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At least 955 records · Page 53

Genetic dissection of natural variation in oilseed traits of camelina by whole‐genome resequencing and QTL mapping

Abstract Camelina [ Camelina sativa (L.) Crantz] is an oilseed crop in the Brassicaceae family that is currently being developed as a source of bioenergy and healthy fatty acids. To facilitate modern breeding efforts through marker‐assisted selection and biotechnology, we evaluated genetic variation among a worldwide collection of 222 camelina accessions. We performed whole‐genome resequencing to obtain single nucleotide polymorphism (SNP) markers and to analyze genomic diversity. We also conducted phenotypic field evaluations in two consecutive seasons for variations in key agronomic traits related to oilseed production such as seed size, oil content (OC), fatty acid composition, and flowering time. We determined the population structure of the camelina accessions using 161,301 SNPs. Further, we identified quantitative trait loci (QTL) and candidate genes controlling the above field‐evaluated traits by genome‐wide association studies (GWAS) complemented with linkage mapping using a recombinant inbred line (RIL) population. Characterization of the natural variation at the genome and phenotypic levels provides valuable resources to camelina genetic studies and crop improvement. The QTL and candidate genes should assist in breeding of advanced camelina varieties that can be integrated into the cropping systems for the production of high yield of oils of desired fatty acid composition.

59 BASIC BIOLOGICAL SCIENCES↗

The radiation instability of thermally stable nanocrystalline platinum gold

Here, recent experimentally validated alloy design theories have demonstrated nanocrystalline binary alloys that are stable against thermally induced grain growth. An open question is whether such thermal stability also translates to stability under irradiation. In this study, we investigate the response to heavy ion irradiation of a nanocrystalline platinum gold alloy that is known to be thermally stable from previous studies. Heavy ion irradiation was conducted at both room temperature and elevated temperatures on films of nanocrystalline platinum and platinum gold. Using scanning/transmission electron microscopy equipped with energy-dispersive spectroscopy and automated crystallographic orientation mapping, we observe substantial grain growth in the irradiated area compared to the controlled area beyond the range of heavy ions, as well as compositional redistribution under these conditions, and discuss mechanisms underpinning this instability. These findings highlight that grain boundary stability against one external stimulus, such as heat, does not always translate into grain boundary stability under other stimuli, such as displacement damage.

36 MATERIALS SCIENCE↗

Complex carbonate phases drive geologic CO2 mineralization

Abstract Geologic carbon sequestration in mafic and ultramafic reservoirs is a scalable strategy for carbon dioxide removal, offering permanent storage via mineralization as stable carbonates. However, there is limited information on the structure and composition of key mineralization endpoints during sequestration. Here, we unravel the atomic structure, composition, and nanoscale morphology of carbonates recovered from a field-scale demonstration of CO 2 mineralization in basalt. Using transmission electron microscopy, we mapped mineralogical variations from the initial to later stages of subsurface carbonate growth and identified a previously unknown cation-ordered ankerite phase that exerts a primary control over carbonation processes. This study has provided a new understanding of subsurface carbonation pathways which will impact the parameterization of predictive geochemical models for future sequestration efforts in basalt formations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Deep level defects and cation sublattice disorder in ZnGeN 2

The III-nitrides have revolutionized lighting technology and power electronics. Expanding the nitride semiconductor family to include the heterovalent ternary nitrides opens up new and exciting opportunities for device design that may help overcome some of the limitations of the binary nitrides as well as new applications. However, the more complex cation sublattice also gives rise to new complexities with both native and extrinsic defects, such as disorder on the cation sublattice. Here, depth-resolved cathodoluminescence spectroscopy and surface photovoltage spectroscopy measurements of defect energy levels in ZnGeN 2 combined with transmission microscopy and crystal lattice diffraction reveal optical signatures of mid-gap states that can be associated with cation sublattice disorder. The energies of these characteristic optical signatures in ZnGeN 2 thin films grown by metal-organic chemical vapor deposition are in good agreement with energy levels predicted by density functional theory for specific thermodynamically stable native point defects. To test the dependence of these defect signatures on crystal atomic composition, we correlated spatially-resolved optical and atomic composition measurements using spatially resolved x-ray photoelectron spectroscopy with systematically varied growth conditions on the same ZnGeN 2 films. The resultant elemental maps versus defect spectral energies and intensities suggest that cation antisite complexes (Zn Ge -Ge Zn ) versus isolated native point defects form preferentially and introduce mid-gap states that dominate electron-hole pair recombination. Complexing of Zn Ge and Ge Zn antisites manifests as disorder in the cation sub-lattice and leads to the formation of wurtzitic ZnGeN 2 as indicated by transmission electron microscopy diffraction patterns and x-ray diffraction (XRD) reciprocal space maps. Furthermore, these findings emphasize the importance of growth conditions to control cation place exchange.

42 ENGINEERING↗

Application of the Chloride Susceptibility Index to Study the Effects of Ni, Cr, Mn and Mo on the Repassivation of Stainless Steels

The effects of Ni, Cr, Mn and Mo on the very earliest stages of repassivation of stainless steels are quantified using the Chloride Susceptibility Index (CSI), which is an ab initio-based index for the evaluation of repassivation tendency. The quinary system of Fe-Ni-Cr-Mn-Mo is studied with density functional theory analysis and an electrochemisorption model developed previously by the authors, which are required to determine the CSI. The adsorption energies of O and Cl to different surface configurations are calculated, and then surface coverage maps of different species on the surface are obtained from the adsorption energies based on the Langmuir isotherm. Finally, CSI is calculated for different compositions of stainless steels. It is found that the effect of alloying elements on promoting repassivation of Fe alloys is in the order of Mn > ≈Ni > Cr > Mo when solute composition is less than 28 wt.%. A strong synergy is found between Cr and Mo such that a combination of these two elements at a certain ratio can give an optimal (low) CSI. Here, the usage of CSI for evaluating repassivation tendency of CRAs is validated by experimental measured repassivation potential, which shows a strong monotonic negative relation with CSI.

36 MATERIALS SCIENCE↗

Numerical simulation of electrothermal de-icing systems

Transient simulations of de-icing of composite aircraft components by electrothermal heating have been computed for both one and two-dimensional rectangular geometries. The implicit Crank-Nicolson formulation is used to insure stability of the finite-differenced heat conduction equations and the phase change in the ice layer is simulated using the Enthalpy method. Numerical solutions illustrating de-icer performance for various composite aircraft blades and environmental conditions are presented. Comparisons are made with previous studies and with available experimental data. Initial results using a coordinate mapping technique to describe the actual blade geometry are discussed.

De Witt, K. J.↗

New results for geologic units mapping of Utah test sites using Landsat TM data

This paper continues a study on the accuracy of geological mapping using Landsat Thematic Mapper data (Short, 1984). In June 1976, both the White Mountain alteration zone and the Waterpocket Fold sedimentary rock sites in Utah were surveyed by the Bendix 24-band scanner on a NASA NC-130B aircraft. Mid-June 1984 TM data for these two sites have been processed like the 1976 data to test the quality of simulation of TM data. Principal-components (PC) color composite images for White Mountain show close correspondence to the Bendix PC images. At this site carbonate strata are uniquely discriminated in both Bendix and TM composites that use an inverted PC 3 image. Alunite/kaolinite and hematite/limonite alteration zones developed on volcanic flows are also sharply separated, but iron oxide and silicified zones are less so. The accuracy of rock-units mapping at the Waterpocket Fold site by supervised classification of the June TM data is significantly better, reaching 70 percent in the best case, than for January 1983 data for that site.

Short, N. M.↗

Metal/Silicate Partitioning at High Pressures and Temperatures

The behavior of siderophile elements during metal-silicate segregation, and their resulting distributions provide insight into core formation processes. Determination of partition coefficients allows the calculation of element distributions that can be compared to established values of element abundances in the silicate (mantle) and metallic (core) portions of the Earth. Moderately siderophile elements, including W, are particularly useful in constraining core formation conditions because they are sensitive to variations in T, P, oxygen fugacity (fO2), and silicate composition. To constrain the effect of pressure on W metal/silicate partitioning, we performed experiments at high pressures and temperatures using a multi anvil press (MAP) at NASA Johnson Space Center and laser-heated diamond anvil cells (LHDAC) at the University of Maryland. Starting materials consisted of natural peridotite mixed with Fe and W metals. Pressure conditions in the MAP experiments ranged from 10 to 16 GPa at 2400 K. Pressures in the LHDAC experiments ranged from 26 to 58 GPa, and peak temperatures ranged up to 5000 K. LHDAC experimental run products were sectioned by focused ion beam (FIB) at NASA JSC. Run products were analyzed by electron microprobe using wavelength dispersive spectroscopy. Liquid metal/liquid silicate partition coefficients for W were calculated from element abundances determined by microprobe analyses, and corrected to a common fO2 condition of IW-2 assuming +4 valence for W. Within analytical uncertainties, W partitioning shows a flat trend with increasing pressure from 10 to 16 GPa. At higher pressures, W becomes more siderophile, with an increase in partition coefficient of approximately 0.5 log units.

Shofner, G.↗

Sub-Micrometer Scale Minor Element Mapping in Interplanetary Dust Particles: A Test for Stratospheric Contamination

Combined X-ray microprobe (XRM), energy dispersive x-ray fluorescence using a Transmission Electron Microscope (TEM), and electron microprobe measurements have determined that the average bulk chemical composition of the interplanetary dust particles (IDPs) collected from the Earth s stratosphere is enriched relative to the CI meteorite composition by a factor of 2 to 4 for carbon and for the moderately volatile elements Na, K, P, Mn, Cu, Zn, Ga, Ge, and Se, and enriched to approximately 30 times CI for Br. However, Jessberger et al., who have reported similar bulk enrichments using Proton Induced X-ray Emission (PIXE), attribute the enrichments to contamination by meteor-derived atmospheric aerosols during the several weeks these IDPs reside in the Earth s atmosphere prior to collection. Using scanning Auger spectroscopy, a very sensitive surface analysis technique, Mackinnon and Mogk have observed S contamination on the surface of IDPs, presumably due to the accretion of sulfate aerosols during stratospheric residence. But the S-rich layer they detected was so thin (approximately 100 angstroms thick) that the total amount of S on the surface was too small to significantly perturb the bulk S-content of a chondritic IDP. Stephan et al. provide support for the contamination hypothesis by reporting the enrichment of Br on the edges of the IDPs using Time-of-Flight Secondary-Ion Mass-Spectrometry (TOFSIMS), but TOF-SIMS is notorious for producing false edge-effects, particularly on irregularly-shaped samples like IDPs. Sutton et al. mapped the spatial distribution of Fe, Ni, Zn, Br, and Sr, at the approximately 2 m scale, in four IDPs using element-specific x-ray fluorescence (XRF) computed microtomography. They found the moderately volatile elements Zn and Br, although spatially inhomogeneous, were not concentrated on the surface of any of the IDPs they examined, suggesting that the Zn and the Br enrichments in the IDPs are not due to contamination during stratospheric residence.

Flynn, G. J.↗

A physical basis for remote rock mapping of igneous rocks using spectral variations in thermal infrared emittance

Results of a theoretical investigation of the relation between spectral features in the 8-12 micrometer region and rock type are presented. Data on compositions of a suite of rocks and measurements of their spectral intensities in 8.2-10.9 and 9.4-12.1 micrometer bands published by Vincent (1973) were subjected to various quantitative procedures. There was no consistent direct relationship between rock group names and the relative spectral intensities. However, there is such a relationship between the Thornton-Tuttle (1960) Differentiation Index and the relative spectral intensities. This relationship is explicable on the basis of the change in average Si-O bond length which is a function of the degree of polymerization of the SiO4 tetrahedra of the silicate minerals in the igneous rocks.

Walter, L. S.↗

A composite large-scale CO survey at high Galactic latitudes in the second quadrant

Surveys of the second quadrant of the Galaxy undertaken with the CfA 1.2-m telescope have been combined to produce a map of approximately 620 sq deg in the 2.6-mm CO (J = 1-0) line at high Galactic latitudes. CO was detected over about 13 percent of the region surveyed, an order of magnitude more gas by area than previously estimated. In contrast, only 26 percent of the area predicted by Desert et al. (1988) to contain molecular gas actually reveals CO, and about two-thirds of the clouds detected are not listed in their catalog of IR excess clouds.

Heithausen, A.↗

A composite large-scale CO survey at high galactic latitudes in the second quadrant

Surveys undertaken in the 2nd quadrant of the Galaxy with the CfA 1.2 m telescope have been combined to produce a map covering about 620 sq deg in the 2.6 mm CO(J = 1 - 0) line at high galactic latitudes. There is CO emission from molecular 'cirrus' clouds in about 13 percent of the region surveyed. The CO clouds are grouped together into three major cloud complexes with 29 individual members. All clouds are associated with infrared emission at 100 micron, although there is no one-to-one correlation between the corresponding intensities. CO emission is detected in all bright and dark Lynds' nebulae cataloged in that region; however not all CO clouds are visible on optical photographs as reflection or absorption features. The clouds are probably local. At an adopted distance of 240 pc cloud sizes range from O.1 to 30 pc and cloud masses from 1 to 1600 solar masses. The molecular cirrus clouds contribute between 0.4 and 0.8 M solar mass/sq pc to the surface density of molecular gas in the galactic plane. Only 26 percent of the 'infrared-excess clouds' in the area surveyed actually show CO and about 2/3 of the clouds detected in CO do not show an infrared excess.

Heithausen, A.↗

Change in land use in the Phoenix (1:250,000) Quadrangle, Arizona between 1970 and 1972: Successful use of proposed land use classification system

Changes in land use in the Phoenix (1:250,000 scale) Quadrangle in Arizona have been mapped using only the images from ERTS-1, tending to verify the utility of a land use classification system proposed for use with ERTS images. The period of change investigated was from November 1970 to late summer or early fall, 1972. Seasonal changes also were studied using successive ERTS images. Types of equipment used to aid interpretation included a color additive viewer, a twenty-power magnifier, a density slicer, and a diazo copy machine for making ERTS color composites in hard copy. Types of changes detected have been: (1) cropland or rangeland developed for new residential areas; (2) rangeland converted to new cropland; and (3) possibly new areas of industrial or commercial development. A map of land use previously compiled from air photos was updated in this manner.

Place, J. L.↗

Surveying Dead Trees and CO2-Induced Stressed Trees Using AVIRIS in the Long Valley Caldera

Since 1980 the Long Valley Caldera in the eastern Sierra Nevada (California) has shown signs of renewed volcanic activity. Frequent earthquakes, a re-inflation of the caldera, hydrothermal activity and gas emissions are the outer symptoms of this renewed activity. In 1990 and 1991 several areas of dying trees were found around Mammoth Mountain. The cause of the die off of the trees was first sought in the persistent drought in the preceding years. However, the trees died regardless of age and species. Farrar et al. (1995) started a soil-gas survey in 1994 in the dead-tree areas and found carbon dioxide concentrations ranging from 30 to 96% at soil depths between 30 and 60 cm. CO2 concentrations in the atmosphere are usually around 0.03% and in the soil profile CO2 levels do commonly not exceed 4 to 5%. Although not much is known about the effect of high levels of carbon dioxide in the soil profile on roots, it is most likely that the trees are dying due to oxygen deprivation: the CO2 drives the oxygen out of the soil. So far, four sites of dead trees have been mapped around Mammoth Mountain. The two largest dying trees sites are located near Horseshoe Lake and near Mammoth Mountain Main Lodge covering approximately an area of 10 and 8 ha respectively. Analysis of the gas composition regarding the He-3/He-4 ratio and the percentage biogenic carbon reveals the source of the gas: the magma body beneath the Long Valley Caldera. Until recently it was not known that volcanoes release abundant carbon dioxide from their flanks as diffuse soil emanations. As a result of the magma gas emission around Mammoth Mountain there is an excellent sequence of dead trees, stressed trees, healthy trees and bare soil surfaces. This research site provides excellent opportunities to: (1) Study the capabilities of imaging spectrometry to map stressed (and dead) pine and fir species; (2) Study methods to separate the vivid vegetation, stressed vegetation and dead vegetation from the soil background of glacial deposits and crystalline rocks. The dead tree areas are located on the flanks of Mammoth Mountain (N:37 deg 37' 45" and W:119 deg 02' 05") at an elevation between 2600 and 3000 meters. The area is covered by an open type of Montane Forest. The dominant tree species are Lodgepole Pine (Pinus contorta), the Red Fir (Abies magnifica) and the Jeffrey Pine (Pinus jeffreyi). The soil surface near Horseshoe Lake is generally fairly bright. The surface is covered by glacial deposits (till) consisting mainly of weathered granitic rocks.

deJong, Steven M.↗

Towards multi-fidelity deep learning of wind turbine wakes

We report engineering wake models that accurately predict wake in a computationally efficient manner are very important for tasks such as layout optimization and control of wind farms. In this paper, we explore an application of deep learning (DL) to learn the wake model from hierarchies of physics-based approaches ranging from analytical models to an approximate form of the Reynolds-averaged Navier-Stokes equations. We first illustrate the application of principal component analysis to obtain a lower-dimensional representation that allows a computationally tractable training and deployment of DL models. Then, the DL model is trained to learn the mapping from input parameter space to the principal components, which are then used to reconstruct the three-dimensional flow field. Additionally, we investigate a composite framework consisting of two neural networks to learn the correlation between low- and high-fidelity data with Gauss and curl models treated as proxies for low- and high-fidelity models, respectively. The prediction from both DL models matches well with the high-fidelity data with a maximum relative percentage error for the kinetic energy flux of <1%. This work opens up possibilities for data-efficient construction of surrogate models for wake prediction that can be used to study the influence of wind speed and yaw angles on wind farm power production.

17 WIND ENERGY↗

Phase coexistence implications of violating Newton’s third law

Newton’s third law, action = reaction, is a foundational statement of classical mechanics. However, in natural and living systems, this law appears to be routinely violated for constituents interacting in a nonequilibrium environment. Here, we use computer simulations to explore the macroscopic phase behavior implications of breaking microscopic interaction reciprocity for a simple model system. We consider a binary mixture of attractive particles and introduce a parameter that is a continuous measure of the degree to which interaction reciprocity is broken. In the reciprocal limit, the species are indistinguishable, and the system phase separates into domains with distinct densities and identical compositions. Furthermore, increasing nonreciprocity is found to drive the system to explore a rich assortment of phases, including phases with strong composition asymmetries and three-phase coexistence. Many of the states induced by these forces, including traveling crystals and liquids, have no equilibrium analogs. By mapping the complete phase diagram for this model system and characterizing these unique phases, our findings offer a concrete path forward toward understanding how nonreciprocity shapes the structures found in living systems and how this might be leveraged in the design of synthetic materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A land use and environmental impact analysis of the Norfolk-Portsmouth SMSA

The feasibility of using remote sensing techniques for land use and environmental assessment in the Norfolk-Portsmouth area is discussed. Data cover the use of high altitude aircraft and satellite remote sensing data for: (1) identifying various heirarchial levels of land use, (2) monitoring land use changes for repetitive basis, (3) assessing the impact of competing land uses, and (4) identifying areas of potential environmental deterioration. High altitude aircraft photographs (scale 1:120,000) acquired in 1959, 1970, and 1972, plus Earth Resources Technology Satellite (ERTS-1) color composite images acquired in 1972 were used for the land use and environmental assessments. The high altitude aircraft photography, as expected, was successfully used to map Level 1, Level 2, as well as some urban Level 3 land use categories. However, the detail of land use analysis obtainable from the ERTS imagery exceeded the expectations for the U.S. Geological Survey's land use classification scheme. Study results are consistent with the initial investigation which determined Level 1 land use change to be 16.7 square km per year.

Mitchel, W. B.↗

The geology of Mars - A brief review of some recent results

Some Mariner 9 data on geologic provinces, volcanic processes, geophysical models, Eolian activity, surface water, and atmospheric composition on Mars are presented. Ways in which this data is expected to be augmented by the Viking mission are briefly reviewed. Information given in map form includes permanent ice, layered deposits, etched plains, volcanic constructs (shields, domes, or cones), volcanic plains, moderately cratered plains, cratered plains, hummocky terrain, channel deposit, undivided plains, and grooved terrain.

Mutch, T. A.↗