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Tc2GaSi crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Tc2GaSi ribbons oriented in the (1, 0, 0) direction. Tc3- is bonded in a linear geometry to one Ga2+ and one Si4+ atom. The Tc–Ga bond length is 2.54 Å. The Tc–Si bond length is 2.28 Å. Ga2+ is bonded in a linear geometry to two equivalent Tc3- atoms. Si4+ is bonded in a linear geometry to two equivalent Tc3- atoms.
ScVTc2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two ScVTc2 ribbons oriented in the (1, 0, 0) direction. Sc3+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Sc–Tc bond lengths are 2.48 Å. V3+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both V–Tc bond lengths are 2.15 Å. Tc3- is bonded in a linear geometry to one Sc3+ and one V3+ atom.
TaTc2Ge is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ta4+ is bonded in a body-centered cubic geometry to eight equivalent Tc3- atoms. All Ta–Tc bond lengths are 2.71 Å. Tc3- is bonded in a body-centered cubic geometry to four equivalent Ta4+ and four equivalent Ge2+ atoms. All Tc–Ge bond lengths are 2.71 Å. Ge2+ is bonded in a body-centered cubic geometry to eight equivalent Tc3- atoms.
YZrTc2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two YZrTc2 ribbons oriented in the (1, 0, 0) direction. Y3+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Y–Tc bond lengths are 2.49 Å. Zr3+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Zr–Tc bond lengths are 2.28 Å. Tc3- is bonded in a linear geometry to one Y3+ and one Zr3+ atom.
PaTc2In is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Pa3+ is bonded in a body-centered cubic geometry to eight equivalent Tc3- atoms. All Pa–Tc bond lengths are 2.90 Å. Tc3- is bonded in a body-centered cubic geometry to four equivalent Pa3+ and four equivalent In3+ atoms. All Tc–In bond lengths are 2.90 Å. In3+ is bonded in a body-centered cubic geometry to eight equivalent Tc3- atoms.
ZrTiTc2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two ZrTiTc2 ribbons oriented in the (1, 0, 0) direction. Zr2+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Zr–Tc bond lengths are 2.31 Å. Ti4+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Ti–Tc bond lengths are 2.17 Å. Tc3- is bonded in a linear geometry to one Zr2+ and one Ti4+ atom.
HfTiTc2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two HfTiTc2 ribbons oriented in the (1, 0, 0) direction. Hf4+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Hf–Tc bond lengths are 2.34 Å. Ti2+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Ti–Tc bond lengths are 2.17 Å. Tc3- is bonded in a linear geometry to one Hf4+ and one Ti2+ atom.
The 2017 hurricane season was extremely active with six major hurricanes, the third most on record. The sea-surface temperatures (SSTs) over the eastern Main Development Region (EMDR), where many tropical cyclones (TCs) developed during active months of August/September, were approximately 0.96 degrees Centigrade above the 1901-2017 average (warmest on record): about 0.42 degrees Centigrade from a long-term upward trend and the rest (around 80 percent) attributed to the Atlantic Meridional Mode (AMM). The contribution to the SST from the North Atlantic Oscillation over the EMDR was a weak warming, while that from ENSO was negligible. Nevertheless, ENSO, the NAO, and the AMM all contributed to favorable wind shear conditions, while the AMM also produced enhanced atmospheric instability. Compared with the strong hurricane years of 2005-2010, the ocean heat content (OHC) during 2017 was larger across the tropics, with higher SST anomalies over the EMDR and Caribbean Sea. On the other hand, the dynamical/thermodynamical atmospheric conditions, while favorable for enhanced TC activity, were less prominent than in 2005-2010 across the tropics. The results suggest that unusually warm SST in the EMDR together with the long fetch of the resulting storms in the presence of record-breaking OHC were key factors in driving the strong TC activity in 2017.
This work examines the assimilation of AIRS (Atmospheric Infrared Sounder) radiances from two points of view: the thinning strategy and the use of cloud-cleared radiances as opposed to clear-sky. Previous published work by this team, based on a very large set of Observing System Experiments performed with a 2014 3DVAR version of the GEOS (Goddard Earth Observing System), has shown that the assimilation of adaptively thinned AIRS cloud-cleared radiances (CCRs) improves the representation of tropical cyclones (TCs) without damaging the global forecast skill. The simple adaptive methodology is based on denser AIRS coverage in moving domains centered on TCs, and sparser coverage everywhere else. Subsequent experiments showed that the adaptive methodology produces good results also when applied to clear-sky CrIS (Cross-track Infrared Sounder) and IASI (Infrared Atmospheric Sounding Interferometer) radiances. In addition, the results indicate that the density of all hyperspectral data assimilated over meteorologically inactive areas is excessive, probably because of horizontal error correlation, suggesting that the global thinning should be more aggressive. More recent work focused on the polar regions has shown another positive impact of assimilating cloud-cleared AIRS radiances instead of clear-sky. The results show that high latitude atmospheric dynamics is very sensitive to the representation of the lower tropospheric temperature structure over the Arctic region. Specifically, assimilation of CCRs over areas that are data poor and also affected by broken stratus clouds, and as such minimally observed by AIRS clear-sky radiances, changes substantially the temperature structure over the Arctic low troposphere. Ingestion of CCRs over the region propagates, through hydrostatic adjustments, to mid-tropospheric geopotential height, allowing for better prediction of mid-latitude waves. In addition, adaptively thinned CCRs also improve the representation of mesoscale convective cyclones at high latitudes. An example of an Antarctic low is provided. Finally, recent ongoing work with the hybrid 4DenVAR GEOS, investigating the 2017 boreal TC season, has confirmed the previous results: namely that aggressively thinned cloud-cleared radiances improve TC structure with no loss of global skill.
Abstract Background The wide applicability of the Naples prognostic score (NPS) is still worthy of further study in gastric cancer (GC). This study aimed to construct a New‐NPS based on the differences in immunity and nutrition in patients with upper and lower gastrointestinal tumors to help obtain an individualized prediction of prognosis. Methods This study retrospectively analyzed patients who underwent radical gastrectomy from April 2014 to September 2016. The cutoff values of the preoperative neutrophil‐to‐lymphocyte ratio (NLR), lymphocyte‐to‐monocyte ratio (LMR), serum albumin (Alb), and total cholesterol (TC) were calculated by ROC curve analysis. ROC and t‐ROC were used to evaluate the accuracy of the prognostic markers. The Kaplan–Meier method and log‐rank test were used to analyze the overall survival probability. Univariate and multivariate analyses based on Cox risk regression were used to show the independent predictors. The nomogram was made by R studio. The predictive accuracy of nomogram was assessed using a calibration plot, concordance index (C‐index), and decision curve. Results A total of 737 patients were included in training cohort, 411 patients were included in validation cohort. ROC showed that the New‐NPS was more suitable for predicting the prognosis of GC patients. NPS = 2 indicated a poor prognosis. Multivariate analysis showed that CEA ( P = 0.026), Borrmann type ( P = 0.001), pTNM ( P < 0.001), New‐NPS ( P < 0.001), and nerve infiltration ( P = 0.035) were independent risk factors for prognosis. Conclusion The New‐NPS based on the cutoff values of NLR, LMR, Alb, and TC is not only suitable for predicting prognosis but can also be combined with clinicopathological characteristics to construct a nomogram model for GC patients.
Spent nuclear fuel contains heavy element fission products that must be separated for effective reprocessing for a safe and sustainable nuclear fuel cycle. 93 Zr and 99 Tc are high-yield fission products that co-transport in liquid-liquid extraction processes. Here we seek atomic-level information of this co-extraction process, as well as fundamental knowledge about Zr IV (and Hf IV ) aqueous speciation in the presence of topology-directing ligands such as pertechnetate (TcO 4 – ) and non-radioactive surrogate perrhenate (ReO 4 – ). In this context, we show that the flat tetrameric oxyhydroxyl-cluster [M IV 4 (OH) 8 (H 2 O) 16 ] 8+ (and related polymers) is dissociated by perrhenate/pertechnetate to yield isostructural dimers, M 2 (OH) 2 (XO 4 – ) 6 (H 2 O) 6 • 3H 2 O (M=Zr/Hf IV ; X=Re/Tc VII ), elucidated by single-crystal X-ray diffraction. We used these model compounds to understand the pervasive 93 Zr- 99 Tc coextraction with further speciation studies in water, nitric acid, and tetrabutylphosphate (TBP) -kerosene; where the latter two media are relevant to nuclear fuel reprocessing. SAXS (small angle X-ray scattering), compositional evaluation, and where experimentally feasible, ESI-MS (electrospray ionization mass spectrometry) showed that perrhenate/pertechnetate influence Zr/Hf IV -speciation in water. Here, in Zr-XO 4 solvent extraction studies to simulate fuel reprocessing, we provide evidence that TcO 4 – enhances extraction of Zr IV , and compositional analysis of the extracted metal-complexes (Zr-ReO 4 study) is consistent with the crystallized Zr IV 2 (OH) 2 (Re VII O 4 – ) 6 (H 2 O) 6 •dimer.
2D van der Waals ferromagnets hold immense promise for spintronic applications due to their controllability and versatility. Despite their significance, the realization and in-depth characterization of ferromagnetic materials in atomically thin single layers, close to the true 2D limit, has been scarce. Here, a successful synthesis of monolayer (ML) 1T-CrTe2 is reported on a bilayer graphene (BLG) substrate via molecular beam epitaxy. Using angle-resolved photoemission spectroscopy and magneto-optical Kerr effect measurements, that the ferromagnetic transition is observed at the Curie temperature (TC) of 150 K in ML 1T-CrTe2 on BLG, accompanied by unconventional temperature-dependent band evolutions. The spectroscopic analysis and first-principle calculations reveal that the ferromagnetism may arise from Goodenough-Kanamori super-exchange and double-exchange interactions, enhanced by the lattice distortion and the electron doping from the BLG substrate. These findings provide pivotal insight into the fundamental understanding of mechanisms governing 2D ferromagnetism and offer a pathway for engineering higher TC in 2D materials for future spintronic devices.
Herein, electroluminescence (EL) and thermal imaging are used to examine p–i–n metal halide perovskite (MHP) photovoltaic (PV) mini-modules (MA0.6FA0.4PbI3, 20 cells, 78 cm2) before and after indoor-accelerated stress testing or outdoor deployment. Distinct spatial patterns in the EL images emerge, which depend on the external stress conditions experienced by the mini-module. Imaging results highlight a distribution of dark speckle features that dominate after UV stress, attributed to widespread interfacial contact degradation. Lateral intensity gradients across cells dominate after thermal cycling (TC) stress, attributed to current crowding near scribe defects. While current–voltage analysis alone does not give full insight on the degradation process, this study shows that distinct degradation modes can be further defined by multimodal electro-optical imaging (i.e., EL combined with photoluminescence and dark lock-in thermography). Neither UV exposure nor TC-accelerated stress testing alone replicates the same degradation signatures observed after outdoor deployment, suggesting that multiple degradation modes occur under concurrent stressors outdoors. Finally, spatial characterization of degradation modes in MHP PV mini-modules before and after accelerated stress testing lays the groundwork for developing targeted accelerated stress testing procedures through comparison with outdoor aging.
A search for new heavy scalars with flavour-violating decays in final states with multiple leptons and b-tagged jets is presented. The results are interpreted in terms of a general two-Higgs-doublet model involving an additional scalar with couplings to the top-quark and the three up-type quarks (ρ tt , ρ tc , and ρ tu ). The targeted signals lead to final states with either a same-sign top-quark pair, three top-quarks, or four top-quarks. The search is based on a data sample of proton-proton collisions at $\sqrt{s}$ = 13 TeV recorded with the ATLAS detector during Run 2 of the Large Hadron Collider, corresponding to an integrated luminosity of 139 fb –1 . Events are categorised depending on the multiplicity of light charged leptons (electrons or muons), total lepton charge, and a deep-neural-network output to enhance the purity of each of the signals. Masses of an additional scalar boson m H between 200 – 630 GeV with couplings ρ tt = 0.4, ρ tc = 0.2, and ρ tu = 0.2 are excluded at 95% confidence level. Additional interpretations are provided in models of R-parity violating supersymmetry, motivated by the recent flavour and (g – 2) μ anomalies.
We report the role of EGR (exhaust gas recirculation) olefinic constituents at advanced combustion conditions in the presence of nitric oxide is unraveled in this study through experimental and modeling efforts using a twin-piston rapid compression machine operating at a stochiometric fuel loading with 20% EGR by mass, pressures of 20 and 40 bar, and temperatures from 680 to 950 K. Five different levels of olefin addition, focusing on ethylene, propene and isobutene, with a fixed amount of NO at 70 ppm are doped into test mixtures of PACE-20, a multi-component gasoline surrogate, where olefin addition effects are characterized through changes in ignition times and heat release rates. Experiments indicate that all three EGR olefins inhibit autoignition reactivity and low-temperature heat release at Tc < 850 K, with isobutene exhibiting the greatest impact, while at Tc > 850 K, low ethylene and propene additions promote reactivity. A recently updated chemical kinetic model, with detailed gasoline/NO x interacting and olefin/NO x interacting chemistry incorporated, is adopted to simulate the experiments. Simulation results are somewhat inconsistent with the experiments, where the model captures the inhibiting effects of all olefins on first-stage ignition reactivity, while consistently predicting a promoting effect on main ignition reactivity. Sensitivity and rate of production analyses reveal that adding olefins greatly alters the role of the consuming pathways for the olefins and their primary derivatives at the initial stage of the oxidation process, particularly with the presence of NO, where the olefins and their derivatives interact with both NO x species such as NO 2 and other species such as OH and HO 2 . The olefin/NO x interactions are particularly pronounced with propene and isobutene addition, where these lead to increased ignition reactivity by facilitating NO production and are mostly responsible for the disagreement between the model and experiments. Further investigations of olefin interacting chemistry, particularly those with NOx species, are needed for chemistry models to accurately predict the complicated effects of EGR.
In this work, integrated experimental tests and computational modeling are proposed to investigate the failure mechanisms of open-hole cross-ply carbon fiber reinforced polymer (CFRP) laminated composites. In particular, we propose two effective methods, which include width-tapered double cantilever beam (WTDCB) and fixed-ratio mixed-mode end load split (FRMMELS) tests, to obtain the experimental data more reliably. We then calibrate the traction-separation laws of cohesive zone model (CZM) used among laminas of the composites by leveraging these two methods. The experimental results of fracture energy, i.e. G Ic and G Tc , obtained from WTDCB and FRMMELS tests are generally insensitive to the crack length thus requiring no effort to accurately measure the crack tip. Moreover, FRMMELS sample contains a fixed mixed-mode ratio of G IIc /G Tc depending on the width taper ratio. Examining comparisons between experimental results of FRMMELS tests and failure surface of B–K failure criterion predicted from a curve fitting, good agreement between the predictions and experimental data has been found, indicating that FRMMELS tests are an effective method to determine mixed-mode fracture criterion. In addition, a coupled experimental-computational modeling of WTDCB, edge notched flexure, and FRMMELS tests are adopted to calibrate and validate the interfacial strengths. Finally, failure mechanisms of open-hole cross-ply CFRP laminates under flexural loading have been studied systematically using experimental and multi-scale computational analyses based on the developed CZM model. The initiation and propagation of delamination, the failure of laminated layers as well as load-displacement curves predicted from computational analyses are in good agreement with what we have observed experimentally.
Mechanical behavior and texture evolution of Mg rare-earth alloy WE43 is investigated for strain-rates 10 -3 /s to upwards of 10 5 /s for the two material conditions - as-cast (AC) and T6 age hardened, rolled plate (RT6). The high strain-rate behavior is tested using both Taylor cylinder impact tests (TC) and split Hopkinson pressure bar tests (SHB) and bulk textures are obtained using neutron diffraction. Unlike the quasi-static strained material, AC and RT6 SHB retained high hardening rates throughout the test, even up to 30% true strain. Moreover, the high strain-rate data revealed that the RT6 material has a much higher strength than the AC material, but similar hardening rates despite significantly different initial texture. The flow stress near yield increased up to I 0% for RT6 and up to 30% for AC as the strain-rate increased six orders of magnitude from quasi-static rates 10 -3 /s to 10 3 /s. Neither material exhibited significant plastic anisotropy over the broad range of strain rates, despite the fact that the RT6 material had a moderately strong initial texture. In the TC tests, the geometric cross-sectional changes and texture along the cylinder from the cylindrical sample foot to head are measured and from the neutron diffraction texture analysis, upper-bound estimates of twin volume fraction are obtained as well as dislocation density from analyzing diffraction peak broadening. Recorded geometrical changes along several loading directions show that the material has deformed remarkably homogeneously under impact. Analysis of deformed textures indicates that {101¯2} extension deformation twinning occurred in the RT6 condition over the range of strain rates, with an upper bound estimate of 40% twin volume fraction for approximately 0.10-0.25 true strain. The peak texture components after the impact have their c-axes closely aligned with the impact direction. As a result, these observations are presented and rationalized in the paper.
The viscosity of glass is the most important technological property to glass manufactures and various applications. Practically, finding an accurate equation to express the glass viscosity behavior in the entire glass transition temperature range is tremendously challenge because it spans more than ten orders of magnitude. After a brief review of existing empirical viscosity equations, this work focuses on the correlating silica viscosity behavior with the evolution of glass medium-range structure, based on the recently proposed nanoflake model. From this new model, a new equation is constructed, which correctly describes the Arrhenius-type behavior of silica viscosity η above the melting temperature Tm, and non-Arrhenius-type behavior from Tm to a critical temperature Tc. At temperature lower than Tc, the equation predicts Arrhenius-type behavior again for the viscous flow with increased activation energy. The new equation agrees with experimental data in the entire temperature spanned from extremely high to extremely low. Furthermore, the application of the new equation is shown to extend to sodium silicate glasses as well.