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At least 955 records · Page 53

Meal Replacement Mass Reduction and Integration Acceptability Study

NASA, in planning for long-duration missions, has an imperative to provide a food system with the necessary nutrition, acceptability, and safety to ensure sustainment of crew health and performance. The Orion Multi-Purpose Crew Vehicle (MPCV) and future exploration missions are mass constrained; therefore the team is challenged to reduce the mass of the food system by 10% while maintaining product safety, nutrition, and acceptability. Commercially available products do not meet the nutritional requirements for a full meal replacement in the spaceflight food system, and it is currently unknown if daily meal replacements will impact crew food intake and psychosocial health over time. The purpose of this study was to develop a variety of nutritionally balanced breakfast replacement bars that meet spaceflight nutritional, microbiological, sensorial, and shelf-life requirements, while enabling a 10% savings in food mass. To date, six nutrient-dense meal replacement bars (approximately 700 calories per bar) have been developed, using traditional methods of compression as well as novel ultrasonic compression technologies developed by Creative Resonance Inc. (Phoenix, AZ). The four highest rated bars were evaluated in the Human Exploration Research Analog (HERA) to assess the frequency with which actual meal replacement options may be implemented. Specifically, overall impact of bars on mood, satiety, digestive discomfort, and satisfaction with food. These factors are currently being analyzed to inform successful implementation strategies where crew maintain adequate food intake. In addition, these bars are currently undergoing shelf-life testing to determine long-term sensory acceptability, nutritional stability, qualitative stability of analytical measurements (i.e. water activity and texture), and microbiological compliance over two years of storage at room temperature and potential temperature abuse conditions to predict long-term acceptability. It is expected that this work will enable a successful meal replacement strategy to be implemented that will maintain crew food consumption and health, while informing exploration missions with appropriate mass savings expectations.

Sirmons, T.↗

Material Response Analysis of a Titan Entry Heatshield

Accurate calculation of thermal protection material response is critical to the vehicle design for missions to the Saturn moon Titan. In this study, Icarus, a three-dimensional, unstructured, finite-volume material response solver under active development at NASA Ames Research Center, is used to compute the in-depth material response of the Huygens spacecraft along its November 11 entry trajectory. The heatshield analyzed in this study consists of a five-layer stack-up of Phenolic Impregnated Carbon Ablator (PICA), aluminum honeycomb, adhesive, and face sheetmaterials. During planetary entry, the PICA outer layer is expected to undergo pyrolysis. A surface energy balance boundary condition that captures both time- and spatial-variance of surface properties during entry is used in the simulation.

material response↗

Optimal Experimental Design With Fast Neural Network Surrogate Models

Designing optimal experiments minimizes the uncertainty of results and maximizes the efficient use of resources. Herein, machine learning surrogate models and the approximate coordinate exchange (ACE) algorithm are used to determine optimum experimental designs over large or arbitrarily restrictive design spaces. Optimal experimental design is particularly salient in materials science where experiments are expensive and material properties must often be inferred indirectly. The proposed framework is demonstrated by finding optimal experiments with which the hidden constituent properties of composite materials can be most efficiently inferred from observable experimental outcomes. The optimum experimental design is given by an information-theoretic criteria, which maximizes the conditional mutual information between the hidden properties and the expected experimental outcomes. To perform tractable optimization a neural network is trained as a surrogate model to mimic a physics based simulation, which can calculate the expected experimental outcome based on a candidate experimental design and sampled constituent properties. The ACE algorithm is used to optimize over large design spaces with many tests and controlled parameters where an exhaustive search would be intractable even with the surrogate model. Using this approach, optimal experimental designs that are consistent with those produced by heuristic knowledge and established best practices are found; then optimal designs in larger design spaces where heuristic knowledge is unavailable are examined.

machine learning↗

Spacesuit and Mobility Performance Changes

The complex interactions between the human body and spacesuit lead to changes inmovement patterns and mobility performancesof the wearer. In general, factors including the geometric properties, such as shape and size, mechanical properties of the suit, and pressurization of the suit are known to be associated with altered movement patterns as compared to an unsuited human.However, their relative contributions have not been explicitly quantified from the mobility performance perspectives. The goal of this study wasthus to assessthe effects fromthe different types of mobility constraintconditions, namely by wearing either a 3D printed hard upper torso (HUT) assembly orfully pressurized spacesuit. The outcome was also compared against the unsuited motions. For this study, an xEMU (exploration Extravehicular Mobility Unit) suitwas considered, which is the next generation spacesuit developed by NASA. In each test condition, the subject was asked to move the arm and hand as prescribedfor different task types, and the corresponding body segment locations were recordedusing a 3D motion capture system. The following three tasks were performedand analyzed: 1) Outward one-handed reaches:the subject in a standing pose made sweeping motions with the extended right arm from the extreme end-to-end positions, including side-to-side at different elevations and top-to-bottom at different azimuths. 2) Outward two-handed reaches:similarto the previous task, howeverthe subject kept the hands together during the motions in order to assessthe areas that can be reached by both hands. 3) Inward one-handed reaches:the subject made right-hand reach motions to the surface of the HUT.The hand traces collected from each task were modeled by a template shape parametrically deformed with a radial basis function. This process enabled foran abstraction of the hand traces into a smooth surface envelope representing the maximally reachable area of the test subject, of which the shapes and sizes were compared across the different test conditions. The preliminary analysis has shown that theoverall size of reachenvelopes decreases in a pressurized suit compared to 3D printed mockup HUT and unsuited conditions. The specific shape of the envelopes, which were determined by the reachable and unreachable zones, alsovary with the testconditions, and the differences werepronounced with the inward reaches to the HUT surface. The latter observation ispotentially relatedto the increased demandfor shoulder and elbow flexions.Overcomingthe resistance from the pressurizedsoft goods and mechanical constraints of the shoulder assemblywas seen to be associated with the difference in motion patterns between the suited and unsuited conditions. Overall, the information quantified from this study is expected to provide structured metrics for spacesuit mobility, which can improve design optimization and human-system integration.

K Han Kim↗

Design and Commissioning of an In-Air Coronagraph Testbed in the HCIT facility at NASA’s Jet Propulsion Laboratory

After completing its duty in the vacuum chamber at the High Contrast Imaging Testbed (HCIT) facility at NASA’s Jet Propulsion Laboratory, the General Purpose Coronagraph Testbed (GPCT) has been retrofitted as the In-Air Coronagraph Testbed (IACT), with the purpose of verification of Boston Micromachines (BMC) 50x50 MEMS deformable mirrors (MEMS DM) performance by contrast comparison before and after random vibration testing. The testbed is configured as a vortex coronagraph, with one MEMS DM in the pupil plane to create a half dark hole in monochromatic light. High wavefront stability is achieved using an environmentally isolating enclosure, based on the enclosure design previously used on Caltech’s High Contrast Spectroscopy Testbed (HCST). Further, a smaller enclosure has been designed which will enforce humidity conditions necessary for the MEMS DM to operate. We expect this testbed to achieve 1e-8 contrast, and will use this contrast level as a baseline to assess survival or failure of MEMS DMs during vibration testing. In this presentation, we will present an overview of the design of the IACT, commissioning results, and plans for upcoming DM tests in preparation for launch on future space telescopes with coronagraph instruments.

Mejia-Prada, Camilo↗

Electrochemical Corrosion of SIMFUEL: Effects of dissolved H2 and noble metal particles

This report describes the results from electrochemical corrosion tests that were conducted using simulated spent fuel (SIMFUEL) materials comprised of UO2 and surrogate fission products. Two SIMFUEL compositions were tested to quantify the effect of noble metal inclusions and dissolved H2 on the UO2 dissolution rate. One material consisted of UO2 with added lanthanide oxides (UO2 N) and the other consisted of UO2 with added lanthanide oxides and noble metals (UO2-H) at concentrations to simulate high burnup fuel. The electrochemical corrosion tests on the SIMFUEL materials were conducted in aqueous electrolyte solutions (pH 10) that were either saturated with air or purged with a H2/Ar gas mixture to maintain a constant dissolved H2 concentration. The results from electrochemical corrosion tests on SIMFUEL can be applied to qualitatively understand and also quantify the separate effects of water chemistry and fuel composition on the degradation behavior of the UO2 matrix. Open circuit potential (OCP) measurements on a SIMFUEL material of known composition (i.e., known fraction of NMPs at the fuel surface) immersed in a known solution chemistry (i.e., pH, Eh, [O2], [H2]) at known temperature provide qualitative insight into the degradation behavior of the UO2 matrix. If the OCP is above the threshold potential at which the oxidative dissolution of U(IV) to U(VI) occurs, the SNF is expected to degrade by oxidative processes under the experimental conditions. The net currents that are measured during potentiostatic tests, during which the surface potential of the SIMFUEL material is fixed by a potentiostat, can be used to quantify the UO2 degradation rate and optimize the rate constant values used in the Fuel Matrix Degradation Model (FMDM) for half reactions that occur on the SNF surface. Specifically, electrochemical measurements enable the estimation of the total anodic current at ECORR–which is the surface potential at which the total anodic and total cathodic currents are equal–so that the rate constant values for key reactions can be calculated. The open circuit potential measurements, potentiostatic tests, surface property measurements (scanning electron microscopy images and electrochemical impedence spectroscopy plots), and solution elemental composition analyses are being performed to update and optimize the FMDM. A case study is presented herein to show how electrochemical corrosion test results and accompanying characterization results for the UO2 N material in air-saturated solution can be used to validate the SNF surface reaction module of the FMDM. Future electrochemical tests will be conducted to provide quantitative information on the effects of NM content (burnup), H2 concentration, water chemistry, temperature, and galvanic couples with cladding and EBS alloys on UO2 degradation that can be used to improve the accuracy and functionality of the FMDM.

Thomas, Sara↗

Evaporator Temperature Transient Testing of a High-Performance Sodium Filled Heat Pipe

Heat pipes are two-phase heat transfer devices that enable passive removal of heat from the reactor core to the power conversion system in heat pipe-cooled microreactor designs. Experimental investigations of heat pipe transients are needed for technology demonstration, verification and validation of numerical codes, and the establishment of regulatory requirements. The Single Primary Heat Extraction and Removal Emulator (SPHERE) facility at Idaho National Laboratory (INL) serves as a platform for evaluating the dynamic response of high-temperature heat pipes under a variety of operating conditions. The present work details the experimental investigation of a high-performance, defined as over 2 kW sodium heat pipe subjected to rapid input power fluctuations induced by sudden changes in the evaporator temperature setpoint. In addition, the heat pipe was subjected to an asymmetrical heat load where a subset of heaters operated at 30% and 70% below their nominal power. These experimental conditions were chosen to simulate thermal and operational stresses expected to be encountered in microreactors to provide data on heat pipe behavior during such important transient events. Key data and performance metrics, including time series of temperatures and strains, axial temperature profiles, thermal response times, and heat transfer capabilities, the thermal output over thermal input, were reported and discussed. The results highlight the resilience of heat pipes, revealing their potential to maintain thermal stability and efficiency under varying power loads. Lastly, the paper concludes with a discussion on the significance of the results and their implications for future research.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

IEA Wind Task 49: Reference Site Conditions for Floating Wind Arrays

The commercial-scale deployment of floating offshore wind (FOW) projects is expected to take place in a diverse range of sites that may differ significantly from existing fixed-bottom projects. FOW farms are particularly sensitive to the water depth and the meteorological and oceanographic (metocean) and geotechnical conditions at the project site due to the wave-induced system motions and loads as well as the anchoring system constraints imposed by the seafloor conditions. Uncertainty around the site conditions will permeate through all aspects of project design, leading to suboptimal and overly conservative designs, increased costs, and adversely affected performance. As FOW expands into a global industry, metocean and geotechnical conditions will increasingly vary for projects located in different geographic regions or in far-from-shore, deep-water sites. This study represents the outputs of work package 1 of International Energy Agency Wind Task 49, which focuses on the integrated design of floating wind arrays. The primary goal of this study is to establish the type of parameters and constraints required to characterize FOW array reference sites; provide a realistic and publicly available set of reference site conditions to the FOW community as a baseline set of data for individual research projects; identify and categorize any critical gaps in the existing data or methodologies required to define reference site characteristics; and inform and support the design of reference FOW arrays. A building block concept was developed for synthesizing reference sites for the design of FOW arrays. The building blocks include three classes of site conditions focusing on the techno-economic design of FOW projects: metocean conditions, seabed conditions, and coastal infrastructure. All reference site data produced and collected in this study are publicly available.

17 WIND ENERGY↗

A Performance analysis of the Claridge-Culp-Liu dehumidification process: A novel approach for drying moist air based on membrane separation, vacuum compression and sub-atmospheric condensation

This article covers a basic model for analyzing the performance of the Claridge-Culp-Liu dehumidification process. The fundamental process efficiency limit for dehumidification is close to COP Carnot , but for the eight dehumidification cases examined, the limiting or ideal energy use required is 26% to 56% that of a Carnot condensing system as shown in an earlier paper. The model presented in this paper is used to show the membrane system performance reduction caused by finite membrane area, finite water vapor permeance, non-zero air permeance, non-zero system air pressure drop, non-ideal compressors, vacuum pumps, and condensers. The performance of a “conservative” membrane system based on the use of existing components is computed for eight specific conditions along with that of a “target” system that assumes expected component performance after additional future component development. The “conservative” membrane system would use 36% to 66% as much energy as a system with a COP=7 chiller to produce the same dehumidification for the eight cases examined while the “target” system would use 15% to 40% the energy of a system with a COP=7 chiller. In addition to the significant energy reduction over conventional technology, the membrane system offers the advantages of: 1) no HFC refrigerant use; 2) direct isothermal control over humidity ratio setpoint; 3) maximum capacity occurs at design conditions; and 4) system generates pure water extracted from air as a by-product.

42 ENGINEERING↗

Computational Analysis of Shock Layer Emission Measurements in an Arc-Jet Facility

This paper reports computational analysis of radiation emission experiments in a high enthalpy arc-jet wind tunnel at NASA Ames Research Center. Recently, as part of ongoing arc-jet characterization work, spectroscopic radiation emission experiments have been conducted at the 20 MW NASA Ames arc-jet facility. The emission measurements were obtained from the arc-jet freestream and from a shock layer formed in front of flatfaced models. Analysis of these data is expected to provide valuable information about the thermodynamic state of the gas in the arc-jet freestream and in the shock layer as well as thermochemical equilibration processes behind the shock in arc-jet flows. Knowledge of the thermodynamic state of the gas in arc-jet test flows and especially within the shock layer is essential to interpret the heat transfer measurements such as in surface catalysis experiments. The present work is a continuation of previous work and focuses on analysis of the emission data obtained at relatively low-pressure conditions for which the arc-jet shock layer is expected to be in thermal and chemical nonequilibrium. Building blocks of the present computational analysis are: (1) simulation of nonequilibrium expanding flow in the converging-diverging conical nozzle and supersonic jet; (2) simulation of nonequilibrium shock layer formed in front of the flat-faced cylinder model; and (3) prediction of line-of-sight radiation from the computed flowfield. For computations of the nonequilibrium flow in the conical nozzle and shock layer, multi-temperature nonequilibrium codes with the axisymmetric formulation are used. For computations of line-of-sight radiation. a nonequilibrium radiation code (NEQAIR) is used to predict emission spectra from the computed flowfield. Computed line-of-sight averaged flow properties such as vibrational and rotational temperatures, species number densities within the shock layer will be compared with those deduced from the experimental spectra. Detailed comparisons of computational and experimental spectra will also be presented.

Gokcen, Tahir↗

Effects of Non-Electrostatic Intermolecular Interactions on the Phase Behavior of pH-Sensitive Polyelectrolyte Complexes

Polyelectrolyte complexes (PECs) offer enormous material tunability and desirable functionalities, and consequently have found broad utility in biomedical and material industries. While poly(acrylic acid) (PAA) and poly( allylamine hydrochloride) (PAH) are a commonly used pairing, various aspects of the phase behavior of PAA-PAH complexes have not been sufficiently quantified. In this work, we present a comprehensive experimental study depicting the binodal phase boundaries for the PAA-PAH complexes prepared under acidic, neutral, and basic conditions using thermogravimetric analysis, turbidimetry, and optical microscopy. Under neutral and basic conditions, phase behaviors of the complexes were largely similar to one another and followed general expectations of PEC phase behavior, except for unusually high resistance to disruption of the complex with added salt. Stable complexes are observed up to 4 M NaCl concentrations. Under acidic conditions, strikingly different phase behaviors of the PAA-PAH complexes were observed. The polymer content in the complex phase increased initially, followed by an expected decrease as salt was added to the complexes. This behavior may result from a combination of associative phase separation of PAA and PAH chains, influenced by electrostatic interactions, and segregative phase separation, which can be ascribed to the influence of a combination of the hydrophobic interactions of the aliphatic polymer backbone and the interpolymer hydrogen bonding of unionized acrylic monomer units. Our systematic investigations over a range of pH detailing these discrepancies in the PAA-PAH phase behavior are expected to clarify the inconsistencies among the reports in the literature and provide the material design strategies for practical use of the PAA-PAH complexes and multilayer assemblies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Comparison of Perturbed Initial Conditions and Multiphysics Ensembles in a Severe Weather Episode in Spain

Ensembles of numerical model forecasts are of interest to operational early warning forecasters as the spread of the ensemble provides an indication of the uncertainty of the alerts, and the mean value is deemed to outperform the forecasts of the individual models. This paper explores two ensembles on a severe weather episode in Spain, aiming to ascertain the relative usefulness of each one. One ensemble uses sensible choices of physical parameterizations (precipitation microphysics, land surface physics, and cumulus physics) while the other follows a perturbed initial conditions approach. The results show that, depending on the parameterizations, large differences can be expected in terms of storm location, spatial structure of the precipitation field, and rain intensity. It is also found that the spread of the perturbed initial conditions ensemble is smaller than the dispersion due to physical parameterizations. This confirms that in severe weather situations operational forecasts should address moist physics deficiencies to realize the full benefits of the ensemble approach, in addition to optimizing initial conditions. The results also provide insights into differences in simulations arising from ensembles of weather models using several combinations of different physical parameterizations.

severe weather↗

Assessment of Amine-Based CO2BOLs for Direct Air Capture

Direct air capture (DAC) technologies extract CO 2 from the atmosphere for CO 2 storage, or utilization. Capturing CO 2 from the air is the most expensive application of carbon capture because CO 2 in the atmosphere is very dilute. There are limited number of CO 2 capture technologies for DAC application. This project aims at developing an energy efficient technology for DAC, leveraging two PNNL’s chemistries (solid and liquid CO 2 capture). Three CO 2 capture sorbents consisting of amine based CO 2 BOLs immobilized in mesoporous silica were designed, synthesized, and tested. These sorbents had ~ 19-23 wt.% amine loadings which is lower than typical amine-based silica sorbents. The surface area and pore volumes of these solid supported CO 2 BOLs are lower compared to those of the pristine silica support. The CO 2 capture performance of these materials was significantly lower than the typical silica supported amines due to low amine loading and higher molecular weight with low amine density. These results show that immobilize CO 2 BOLs in silica are not viable materials for removing CO 2 from ambient air. This project also designed, synthesized at tested liquid solvents for DAC application. Solvent properties that is vapor pressure, CO 2 uptake capacity, kinetics, and viscosity for three novel solvents were evaluated. The CO 2 uptake capacity for one of the most promising amine-based solvent BEPBEGDA was the highest at 13.2 wt% corresponding to 97 mol%. The vapor pressure of the BEPBEGDA solvents were very low at 80 °C compared to other solvents making them suitable for DAC application. The effect of humidity on the CO 2 capture performance of these solvents was evaluated which shows that presence of moisture doesn’t have a negative effect on the CO 2 uptake performance but makes it slightly better. The performances of these solvents were slightly below that of the 0.1M NaOH solution tested under similar conditions. Despite of the slightly lower CO 2 uptake, it is expected that these liquid solvents will have lower regeneration temperature and minimum evaporative losses due their low vapor pressure. Future work will focus on optimization of the liquid solvents for DAC application to improve both CO 2 capture efficiency and capacity without viscosity and vapor pressure increase. Testing of these solvents under DAC conditions using a gas liquid contactor that mimic industrial applications is needed. Solvent cost projection, techno-economic analysis and life cycle analysis are required to evaluate economic viability of this technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mechanisms for the Crystallization of ZBLAN

The objective of this ground based study is to test the hypothesis that shear thinning (the non-Newtonian response of viscosity to shear rate) is a viable mechanism to explain the observation of enhanced glass formation in numerous low-g experiments. In 1-g, fluid motion results from buoyancy forces and surface tension driven convection. This fluid flow will introduce shear in undercooled liquids in 1-g. In low-g it is known that fluid flows are greatly reduced so that the shear rate in fluids can be extremely low. It is believed that some fluids may have weak structure in the absence of flow. Very small shear rates could cause this structure to collapse in response to shear resulting in a lowering of the viscosity of the fluid. The hypothesis of this research is that: Shear thinning in undercooled liquids decreases the viscosity, increasing the rate of nucleation and crystallization of glass forming melts. Shear in the melt can be reduced in low-g, thus enhancing undercooling and glass formation. The viscosity of a model glass (lithium di-silicate, L2S) often used for crystallization studies has been measured at very low shear rates using a dynamic mechanical thermal analyzer. Our results are consistent with increasing viscosity with a lowering of shear rates. The viscosity of L2S may vary as much as an order of magnitude depending on the shear rate in the temperature region of maximum nucleation and crystal growth. Classical equations for nucleation and crystal growth rates, are inversely related to the viscosity and viscosity to the third power respectively. An order of magnitude variation in viscosity (with shear) at a given temperature would have dramatic effects on glass crystallization Crystallization studies with the heavy metal fluoride glass ZBLAN (ZrF2-BaF2-LaF3-AlF3-NaF) to examine the effect of shear on crystallization are being initiated. Samples are to be melted and quenched under quiescent conditions at different shear rates to determine the effect on crystallization. The results from this study are expected to advance the current scientific understanding of glass formation in low-g and glass crystallization under glass molding conditions and will improve the scientific understanding of technological processes such as fiber pulling, bulk amorphous alloys, and glass fabrication processes.

Ethridge, Edwin C.↗

Investigations on the Thermal-hydraulic Behavior of Accident Tolerant Fuel Cladding Materials

Since the 2011 Fukushima accident, significant research has been devoted to developing accident-tolerant fuel (ATF) cladding materials. These investigations have mostly focused on the ability to resist runaway steam oxidation and retain mechanical strength and structural integrity under thermal shocks. However, much remains unknown about the materials’ thermal-hydraulic behavior, particularly under light-water reactor (LWR) operating conditions. Two phenomena that determine safety margins in both normal and off-normal operating conditions - i.e., the critical heat flux (CHF) and Leidenfrost point (LFP) temperature - have not been investigated thoroughly for ATF materials. Surface properties, such as wettability and roughness, are known to influence pool and flow boiling CHF, as well as the LFP temperature. However, little is known about the surface wettability of ATF materials, particularly at LWR pressure and temperature. Little has been done on flow-boiling CHF and quenching heat transfer, especially for droplet quenching. Nonetheless, it is known that CHF in transient conditions, e.g., an exponentially escalating power transient, can be significantly different from that expected in steady-state operation. Very few studies have investigated transient CHF, either on ATF materials or under LWR pressure and temperature. The thorough understanding of transient CHF under prototypical reactor conditions will benefit not only the deployment of ATF but also the upcoming national efforts to study transient ATF behavior in the Transient Reactor Test Facility (TREAT) at Idaho National Laboratory. In summary, as a part of ATF development efforts, there is an urgent need to understand how and how much these materials may affect two-phase heat transfer phenomena in nuclear reactor conditions.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Altitude-Test-Chamber Investigation of the Endurance and Performance Characteristics of the J65-W-7 Engine at a Mach Number of 2.0

An investigation of the endurance characteristics, at high Mach number, of the J65-W-7 engine was made in an altitude chamber at the Lewis laboratory. The investigation was made to determine whether this engine can be operated at flight conditions of Mach 2 at 35,000-feet altitude (inlet temperature, 250 F) as a limited-service-life engine Failure of the seventh-stage aluminum compressor blades occurred in both engines tested and was attributed to insufficient strength of the blade fastenings at the elevated temperatures. For the conditions of these tests, the results showed that it is reasonable to expect 10 to 15 minutes of satisfactory engine operation before failure. The high temperatures and pressures imposed upon the compressor housing caused no permanent deformation. In general, the performance of the engines tested was only slightly affected by the high ram conditions of this investigation. There was no discernible depreciation of performance with time prior to failure.

Biermann, A.E.↗

Role of heterogeneous surface wettability on dynamic immiscible displacement, capillary pressure, and relative permeability in a CO 2 -water-rock system

Numerical examination of CO 2 displacement in brine filled rock pores with varying wettability. Results show that as the CO 2 contact angles on the rock surface increased (intermediate water wetting conditions) negative entry pressures for CO 2 displacement were observed, indicating that when heterogeneous surface wettability is accounted for, greater mobility of CO 2 into rock pores is expected. In addition, simulated relative permeability CO 2 curves with heterogeneous intermediate water wetting conditions exhibited a greater amount of variation, indicative of a complex interrelation of geometric capillary restrictions and surface wettability.

58 GEOSCIENCES↗

Impact of Non-Steady State Operation on Cooling Water Consumption at Coal- and Natural Gas-Fired Power Plants

Increased renewable energy penetration in the electricity grid in coming decades will result in more frequent cycling at thermal power plants. Simultaneously, thermal power plants may face water scarcity with declining availability of cooling water. Therefore, to enhance thermal power plants’ resiliency to water shortages it is important to understand how non-steady conditions due to cycling will impact cooling water consumption and withdrawal intensity. Non-steady operation at power plants has been previously shown to decrease power plant thermal efficiency. Energy balance models have also demonstrated that a decrease in thermal efficiency is expected to increase cooling water consumption intensity. Furthermore, past work has used operating hours data to show idling and cycling gaps where cooling systems operate more than corresponding generators. As a result, an increase in cycling behavior may impact cooling water consumption and withdrawal intensity. This study uses data from the Energy Information Administration (EIA) and Environmental Protection Agency (EPA) to quantify the impact of cycling cooling water consumption intensity for recirculating cooling systems and withdrawal intensity for once-through cooling systems using energy balance and statistical approaches. In a novel application of a fixed effects model to study the effect of temperature on cooling water consumption and withdrawal intensity, this study finds temperature was consistently expected to increase consumption intensity and withdrawal intensity. Non-steady state conditions do not increase cooling water consumption intensity with statistical significance across unit types. However, additional validation of cooling water data is required to confirm these observed trends due to the sensitivity of these findings to model form and concerns with data quality of the dependent variables, cooling water consumption and withdrawal.

20 FOSSIL-FUELED POWER PLANTS↗