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At least 955 records · Page 53

Chlorine chemistry in the Antarctic stratosphere - Impact of OClO and Cl2O2 and implications for observations

Theories have been proposed to relate the reduction of O3 during Antarctic spring to catalytic cycles involving chlorine and bromine species. A necessary condition for any chlorine-catalyzed scheme is that a large fraction of the chlorine must be in the form of ClO in the lower stratosphere. It has been suggested that these high levels of ClO could be maintained by fast heterogeneous reactions, whose rates are not known at present. Model calculations based on the above mechanisms predict considerable amounts of OClO and Cl2O2, particularly during the night. Results of calculations of the diurnal variations of ClO, OClO, and Cl2O2 during Antarctic spring are presented for different cases. Results from the calculations suggest that coincident measurements of the total column abundance and diurnal variation of ClO and OClO may help constrain key aspects of the proposed chemical mechanisms. Removal of O3 by the catalytic cycle involving Cl2O2 could be as important as that involving BrO for present levels of chlorine, provided that Cl2O2 photolyzes rapidly to yield Cl and ClO2. It is shown that there is no synergy between these two cycles, since they both compete for the available ClO.

Rodriguez, Jose M.↗

Meteoric material and the behavior of upper stratospheric polar zone

Ozone mixing ratios as a function of pressure level and time are presented based on data obtained with the Nimbus-7 SBUV instrument between 1979 and 1984, and implications of this data for the explanations of the spring Antarctic ozone depletion are considered. It is suggested that meteoric atoms react with the atmosphere to bond to OH, and subsequently react with HCl to form salts, resulting in the accumulation of chlorine during polar winter. The sudden release of this chlorine from photodissociation of these salts during spring could account for the loss of ozone in the upper atmosphere.

Aikin, A. C.↗

Cloud-to-ground lightning flash characteristics from June 1984 through May 1985

A magnetic direction-finding network for the detection of lightning cloud-to-ground strikes has been installed along the east coast of the United States. Time, location, flash polarity, stroke count, and peak signal amplitude are recorded in real time. The data were recorded from Maine to North Carolina and as far west as Ohio; analyses were restricted to flashes within 300 km of a direction finder. Measurements of peak signal strength have been obtained from 720,284 first return strokes lowering negative charge. The resulting distribution indicates that few negative strokes have peak currents exceeding 100 kA. Measurements have also been obtained of peak signal strength from 17,694 first return strokes lowering positive charge. These strokes have a median peak current of 45 kA, with some peak currents reaching 300-400 kA. The median peak signal strength and the peak current, double from summer to winter for both negative and positive first return strokes. The polarity of ground flashes is observed to be less than 5 percent positive throughout the summer and early fall, then increases to over 50 percent during the winter, and returns to less than 10 percent in early spring. The percent of positive flashes with one stroke is observed to be approximately 90 percent throughout the year. The percent of negative flashes with one stroke is observed to increase from 40 percent in the summer to approximately 80 percent in January, returning to less than 50 percent in the spring.

Orville, Richard E.↗

Zero-Deadband Ball Bearings

Proposed supports for ball bearings press outer races against balls without radial clearance. Diaphragm-like axially flexible springs eliminate deadband and consequent nonlinear radial vibrational response of rotor. If shaft needs two bearings at each end, they are supported independently or connected in series by U-spring. Mechanical stops limit axial travel of shaft.

Hine, Michael J.↗

Semiautomatic Probe-And-Drogue Attachment Mechanism

Spring-loaded pawls provide quick coupling. As probe enters drogue during coupling, three spring-loaded pawls in probe latch probe in drogue, preventing accidental uncoupling. Then worm-gear mechanism turned by standard 0.25-in. (6.35-mm) tool transfers motion to central threaded shaft, extending cap at tip of probe until all play taken up. This centers probe in drogue and renders coupling pawls to extend again. New mechanism useful for coupling modular components in other applications where ease and security of attachment, precise final alignment, and ease of removal important and where stresses and bending reasonably low.

Wanagas, John D.↗

Simplified Analysis Of Vehicle/Payload Vibrations

Simplified mathematical model of coupled vibrations of vehicle and its payloads used in stability analysis for control purposes. Multiple-payload stability criterion extension of single-payload criterion based on measurements and detailed calculations of fundamental vibrational modes of vehicle and payload. Represented in simplified form by coupled masses and springs vibrating in one dimension, each spring having stiffness that gives rise to previously determined fundamental vibrational frequency associated mass in absence of coupling with other mass. Developed to avoid complexity and cost of full vibrations/stability calculations for each different combination of Space Shuttle payloads, simplified analysis technique also useful in assessing stability in loaded airplanes, ships, trucks, cranes, and conveyor systems.

Yu, Reginald R. J.↗

Non-linear shipboard shock analysis of the Tomahawk missile shock isolation system

The identification, quantification, computer modeling and verification of the Tomahawk nonlinear liquid spring shock isolation system in a surface ship Vertical Launch System (VLS) are discussed. The isolation system hardware and mode of operation is detailed in an effort to understand the nonlinearities. These nonlinearities are then quantified and modeled using the MSC/NASTRAN finite element code. The model was verified using experimental data from the Navel Ordnance Systems Center MIL-S-901 medium weight shock tests of August 1986. The model was then used to predict the Tomahawk response to the CG-53 USS Mobile Bay shock trials of May-June 1987. Results indicate that the model is an accurate mathematical representation of the physical system either functioning as designed or in an impaired condition due to spring failure.

Leifer, Joel↗

Stressed photoconductive detector for far-infrared space applications

An optimized leaf-spring apparatus for applying uniaxial stress to a Ge:Ga far-IR photoconductor has been designed and tested. This design has significant advantages for space applications which require high quantum efficiency and stable operation over long periods of time. The important features include adequate spring deflection with relatively small overall size, torque-free stress, easy measurement of applied stress, and a detector configuration with high responsivity. One-dimensional arrays of stressed photoconductors can be constructed using this design. A peak responsivity of 38 A/W is achieved in a detector with a cutoff wavelength of 200 microns, which was operated at a temperature of 2.0 K and a bias voltage equal to one-half of the breakdown voltage.

Wang, J.-Q.↗

Antarctic ozone - Meteoric control of HNO3

Atmospheric circulation leads to an accumulation of debris from meteors in the Antarctic stratosphere at the beginning of austral spring. The major component of meteoric material is alkaline, comprised predominantly of the oxides of magnesium and iron. These metals may neutralize the natural acidity of stratospheric aerosols, remove nitric acid from the gas phase, and bond it as metal nitrates in the aerosol phase. Removal of nitric acid vapor has been previously shown to be a critical link in the photochemical depletion of ozone in the Antarctic spring, by allowing for increased catalytic loss from chlorine and bromine.

Prather, Michael J.↗

Comment on 'Further interpretation of satellite measurements of Antarctic total ozone'

It is argued that the best explanation for the 1980-1982 Total Ozone Mapping Spectrometer (TOMS) data showing a decline in zonal monthly mean total ozone for Octobers between 1979 and 1985/86 for all latitudes south of 40 S (as reported by Stolarski and Schoeberl, 1986) is a near-cancellation between an ozone source and a newly developed chemical sink for ozone, with both initiated by the arrival of spring in the southern hemisphere. In a reply by Schoeberl and Stolarski, additional TOMS observations are reported which suggest that some uncompensated ozone loss may be occurring in the spring Antarctic in the most recent years. A significant change in the midlatitude ozone source appears to have occurred as well. The observations show the importance of the final warming in setting up the summertime ozone distribution.

Eliott, Scott↗

The direction of water transport on Mars: A possible pumping mechanism

It is suggested that an atmospheric pumping mechanism might be at work in which water is preferentially transported into the north by a mass outflow wind (due to sublimation from polar cap) that is stronger during southern spring than it is during northern spring. The mechanism is provided by the asymmetric seasonal temperature distribution produced by the eccentric martial orbit and by the associated seasonal asymmetry in the carbon dioxide cycle. The alternating condensation and sublimation of CO2 at the poles produces condensation winds which, in turn, contribute to the meridional transport of water vapor.

James, P. B.↗

Evolution of polar stratospheric clouds during the Antarctic winter

The occurrence of Polar Stratospheric Clouds (PSCs), initially inferred from satellite measurements of solar extinction, have now also been noted by the recent scientific expeditions in the Antarctic. The presence of such clouds in the Antarctic has been postulated to play a significant role in the depletion of ozone during the transition from winter to spring. The mechanisms suggested involve both dynamical and chemical processes which, explicity or implicitly, are associated with the ice particles constituting the PSCs. It is, thus, both timely and necessary to investigate the evolution of these clouds and ascertain the nature and magnitude of their influences on the state of the Antarctic stratosphere. To achieve these objectives, a detailed microphysical model of the processes governing the growth and sublimation of ice particles in the polar stratosphere was developed, based on the investigations of Ramaswamy and Detwiler. The present studies focus on the physical processes that occur at temperatures below those required for the onset of ice deposition from the vapor phase. Once these low temperatures are attained, the deposition of water vapor onto nucleation particles becomes extremely significant. First, the factors governing the magnitude of growth and the growth rate of ice particles at various altitudes are examined. Second, the ice phase mechanisms are examined in the context of a column model with altitudes ranging from 100 to 5 mb pressure levels. The column microphysical model was used to perform simulations of the cloud evolution, using the observed daily temperatures. The effect due to the growth of the particles on the radiation fields are also investigated using a one dimensional radiative transfer model. Specifically, the perturbations in the longwave cooling and that in the shortwave heating for the late winter/early spring time period are analyzed.

Ramaswamy, V.↗

Visible and near-ultraviolet spectroscopy at Thule AFB (76.5 N) from January 28 - February 15, 1988

Near-ultraviolet and visible spectrographs identical to those employed at McMurdo Station, Antarctica (77.8 S) during the austral spring seasons of 1986 and 1987 were used to study the stratosphere above Thule, Greenland (76.5 N) during early spring, 1988. Observations were carried out both at night using the direct moon as a light source, and during the day by collecting the scattered light from the zenith sky when solar zenith angles were less than about 94.5 degrees. Excellent meteorological conditions prevailed in the troposphere and stratosphere at Thule. Surface weather was extremely clear over most of the period, facilitating measurements of the direct light from the moon. The lower stratospheric arctic polar vortex was located very near Thule throughout the observing period, and temperature at the 30 mbar level were typically below -80 C above Thule, according to the National Meteorological Center daily analyses. Thus conditions were favorable for polar stratospheric cloud formation above Thule. Total column ozone abundances were about 350 to 400 Dobson units, and did not suggest a clear temporal trend over the observing period. Stratospheric nitrogen dioxide measurements were complicated by the presence of a large component of tropospheric pollution on many occasions. Stratospheric nitrogen dioxide could be identified on most days using the absorption in the scattered light from the zenith sky, which greatly enhances the stratospheric airmass while suppressing the tropospheric contribution. These measurements suggest that the total vertical column abundance of nitrogen dioxide present over Thule in February was extremely low, sometimes as low as 3 x 10 to the 14th per sq cm. The abundance of nitrogen dioxide increased systemically from about 3 x 10 to the 14th in late January to 1.0 x 10 to the 15th per sq cm in mid-February, perhaps because of photolysis of N2O5 in the upper part of the stratosphere, near 25 to 35 km.

Mount, G. H.↗

The interannual variability of atmospheric water vapor on Mars

The acquisition of several north-south scans during the Survey/Completion Mission by the Mars Atmospheric Water Detector (MAWD) onboard Viking Orbiter 1 make it possible to compare water vapor column abundance during northern spring and early summer seasons from three successive Mars years. All three years exhibit very similar seasonal trends. Differences between years tend to be localized, and not regional, with maximum differences between years occurring in the same general areas that the day-to-day variability of water vapor as observed by MAWD is large. It is suggested that the observed year-to-year differences are also artifacts of clouds in the MAWD field of view and that there is remarkably little difference in the water cycle during northern spring and early summer, despite very different dust storm episodes during the preceding three years.

Zurek, Richard W.↗

Remote sensing of ocean color in the Arctic

The main objectives of the research are: to increase the understanding of biological production (and carbon fluxes) along the ice edge, in frontal regions, and in open water areas of the Arctic and the physical factors controlling that production through the use of satellite and aircraft remote sensing techniques; and to develop relationships between measured radiances from the Multichannel Aircraft Radiometer System (MARS) and the bio-optical properties of the water in the Arctic and adjacent seas. Several recent Coastal Zone Color Scanner (CZCS) studies in the Arctic have shown that, despite constraints imposed by cloud cover, satellite ocean color is a useful means of studying mesoscale physical and biological oceanographic phenomena at high latitudes. The imagery has provided detailed information on ice edge and frontal processes such as spring breakup and retreat of the ice edge, influence of ice on ice effects of stratification on phytoplankton production, river sediment transport, effects of spring runoff, water mass boundaries, circulation patterns, and eddy formation in Icelandic waters and in the Greenland, Barents, Norwegian, and Bering Seas.

Maynard, N. G.↗

Observations of, and sources of the spatial and temporal variability of ozone in the middle atmosphere on climatological time scales (OZMAP) and equatorial dynamics: Seasonal variations of ozone trends

The long term trends (least square linear regression with time) of ozone content at seven European, seven North American, three Japanese and two tropical stations during 21 years (1964 to 1984) are analyzed. In all regions negative trends are observed during the 1970s, but are partly compensated by limited periods of positive trends during the late 1960s and late 1970s. Solely the North American ozone data show negative trends in all 10 year periods. When the long term ozone trends are evaluated for each month of the year separately, a seasonal variation is revealed, which in Europe and North America has largest negative trends in late winter and spring. While in Europe the negative trends in winter/spring are partly compensated by positive trends in summer, in North America the summer values reach only zero, retaining the significant negative trend in annual mean values. In contrast to the antarctic ozone hole, the spring reduction of ozone in Europe and in North America is associated with stratospheric temperatures increasing in the analyzed period and therefore is consistent with the major natural ozone production and loss processes.

Entzian, G.↗

A study of the stratospheric final warming of 1982 in the Southern Hemisphere

Data obtained from stratospheric sounding units on board the NOAA-6 satellite were used to investigate the three-dimensional evolution of the final warming that takes place in the stratosphere of the Southern Hemisphere during spring, with particular attention given to the events of spring 1982. Evidence is presented for a strong influence of the topography of the Southern Hemisphere on the evolution of the final warming. An association was found between the location of anticylones in the upper stratosphere, warm pools of air in the lower stratosphere, and a climatological split of the westerly jet stream in the upper troposphere.

Mechoso, C. R.↗

The 1988 Antarctic ozone depletion - Comparison with previous year depletions

The 1988 spring Antarctic ozone depletion was observed by TOMS to be substantially smaller than in recent years. The minimum polar total ozone values declined only 15 percent during September 1988, compared to nearly 50 percent during September 1987. At southern midlatitudes, exceptionally high total ozone values were recorded beginning in July 1988. The total integrated southern hemispheric ozone increased rapidly during the Austral spring, approaching 1980 levels during October. The high midlatitude total ozone values were associated with a substantial increase in eddy activity as indicated by the standard deviation in total ozone in the zonal band 30-60 deg S. Mechanisms through which the increased midlatitude eddy activity could disrupt the formation of the Antarctic ozone hole are briefly discussed.

Schoeberl, Mark R.↗