sub 100–x} nanocomposite films with a ferromagnetic alloy content x = 6–48 at % are comprehensively studied. The films are shown to consist of ensembles of CoFe granules 2–4 nm in size, which are strongly elongated (up to 10–15 nm) in the nanocomposite growth direction and are located in an LiNbO{sub y} matrix with a high content of Fe{sup 2+} and Co{sup 2+} magnetic ions (up to 3 × 1022 cm{sup –3}). At T ≤ 25 K, a paramagnetic component of the magnetization of nanocomposites is detected along with a ferromagnetic component, and the contribution of the former component is threefold that of the latter. A hysteresis of the magnetization is observed below the percolation threshold up to x ≈ 33 at %, which indicates the appearance of a superferromagnetic order in the nanocomposites. The temperature dependence of the electrical conductivity of the nanocomposites in the range T ≈ 10–200 K on the metallic side of the metal–insulator transition (44 at % < x < 48 at %) is described by a logarithmic law σ(T) ∝ lnT. This law changes into the law of “1/2” at x ≤ 40 at %. The tunneling anomalous Hall effect is strongly suppressed and the longitudinal conductivity turns out to be lower than in a (CoFeB){sub x}(AlO{sub y}){sub 100–x} composite material by an order of magnitude. The capacitor structures based on (CoFeB){sub x}(LiNbO{sub y}){sub 100–x} films exhibit resistive switching effects. They are related to (i) the formation of isolated chains of elongated granules and an anomalously strong decrease in the resistance in fields E > 10{sup 4} V/cm because of the suppression of Coulomb blockage effects and the generation of oxygen vacancies V{sub O} and (ii) the injection (or extraction) of V{sub O} vacancies (depending on the sign of voltage) into a strongly oxidized layer in the nanocomposites, which is located near an electrode of the structure and controls its resistance. The number of stable resistive switchings exceeds 10{sup 5} at a resistance ratio R{sub off}/R{sub on} ~ 50.
36 MATERIALS SCIENCE↗
The distribution of an electric field in p-n junctions of silicon edgeless detectors
Development of silicon edgeless detectors started in 2004 and was motivated by preparations for the total elastic and diffractive cross-section measurement (TOTEM) experiment at the Large Hadron Collider (LHC) at CERN. In the context of this experiment, it would be necessary to detect protons scattered at ultimately small angles with respect to the LHC proton beam, which brings about a limitation imposed on the maximum distance between the beam and the sensitive region of the detector. In order to solve this problem, a new type of silicon detector (edgeless detectors) was developed; these detectors have the structure, which controls the distribution of the current near the edge of the p-n junction. In this paper we report the results of studying the distribution of the potential and an electric field in the region of the cut edge in the silicon edgeless detectors; the models, which account for the obtained results, as well as their consistency with current-voltage characteristics of silicon edgeless detectors developed for the TOTEM experiment, are discussed.
36 MATERIALS SCIENCE↗
Zinc-oxide-based nanostructured materials for heterostructure solar cells
Results obtained in the deposition of nanostructured zinc-oxide layers by hydrothermal synthesis as the basic method are presented. The possibility of controlling the structure and morphology of the layers is demonstrated. The important role of the procedure employed to form the nucleating layer is noted. The faceted hexagonal nanoprisms obtained are promising for the fabrication of solar cells based on oxide heterostructures, and aluminum-doped zinc-oxide layers with petal morphology, for the deposition of an antireflection layer. The results are compatible and promising for application in flexible electronics.
36 MATERIALS SCIENCE↗
Defect Mode in Microwave Waveguide Bragg Structures with Metal Pins
A waveguide Bragg structure containing equidistant cylindrical pins that are galvanically coupled to a wide wall of the waveguide is used to implement frequency response functions characterized by the presence of a band gap. Characteristics of a defect mode of the microwave photonic crystal with a pin element as a defect with an n–i–p–i–n structure with controlled conductivity placed in the capacitive gap are experimentally studied and calculated. Controlled reflectance of a microwave signal with a dynamic range of greater than 50 dB is obtained at the frequency of the defect mode.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Simulator for Wind Farm Applications (SOWFA) [SWR-14-12]
A modular tool for simulating wind plant aerodynamics with computational fluid dynamics and turbine structural and control response to the incoming flow.
Lee, Sang↗
Geologic Map and Cross Sections of the McGinness Hills Geothermal Area - GIS Data
Geologic map data in shapefile format that includes faults, unit contacts, unit polygons, attitudes of strata and faults, and surficial geothermal features. 5 cross-sections in Adobe Illustrator format. Comprehensive catalogue of drill-hole data in spreadsheet, shapefile, and Geosoft database formats. Includes XYZ locations of well heads, year drilled, type of well, operator, total depths, well path data (deviations), lithology logs, and temperature data. 3D model constructed with EarthVision using geologic map data, cross-sections, drill-hole data, and geophysics.
15 GEOTHERMAL ENERGY↗
Geologic Map of the Neal Hot Springs Geothermal Area - GIS Data
Neal Hot Springs—ESRI Geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, unit polygons, and attitudes of strata and faults. - List of stratigraphic units and stratigraphic correlation diagram. - Three cross‐sections. - Locations of production, injection, and exploration wells. - Locations of 40Ar/39Ar samples. - Location of XRF geochemical samples. - 3D model constructed with EarthVision using geologic map data, cross‐sections, drill‐hole data, and geophysics (model not in the ESRI geodatabase).
15 GEOTHERMAL ENERGY↗
Geologic Map and GID Data for the Salt Wells Geothermal Area
Salt Wells—ESRI Geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, dikes, unit polygons, and attitudes of strata and faults. - List of stratigraphic units and stratigraphic correlation diagram. - Locations of 40Ar/39Ar samples.
15 GEOTHERMAL ENERGY↗
Geologic Map and GIS Data for the Tuscarora Geothermal Area
Tuscarora—ESRI Geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, unit polygons, and attitudes of strata and faults. - List of stratigraphic units and stratigraphic correlation diagram. - Detailed unit descriptions of stratigraphic units. - Five cross‐sections. - Locations of production, injection, and monitor wells. - 3D model constructed with EarthVision using geologic map data, cross‐sections, drill‐hole data, and geophysics (model not in the ESRI geodatabase).
15 GEOTHERMAL ENERGY↗
Geologic Map and GIS Data for the Wabuska Geothermal Area
Wabuska—ESRI geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, veins, dikes, unit polygons, and attitudes of strata. - List of stratigraphic units and stratigraphic correlation diagram. - One cross‐section.
15 GEOTHERMAL ENERGY↗
Regional Slip Tendency Analysis of the Great Basin Region
Slip and dilation tendency on the Great Basin fault surfaces (from the USGS Quaternary Fault Database) were calculated using 3DStress (software produced by Southwest Research Institute). Slip and dilation tendency are both unitless ratios of the resolved stresses applied to the fault plane by the measured ambient stress field. - Values range from a maximum of 1 (a fault plane ideally oriented to slip or dilate under ambient stress conditions) to zero (a fault plane with no potential to slip or dilate). - Slip and dilation tendency values were calculated for each fault in the Great Basin. As dip is unknown for many faults in the USGS Quaternary Fault Database, we made these calculations using the dip for each fault that would yield the maximum slip or dilation tendency. As such, these results should be viewed as maximum slip and dilation tendency. - The resulting along-fault and fault-to-fault variation in slip or dilation potential is a proxy for along-fault and fault-to-fault variation in fluid flow conduit potential. Stress Magnitudes and directions were calculated across the entire Great Basin. Stress field variation within each focus area was approximated based on regional published data and the world stress database (Hickman et al., 2000; Hickman et al., 1998 Robertson-Tait et al., 2004; Hickman and Davatzes, 2010; Davatzes and Hickman, 2006; Blake and Davatzes 2011; Blake and Davatzes, 2012; Moeck et al., 2010; Moos and Ronne, 2010 and Reinecker et al., 2005). The minimum horizontal stress direction (Shmin) was contoured, and spatial bins with common Shmin directions were calculated. Based on this technique, we subdivided the Great Basin into nine regions (Shmin
15 GEOTHERMAL ENERGY↗
Multiscale approaches for optimizing the impact of strain on Na-ion battery cycle life
Abstract The high costs and geopolitical challenges inherent to the lithium-ion (Li-ion) battery supply chain have driven a rising interest in the development of sodium-ion (Na-ion) batteries as a potential alternative. Unfortunately, the larger ionic radius of Na limits the reversibility of cycling because of the extensive atomic rearrangements that accompany Na-ion insertion, which in turn limit diffusion and charging speed, and lead to rapid degradation of the electrodes. The Center for Strain Optimization for Renewable Energy (STORE) was established to address these challenges and develop new electrode materials for Na-ion cells. This article discusses the current state-of-the-art materials used in Na-ion cells and several directions that STORE believes are critical to understand and control the structural and volumetric changes during the reversible (de)insertion of large cations. Graphical abstract Highlights Understanding the fundamental way materials respond to localized strains at the atomic length-scale is a critical first step in the development of highly reversible, long cycle life, Na-ion insertion hosts. This perspective explores a variety of methods that can be employed to mitigate the detrimental effects of large strain. The insights gained from these investigations should help lay the foundation for the creation of more economical and sustainable batteries that could have immediate impact on global energy infrastructure. Discussion Although there is near universal agreement that electrochemical energy storage must be an integral part of a green-energy future, there is less agreement about how to reduce the cost of energy storage. Replacing high-cost lithium-ion cells with lower-cost sodium-ion batteries is one option frequently considered in future energy models, but the details of what can be achieve with optimized sodium cell performance remains unclear. Here we posit that developing methods to mitigating strain on the electrode particle length scale is a key factor for achieving long-cycle-life sodium-ion batteries. Mitigating strain on the atomic scale suppress electrode-level volume change. Allowing for fast cycling in materials without the problems of electrode cracking or delamination. We further posit that understanding volume change in sodium-ion electrodes at a fundamental level will lead to the designing new sodium-ion electrode materials that will allow for efficient, stable, lower-cost energy storage.
Brady, Michael J.↗
Real-Time Longitudinal Profile Measurement of Operational Hâ» Beam at the SNS Linac Using a Laser Comb
We demonstrate a novel technique to measure the longitudinal profile of an operational hydrogen ion (Hâ») beam in a non intrusive, real-time fashion. The measurement is conducted based on the photo-ionization of the ion beam with a phase modulated laser comb pico-second laser pulses with controllable temporal structure. The measurement technique has been applied to a 1-GeV, 1.4-MW Hâ» beam at the Spallation Neutron Source (SNS) high energy beam transport (HEBT). A stroboscopic photo-graph of Hâ» beamμbunch can be obtained by using a phase modulated laser comb. The entire measurement takes only 700 us.
Liu, Yun↗
A New Method for Grain Texture Manipulation in Post-Deposition Niobium Films
Niobium films are frequently grown using forms of energetic condensation, with modest substrate temperatures to control grain structure. As an alternative, energetic deposition onto a cold substrate results in a dense amorphous film, with a much larger energy density than the re-crystallized state. Re-crystallization is then performed using a pulsed UV (HIPPO) laser, with minimal damage to the substrate. In addition, a graded interface between the substrate and Nb film is created during the early stages of energetic deposition. Experimental approach and apparatus are described.
Musson, J.↗
Offshore Renewable Energy R&D (Fact Sheet)
This fact sheet describes the offshore renewable energy R&D efforts at NREL's NWTC. As the United States increases its efforts to tap the domestic energy sources needed to diversify its energy portfolio and secure its energy supply, more attention is being focused on the rich renewable resources located offshore. Offshore renewable energy sources include offshore wind, waves, tidal currents, ocean and river currents, and ocean thermal gradients. According to a report published by the National Renewable Energy Laboratory (NREL) in 2010,1 U.S. offshore wind resources have a gross potential generating capacity four times greater than the nation's present electric capacity, and the Electric Power Research Institute estimates that the nation's ocean energy resources could ultimately supply at least 10% of its electric supply. For more than 30 years, NREL has advanced the science of renewable energy while building the capabilities to guide rapid deployment of commercial applications. Since 1993, NREL's National Wind Technology Center (NWTC) has been the nation's premier wind energy research facility, specializing in the advancement of wind technologies that range in size from a kilowatt to several megawatts. For more than 8 years, the NWTC has been an international leader in the field of offshore floating wind system analysis. Today, researchers at the NWTC are taking their decades of experience and extensive capabilities and applying them to help industry develop cost-effective hydrokinetic systems that convert the kinetic energy in water to provide power for our nation's heavily populated coastal regions. The center's capabilities and experience cover a wide spectrum of wind and water energy engineering disciplines, including atmospheric and ocean fluid mechanics, aerodynamics; aeroacoustics, hydrodynamics, structural dynamics, control systems, electrical systems, and testing.
14 SOLAR ENERGY↗