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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 955 records · Page 53
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Epitaxially crystallized polyethylene exhibiting near‐equilibrium melting temperatures*

Abstract The morphology and orientation of polymer crystals are important factors which determine the performance of thin‐film, polymer‐based technologies such as organic electronic devices and gas separation membranes. Here, we utilize polymer‐substrate epitaxy to achieve a highly oriented crystalline morphology during thin‐film processing. To accomplish this, we employ matrix‐assisted pulsed laser evaporation (MAPLE), a slow physical vapor deposition process, to deposit linear polyethylene epitaxially atop a graphene substrate. Via MAPLE, we demonstrate the ability to achieve a film morphology comprised of well‐aligned, edge‐on crystalline lamellae. Furthermore, we show that MAPLE can be exploited to grow crystalline lamellae composed entirely of extended polymer chains which exhibit a near‐equilibrium melting temperature. Our study demonstrates that MAPLE, as a bottom‐up approach, can deposit polymer thin films with improved control over crystalline morphology.

Wang, Yucheng↗
NASA NTRS1982

Dynamics of subjective discomfort in motion sickness as measured with a magnitude estimation method

Eight subjects, wearing left-right vision reversing goggles, executed sequences of controlled active head movements to provoke motion sickness. Head movement sequences were interspaced with periods of eye closure and no head movement to permit partial remission of symptoms between sequences. Subjects reported the level of discomfort experienced by using a magnitude estimation technique derived from Stevens' (1957) ratio scaling method. Using this approach, we demonstrated that the time course of subjective discomfort exhibits a profile, similar in all our subjects, characterized by both fast and slow response components. The potential usefulness of magnitude estimation for research on the dynamic properties of the mechanism generating motion sickness symptoms is discussed.

Bock, O. L.↗
NASA NTRS2011

Flight Testing of the Forward Osmosis Bag for Water Recovery on STS-135

The Forward Osmosis Bag (FOB) is a personal water purification device for recovery of potable liquid from almost any non-potable water source. The FOB experiment was flown as a sortie mission on STS-135/ULF7 using flight-certified materials and a design based on the X-Pack(TradeMark) from Hydration Technology Innovations (Albany, OR). The primary objective was to validate the technology for use under microgravity conditions. The FOB utilizes a difference in solute concentration across a selectively permeable membrane to draw water molecules from the non-potable water while rejecting most chemical and all microbial contaminants contained within. Six FOB devices were tested on STS-135 for their ability to produce a potable liquid permeate from a feed solution containing 500 mL potassium chloride (15 g/L) amended with 0.1% methyl blue dye (w:v) tracer against an osmotic gradient created by addition of 60 mL of concentrate containing the osmolytes fructose and glucose, and 0.01% sodium fluorescein (w:v) tracer. Three FOB devices were physically mixed by hand for 2 minutes by a crewmember after loading to augment membrane wetting for comparison with three unmixed FOB devices. Hydraulic flux rate and rejection of salt and dye in microgravity were determined from a 60-mL sample collected by the crew on orbit after 6 hours. Post-flight analysis of samples collected on orbit demonstrated that the Forward Osmosis Bag achieved expected design specifications in microgravity. The hydraulic flux rate of water across the membrane was reduced approximately 50% in microgravity relative to ground controls that generated an average of 50 mL per hour using the same water and osmolyte solutions. The membrane rejected both potassium and chloride at >92% and methyl blue dye at >99.9%. Physical mixing of the FOB during water recovery did not have any significant effect on either flux rate or rejection of solutes from the water solution. The absence of buoyancy-driven convection in microgravity suggests that mass transport was dominated by diffusion, slowing the rate of permeate production across the membrane. It is possible that a predicted reduction in concentration polarization at the membrane surface that may have acted to increase the rate of permeate production in microgravity was negligible under the described test conditions.

Roberts, Michael S.↗
NASA NTRS1989

Changes of muscle function and size with bedrest

The impact of a short-term head-down bedrest on the skeletal-muscle function of humans was investigated in healthy males subjected (after five days of control period) to 30-day 6-deg head-down bed rest (BR) followed by a five-day recovery period. It was found that the head-down BR led to a decrease in force developed by the knee extensor muscle group during maximal voluntary efforts, with the average reduction of 21 percent across the speeds of concentric and eccentric muscle action. Significant decreases were also found in the cross-sectional areas of slow-twitch and fast-twitch muscle fibers of the vastus lateralis.

Dudley, Gary A.↗
NASA NTRS1991

Charged-particle induced alterations of surfaces in the outer solar system

Researchers calculated the plasma bombardment profiles of the surfaces of the icy Saturnian satellites in order to interpret reflection spectra and the effect of charged particles on the surfaces (mantles) of Pluto and of comets in the Oort cloud. Pluto's exposure to cosmic rays results in a slow alteration of the reflectance if the methane condensed on its surface. The UV absorbed in the atmosphere can produce precipitates. The researchers showed that, depending on the rates of the competing regolith processes and rates for replenishment of the methane, the surface can appear bright, red, or dark. Using laboratory data, they showed that the amount of darkening occurring in one orbit is small. Therefore, transport, burial, and re-exposure of organic sediments must control the reflectance, and the average reflectance is established by the radiation altered species accumulated over many orbits with the observed spatial, and possible temporal, differences in albedo due to transport. The cosmic rays, although producing changes in reflectance slowly, do so inevitably. Therefore, the fact that the surface is not dark everywhere implies that it is active and the exposure rates vs. depth into the surface of Pluto can be used to constrain turnover rates. Comets in the Oort cloud experience similar rates.

Johnson, R. E.↗
NASA NTRS2019

Continuous Electrode Inertial Electrostatic Confinement Fusion

The NIAC Phase I project on Inertial Electrostatic Confinement was a continuation of early stage research that was funded by an NSTRF. The student on the project, Andrew Chap, was funded by the NSTRF from Fall 2013 through the Summer of 2017, and then was funded on the NIAC through the completion of his PhD. A significant amount of work targeting the plasma confinement physics was the focus of his NSTRF, and over the course of that effort he developed a number of analyses and computational tools that leveraged GPU parallelization. A detailed discussion of these models can be found in his dissertation, which has been included as Appendix D in this report. As a requirement for the NSTRF, Andrew's full dissertation was submitted at the end of the program.Having developed the computational tools, a substantial amount of simulation and analyses leveraging those tools were conducted during the Fall of 2017, under the auspices of the NIAC funded research. Much of this work targeted optimization of the confinement fields, investigating their structure and the possible advantages of having them be time-varying. The results of these simulations can also be found in Appendix D.One of the main results from this research is that the density of ions electrostatically confined within the system can indeed be increased by several orders of magnitude by optimizing the radial potential distribution, and by dynamically varying these fields to maintain compressed ion bunches. An electron population can also be confined within the core by a static radial cusped magnetic field,which helps to support a greater ion density within the core. The issue with the confinement mechanism is that as the ion densities are increased toward fusion-relevant levels, the electrostatic forces generated by the confined electron population become so great that the ions are no longer energetic enough to leave the device core. As their excursions into the outer channels are diminished, the mechanism that is used to maintain their non-thermal velocity distributions becomes ineffective, and eventually the ions become fully confined within the core, where they thermalize. A possible fix to the problem comes by discarding the active ion control (a main pillar of the concept)but retaining the structure of the permanent magnet confinement of the electron population. Such cusped field confinement has been the focus of other IEC approaches (e.g. Polywell), but the high transparency of the permanent magnet structure lends itself to better ion extraction and power conversion (a second pillar of the concept). The question then becomes whether any influence on the ion evolution within the core can be achieved to slow the thermalization of the ions. Such approaches have been studied in highly idealized analytic models, but face major criticisms within the literature. While this is a possible path forward, the uncertainty in the approach did not warrant committing NIAC Phase II resources to investigating the concept at this time.

Sedwick, Raymond↗
NASA NTRSDate not supplied

Implementation of a Six Degree of Freedom Precision Lunar Landing Algorithm Using Dual Quaternion Representation

In this study, a powered descent guidance algorithm using a unit dual quaternion represen- tation of the vehicle dynamics is implemented in a high-fidelity simulation and on representative flight hardware. This Dual-Quaternion Guidance (DQG) algorithm is applied to the precision lunar landing problem which levies complex constraints upon the trajectory, including state triggered attitude constraints to enable terrain-relative navigation and hazard detection as well as real-time requirements for landing site re-designation. The investigation explores DQG’s usefulness as a mission design tool as well as a real-time guidance algorithm and defines real-time performance requirements for the hazard detection and avoidance (HDA) re-targeting phase of precision lunar landing. The experiment is presented in two parts. First, DQG is implemented within a high-fidelity Monte Carlo simulation to tune the algorithm’s parameters for the simulated vehicle, to refine the mission design, and to develop guidance update timing requirements to perform the HDA maneuver. DQG generates trajectories online for the divert which are tracked by the vehicle’s inner-loop controllers to the targeted landing site. Second, DQG is run on representative hardware to demonstrate real-time operation through a divert maneuver. These results allow for rapid, flexible, optimal mission design satisfying complex constraints, and for the definition of real-time performance requirements for the HDA operations inherent in precision lunar landing. The HDA divert maneuver is found to require guidance trajectory updates in less than three seconds. DQG is found to be too slow to meet this update timing on the descent and landing computer (DLC) in its current implementation. DQG running on alternative hardware can meet the update rate requirement. Algorithm implementation improvements are also recommended which are expected to speed up computation sufficiently to meet requirements on the DLC.

GN&C↗
DOE OSTI2024

Characterizing the combined impact of nucleation-driven precipitation and secondary passivation on carbon mineralization

The evolution of mineral reactive surface area is one of the primary phenomena controlling the progression and extent of mineral carbonation. The CO 2 mineralization begins with nucleation of crystals that provide initial surface area for subsequent growth of the mineral. However, many reactive transport models (RTMs) for CO 2 mineralization do not include the nucleation process. The few RTMs that do include it are yet to be validated against experimental data. Similarly, many RTMs ignore passivating effects of the secondary mineral, which coats the surface of the dissolving mineral, slow down the reaction process, and reduce the total extent of carbonation. Furthermore, the combined impact of nucleation and passivation on carbon mineralization is yet to be properly characterized. In this study, we consider the coupled effects of passivation and nucleation on the mineralization extent. The nucleation-driven precipitation model relies on the formation of nuclei to provide a surface area for crystal growth, while a new model is proposed to account for passivation effects. Our analysis shows that (i) omission of nucleation leads to overestimation of extent of mineralization, and (ii) omission of passivation leads to overestimation of host rock reactivity. The model was evaluated via comparison with CO 2 mineralization data from the literature and models that ignore these processes. We observed that including nucleation and passivation lead to closer predictions of the CO 2 mineralization extent. Therefore, this study highlights the importance of including the coupled nucleation-driven precipitation and secondary passivation in RTMs. Here, the findings from the study can be applied in various scientific and engineering applications such as petroleum production, cement carbonation, CO 2 sequestration, chemical weathering, and concrete degradation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Ionic Liquid Facilitated Solvent‐Phase Polymerization of Ultrasmooth Coatings of Polycatecholamines

Mussel-inspired polycatecholamine coatings and films have proven to be versatile materials for surface modification. However, the progress of chemically modified coatings with tailored properties has been slow due to the lack of definitive evidence of their polymeric structure. Polycatecholamines form aggregates during polymerization, and their formation mechanism has been a subject of debate owing to their insolubility in traditional molecular solvents. Exploiting the capability of ionic liquids (ILs) to exhibit strong electrostatic interactions, herein, the first solution-phase polymerization approach is reported to achieve polymerization of four catecholamines – dopamine (DA), norepinephrine (NE), L-3,4-dihydroxyphenylalanine (L-DOPA), and adrenaline (AD). Kinetic control over the polymerization process in the solution phase enabled it to follow the process with 1 H NMR spectroscopy, revealing the formation of structural features of resulting complex heterogeneous and soluble polymers. The polymers are both covalent and associative in nature. Solution phase polymerization prevented the formation of large aggregates in the solution, thus facilitating the formation of coatings that are ultra-smooth and have root mean square roughness of the order of sub-nm to nm scale.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Scalable graphene sensor array for real-time toxins monitoring in flowing water

Abstract Risk management for drinking water often requires continuous monitoring of various toxins in flowing water. While they can be readily integrated with existing water infrastructure, two-dimensional (2D) electronic sensors often suffer from device-to-device variations due to the lack of an effective strategy for identifying faulty devices from preselected uniform devices based on electronic properties alone, resulting in sensor inaccuracy and thus slowing down their real-world applications. Here, we report the combination of wet transfer, impedance and noise measurements, and machine learning to facilitate the scalable nanofabrication of graphene-based field-effect transistor (GFET) sensor arrays and the efficient identification of faulty devices. Our sensors were able to perform real-time detection of heavy-metal ions (lead and mercury) and E. coli bacteria simultaneously in flowing tap water. This study offers a reliable quality control protocol to increase the potential of electronic sensors for monitoring pollutants in flowing water.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Arctic soil patterns analogous to fluid instabilities

Significance Slow-moving arctic soils form patterns resembling those found in common fluids, such as paint and cake icing drips. Inspired by fluid instabilities, we develop a conceptual model for soil patterns and use mathematical analysis to predict their wavelength. In particular, we propose that soil patterns arise due to competition between gravity and cohesion or the “stickiness” of soil grains. We compare our theoretical predictions with a dataset of soil features from Norway, finding that soil patterns are controlled by fluid-like properties as well as climate. Our work provides a physical explanation for a common pattern on both Earth and Mars, with implications for our understanding of landscapes and complex materials composed of both granular and fluid components.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Ply Strength Prediction of Unidirectional Continuous Carbon Fiber Composites

As inhomogeneous orthotropic materials, composite mechanical properties can be difficult to predict. Even with tight fabrication process controls, there is always some microstructural variation that will affect these properties. As a highly defect-dependent phenomena, mechanical strength is even more subject to variation, especially considering that composites exhibit multiple potential failure modes. The most direct way to determine composite material strength is via experimental testing, maintaining loading and specimen morphology as close as possible to the in situ states. When multiple materials and designs are being considered, this process is often prohibitively costly and slow. However, some approximations and rules of thumb can consistently guide the design process and consideration of alternatives.

36 MATERIALS SCIENCE↗
NASA NTRS1984

The effect of viscosity on impact cratering and possible application to the icy satellites of Saturn and Jupiter

Impact experiments in Newtonian fluids with a range of viscosities of 0.001 to 60 Pa s demonstrate that transient crater volume and shape depend on target viscosity as well as on gravity. Volume is reduced, and depth-to-diameter ratio is increased for cratering events in which viscosity plays a dominant role. In addition to being affected by target kinematic viscosity, viscous scaling is most strongly influenced by projectile diameter, less strongly by projectile velocity, and least strongly by gravity. In a planetary context, viscous effects can occur for craters formed by small or slow moving impacting bodies, low planetary surface densities, high surface viscosities, and low gravity values; conditions all likely for certain impacts into the icy satellites of Saturn and Jupiter, especially if liquid mantles were still present beneath solid crusts. Age dating based on crater counts and size-frequency distributions for these icy bodies may have to be modified to account for the possibility that viscosity-dominated craters were initially smaller and deeper than their gravity-controlled counterparts.

Fink, J.↗
NASA NTRS1992

Dynamics of the G-excess illusion

The G-excess illusion is increasingly recognized as a cause of aviation mishaps especially when pilots perform high-speed, steeply banked turns at low altitudes. Centrifuge studies of this illusion have examined the perception of subject orientation and/or target displacement during maintained hypergravity with the subject's head held stationary. The transient illusory perceptions produced by moving the head in hypergravity are difficult to study onboard centrifuges because the high angular velocity ensures the presence of strong Coriolis cross-coupled semicircular canal effects that mask immediate transient otolith-organ effects. The present study reports perceptions following head movements in hypergravity produced by high-speed aircraft maintaining a banked attitude with low angular velocity to minimize cross-coupled effects. Methods: Fourteen subjects flew on the NASA KC-135 and were exposed to resultant gravity forces of 1.3, 1.5, and 1.8 G for 3 minute periods. On command, seated subjects made controlled head movements in roll, pitch, and yaw at 30 second intervals both in the dark and with faint targets at a distance of 5 feet. Results: head movement produced transient perception of target displacement and velocity at levels as low as 1.3 G. Reports of target velocity without appropriate corresponding displacement were common. At 1.8 G when yaw head movements were made from a face down position, 4 subjects reported oscillatory rotational target displacement with fast and slow alternating components suggestive of torsional nystagmus. Head movements evoked symptoms of nausea in most subjects, with 2 subjects and 1 observer vomiting. Conclusions: The transient percepts present conflicting signals, which introduced confusion in target and subject orientation. Repeated head movements in hypergravity generate nausea by mechanisms distinct from cross-coupled Coriolis effects.

Baylor, K. A.↗
DOE OSTI2021

Bayesian sparse learning with preconditioned stochastic gradient MCMC and its applications

Deep neural networks have been successfully employed in an extensive variety of research areas, including solving partial differential equations. Despite its significant success, there are some challenges in effectively training DNN, such as avoiding overfitting in over-parameterized DNNs and accelerating the optimization in DNNs with pathological curvature. Here, we propose a Bayesian type sparse deep learning algorithm. The algorithm utilizes a set of spike-and-slab priors for the parameters in the deep neural network. The hierarchical Bayesian mixture will be trained using an adaptive empirical method. That is, one will alternatively sample from the posterior using preconditioned stochastic gradient Langevin Dynamics (PSGLD), and optimize the latent variables via stochastic approximation. The sparsity of the network is achieved while optimizing the hyperparameters with adaptive searching and penalizing. A popular SG-MCMC approach is Stochastic gradient Langevin dynamics (SGLD). However, considering the complex geometry in the model parameter space in nonconvex learning, updating parameters using a universal step size in each component as in SGLD may cause slow mixing. To address this issue, we apply a computationally manageable preconditioner in the updating rule, which provides a step-size parameter to adapt to local geometric properties. Moreover, by smoothly optimizing the hyperparameter in the preconditioning matrix, our proposed algorithm ensures a decreasing bias, which is introduced by ignoring the correction term in the preconditioned SGLD. According to the existing theoretical framework, we show that the proposed algorithm can asymptotically converge to the correct distribution with a controllable bias under mild conditions. Numerical tests are performed on both synthetic regression problems and learning solutions of elliptic PDE, which demonstrate the accuracy and efficiency of the present work.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

DIII-D research to provide solutions for ITER and fusion energy

The DIII-D tokamak has elucidated crucial physics and developed projectable solutions for ITER and fusion power plants in the key areas of core performance, boundary heat and particle transport, and integrated scenario operation, with closing the core-edge integration knowledge gap being the overarching mission. New experimental validation of high-fidelity, multi-channel, non-linear gyrokinetic turbulent transport models for ITER provides strong confidence it will achieve Q ≥ 10 operation. Experiments identify options for easing H-mode access in hydrogen, and give new insight into the isotopic dependence of transport and confinement. Analysis of 2,1 islands in unoptimized low-torque IBS demonstration discharges suggests their onset time occurs randomly in the constant β phase, most often triggered by non-linear 3-wave coupling, thus identifying an NTM seeding mechanism to avoid. Pure deuterium SPI for disruption mitigation is shown to provide favorable slow cooling, but poor core assimilation, suggesting paths for improved SPI on ITER. At the boundary, measured neutral density and ionization source fluxes are strongly poloidally asymmetric, implying a 2D treatment is needed to model pedestal fuelling. Detailed measurements of pedestal and SOL quantities and impurity charge state radiation in detached divertors has validated edge fluid modelling and new self-consistent 'pedestal-to-divertor' integrated modeling that can be used to optimize reactors. New feedback adaptive ELM control minimizes confinement reduction, and RMP ELM suppression with sustained high core performance was obtained for the first time with the outer strike point in a W-coated, compact and unpumped small-angle slot divertor. Advances have been made in integrated operational scenarios for ITER and power plants. Wide pedestal intrinsically ELM-free QH-modes are produced with more reactor-relevant conditions, Low torque IBS with W-equivalent radiators can exhibit predator-prey oscillations in Te and radiation which need control. High-β P scenarios with q min > 2, q 95 –7.9, β N > 4, β T –3.3% and H 98y2 > 1.5 are sustained with high density ($\overline{n}$ = 7E19 m -3 , f G –1) for 6 τ E , improving confidence in steady-state tokamak reactors. Diverted NT plasmas achieve high core performance with a non-ELMing edge, offering a possible highly attractive core-edge integration solution for reactors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1987

Size and metabolic properties of single muscle fibers in rat soleus after hindlimb suspension

The effect of 28-day-long hind-limb suspension (HS) combined with 10 daily forceful lengthening contractions of the limb on the morphological and metabolic properties of individual fibers of the soleus was studied in rats, using quantitative histochemical techniques. Compared with nonsuspended controls (CON), soleus wet weights of HS rats were decreased by 49 percent; the fibers staining lightly for myosin ATPase ('light-ATPase' fibers) atrophied more than the 'dark-ATPase' fibers. Single-fiber alpha-glycerophosphate dehydrogenase (GPD) and succinate dehydrogenase (SDH) activities were higher in HS than in CON rats. Daily forceful lengthening contractions did not prevent the HS-induced changes. The results support the view that the soleus fibers can change from a slow-twitch oxidative to a fast-twitch oxidative-glycolytic profile, but rarely to a fast-twitch glycolytic one, and that the SDH and GPD activities per volume of tissue can be increased even when there are severe losses of contractile proteins.

Hauschka, Edward O.↗
NASA NTRS1996

Ulysses observations of double ion beams associated with coronal mass ejections

Coronal mass ejections (CME's) are thought to result from the loss of stability within a magnetically confined coronal structure leading to its radial expansion into interplanetary space. As the CME expands into the corona current sheets will form between the expanding CME and surrounding field lines in the ambient wind. This configuration may lead to reconnection between the CME and adjacemt field lines. Such reconnection may produce double ion beams as has been observed in the terrrestrial magnetosphere. We examine all 24 distinct signatures of CME's observed by Ulysses during the in-ecliptic portion of the mission. In 5 of these 24 cases the ion spectra were not clear and thus the presence of double ion beams could not be determined. In 13 of the remaining 19 CME's double ion beams were found on the leading and/or trailing edge of the CME but not in the interior of the CME. In 3 of the CME's double ion beams were found throughout the CME while in the remaining 3 CME's double ion beams were not present near or just inside of the CME. In contrast in a control sample of 19 randomly chosen intervals, double ion beams were present at the leading and/or trailing edges of the random intervals in only 3 of the 19 cases. There appears to be no correlation between probability of occurrence of double ion beams and a magnetic cloud or non-cloud configuration of the CME and no correlation between the presence of the double ion beams at the edges of the CME and the CME being a fast or slow CME.

Hammond, C. M.↗