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At least 955 records · Page 53

Role of gas-surface interactions in the reduction of OGO 6 neutral-particle mass spectrometer data

Data obtained with the quadrupole mass spectrometer aboard the OGO 6 satellite show the effects of significant surface interaction processes, including nearly complete recombination of incoming atomic oxygen on the walls of the instrument antechamber plus absorption and desorption of oxygen and carbon monoxide. The observed data are fit by solving the time-dependent continuity equations accounting for production and loss of atomic oxygen, molecular oxygen, and (in the case of mass 28) carbon monoxide. The surface parameters that best fit the data are selected and applied to the determination of ambient densities and their estimated errors.

Hedin, A. E.↗

Methods of measurement for semiconductor materials, process control, and devices

This progress report describes NBS activities directed toward the development of methods of measurement for semiconductor materials, process control, and devices. Significant accomplishments during this reporting period include design of a plan to provide standard silicon wafers for four-probe resistivity measurements for the industry, publication of a summary report on the photoconductive decay method for measuring carrier lifetime, publication of a comprehensive review of the field of wire bond fabrication and testing, and successful completion of organizational activity leading to the establishment of a new group on quality and hardness assurance in ASTM Committee F-1 on Electronics. Work is continuing on measurement of resistivity of semiconductor crystals; characterization of generation-recombination-trapping centers in silicon; study of gold-doped silicon; development of the infrared response technique; evaluation of wire bonds and die attachment; and measurement of thermal properties of semiconductor devices, delay time and related carrier transport properties in junction devices, and noise properties of microwave diodes.

Bullis, W. M.↗

Investigation of atomic oxygen-surface interactions related to measurements with dual air density explorer satellites

For a number of candidate materials of construction for the dual air density explorer satellites the rate of oxygen atom loss by adsorption, surface reaction, and recombination was determined as a function of surface and temperature. Plain aluminum and anodized aluminum surfaces exhibit a collisional atom loss probability alpha .01 in the temperature range 140 - 360 K, and an initial sticking probability. For SiO coated aluminum in the same temperature range, alpha .001 and So .001. Atom-loss on gold is relatively rapid alpha .01. The So for gold varies between 0.25 and unity in the temperature range 360 - 140 K.

Wood, B. J.↗

Interferometric rotation sensor

An interferometric rotation sensor and control system is provided which includes a compound prism interferometer and an associated direction control system. Light entering the interferometer is split into two paths with the light in the respective paths being reflected an unequal number of times, and then being recombined at an exit aperture in phase differing relationships. Incoming light is deviated from the optical axis of the device by an angle, alpha. The angle causes a similar displacement of the two component images at the exit aperture which results in a fringe pattern. Fringe numbers are directly related to angle alpha. Various control systems of the interferometer are given.

Walsh, T. M.↗

Stellar Bragg crystal X-ray spectrometry on OSO-1

A high sensitivity crystal X-ray spectrometer for use on the Orbiting Solar Observatory (mission 1) satellite is described. This instrument will be used to obtain both solar and stellar spectra in the energy range 2 to 8 keV. In the stellar mode, the shape of the continua, the strength of lines, and the strength of recombination and absorption edge were determined. If lines or edges are detected, such data will provide direct evidence regarding the physical conditions in the emitting and absorbing regions. If only upper bounds are established, the data can be used to constrain theoretical models. In any case, precise continuum shapes will be established for a number of the brighter X-ray sources. Numerical estimates of the sensitivity of the instrument for these various purposes are given.

Landecker, P. B.↗

An experimental investigation of mesospheric ionization

Mesospheric ionization and its variability are examined. Data were obtained primarily by the parachute-borne blunt probe technique conducted in coordinated rocket experiments at White Sands Missile Range, New Mexico and Wallops Island, Virginia. Electrical conductivity measurements and deduced charge density values from ten rocket launches are presented and discussed. Positive ion conductivity and electron density were found to be relatively invariant with height between 45 and 60 km. Variations in positive conductivity of a factor of two and enhancements in negative conductivity by as much as a factor of four were measured by the blunt probe. A simple lumped parameter ion chemistry model is shown to satisfactorily explain the charge density values for the undisturbed lower D-region. Implications of the data in terms of this model are considered. The principal loss mechanism for positive ions in the 45 to 60 km. region is concluded to be dissociative recombination. Electron densities deduced from the conductivity data are explained by detachment involving a minor neutral constituent which is mixed between 65 and 45 km. and then cuts off sharply below 45 km. A correlation study involving blunt probe measurements shows relatively good agreement between variations in positive conductivity and temperature.

Mitchell, J. D.↗

Effects of nuclear radiation on a high-reliability silicon power diode. 4: Analysis of reverse bias characteristics

The effects of nuclear radiation on the reverse bias electrical characteristics of one hundred silicon power diodes were investigated. On a percentage basis, the changes in reverse currents were large but, due to very low initial values, this electrical characteristic was not the limiting factor in use of these diodes. These changes were interpreted in terms of decreasing minority carrier lifetimes as related to generation-recombination currents. The magnitudes of reverse voltage breakdown were unaffected by irradiation.

Been, J. F.↗

Ionospheric scale height from the refraction of satellite signals.

Accurate observations of the elevation angle of arrival of 20 MHz signals from the polar orbiting satellite Beacon-B for a 20 month period have provided transmission ionograms which may be reduced to give Hp the scale height at the peak of the ionosphere. Noon seasonal averages of Hp are 1.35 (in winter) to 1.55 (in summer) times greater than the scale height obtained from bottom-side ionograms. A comparison of scale height at the peak with routine measurements of total content and peak electron density indicates that the O+/H+ transition level is above 1000 km during the day but comes down to about 630 km on winter nights. A predawn peak in the overall scale height is caused by a lowering of the layer to a region of increased recombination and is magnified in winter by low O+/H+ transition levels.

Heron, M. L.↗

Dayglow forbidden O I 6300 and 5577 A lines in the early morning ionosphere.

Data on a developing morning ionosphere have been obtained by rocket measurement of the atomic oxygen red- and green-line airglow emissions and of the composition of the neutral and ionized constituents of the upper atmosphere. The use of tilting-filter photometers for the optical measurements resulted in reliable and accurate height profiles of the airglow intensity from below 100 to 245 km. The roles of the excitation of both O(super 1 D) and O(super 1 S) atoms by the dissociative recombination of O2(+) and electron impact were studied by using the 6300- and 5577-A data in conjunction with the ion composition measurements. The component of photodissociative excitation of O(super 1 D) by solar radiation in the Schumann-Runge continuum of O2 absorption was assessed as being approximately twice that determined for a previous rocket experiment.

Schaeffer, R. C.↗

Metallic ions in the equatorial ionosphere.

Four positive ion composition measurements of the equatorial E region at Thumba, India, are presented. During the day, the major ions between 90 and 125 km are NO+ and O2+. The relative concentrations are similar to those observed at midlatitudes but exhibit unusual structural behavior with altitude. A metallic ion layer centered at 92 km is found to contain Mg+, Fe+, Ca+, K+, Al+, Na+, and possibly Si+ ions. The layer is explained in terms of a similarly shaped altitude distribution of neutral atoms that are photoionized and charge exchanged with NO+ and O2+. Three-body reactions form molecular metallic ions that are rapidly lost by dissociative ion-electron recombination.

Aikin, A. C.↗

Measurement of Debye length in laser-produced plasma.

The Debye length of an expanded plasma created by placing an evacuated chamber with an entrance slit in the path of a freely expanding laser produced plasma was measured, using the slab geometry. An independent measurement of electron density together with the observed value for the Debye length also provided a means for evaluating the plasma electron temperature. This temperature has applications in ascertaining plasma conductivity and magnetic field necessary for confinement of the laser produced plasma. Also, the temperature obtained would be useful in analyzing electron-ion recombination rates in the expanded plasma and the dynamics of the cooling process of the plasma expansion.

Ehler, W.↗

The diurnal heat budget of the thermosphere.

Detailed numerical calculations of thermospheric heat sources and sinks are presented and their relative importance is discussed in reference to the energy balance phenomena of the neutral atmosphere. It is shown that the thermal energy available from the absorption in the Schumann-Runge continuum leading to photo-dissociation of O2 is by far the largest energy source in the lower thermosphere. Other sources of varying importance in different altitude ranges are: (1) energy from photoelectrons; (2) energy exchange from thermal plasma; (3) chemical reaction (ion-electron dissociative recombination) energy gain; (4) kinetic and dissipative energy associated with the neutral wind. The energy sinks of importance are (1) thermal conduction at the lower boundary (120 km); and (2) radiative cooling of atomic oxygen. It is shown that the combined energy from processes 2 to 4 constitutes only a small fraction of the total energy available from photoelectrons and is in phase with the latter. These secondary sources (processes 2 to 4), therefore, do not constitute a significant energy source and their contribution can be simply incorporated into photoelectron energy (process 1) by defining an effective photoionization heating efficiency.

Chandra, S.↗

Molecule formation. I - In normal H I clouds. II - In interstellar shock waves.

The formation of simple molecules and their role in the chemistry and physics of the interstellar medium is considered. The requirements for recombination reactions to occur on interstellar grains with the subsequent buildup of a molecular mantle are discussed. Together with a discussion of depletion and heating of the evolving gas, this forms the basis for a treatment of the precollision history of dust and gas. All the chemical reactions included in the calculations are given, as well as the results of calculations for two values of the intercloud pressure and for a range of cloud masses. Shock waves in clouds whose precollision history has been calculated are treated, followed by discussion of the shock structure and the dynamics of the grains. The process of sputtering is treated, and expressions are given for the cooling rates, including cooling due to the molecules formed behind the shock front. All the chemical reactions included in the calculations are given, as well as the results of calculations for a range of shock velocities and initial molecular hydrogen abundances.

Aannestad, P. A.↗

Effect of surface catalytic activity on stagnation heat-transfer rates.

An experiment was made to determine the effect heterogeneous catalytic surface reactions have on heat-transfer rates in highly frozen low-density stagnation-point boundary layers. Data were obtained in arc-heated facilities that were capable of producing large percentages of chemical energy frozen in a supersonic freestream. The heat-transfer rate to a silicon-dioxide surface was reduced to a minimum value of only one-third of the value obtained on relatively active nickel and platinum surfaces. This is the result of its low catalytic efficiency. Ionization energy was recovered on both the active and the inactive surfaces, indicating that this energy either was released many times faster than the recombination energy or was not controlled by the surface composition.

Anderson, L. A.↗

Conjugate photoelectron excitation of O I 4368 airglow emission.

Conjugate photoelectron fluxes are shown to be mainly responsible for the excitation of O I 4368 radiation observed with a grille spectrometer located at Langmuir Laboratory, New Mexico (L equals 1.7). On the basis of observations of O I 7774 and 4368 tropical emissions at Agulhas, Negras, Brazil (L equals 1.1), the contribution of radiative recombination to the New Mexico intensity is shown to be small. Conjugate photoelectron excitation at the Brazilian site has not been observed.

Christensen, A. B.↗

Liquid propellant rockets.

A brief overview of the state of knowledge in liquid rocket technology is presented and examples are provided of instances where some fundamental principles of chemistry, fluid mechanics, and mathematics can be applied. A liquid propellant rocket classification is discussed together with rocket system performance, applications for liquid propellants, the effective exhaust velocity, aspects of simplified nozzle expansion, questions about theoretical propellant performance, the effect of chamber pressure on equilibrium performance, and the kinetic recombination in nozzles. Details of propellant combustion are examined, giving attention to propellant injection, evaporation-controlled combustion, combustion instability, and monopropellant decomposition.

Dipprey, D. F.↗

Equatorial airglow and the ionospheric geomagnetic anomaly.

Ogo 4 observations of the O I (6300-A) emissions have revealed a global pattern hitherto undetected from the ground-based observations. It is seen that the postsunset emission of O I (6300 A) in October 1967 is very asymmetrical with respect to the geomagnetic equator in certain longitude regions and shows poor correlation with the electron density measured simultaneously from the same spacecraft. This asymmetry is less marked in the UV airglow, O I (1356 A), which appears to vary as the square of the maximum electron density in the F region. The horizon scan data of the 6300-A airglow reveal that the latitudinal asymmetry is associated with asymmetry in the height of the O I (6300-A) emission and hence with the altitude of the F2 peak. From the correlative studies of the airglow and the ionospheric measurements the mechanisms of the UV and the 6300 A emissions are discussed in terms of the processes involving radiative and dissociative recombination. Theoretical expressions are developed which relate the airglow data to the ionospheric parameters.

Chandra, S.↗

Role of gas-surface interactions in the reduction of Ogo 6 neutral particle mass spectrometer data.

Data obtained with the quadrupole mass spectrometer aboard the Ogo 6 satellite show the effects of significant surface interaction processes, including nearly complete recombination of incoming atomic oxygen on the walls of the instrument antechamber plus adsorption and desorption of oxygen and carbon monoxide. The observed data are fit by solving the time-dependent continuity equations accounting for production and loss of atomic oxygen, molecular oxygen, and (in the case of mass 28) carbon monoxide. The surface parameters that best fit the data are selected and applied to the determination of ambient densities and their estimated errors.

Hedin, A. E.↗