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At least 955 records · Page 53
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NASA NTRS1994

Reply

While Hegg et al. (1993) accepts the criticism of Anderson et al. (1994) in principle, this involves the adoption of an aerosol composition model and the model that they propose to reconcile these observations with the assertion of Charlson et al. (1992) does not agree with many observations, particularly those made over the North Atlantic Ocean. Although the use of a gain factor (i.e. the partial derivative of aerosol mass with respect to the sulfate ion), proposed by Anderson et al., may be valid for particular cases where a proposed composition model really reflects the actual aerosol composition, this procedure is considered questionable in general. The use of sulfate as a tracer for nonsulfate aerosol mass is questionable, because in the present authors' data set, sulfate averaged only about 26% of the dry aerosol mass. The ammonium mass associated with sulfate mass is not analogous to that betwen the oxygen mass and sulfur mass in the sulfate ion. Strong chemical bonds are present between sulfur and oxygen in sulfate, whereas ammonium and sulfate in haze droplets are ions in solution that may or may not be associated with one another. Thus, there is no reason to assume that sulfate will act as a reliable tracer of ammonium mass. Hegg et al. expresses the view that their approach used for estimating sulfate light scattering efficiency is appropriate for the current level of understanding of atmospheric aerosols.

Hegg, Dean A.↗
NASA NTRS1980

Saturn - UBV photoelectric pinhole scans of the disk. II

During the 1980 Saturn apparition, UBV pinhole scans of the disk were obtained with a photoelectric area-scanning photometer. An analysis of these data reveals that the atmosphere of Saturn can be represented by a finite clear H2 layer overlying a semiinfinite absorbent aerosol haze. The extent of the clear H2 region appears to be latitude-dependent; the H2 column density varies systematically from about 15 km-am over the equatorial and polar regions to about 31 km-am at temperate latitudes. A previous conclusion that the aerosol haze is strongly absorbent in the UV is confirmed; its effective U-band single-scattering albedo is about 0.4. Latitudinal disk structure at visual wavelengths appears to be the result of local variations in the volume density of absorbent particles in the aerosol layer.

Price, M. J.↗
NASA NTRS2017

Correlation Between Soil Moisture and Dust Emissions: An Investigation for Global Climate Modeling

This work is using the newly available NASA SMAP soil moisture measurement data to evaluate its impact on the atmospheric dust emissions. Dust is an important component of atmospheric aerosols, which affects both climate and air quality. In this work, we focused on semi-desert regions, where dust emissions show seasonal variations due to soil moisture changes, i.e. in Sahel of Africa. We first identified three Aerosol Robotic Network (AERONET) sites in the Sahel (IER_Cinzana, Banizoumbou, and Zinder_Airport). We then utilized measurements of aerosol optical depth (AOD), fine mode fraction, size distribution, and single-scattering albedo and its wave-length dependence to select dust plumes from the available measurements We matched the latitude and longitude of the AERONET station to the corresponding SMAP data cell in the years 2015 and 2016, and calculated their correlation coefficient. Additionally, we looked at the correlation coefficient with a three-day and a five-day shift to check the impact of soil moisture on dust plumes with some time delay. Due to the arid nature of Banizoumbou and Zinder_Airport, no correlation was found to exist between local soil moisture and dust aerosol load. While IER_Cinzana had soil moisture levels above the satellite threshold of 0.02cm3/cm3, R-value approaching zero indicated no presence of a correlation. On the other hand, Ilorin demonstrated a significant negative correlation between aerosol optical depth and soil moisture. When isolating the analysis to Ilorin's dry season, a negative correlation of -0.593 was the largest dust-isolated R-value recorded, suggesting that soil moisture is driven the dust emission in this semi-desert region during transitional season.

climate↗
NASA NTRS1978

Analytical inversions in remote sensing of particle size distributions. I - Multispectral extinctions in the anomalous diffraction approximation. II Angular and spectral scattering in diffraction approximations

Consideration is given to analytical inversions in the remote sensing of particle size distributions, noting multispectral extinctions in anomalous diffraction approximation and angular and spectral scattering in diffraction approximation. A closed-form analytical inverse solution is derived in order to reconstruct the size distribution of atmospheric aerosols. The anomalous diffraction approximation to Mie's solution is used to describe the particles. Experimental data yield the geometrical area of aerosol polydispersion. Size distribution is thus found from a set of multispectral extinction measurements. In terms of the angular and spectral scattering of light in a narrow forward cone, it is shown that an analytical inverse solution may also be found for the Fraunhofer approximation to the Kirchhoff diffraction, and for an improved expression of this approximation due to Penndorf (1962) and Shifrin-Punina (1968).

Fymat, A. L.↗
DOE OSTI2024

Helium-electrospray improves sample delivery in X-ray single-particle imaging experiments

Abstract Imaging the structure and observing the dynamics of isolated proteins using single-particle X-ray diffractive imaging (SPI) is one of the potential applications of X-ray free-electron lasers (XFELs). Currently, SPI experiments on isolated proteins are limited by three factors: low signal strength, limited data and high background from gas scattering. The last two factors are largely due to the shortcomings of the aerosol sample delivery methods in use. Here we present our modified electrospray ionization (ESI) source, which we dubbed helium-ESI (He-ESI). With it, we increased particle delivery into the interaction region by a factor of 10, for 26 nm-sized biological particles, and decreased the gas load in the interaction chamber corresponding to an 80% reduction in gas scattering when compared to the original ESI. These improvements have the potential to significantly increase the quality and quantity of SPI diffraction patterns in future experiments using He-ESI, resulting in higher-resolution structures.

Science & Technology - Other Topics↗
NASA NTRS1975

Derivation of phase functions from multiply scattered sunlight transmitted through a hazy atmosphere

The intensity of sunlight multiply scattered in model atmospheres is derived from the equation of radiative transfer by an analytical small-angle approximation. The approximate analytical solutions are compared to rigorous numerical solutions of the same problem. Results obtained from an aerosol-laden model atmosphere are presented. Agreement between the rigorous and the approximate solutions is found to be within a few per cent. The analytical solution to the problem which considers an aerosol-laden atmosphere is then inverted to yield a phase function which describes a single scattering event at small angles. The effect of noisy data on the derived phase function is discussed.

Weinman, J. A.↗
NASA NTRS2017

Information Content of Bistatic Lidar Observations of Aerosols from Space

We present, for the first time, a quantitative retrieval error-propagation study for a bistatic high spectral resolution lidar (HSRL) system intended for detailed quasi-global monitoring of aerosol properties from space. Our results demonstrate that supplementing a conventional monostatic HSRL with an additional receiver flown in formation at a scattering angle close to 165 degrees dramatically increases the information content of the measurements and allows for a sufficiently accurate characterization of tropospheric aerosols. We conclude that a bistatic HSRL system would far exceed the capabilities of currently flown or planned orbital instruments in monitoring global aerosol effects on the environment and on the Earth's climate. We also demonstrate how the commonly used a priori 'regularization' methodology can artificially reduce the propagated uncertainties and can thereby be misleading as to the real retrieval capabilities of a measurement system.

lidar↗
NASA NTRS2011

Multiangle Implementation of Atmospheric Correction (MAIAC):: Radiative Transfer Basis and Look-up Tables - 1

This paper describes a radiative transfer basis of the algorithm MAIAC which performs simultaneous retrievals of atmospheric aerosol and bidirectional surface reflectance from the Moderate Resolution Imaging Spectroradiometer (MODIS). The retrievals are based on an accurate semianalytical solution for the top-of-atmosphere reflectance expressed as an explicit function of three parameters of the Ross-Thick Li-Sparse model of surface bidirectional reflectance. This solution depends on certain functions of atmospheric properties and geometry which are precomputed in the look-up table (LUT). This paper further considers correction of the LUT functions for variations of surface pressure/height and of atmospheric water vapor, which is a common task in the operational remote sensing. It introduces a new analytical method for the water vapor correction of the multiple ]scattering path radiance. It also summarizes the few basic principles that provide a high efficiency and accuracy of the LUT ]based radiative transfer for the aerosol/surface retrievals and optimize the size of LUT. For example, the single-scattering path radiance is calculated analytically for a given surface pressure and atmospheric water vapor. The same is true for the direct surface-reflected radiance, which along with the single-scattering path radiance largely defines the angular dependence of measurements. For these calculations, the aerosol phase functions and kernels of the surface bidirectional reflectance model are precalculated at a high angular resolution. The other radiative transfer functions depend rather smoothly on angles because of multiple scattering and can be calculated at coarser angular resolution to reduce the LUT size. At the same time, this resolution should be high enough to use the nearest neighbor geometry angles to avoid costly three ]dimensional interpolation. The pressure correction is implemented via linear interpolation between two LUTs computed for the standard and reduced pressure levels. A linear mixture and a modified linear mixture methods are used to represent different aerosol types in the aerosol/surface retrievals from several base models of the fine and coarse aerosol fractions. In summary, the developed LUT algorithm allows fast high-accuracy simulations of the outgoing radiance with full variability of the atmospheric and surface bidirectional reflectance properties for the aerosol/surface remote sensing.

Lyapustin, Alexei↗
NASA NTRS1994

Clouds, hazes, and the stratospheric methane abundance in Neptune

Analysis of high-spatial-resolution (approximately 0.8 arcsec) methane band and continuum imagery of Neptune's relatively homogeneous Equatorial Region yields significant constraints on (1) the stratospheric gaseous methane mixing ratio (f(sub CH4, S)), (2) the column abundances and optical properties of stratospheric and tropospheric hydrocarbon hazes, and (3) the wavelength-dependent single-scattering albedo of the 3-bar opaque cloud. From the center-to-limb behavior of the 7270-A and 8900-A CH4 bands, the stratospheric methane mixing ratios is limited to f(sub CH4, S) less than 1.7 x 10(exp -3), with a nominal value of f(sub CH4, S) = 3.5 x 10(exp -4), one to two orders of magnitude less than pre-Voyager estimates, but in agreement with a number of recent ultraviolet and thermal infrared measurements, and largely in agreement with the tropopause mixing ratio implied by Voyager temperature measurements. Upper limits to the stratospheric haze mass column abundance and 6190-A and 8900-A haze opacities are 0.61 micrograms/sq cm and 0.075 and 0.042, respectively, with nominal values of 0.20 micrograms/sq cm and 0.025 and 0.014 for the 0.2 micrometers radius particles preferred by the recent Voyager PPS analysis of Pryor et al. (1992). The tropospheric CH4 haze opacities are comparable to that found in the stratosphere, i.e., upper limits of 0.104 and 0.065 at 6190 A and 8900 A, respectively, with nominal values of 0.085 and 0.058. This indicates a column abundance less than 11.0 micrograms/sq cm, corresponding to the methane gas content within a well-mixed 3% methane tropospheric layer only 0.1 cm thick near the 1.5-bar CH4 condensation level. Conservative scattering is ruled out for the opaque cloud near 3 bars marking the bottom of the visible atmosphere. Specifically, we find cloud single-scattering albedos of 0.915 +/- 0.006 at 6340 A, 0.775 +/- 0.012 at 7490 A, and 0.803 +/- 0.010 at 8260 A. Global models utilizing a complete global spectrum confirm the red-absorbing character of the 3-bar cloud. The global-mean model has approximately 7.7 times greater stratospheric aerosol content than the Equatorial Region. An analysis of stratospheric haze precipitation rates indicates a steady-state haze production rate of 0.185-1.5 x 10(exp -14) g/sq cm/s, in agreement with recent theoretical photochemical estimates. Finally, reanalysis of the Voyager PPS 7500-A phase angle data utilizing the f(sub CH4, S) value derived here confirms the Pryor et al. result of a tropospheric CH4 haze opacity of a few tenths in the 22-30 degs S latitude region, several times that of the Equatorial Region or of the globe. The factor-of-10 reduction in f(sub CH4, S) below that assumed by Pryor et al. implies decreased gas absorption and consequently a decrease in the forward-scattering component of tropospheric aerosols.

Baines, Kevin H.↗
NASA NTRS2019

Spatial Distribution of Aerosol Microphysical and Optical Properties and Direct Radiative Effect from the China Aerosol Remote Sensing Network

Multi-year observations of aerosol microphysical and optical properties, obtained through ground-based remote sensing at 50 China Aerosol Remote Sensing Network (CARSNET) sites, were used to characterize the aerosol climatology for representative remote, rural, and urban areas over China to assess effects on climate. The annual mean effective radii for total particles (ReffT) decreased from north to south and from rural to urban sites, and high total particle volumes were found at the urban sites. The aerosol optical depth at 440 nm (AOD440 nm) increased from remote and rural sites (0.12) to urban sites (0.79), and the extinction Ångström exponent (EAE440–870 nm) increased from 0.71 at the arid and semi-arid sites to 1.15 at the urban sites, presumably due to anthropogenic emissions. Single-scattering albedo (SSA440 nm) ranged from 0.88 to 0.92, indicating slightly to strongly absorbing aerosols. Absorption AOD440 nm values were 0.01 at the remote sites versus 0.07 at the urban sites. The average direct aerosol radiative effect (DARE) at the bottom of atmosphere increased from the sites in the remote areas (−24.40 W m−2) to the urban areas (−103.28 W m−2), indicating increased cooling at the latter. The DARE for the top of the atmosphere increased from −4.79 W m−2 at the remote sites to −30.05 W m−2 at the urban sites, indicating overall cooling effects for the Earth–atmosphere system. A classification method based on SSA440 nm, fine-mode fraction (FMF), and EAE440–870 nm showed that coarse-mode particles (mainly dust) were dominant at the rural sites near the northwestern deserts, while light-absorbing, fine-mode particles were important at most urban sites. This study will be important for understanding aerosol climate effects and regional environmental pollution, and the results will provide useful information for satellite validation and the improvement of climate modelling.

Huizheng Che↗
NASA NTRS1999

A New Instrument for Measurement of the Solar Aureole Radiance Distribution from Unstable Platforms

A novel imaging solar aureole radiometer, which can obtain absolute radiometric measurements of the solar aureole when operated on an unstable platform is described. A CCD array is used to image the aureole, while a neutral density occulter on a long pole blocks the direct solar radiation. This ensures accurate direction registration as the sun appears in acquired images, and the total circumsolar region is measured simultaneously. The imaging nature of this instrument along with a special triggering device permit acquisition of the circumsolar sky radiance within 7.5 degrees of the center of the solar disk, and within 1 degree of the edge of the solar disk. This innovation makes possible for the first time, reliable and accurate radiometric measurements of the solar aureole from unstable mobile platforms such as ships. This allows determination small angle atmospheric scattering. The instrument has been used in field studies of atmospheric aerosols and will be used in satellite validation and calibration campaigns.

Ritter, Joseph M.↗
NASA NTRS2000

Ground-Based Lidar Measurements of Aerosols During ACE-2 Instrument Description, Results, and Comparisons with Other Ground-Based and Airborne Measurements

A micro-pulse lidar system (MPL) was used to measure the vertical and horizontal distribution or aerosols during the Aerosol Characterization Experiment 2 (ACE-2) in June and July of 1997. The MPL measurements were made at the Izana observatory (IZO), a weather station located on a mountain ridge (28 deg 18'N, 16 deg 30'W, 2367 m asl) near the center of the island of Tenerife, Canary Islands. The MPL was used to acquire aerosol backscatter, extinction, and optical depth profiles for normal background periods and periods influenced by Saharan dust from North Africa. System tests and calibration procedures are discussed, and in analysis of aerosol optical profiles acquired during ACE-2 is presented. MPL data taken during normal IZO conditions (no dust) showed that upslope aerosols appeared during the day and dissipated at night and that the layers were mostly confined to altitudes a few hundred meters above IZO. MPL data taken during a Saharan dust episode on 17 July showed that peak aerosol extinction values were an order of magnitude greater than molecular scattering over IZO. and that the dust layers extended to 5 km asl. The value of the dust backscatter-extinction ratio was determined to be 0.027 + 0.007 per sr. Comparisons of the MPL data with data from other co-located instruments showed good agreement during the dust episode.

Welton, Ellsworth J.↗
NASA NTRS2000

Ground-Based Lidar Measurements of Aerosols During ACE-2: Instrument Description, Results, and Comparisons with Other Ground-Based and Airborne Measurements

A micro-pulse lidar system (MPL) was used to measure the vertical and horizontal distribution of aerosols during the Aerosol Characterization Experiment 2 (ACE-2) in June and July of 1997. The MPL measurements were made at the Izana observatory (IZO), a weather station located on a mountain ridge (28 deg 18 min N, 16 deg 30 min W, 2367 m asl) near the center of the island of Tenerife, Canary Islands. The MPL was used to acquire aerosol backscatter, extinction, and optical depth profiles for normal background periods and periods influenced by Saharan dust from North Africa. System tests and calibration procedures are discussed, and an analysis of aerosol optical profiles acquired during ACE-2 is presented. MPL data taken during normal IZO conditions (no dust) showed that upslope aerosols appeared during the day and dissipated at night and that the layers were mostly confined to altitudes a few hundred meters above IZO. MPL data taken during a Saharan dust episode on 17 July showed that peak aerosol extinction values were an order of magnitude greater than molecular scattering over IZO, and that the dust layers extended to 5 km asl. The value of the dust backscatter-extinction ratio was determined to be 0.027 +/- 0.007 sr(exp -1). Comparisons of the MPL data with data from other collocated instruments showed good agreement during the dust episode.

Welton, Ellsworth J.↗
NASA NTRS2010

Assessment of Biases in MODIS Surface Reflectance Due to Lambertian Approximation

Using MODIS data and the AERONET-based Surface Reflectance Validation Network (ASRVN), this work studies errors of MODIS atmospheric correction caused by the Lambertian approximation. On one hand, this approximation greatly simplifies the radiative transfer model, reduces the size of the look-up tables, and makes operational algorithm faster. On the other hand, uncompensated atmospheric scattering caused by Lambertian model systematically biases the results. For example, for a typical bowl-shaped bidirectional reflectance distribution function (BRDF), the derived reflectance is underestimated at high solar or view zenith angles, where BRDF is high, and is overestimated at low zenith angles where BRDF is low. The magnitude of biases grows with the amount of scattering in the atmosphere, i.e., at shorter wavelengths and at higher aerosol concentration. The slope of regression of Lambertian surface reflectance vs. ASRVN bidirectional reflectance factor (BRF) is about 0.85 in the red and 0.6 in the green bands. This error propagates into the MODIS BRDF/albedo algorithm, slightly reducing the magnitude of overall reflectance and anisotropy of BRDF. This results in a small negative bias of spectral surface albedo. An assessment for the GSFC (Greenbelt, USA) validation site shows the albedo reduction by 0.004 in the near infrared, 0.005 in the red, and 0.008 in the green MODIS bands.

Wang, Yujie↗
NASA NTRS2017

Developing and Diagnosing Climate Change Indicators of Regional Aerosol Optical Properties

Given the importance of aerosol particles to radiative transfer via aerosol-radiation interactions, a methodology for tracking and diagnosing causes of temporal changes in regional-scale aerosol populations is illustrated. The aerosol optical properties tracked include estimates of total columnar burden (aerosol optical depth, AOD), dominant size mode (Ångström exponent, AE), and relative magnitude of radiation scattering versus absorption (single scattering albedo, SSA), along with metrics of the structure of the spatial field of these properties. Over well-defined regions of North America, there are generally negative temporal trends in mean and extreme AOD, and SSA. These are consistent with lower aerosol burdens and transition towards a relatively absorbing aerosol, driven primarily by declining sulfur dioxide emissions. Conversely, more remote regions are characterized by increasing mean and extreme AOD that is attributed to increased local wildfire emissions and long-range (transcontinental) transport. Regional and national reductions in anthropogenic emissions of aerosol precursors are leading to declining spatial autocorrelation in the aerosol fields and increased importance of local anthropogenic emissions in dictating aerosol burdens. However, synoptic types associated with high aerosol burdens are intensifying (becoming more warm and humid), and thus changes in synoptic meteorology may be offsetting aerosol burden reductions associated with emissions legislation.

Ryan C Sullivan↗
DOE OSTI2024

Titanium Dioxide Nanomaterial Ink Production Through Laser Ablation Synthesis in Solution for Printed Electronics Applications

Flexible and printed electronics have become increasingly popular as they make possible the production of flexible, low-cost, multifunction devices that are unachievable through traditional manufacturing methods. The printed films are significantly impacted and thus limited by the existing ink production process. Herein, an alternate technique of generating high-quality titanium dioxide (TiO 2 ) nanoparticle ink compatible with aerosol jet printing using laser ablation synthesis in solution (LASiS) is showcased. Dynamic light scattering data and transmission electron microscopy confirm the particle size distribution. UV–vis measurements are performed, and the Beer–Lambert relationship is used to determine the concentration of the generated ink. The inks generated at two different repetition rates are compared: 200 kHz and 1 MHz. X-Ray diffraction analysis of the aerosol jet printed thin film post-thermal sintering confirms the grain size and phase purity of the printed thin films. This work demonstrates the effectiveness of the LASiS technique in producing printable nanoparticle inks with little-to-no postprocessing.

36 MATERIALS SCIENCE↗
NASA NTRS1975

A comparison of dustsonde and LIDAR measurements of stratospheric aerosols

This paper describes the results and analysis of an experiment to compare the stratospheric aerosol profiles as measured by a balloon-borne in situ particle counter and by the backscattered light from a ground-based laser radar (LIDAR) operating at a wavelength of 6943 A. The profile comparison agrees within the experimental errors for particles with radii greater than 0.25 micrometer and for altitudes between 15 and 28 kilometers. Following the calibration tests, the LIDAR was used to monitor the stratospheric aerosols at Hampton, Virginia. Enhanced backscatter appeared sporadically in November and December of 1974 over Hampton; scattering ratios averaged over altitude increments of 450 meters range from 1.10 at 20 kilometers in early November to 3.3 at 17 kilometers on December 18. The source of this enhanced backscattering is attributed to the aerosols associated with the eruption of the Fuego volcano in Guatemala in mid-October.

Remsberg, E. E.↗