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At least 955 records · Page 53

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DOE OSTI2020

Carburization of metals by a chemical mechanism of carbon transport through molten fluoride salts

Carburization of structural alloys used in Fluoride Cooled High Temperature Reactors (FHR) can result from the interaction between the metal and graphite components and cause changes in alloy properties. However, carburization requires transport of carbon from graphite to alloy surfaces through the molten fluoride coolant. This work introduces an alternative to previously proposed carbon transport mechanisms. The new mechanism is based on the generation of carbonate ions (CO 3 2- ) by oxide impurities in the salt reacting with graphite. CO 3 2- is then reduced on metal surfaces to deposit carbon. This work demonstrates the reduction of dissolved CO 3 2- on pure Fe, Ni, Cr, Mo, and W surfaces without an applied potential in molten FLiNaK at 700 °C. Finally, we also demonstrate that the interaction between oxide and graphite in molten FLiNaK media produces CO 3 2- .

36 MATERIALS SCIENCE↗

DOE OSTI2023

Activation Analysis in Preparation for a Tungsten Irradiation Experiment at LANSCE

To organize the safe handling of activated material, knowing the residual dose rates is crucial. Here, in this work, we present the pre-experiment activation analysis for an experiment in which tungsten blocks are irradiated by 800-MeV protons. In this analysis, we use the Monte Carlo N-Particle (MCNP) code for radiation transport, Attila4MC for unstructured mesh generation, and Activation in Accelerator Radiation Environments (AARE), including CINDER2008, for activation analysis. If the tungsten blocks must be removed within a day after the experiment, then exposure to personnel entering the room must be reduced. One exposure-reduction strategy is to add carbon steel shielding around the tungsten blocks, efficiently reducing the dose from the activated tungsten. However, the shielding becomes activated itself during irradiation: 56Mn is the dominant contributor for short decay times. The actual schedule at the time of the experiment allowed sufficient cool-off time for the tungsten in the room so that additional shielding was not necessary. A less rigorous comparison of the calculated values with the post-experiment measurements showed reasonable agreement.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2021

U.S.-China Clean Energy Research Center Building Energy Efficiency (CERC-BEE) Open-Source Retrofit Targeting Tool (CRADA FP00007338 Final Report)

To increase the cost-saving energy and carbon dioxide (CO 2 ) emissions reductions in buildings and portfolios at the scale and speed necessary to limit climate change, researchers at LBNL and Johnson Controls (JCI) developed the Building Efficiency Targeting Tool for Energy Retrofits (BETTER). BETTER is a software tool that consists of three components: (1) the BETTER analytical engine source code (which was developed with intellectual property provided by JCI under CRADA FP00007338); (2) the BETTER web application, developed by LBNL and McQuillen Interactive Pty. Ltd; and (3) the BETTER application programming interface (API), also developed by LBNL and McQuillen Interactive Pty. Ltd. BETTER enables building and portfolio owners, managers, and service providers worldwide to quickly, easily identify cost-saving energy efficiency retrofits in existing buildings and portfolios without expensive site visits or complex modeling. With minimal data input, the tool benchmarks a building’s electric and fossil energy usage against peers; quantifies energy, cost and greenhouse gas (GHG) emission reduction potentials at the building and portfolio levels; and recommends energy efficiency measures to decarbonize and electrify buildings and portfolios, targeting specific energy savings levels. No other tool so comprehensively analyzes buildings and portfolios with such ease. If fully implemented, it is estimated that BETTER could help reduce emissions equivalent to planting 1.3 billion trees globally by 2030. Moreover, an additional 50-75% of embodied GHG emissions could be avoided in each case where BETTER results in a building being retrofitted instead of demolished and replaced, providing substantial additional decarbonization benefits for the buildings sector. BETTER has garnered multiple awards and avid interest from investors. In 2020, it earned a R&D 100 Award for innovation and a LBNL Director’s Award for Technology Transfer. In 2021, BETTER was named an EarthX E-Capital Summit Climate Tech Prize semi-finalist

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2023

Manipulation of glycogen and sucrose synthesis increases photosynthetic productivity in cyanobacteria

Photosynthetic productivity is limited by low energy conversion efficiency in naturally evolved photosynthetic organisms, via multiple mechanisms that are not fully understood. Here we show evidence that extends recent findings that cyanobacteria use “futile” cycles in the synthesis and degradation of carbon compounds to dissipate ATP. Reduction of the glycogen cycle or the sucrose cycle in the model cyanobacterium Synechocystis 6803 led to redirection of cellular energy toward faster growth under simulated outdoor light conditions in photobioreactors that was accompanied by higher energy charge [concentration ratio of ATP/(ATP + ADP)]. Such manipulation of energy metabolism may have potential in engineering microalgal chassis cells to increase productivity of biomass or target metabolites.

09 BIOMASS FUELS↗

NASA NTRS1971

Progress in reducing exhaust pollutants from jet aircraft

Reductions in smoke level and carbon monoxide emissions resulting from air-assist fuel nozzles in jet aircraft exhaust pollutant tests

Butze, H. F.↗

NASA NTRS1972

Aircraft engine pollution reduction

Rudey, R. A.↗

NASA NTRS1972

Aircraft engine pollution reduction.

The effect of engine operation on the types and levels of the major aircraft engine pollutants is described and the major factors governing the formation of these pollutants during the burning of hydrocarbon fuel are discussed. Methods which are being explored to reduce these pollutants are discussed and their application to several experimental research programs are pointed out. Results showing significant reductions in the levels of carbon monoxide, unburned hydrocarbons, and oxides of nitrogen obtained from experimental combustion research programs are presented and discussed to point out potential application to aircraft engines. An experimental program designed to develop and demonstrate these and other advanced, low pollution combustor design methods is described. Results that have been obtained to date indicate considerable promise for reducing advanced engine exhaust pollutants to levels significantly below current engines.

Rudey, R. A.↗

NASA NTRS1974

Feasibility demonstration of a road vehicle fueled with hydrogen-enriched gasoline

Evaluation of the concept of using hydrogen-enriched gasoline in a modified internal combustion engine in order to make possible the burning of ultralean mixtures. The use of such an engine in a road vehicle demonstrated that the addition of small quantities of gaseous hydrogen to gasoline resulted in significant reductions in exhaust emissions of carbon monoxide and nitrogen oxides as well as in thermal efficiency improvements of the engine performance.

Hoehn, F. W.↗

NASA NTRS1988

Pretreatment of CO oxidation catalysts

CO oxidation catalysts with high activity in the range of 25 C to 100 C are important for long-life, closed-cycle operation of pulsed carbon dioxide 2 lasers. A reductive pretreatment with either CO or H sub 2 was shown to significantly enhance the activity of a commerically-available platinum on tin (IV) oxide (Pt/SnO2) catalyst relative to an oxidative or inert pretreatment or no pretreatment. Pretreatment at temperatures of 175 C and above caused an initial dip in observed CO or O sub 2 loss or CO sub 2 formation in a test gas mixture of 1 percent CO and 0.5 percent O sub 2 in a He gas matrix before a steady-state yield was obtained. This dip was found to be caused by dehydration of the surface of the catalyst and was readily eliminated by humidifying the catalyst or the test gas mixture. It was also found that too much moisture resulted in a lower overall yield of CO sub 2. Under similar conditions, it is hypothesized that the effect of the humidification is to increase the concentration of OH groups on the surface of the catalyst. The effect of having high concentration of CO sub 2 in the test gas mixture upon the loss of CO and O sub 2 as well as the effect of periods of relaxation of the catalyst under non-test gas conditions was studied. The purpose of these studies was to gain an insight into the mechanism of CO oxidation on this type of catalyst.

Vannorman, John D.↗

NASA NTRS1990

Hot corrosion of silicon carbide and silicon nitride at 1000 C

The sodium sulfate hot corrosion of silicon-based ceramics at 1000 C has been extensively studied. Deposition of the sodium sulfate corrodant from combustion products is discussed in relation to sodium air impurity and sulfur fuel impurity content. Corrosion occurs by the combined processes of oxidation to form protective silica scales and dissolution of these scales to form nonprotective sodium silicates. The chemical corrosion mechanisms are presented in terms of acidic/basic dissolution of oxides in molten salts. The reactions are strongly influenced by the presence of free carbon in the ceramic. Strength reductions have been measured and are attributed to pitting in SiC and grain boundary attack in Si3N4. Initial results of burner corrosion of two ceramic matrix composites are consistent with the models developed for monolithic ceramics.

Fox, Dennis S.↗

NASA NTRS1991

The biogeochemistry of microbial mats, stromatolites and the ancient biosphere

Stromatolites offer an unparalleled geologic record of early life, because they constitute the oldest and most abundant recognizable remains of microbial ecosystems. Microbial mats are living homologs of stromatolites; thus, the physiology of the microbiota as well as the processes which create those features of mats (e.g., biomarker organic compounds, elemental and stable isotopic compositions) which are preserved in the ancient record. Observations of the carbon isotopic composition (delta C-13) of stromatolites and microbial mats were made and are consistent with the hypothesis that atmospheric CO2 concentrations have declined by at least one to two orders of magnitude during the past 2.5 Ga. Whereas delta C-13 values of carbonate carbon average about 0 permil during both the early and mid-Proterozoic, the delta C-13 values of stromatolitic organic matter increase from an average of -35 between 2.0 and 2.6 Ga ago to an average of about -28 about 1.0 Ga ago. Modern microbial mats in hypersaline environments have delta C-13 values typically in the range of -5 to -9, relative to an inorganic bicarbonate source at 0 permil. Both microbial mats and pur cultures of cyanobacteria grown in waters in near equilibrium with current atmospheric CO2 levels exhibit minimal discrimination against C-13. In contrast, hot spring cyanobacterial mats or cyanobacterial cultures grown under higher CO2 levels exhibit substantially greater discrimination. If care is taken to compare modern mats with stromatolites from comparable environments, it might be possible to estimate ancient levels of atmospheric CO2. In modern microbial mats, a tight coupling exists between photosynthetic organic carbon production and subsequent carbon oxidation, mostly by sulfate reduction. The rate of one process fuels a high rate of the other, with much of the sulfate reduction occurring within the same depth interval as oxygenic photosynthesis. Other aspects of this study are presented.

Desmarais, D. J.↗

NASA NTRS1991

Modeling of advanced ECLSS/ARS with ASPEN

System-level ASPEN models were developed for the CO2 partial reduction subsystem and a bioregenerative life support subsystem (BRLSS). The individual component and subsystem models were integrated into three different system-level atmospheric revitalization subsystem (ARS) models: baseline physico-chemical, BRLSS, and partial reduction of Martian CO2. The Aspen models were based on FORTRAN interfaces necessary for integration with another program, G189A, to perform quasi-transient modeling. Detailed reactor models were prepared for the two CO2 reduction reactors (Bosch and Advanced Carbon Formation), and the low-temperature trace contaminant oxidation reactor.

Kolodney, M.↗

NASA NTRS2002

Pure Water From a Pure Genius

Ammonium perchlorate is widely used throughout the aerospace, munitions, and pyrotechnics industries as a primary ingredient in solid rocket and missile propellants, fireworks, and explosive charges. This highly soluble salt has tainted soils and water sources all over the world, and is believed to be an endocrine disrupter, adversely affecting the growth patterns of a fetus or a young child. UMPQUA Research Company (URC), once a small drinking water testing laboratory and a research and development contractor for NASA's manned spaceflight applications, has evolved to become a leader in water purification and analysis. With a total of 11 patents issued for new technologies created by URC under NASA SBIR contracts and a 25-year commitment to water recycling, the company clearly possessed the qualifications necessary to tackle the presence of perchlorate in water. An SBIR contract with NASA's Marshall Space Flight Center that concentrated on the stringent water quality requirements of long-term, manned spaceflight was the source for URC's process and catalyst to facilitate the destruction of perchlorate and nitrate in water. URC licensed the rights of its unique reduction reaction process to Calgon Carbon Corporation for use with the company's perchlorate/nitrate remediation process, otherwise known as ISEP(R).

Source record↗

NASA NTRS2003

Oxidation Kinetics and Strength Degradation of Carbon Fibers in a Cracked Ceramic Matrix Composite

Experimental results and oxidation modeling will be presented to discuss carbon fiber susceptibility to oxidation, the oxidation kinetics regimes and composite strength degradation and failure due to oxidation. Thermogravimetric Analysis (TGA) was used to study the oxidation rates of carbon fiber and of a pyro-carbon interphase. The analysis was used to separately obtain activation energies for the carbon constituents within a C/SiC composite. TGA was also conducted on C/SiC composite material to study carbon oxidation and crack closure as a function of temperature. In order to more closely match applications conditions C/SiC tensile coupons were also tested under stressed oxidation conditions. The stressed oxidation tests show that C/SiC is much more susceptible to oxidation when the material is under an applied load where the cracks are open and allow for oxygen ingress. The results help correlate carbon oxidation with composite strength reduction and failure.

Halbig, Michael C.↗

NASA NTRS2008

Oxidation-reduction catalyst and its process of use

This invention relates generally to a ruthenium stabilized oxidation-reduction catalyst useful for oxidizing carbon monoxide, and volatile organic compounds, and reducing nitrogen oxide species in oxidizing environments, substantially without the formation of toxic and volatile ruthenium oxide species upon said oxidizing environment being at high temperatures.

Jordan, Jeffrey D.↗

NASA NTRS2011

High Resolution Camera for Mapping Titan Surface

Titan, Saturn's largest moon, has a dense atmosphere and is the only object besides Earth to have stable liquids at its surface. The Cassini/Huygens mission has revealed the extraordinary breadth of geological processes shaping its surface. Further study requires high resolution imaging of the surface, which is restrained by light absorption by methane and scattering from aerosols. The Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini spacecraft has demonstrated that Titan's surface can be observed within several windows in the near infrared, allowing us to process several regions in order to create a geological map and to determine the morphology. Specular reflections monitored on the lakes of the North Pole show little scattering at 5 microns, which, combined with the present study of Titan's northern pole area, refutes the paradigm that only radar can achieve high resolution mapping of the surface. The present data allowed us to monitor the evolution of lakes, to identify additional lakes at the Northern Pole, to examine Titan's hypothesis of non-synchronous rotation and to analyze the albedo of the North Pole surface. Future missions to Titan could carry a camera with 5 micron detectors and a carbon fiber radiator for weight reduction.

Cassini↗

DOE OSTI2022

Global Energy Policy to Achieve the United States’ Nationally Determined Contributions: Potential Pathway

In 2021, the United States declared its Nationally Determined Contribution (NDC) in preparation for the COP26 climate summit, setting goals to achieve zero emission electricity by 2035, and reducing net emissions by 50–52% compared to 2005 levels. The current U.S. energy policies were found to not be adequate to meet these goals, thus it is necessary to draft a pathway to achieving these goals through policy changes. This study focused on foreign energy policies to analyze the most effective policies in a host of sectors. By identifying the most ambitious and effective policies from around the world in each sector, this study was able to suggest a policy pathway that can potentially achieve both of goals set in the NDC. In guiding the development of the proposed policy pathway, this study analyzed policies from Australia, Canada, California, China, Denmark, France, Germany, Japan, Russia, South Korea, Sweden, the United Kingdom, and the United States. This study found that the most drastic CO2 reductions came from low-carbon electricity policy, but contributions were also made from carbon capture, reforestation, hydrogen, energy efficiency, and climate smart agriculture.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2025

Better Climate Challenge Working Groups Non-Energy Benefits of Energy Projects-Improving Financial Payback

Energy efficiency is a key strategy recently identified by the United States Department of Energy as a pillar of industrial decarbonization. For manufacturing companies, improving energy efficiency will reduce money spent on energy utilities such as gas, electricity, and oil. Energy improvement projects also provide valuable benefits outside of simple operating cost reductions, such as reducing the carbon footprint, improving safety metrics and even enhancing quality and productivity. Unfortunately, energy efficiency projects have typically faced an adoption gap, even when they meet criteria such as payback period for capital projects. The inclusion and quantification of non-energy benefits (NEBs), also known as co-benefits, in the decision-making process for energy efficiency projects can improve the overall financial payback periods for those projects as well as potentially improve the company's key performance metrics aligned with business strategies. There are no readily available tools that facilitate this, however, and the most used tools for energy audits address NEBs in a perfunctory way if at all. We integrated research for finding and quantifying non-energy benefits of energy efficiency projects into a commonly recognized continuous improvement practice, the Define, Measure, Analyze, Improve and Control (DMAIC) Process. This process, along with software and supplemental materials, guides energy assessments to find and to quantify NEBs associated with energy conservation opportunities. Our aim is to deliver an easy to use and effective process and software tool and to maximize return on investment for energy efficiency projects as well as contribute to companies' strategic performance goals.

DMAIC↗