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NASA NTRS2002

Developmental regulation of the effects of fibroblast growth factor-2 and 1-octanol on neuronogenesis: implications for a hypothesis relating to mitogen-antimitogen opposition

Neocortical neurons arise from a pseudostratified ventricular epithelium (PVE) that lies within the ventricular zone (VZ) at the margins of the embryonic cerebral ventricles. We examined the effects of fibroblast growth factor-2 (FGF-2) and 1-octanol on cell output behavior of the PVE in explants of the embryonic mouse cerebral wall. FGF-2 is mitogenic and 1-octanol antimitogenic in the PVE. Whereas all postmitotic cells migrate out of the VZ in vivo, in the explants some postmitotic cells remain within the VZ. We refer to these cells as the indeterminate or I fraction, because they neither exit from the VZ nor reenter S phase as part of the proliferative (P) fraction. They are considered to be either in an extremely prolonged G(1) phase, unable to pass the G(1)/S transition, or in the G(0) state. The I fate choice is modulated by both FGF-2 and 1-octanol. FGF-2 decreased the I fraction and increased the P fraction. In contrast, 1-octanol increased the I fraction and nearly eliminated the P fraction. The effects of FGF-2 and 1-octanol were developmentally regulated, in that they were observed in the developmentally advanced lateral region of the cerebral wall but not in the medial region. Copyright 2002 Wiley-Liss, Inc.

NASA Discipline Developmental Biology↗

NASA NTRS2014

Aircraft Turbine Engine Control Research at NASA Glenn Research Center

This lecture will provide an overview of the aircraft turbine engine control research at NASA (National Aeronautics and Space Administration) Glenn Research Center (GRC). A brief introduction to the engine control problem is first provided with a description of the current state-of-the-art control law structure. A historical aspect of engine control development since the 1940s is then provided with a special emphasis on the contributions of GRC. The traditional engine control problem has been to provide a means to safely transition the engine from one steady-state operating point to another based on the pilot throttle inputs. With the increased emphasis on aircraft safety, enhanced performance and affordability, and the need to reduce the environmental impact of aircraft, there are many new challenges being faced by the designers of aircraft propulsion systems. The Controls and Dynamics Branch (CDB) at GRC is leading and participating in various projects in partnership with other organizations within GRC and across NASA, other government agencies, the U.S. aerospace industry, and academia to develop advanced propulsion controls and diagnostics technologies that will help meet the challenging goals of NASA programs under the Aeronautics Research Mission. The second part of the lecture provides an overview of the various CDB technology development activities in aircraft engine control and diagnostics, both current and some accomplished in the recent past. The motivation for each of the research efforts, the research approach, technical challenges and the key progress to date are summarized. The technologies to be discussed include system level engine control concepts, gas path diagnostics, active component control, and distributed engine control architecture. The lecture will end with a futuristic perspective of how the various current technology developments will lead to an Intelligent and Autonomous Propulsion System requiring none to very minimum pilot interface, interfacing directly with the flight management system to determine its mode of operation, and providing personalized engine control to optimize its performance given the current condition and mission objectives.

Propulsion↗

NASA NTRS2014

Air Breathing Propulsion Controls and Diagnostics Research at NASA Glenn Under NASA Aeronautics Research Mission Programs

Engine Control↗

NASA NTRS2015

Photoejection with Excitation in H(-) and Other Systems

Lyman-alpha radiation, 1216 Angstroms , has been seen from the sun and from various astrophysical sources. This radiation arises from the radiative transition from the 2p(sup 2P) state to the 1s(sup 2S) state of the hydrogen atom. The 2P state can be excited from the 1s(sup 2S) state by electron impact. However, it is possible to produce this excited state by photodetachment of the H(-) ion, leaving the H atom in the 2P state. We have calculated cross sections for this process using Hylleraas-type functions for the H− ion and using the exchange approximation for the photoelectron in the final continuum states of angular momenta equal to 0 and 2. The photoabsorption cross sections in H−ions or He atoms leaving the hydrogen atom and helium ion in 2(sup 2S) are also calculated. Similar calculations havebeen carried out for the Li(+), Be2(+), and C4(+) ions.

photoejection↗

NASA NTRS2018

Active Gas-Gap Heat Switch with Fast Thermal Response

An active gas-gap heat switch may significantly reduce the time required to transition between the open and closed states, reduce the heat require to warm the getter, and reduce the heat that leaks from the getter to the switch body. A thermal interface at one end of the active gas-gap heat switch may include a plurality of fins. A getter assembly may be hermetically attached to the thermal interface and a containment tube may surround and house the plurality of fins.

Shirron, Peter J.↗

NASA NTRS2021

Habitability Models for Astrobiology

Habitability has been generally defined as the capability of an environment to support life. Ecologists have beenusing Habitat Suitability Models (HSMs) for more than four decades to study the habitability of Earth fromlocal to global scales. Astrobiologists have been proposing different habitability models for some time, with lit-tle integration and consistency among them, being different in function to those used by ecologists. Habitabilitymodels are not only used to determine whether environments are habitable, but they also are used to charac-terize what key factors are responsible for the gradual transition from low to high habitability states. Here wereview and compare some of the different models used by ecologists and astrobiologists and suggest how theycould be integrated into new habitability standards. Such standards will help improve the comparison and charac-terization of potentially habitable environments, prioritize target selections, and study correlations between habit-ability and biosignatures. Habitability models are the foundation of planetary habitability science, and the synergybetween ecologists and astrobiologists is necessary to expand our understanding of the habitability of Earth,the Solar System, and extrasolar planets.

Habitability↗

NASA NTRS2023

Cavity Ring-Down Spectroscopy of Anthracene, 9-Methylanthracene, and 2 Methylanthracene in Supersonic Expansion

The S0–S1 absorption spectra of anthracene (C14H10), 9-methylanthracene (C15H12), and 2-methylanthracene (C15H12) are measured in the ultraviolet region between 330 and 375 nm (26,666 to 30,303 cm–1) with cavity ring-down spectroscopy in supersonic free-jet expansions of argon. The associated vibronic band systems and their spectroscopic assignments are discussed and compared to previous studies performed using fluorescence excitation and dispersed fluorescence techniques. Density functional theory (DFT) calculations were carried out to study the structures and evaluate the vibrational transitions of the ground and excited states. Time-dependent DFT calculations of the first electronic excited states and Franck–Condon factor calculations were carried out to assist in the assignment of the experimentally measured vibronic bands. The vibronic spectra obtained in absorption agree well with fluorescence excitation spectra in terms of peak positions but exhibit different relative band intensities. We find a very good match between experimentally obtained vibronic line positions and the peak positions of the quantum chemically calculated Franck–Condon excitation lines.

Salma Bejaoui↗

NASA NTRS1977

Matrix glass vs. intruded glass in lunar breccia 15286

The viscous flow and crystallization behavior of the matrix composition of breccia 15286 have been determined in the 1159-1307 C and 644-770 C temperature ranges. The Shaw (1972) model and, to a slightly lesser extent, the semiempirical Bottinga and Weill (1972) model describe the variation of viscosity with temperature. The crystal growth rate has been determined over the temperature range 821-1185 C. Time-temperature-transformation, logarithmic cooling, and continuous cooling curves were constructed; a nucleation barrier of 60 kT at a relative undercooling of 0.2 is assumed. It is estimated that the matrix of 15286 breccia cooled at a rate greater than 80 K/min through the glass transition region. The increase in density that occurs when the matrix glass is annealed suggests that the breccia was formed by cooling from the molten state rather than by direct shock-induced transition from crystal to glass. Viscous sintering under continuous cooling and logarithmic cooling conditions is analyzed.

Handwerker, C. A.↗

NASA NTRS1990

The C9 cluster - Structure and infrared frequencies

A structural characterization is presented for C9, the largest cluster predicted to have a linear ground state. IR laser diode absorption spectroscopy of a supersonic carbon jet is used to measure 51 lines of the nu6 (sigma u) antisymmetric stretch fundamental transition within the linear 1Sigma(g)+ ground electronic state of C9. The measured ground state rotational constant suggests an effective C-C bond length which is in good agreement with ab initio theory and consistent with cumulenic bonding in this cluster.

Heath, J. R.↗

NASA NTRS1983

Vortices, stability, and turbulence

The transition process between laminar flow to turbulent flow is discussed in terms of a third state of fluid motion, vortical motion that is approximately periodic in space and/or time and displays symmetrical properties. The possibility that the transition from laminar to turbulent flow is accompanied by intermediate vortical states, with turbulence being an instability of the vortical states, is examined, with consideration given to the hypothesis that the turbulent state retains a memory of the vortex structures. Solutions are sought for the Navier-Stokes equations for a viscous liquid in a channel. Instances of inviscid vortical states and the presence of a three-dimensional instability are studied, demonstrating that transition phenomena can be explained qualitatively in terms of vortical state characteristics.

Saffman, P. G.↗

NASA NTRS1977

Rotational and vibrational transitions for Li + H2 collisions

Close coupling calculations for integral and differential cross sections have been carried out for Li + H2 collisions with an ab initio Hartree-Fock potential energy surface. Rotational, vibrational, and vib-rotational excitation cross sections are reported at 0.4336 eV, 0.7 eV, and 0.8673 eV in the center of mass system. For pure rotational excitations, which dominate the inelastic scattering, coupling with vibrational states is not very important. For vibrational transitions, the influence of large multiquantum rotational transitions is far less than that found for Li(+) + H2 collisions.

Choi, B. H.↗

NASA NTRS1991

Theoretical study of the spectroscopy of FeH(+)

High-level ab initio calculations are reported for the low-lying states of the FeH(+) molecule. The ground state is determined to be X 5Delta with the low-lying 5Pi state lying about 600/cm higher. The excited states of FeH(+) are repulsive in the Franck-Condon region of the ground state. Thus it is likely that FeH(+) is photodissociated in stellar atmospheres. The strongest transition should be the (3) 5Delta - X 5Delta transition near 30,000/cm, which should give rise to a structureless feature in the absorption spectrum due to the repulsive nature of the upper state. All of the perpendicular transitions are computed to be very weak. The D0 value of FeH(+) is computed to be 50.2 kcal/mole, which should be the most accurate theoretical value to date.

Langhoff, Stephen R.↗

NASA NTRS1996

Investigation of Oxygen-Induced Quenching of Phosphorescence in Photoexcited Aromatic Molecules by Positron Annihilation Spectroscopy

Platinum OctaEthyl Porphyrin (Pt.OEP) is an efficient phosphor under ultraviolet excitation. The phosphorescent triplet state P(T(Sup 1)) is readily quenched by the oxygen O2 molecules. This phenomenon is being utilized as the basis for global air pressure measurements in aerodynamic facilities at various laboratories. The exact mechanism by which O2 molecules quench the P(T(Sup 1) approaches P(S(Sub O)) transitions is still unknown. The diamagnetic singlet states P(S(Sub n)), which feed P(T(Sub 1)) states via intersystem crossings, would presumably not be affected by O2. It must be only the magnetic P(T(Sub 1)) states, which can interact with the paramagnetic O2 molecules, that are affected. However, our positron lifetime and Doppler broadening studies suggest the formation of O2P(S(Sub n)), complexes which can also eventually reduce the population of the P(T(Sub 1)) states (i.e., quench phosphorescence). This reduction is possible because higher triplet states in (Pt.OEP) are admixed with the P(S(Sub 1)), states via spin orbit interactions. The experimental procedures and the results of various measurements are presented in this paper.

Singh, Jag J.↗

NASA NTRS1984

Laboratory submillimeter transition frequencies of Li-7H and Li-6H

The fundamental (J = 1 - 0) rotational transition frequencies of Li-7H and Li-6H in their ground (v = 0) vibrational states and of Li-7H in its first excited (v = 1) vibrational state have been measured in the laboratory. Use of these transition frequencies should permit astronomical investigations of LiH abundances in red giant stars of high lithium abundance.

Plummer, G. M.↗

NASA NTRS1986

Accurate ab initio calculations which demonstrate a 3 Pi u ground state for Al2

The spectroscopic parameters and separations between the three low-lying X 3 Pi u, A 3 Sigma g -, and a 1 Sigma g + states of Al2 are studied as a function of both the one-particle and n-particle basis set. Approximate correlation treatments are calibrated against full Cl calculations correlating the six valence electrons in a double-zeta plus two d-function basis set. Since the CASSCF/MRCI 3 Pi u to 3 Sigma g - separation is in excellent agreement wtih the FCI value, the MRCI calculations were carried out in an extended (20s13p6d4f)/(6s5p3d2f) gaussian basis. Including a small correction for relativistic effects, the best estimate is that 3 Sigma g - state lies 174/cm above the 3 Pi u ground state. The 1 Sigma g + state lies at least 2000/cm higher in energy. At the CPF level, inclusion of 2s and 2p correlation has little effect on D sub e, reduces T sub e by only 26/cm, and shortens the bond lengths by about 0.02 a sub o. Further strong support for a 3 Pi u ground state comes from the experimental absorption spectra, since both observed transitions can be convincingly assigned as 3 Pi u yields 3 Pi g. The (2) 3 Pi g state is observed to be sensitive to the level of correlation treatment, and to have its minimum shifted to shorter rho values, such that the strongest experimental absorption peak probably corresponds to the 0 yields 2 transition.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1988

The gamma 1 and gamma 3 bands of (16)O3: Line positions and intensities

Using 0.005/cm-resolution Fourier transform spectra of samples of ozone, the gamma 1 and gamma 3 bands of (16)O3 have been reanalyzed to obtain accurate line positions and an extended set of upper state rotational levels (J up to 69, K sub a up to 20). Combined with the available microwave data, these upper state rotational levels were satisfactorily fitted using a Hamiltonian which takes explicitly into account the strong Coriolis interaction affecting the rotational levels of these two interacting states. In addition, 350 relative line intensities were measured from which the rotational expansions of the transition moment operators for the gamma 1 and gamma 3 states have been deduced. Finally, a complete listing of line positions, intensities, and lower state energies of the gamma 1 and gamma 3 bands of (16)O3 has been generated.

Flaud, J.-M.↗

NASA NTRS2003

Baseline Testing of the Club Car Carryall With Asymmetric Ultracapacitors

The NASA John H. Glenn Research Center initiated baseline testing of the Club Car Carryall with asymmetric ultracapacitors as a way to reduce pollution in industrial settings, reduce fossil fuel consumption, and reduce operating costs for transportation systems. The Club Car Carryall provides an inexpensive approach to advance the state of the art in electric vehicle technology in a practical application. The project transfers space technology to terrestrial use via non-traditional partners, and provides power system data valuable for future space applications. The work was done under the Hybrid Power Management (HPM) Program, which includes the Hybrid Electric Transit Bus (HETB). The Carryall is a state of the art, ground up, electric utility vehicle. A unique aspect of the project was the use of a state of the art, long life ultracapacitor energy storage system. Innovative features, such as regenerative braking through ultracapacitor energy storage, are planned. Regenerative braking recovers much of the kinetic energy of the vehicle during deceleration. The Carryall was tested with the standard lead acid battery energy storage system, as well as with an asymmetric ultracapacitor energy storage system. The report concludes that the Carryall provides excellent performance, and that the implementation of asymmetric ultracapacitors in the power system can provide significant performance improvements.

Eichenberg, Dennis J.↗

NASA NTRS1981

GaAs-oxide interface states - A gigantic photoionization effect and its implications to the origin of these states

Gigantic photoionization was discovered on GaAs-oxide interfaces leading to the discharge of deep surface states with rates exceeding 1000 times those of photoionization transitions to the conduction band. It exhibits a peak similar to acceptor-donor transitions and is explained as due to energy transfer from photo-excited donor-acceptor pairs to deep surface states. This new process indicates the presence of significant concentrations of shallow donor and acceptor levels not recognized in previous interface models.

Lagowski, J.↗