Results for “continuous flow” — Page 53

NASA NTRSDate not supplied

In-Lab Rapid Analytical Detection of Lunar Volatiles By Universal Gas Analyzer With Comparison to GC-MS System

Introduction: The curation of permanently shadowed regions (PSRs) [1] on the lunar surface is centered around studies based upon the observed volatiles from the LCROSS mission [2]. The rapid detection of important volatile gases and vapors present in planetary bodies and Astromaterials by a standalone analytical device is an area of intense research interest in our group and Planetary Exploration & Astromaterials Research Laboratory (PEARL) facility and this work is relevant to the future preparation of viable lunar simulants for testing curation efforts down the road. The groundbreaking results obtained from the LCROSS Mission [2] open the requirements for the direct detection of volatiles present in regolith materials collected from the lunar surface. The mass spectrometry of volatile chemicals is a general technique that utilizes a set of instruments that creates charged ions from a gaseous chemical species and measures the intensities vs. mass-to-charge ratio (m/z) [3]. In this context, we discuss in-lab experimental results and procedures for rapid qualitative analysis of main LCROSS volatiles (water, H2S, NH3, CO2, and CH3OH) by a Universal Gas Analyzer (UGA) instrument. Additionally, the instrument performance was evaluated by measuring the isotopic abundance ratio of atmospheric Ar-40 to Ar-36 present in room air since, argon is a relevant gas in planetary studies as it can provide an insight and reference point to isotope studies [4]. Additional, cross comparisons were attempted and made between the two instruments to develop a robust analytical technique by comparing mass spectral data for H2S headspace samples with a Trace-1310/ ISQ 7000 (ThermoFisher Scientific.) GC-MS system. Background: The benchtop UGA System is equipped with an SRS UGA 300 quadrupole mass spectrometer designed and built by Stanford Research Systems [5]. This system can be configured for several types of gaseous chemical analysis. The inlet line continuously samples gases at low flow rates (several milliliters per minute) through a capillary limiting the intake pressure making the instrument ideal for online analysis of select gases and/or room atmosphere. Moreover, in our current UGA system, a change in composition at the inlet can be detected in about 200 milliseconds and a complete spectrum is acquired (for a range of 1-100 amu) in under 45 sec with masses measured at rates up to 25 msec per point [5]. This system provides a quick upstream analytical data that we can then compare to results obtained by our GC-MS system. Sample Preparation: Small volume (2-4 mL) of analyte sample was taken in a 10 mL glass vial and sealed with a crimped cap and purged with pure Ar or N2 gas to displace air from the top. The headspace sample was scanned by the UGA instrument at analog, histogram, and pressure vs. time modes. The isotopic abundance ratio for 40Ar-to-36Ar was estimated by measuring partial pressure vs. time scans and setting the mass at 40 and 36 respectively. Results and Discussions: In this work, we have investigated the applicability of the UGA system by qualitative analysis of a series of LCROSS volatiles measured individually. Fig. 1 demonstrates a set of vertically offset spectra for the partial pressures measured as a function of mass-to-charge (m/z) ratios. The average acquisition time for each spectrum was less than a minute suggesting that the UGA system is ideal for quick analysis of geochemical volatiles. For the cross-comparison, we analyzed an H2S headspace sample by a Trace-1310/ISQ-7000 system and compared mass spectral data with previously measured UGA histogram scan data (Fig. 2). In both cases, major peak positions are the same, however, the intensities of fragment ions ([1H132S]+ and [32S]+) are higher for UGA suggesting that the fragment ionization process is stronger in UGA compared to that of GC-MS. To investigate how the integrated area under each chromatogram varies with the headspace sample volume, a set of five H2S headspace samples with increasing volumes was analyzed by the GC-MS system (Fig. 3, inset). A small volume (e.g., 200 to 1000 µL) of H2S/H2O vapor was withdrawn from a 20 mL stock sample vial containing ~5 mL of 0.4% H2S in water by a gas-tight syringe and added to another 20 mL vial filled with argon and analyzed by the GC-MS system. Finally, the UGA detector sensitivity was evaluated by calculating the atmospheric 40Ar-to-36Ar isotopic abundance ratio in room air by running a partial pressure vs. time scan with setting the atomic mass at 40, and 36. Fig. 4(a) shows a ~25 min duration “P vs. time” scan for 40Ar (plot for 36Ar is not shown). The partial pressure values (~100 points) were corrected by subtracting the corresponding background pressure value for 37Ar and utilized to calculate 40Ar-to-36Ar isotopic abundance ratios as shown by Fig. 4b. The average isotopic abundance ratio is ~306 with a 2*STDEV ~13. This abundance ratio is significantly close to the previously reported value of 298.56 [6] and the ratio obtained by our GC-MS system (303 for a UHP grade Ar sample). Conclusions: Our study strongly evidenced that the benchtop UGA system is a valuable analytical tool for the detection of major LCROSS volatiles. The rapid scanning capability, the inexpensiveness of the whole system, and impressive detection sensitivity prove its worthiness as an essential device for advanced geochemical applications. Moreover, cross comparisons with the GC-MS provide important bridges into advanced curatorial efforts into the future. References: [1] Bickel, V.T., et al. (2021) Nat Commun 12, 5607. [2] Colaprete, A., et al. (2010) Science, 330, 463-468. [3] Glavin, D. P. et al. (2012) 2012 IEEE Aerospace Conference, 1-11. [4] Willett, C. D., et al. (2022) Geochimica et Cosmochimica Acta 329, 119-134. [5] Operation Manual and Programming Reference. (2018) Universal gas Analyzers, Stanford Research Systems. [6] Lee, J. Y., et al. (2006) Geochimica et Cosmochimica Acta 70, 4507–4512. Notes: (4 figures are attached with text as shown by the attached file)

Curation↗

NASA NTRS1976

A theoretical study of the acoustic impedance of orifices in the presence of a steady grazing flow

Oscillatory fluid flow in the vicinity of a circular orifice with a steady grazing flow is analyzed. A simplified system of partial differential equations is obtained by starting with the momentum and continuity equations and by assuming that the flow can be represented as an oscillatory motion superimposed on the (known) steady flow. It is found that the equations are linear in the region where grazing-flow effects dominate; a solution and the resultant orifice impedance are given for this region. It is tentatively concluded that orifice resistance is directly proportional to grazing-flow velocity and that the orifice inductive end correction is not a function of grazing flow.

Rice, E. J.↗

NASA NTRS1981

Magnetic fields on the Sun

Synoptic observations of solar magnetic fields are discussed. Seen in long-term averages, the magnetic fields of the Sun show distinctive behavior. The active-region latitudes are characterized by magnetic fields of preceding polarity. The flow of following polarity fields to make up the polar fields is episodic, not continuous. This field motion is a directed poleward flow and is not due to diffusion. The total magnetic flux on the solar surface, which is related linearly to the calcium emission in integrated sunlight, varies from activity minimum to maximum by a factor of 2 or 3. Nearly all this flux is seen at active-region latitudes-only about 1% is at the poles. The total flux of the Sun disappears from the surface at a very rapid rate and is replaced by new flux. All the field and flux patterns that we see originate in active-region latitudes. The polar magnetic fields of the Sun were observed to change polarity recently. The variations of the full-disk solar flux are shown to lead to the proper rotation rate of the Sun, but the phase of the variations is constant for only a year or two at most.

Howard, R.↗

NASA NTRS1992

LV software for supersonic flow analysis

The NASA Lewis Research Center (LeRC) maintains a leadership position in research into advanced aerospace propulsion systems. For the next generation of aircraft, engine designs continue to involve complex, high-speed flows. Performing the detailed flow diagnostics to properly evaluate these designs requires advanced instrumentation to probe these highly turbulent flows. The hostile flow environment often requires nonintrusive measurement techniques such as the laser velocimeter (LV). Since the LV is a proven instrument for nonintrusive flow measurement, it can provide quantitative velocity data with minimal interference to the flow. Based on anticipated flow conditions, laser velocimeter systems were procured from TSI, Inc. The initial system utilized counter processor technology, but later procurements this past year include a more advanced, correlator-based processor, which significantly improves the overall LV performance. To meet the needs of advanced research into propulsion, this instrument must be integrated into an existing VAX/VMS computer system for data acquisition, processing, and presentation. The work done under this grant before this period concentrated on developing the software required to setup and acquire data from the TSI MI-990 multichannel interface, and the RMR 1989 rotating machinery resolver. With the basis established for controlling the operation of the LV system, software development this past year shifted in emphasis from instrumentation control and data acquisition to data analysis and presentation. The progress of the program is reported.

Bell, William A.↗

NASA NTRS1978

LSSA large area silicon sheet task continuous Czochralski process development

A Czochralski crystal growing furnace was converted to a continuous growth facility by installation of a premelter to provide molten silicon flow into the primary crucible. The basic furnace is operational and several trial crystals were grown in the batch mode. Numerous premelter configurations were tested both in laboratory-scale equipment as well as in the actual furnace. The best arrangement tested to date is a vertical, cylindrical graphite heater containing small fused silicon test tube liner in which the incoming silicon is melted and flows into the primary crucible. Economic modeling of the continuous Czochralski process indicates that for 10 cm diameter crystal, 100 kg furnace runs of four or five crystals each are near-optimal. Costs tend to asymptote at the 100 kg level so little additional cost improvement occurs at larger runs. For these conditions, crystal cost in equivalent wafer area of around $20/sq m exclusive of polysilicon and slicing was obtained.

Rea, S. N.↗

NASA NTRS1987

Compressible flow in a diffusing S-duct with flow separation

Local flow velocity vectors, as well as static and total pressures along ten radial traverses, were obtained at six stations for secondary flows in a diffusing 30-30-deg S-duct with circular cross section. The strong secondary flow measured in the first bend continued into the second with new vorticity produced in the opposite direction. Contour plots representing the transverse velocity field, as well as total and static pressure contours, have been obtained. As a result of the secondary flow and subsequent separation, substantial total pressure distortion is noted to occur at the duct exit.

Vakili, A. D.↗

DOE OSTI2021

Geometric Optimization of an Electrochemical Purification Cell to Prevent Corrosion in CSP Plants During Operation

When exposed to moisture or oxygen, molten chloride salts produce corrosive impurities which degrade containment alloys. As a result, this can significantly decrease the lifetime and increase costs of molten-salt-based systems. To overcome this barrier, we designed and modeled an electrochemical purification cell to remove the corrosive impurity MgOH+. Various reactor architectures, including constant stirred tank reactors (CSTRs) and plug flow reactors (PFRs) were investigated. Steady-state thermoelectric properties were evaluated, allowing assessment of the effects of structure and design parameters such as flow rate, cell length, and cross-sectional area of molten salt. The results suggest that our design could most effectively increase reliability and decrease costs of molten-chloride-salt-based systems by protecting them during continuous operation using an annular plug flow reactor.

chloride salts↗

NASA NTRS2021

A Computational Analysis of Boundary Layer Instability over the BOLT Configuration

The complex boundary layer flow over the BOLT flight configuration is known to exhibit multiple and potentially interacting instability mechanisms. This paper represents a continuation of our numerical investigation of the flow instabilities over the main test surface of the BOLT configuration by using state-of-the-art tools in multidimensional instability analysis. Specifically, the paper extends our previous computations by considering the separate effects of a nonzero angle-of-attack and a nonzero yaw on the modal instability characteristics of the boundary layer streaks adjacent to the minor-axis symmetry plane. At a selected condition from the ascent part of the anticipated flight trajectory, either type of departure from the design condition is shown to have a considerable impact on the structure of the laminar basic state and, hence, also on the amplification characteristics of the instability waves. A broader set of computations, including N-factor predictions for the relevant instabilities, will be presented in the final paper.

Boundary layer transition↗

NASA NTRS2021

A Computational Analysis of Boundary Layer Instability over the BOLT Configuration

The complex boundary layer flow over the BOLT flight configuration is known to exhibit multiple and potentially interacting instability mechanisms. This paper represents a continuation of our numerical investigation of the flow instabilities over the main test surface of the BOLT configuration by using state-of-the-art tools in multidimensional instability analysis. Specifically, the paper extends our previous computations by considering the separate effects of a nonzero angle of attack and a nonzero yaw on the modal instability characteristics of the boundary layer streaks adjacent to the minor-axis symmetry plane, specifically near both ends of the azimuthal region of a thick boundary layer in the middle, where this region rapidly changes to a thinner boundary layer on either side. At the t = 28.8767 s condition from the ascent part of the anticipated flight trajectory with a flight Mach number of M ∞ = 5.53 and unit Reynolds number of 4.25 x 10 6 /m, either type of departure from the design condition is shown to have a considerable impact on the structure of the basic state rollup within the region of interest and, hence, also on the amplification characteristics of instability waves within the resulting streaks. Yet, for a yaw angle of β = 4 degrees, the computations indicate only a slight reduction with respect to the peak N-factor of nearly 11 at the design condition of zero degrees yaw and zero degrees angle of attack. In contrast, an angle of attack equal to α = 4 degrees, the peak N-factor decreases to nearly 6 on the leeward side and increases above 16 on the windward side, making the onset of transition highly likely on the windward side. Computations also highlight the role of streak instabilities that originate as Mack mode disturbances and also demonstrate the potential pitfalls in using surface pressure sensors alone to gauge the magnitude of instability amplification.

Boundary layer transition↗

NASA NTRS2021

A Computational Analysis of Boundary Layer Instability over the BOLT Configuration (Effect of Nonzero AoA and Yaw)

The complex boundary layer flow over the BOLT flight configuration is known to exhibit multiple and potentially interacting instability mechanisms. This paper represents a continuation of our numerical investigation of the flow instabilities over the main test surface of the BOLT configuration by using state-of-the-art tools in multidimensional instability analysis. Specifically, the paper extends our previous computations by considering the separate effects of a nonzero angle of attack and a nonzero yaw on the modal instability characteristics of the boundary layer streaks adjacent to the minor-axis symmetry plane, specifically near both ends of the azimuthal region of a thick boundary layer in the middle, where this region rapidly changes to a thinner boundary layer on either side. At the t = 28.8767 s condition from the ascent part of the anticipated flight trajectory with a flight Mach number of M ∞ = 5.53 and unit Reynolds number of 4.25 x 10 6 /m, either type of departure from the design condition is shown to have a considerable impact on the structure of the basic state rollup within the region of interest and, hence, also on the amplification characteristics of instability waves within the resulting streaks. Yet, for a yaw angle of β = 4 degrees, the computations indicate only a slight reduction with respect to the peak N-factor of nearly 11 at the design condition of zero degrees yaw and zero degrees angle of attack. In contrast, an angle of attack equal to α = 4 degrees, the peak N-factor decreases to nearly 6 on the leeward side and increases above 16 on the windward side, making the onset of transition highly likely on the windward side. Computations also highlight the role of streak instabilities that originate as Mack mode disturbances and also demonstrate the potential pitfalls in using surface pressure sensors alone to gauge the magnitude of instability amplification.

Boundary layer transition↗

NASA NTRS1981

Combined single-pulse holography and time-resolved laser schlieren for flow visualization

A pulsed ruby laser and continuous-wave argon ion laser were used in a combined setup at the Langley Expansion Tube for single pulse holography and time resolved laser schlieren with a common optical axis. The systems can be operated simultaneously for a single run. For a single frame, the pulsed holographic setup offers the options of shadowgraph, Schlieren, and interferometry from the reconstructed hologram as well as the advantage of post-run sensitivity adjustments. For flow establishment studies the time resolved laser Schlieren provides visualization of the flow field every 12.5 microns for up to 80 frames with an exposure time per frame of 5.4 microns.

Burner, A. W.↗

NASA NTRS1983

Development of a multiple-parameter nonlinear perturbation procedure for transonic turbomachinery flows: Preliminary application to design/optimization problems

An investigation was conducted to continue the development of perturbation procedures and associated computational codes for rapidly determining approximations to nonlinear flow solutions, with the purpose of establishing a method for minimizing computational requirements associated with parametric design studies of transonic flows in turbomachines. The results reported here concern the extension of the previously developed successful method for single parameter perturbations to simultaneous multiple-parameter perturbations, and the preliminary application of the multiple-parameter procedure in combination with an optimization method to blade design/optimization problem. In order to provide as severe a test as possible of the method, attention is focused in particular on transonic flows which are highly supercritical. Flows past both isolated blades and compressor cascades, involving simultaneous changes in both flow and geometric parameters, are considered. Comparisons with the corresponding exact nonlinear solutions display remarkable accuracy and range of validity, in direct correspondence with previous results for single-parameter perturbations.

Stahara, S. S.↗

DOE OSTI2024

Fluid flow and solute transport simulations in tight geologic formations: Discrete fracture network and continuous time random walk analyses

Not provided.

Engineering↗

DOE OSTI2022

Predictive Large-Eddy Simulation of Supercritical-Pressure Reactive Flows in the Cold Ignition Regime

This report describes a one-year study performed under DOE sponsorship, continuing the investigation of high-pressure turbulent reactive flows. The interest is in the effect of the chemical species distribution in high-pressure turbulent flows in the presence of strong temperature gradients as would occur during reactions in realistic flows. The prime example of such flows are boundary layers in which the wall is at a lower temperature than that of the fluid, as would be the case in Diesel engines. Previous DOE BES work in the program further highlighted the importance of the boundary layer as a configuration for fundamental studies: soot formation in boundary layers is still a problem poorly understood and depends on the availability of particular chemical species at that location, and when boundary layer Large Eddy Simulations results were compared with measurements, the agreement was unfavorable, showing that this important ‘unit’ problem is not well understood. To understand this unit problem, modeling and Direct Numerical Simulations of this unit problem were conducted for the simplest possible multispecies system, that is a binary-species system. The results discovered a new phenomenon, that is, Soret effect induced uphill diffusion. The far-reaching implication is that through an imposed wall/fluid temperature difference it is possible to control the distribution of the species in the boundary layer. Because the results have been documented in one paper published in the refereed literature, and also in conference papers, this final report is in the form of an Executive Summary succinctly describing the results and putting them in perspective with respect to existing information. The refereed and conference papers published are individually listed as Appendices and attached to this report. One manuscript is still in progress and is thus not listed.

74 ATOMIC AND MOLECULAR PHYSICS↗

NASA NTRS2003

Flow-dependent regulation of endothelial nitric oxide synthase: role of protein kinases

Vascular endothelial cells are directly and continuously exposed to fluid shear stress generated by blood flow. Shear stress regulates endothelial structure and function by controlling expression of mechanosensitive genes and production of vasoactive factors such as nitric oxide (NO). Though it is well known that shear stress stimulates NO production from endothelial nitric oxide synthase (eNOS), the underlying molecular mechanisms remain unclear and controversial. Shear-induced production of NO involves Ca2+/calmodulin-independent mechanisms, including phosphorylation of eNOS at several sites and its interaction with other proteins, including caveolin and heat shock protein-90. There have been conflicting results as to which protein kinases-protein kinase A, protein kinase B (Akt), other Ser/Thr protein kinases, or tyrosine kinases-are responsible for shear-dependent eNOS regulation. The functional significance of each phosphorylation site is still unclear. We have attempted to summarize the current status of understanding in shear-dependent eNOS regulation.

Non-NASA Center↗

NASA NTRS2012

Flow Analysis Tool White Paper

Faster networks are continually being built to accommodate larger data transfers. While it is intuitive to think that implementing faster networks will result in higher throughput rates, this is often not the case. There are many elements involved in data transfer, many of which are beyond the scope of the network itself. Although networks may get bigger and support faster technologies, the presence of other legacy components, such as older application software or kernel parameters, can often cause bottlenecks. Engineers must be able to identify when data flows are reaching a bottleneck that is not imposed by the network and then troubleshoot it using the tools available to them. The current best practice is to collect as much information as possible on the network traffic flows so that analysis is quick and easy. Unfortunately, no single method of collecting this information can sufficiently capture the whole endto- end picture. This becomes even more of a hurdle when large, multi-user systems are involved. In order to capture all the necessary information, multiple data sources are required. This paper presents a method for developing a flow analysis tool to effectively collect network flow data from multiple sources and provide that information to engineers in a clear, concise way for analysis. The purpose of this method is to collect enough information to quickly (and automatically) identify poorly performing flows along with the cause of the problem. The method involves the development of a set of database tables that can be populated with flow data from multiple sources, along with an easyto- use, web-based front-end interface to help network engineers access, organize, analyze, and manage all the information.

Boscia, Nichole K.↗

NASA NTRS1977

High power gas laser - Applications and future developments

Fast flow can be used to create the population inversion required for lasing action, or can be used to improve laser operation, for example by the removal of waste heat. It is pointed out that at the present time all lasers which are capable of continuous high-average power employ flow as an indispensable aspect of operation. High power laser systems are discussed, taking into account the gasdynamic laser, the HF supersonic diffusion laser, and electric discharge lasers. Aerodynamics and high power lasers are considered, giving attention to flow effects in high-power gas lasers, aerodynamic windows and beam manipulation, and the Venus machine. Applications of high-power laser technology reported are related to laser material working, the employment of the laser in controlled fusion machines, laser isotope separation and photochemistry, and laser power transmission.

Hertzberg, A.↗

NASA NTRS1988

Consistent boundary conditions for Reduced Navier-Stokes (RNS) scheme applied to 3-dimensional internal viscous flows

A consistent and efficient set of boundary conditions is developed for the multi-sweep space-marching pressure-elliptic Reduced Navier-Stokes (RNS) scheme as applied for 3-D internal viscous flow problems. No-slip boundary conditions are directly imposed on the solid walls. There is no iteration procedure required in the cross plane to ensure mass conservation across each marching plane. The finite difference equations forming the coefficient matrix are ordered such that the surface normal velocity is specified on all the solid walls; unlike external flows, a pressure boundary condition in the cross plane is not required. Since continuity is directly satisfied at all points in the flow domain, the first order momentum equations can be solved directly for the pressure without the need for a Poisson pressure correction equation. The procedure developed herein can also be applied with periodic boundary conditions. The analysis is given for general compressible flows. Incompressible flow solutions are obtained, for straight and curved ducts of square cross section, to validate the procedure. These solutions are used to demonstrate the applicability of the RNS scheme, with the improved boundary conditions for internal flows with strong interaction, as would be encountered in ducts and turbomachinery geometries.

Reddy, D. R.↗