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At least 955 records · Page 53

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NASA NTRS1975

Behaviour of nitric oxide trails deposited in the mesosphere and stratosphere

The transient behavior of a nitric oxide trail deposited at approximately 60 km altitude is studied by the solution of the appropriate multidimensional diffusion equation which includes terms representing the effects of wind shear. Similar analysis is then carried out for the situation in the stratosphere. Trail behavior is found to be relatively independent of altitude and background ozone, but strongly dependent on the magnitude of eddy diffusity and the initial nitric oxide concentration. The nitric oxide trail reacts with ambient ozone to form nitrogen dioxide. For a trail 100 m initial radius, an ozone hole will form to a maximum size in 4 to 6 hours and then decay. The overall recovery time of the atmosphere following the creation of the trail is less than 12 hours.

Eberstein, I. J.↗

NASA NTRS1974

On-orbit performance of the Skylab astronaut maneuvering research vehicle

The present work evaluates the results of flight tests of the Astronaut Maneuvering Research Vehicle (AMRV) conducted inside the Skylab Orbital Workshop. The vehicle is an autonomous mobility aid which allows the pilot to control his position and orientation in space without the necessity of reacting against the spacecraft. The purpose of the tests was to obtain operation experience and engineering/human performance data in a zero gravity environment, to correlate on-orbit data with simulation data, and to recommend a design configuration for future operational maneuvering units. Four different techniques for controlling AMRV dynamics were tested: hand-held maneuvering unit, direct, rate gyro, and control moment gyro operating modes.

Murtagh, T. B.↗

NASA NTRS1974

Structure and properties of solid surfaces

Difficulties in experimental studies of crystalline surfaces are related to the fact that surface atoms have an intrinsic tendency to react with their environment. A second problem is connected with the effective thickness of surfaces, which ranges from one to several atom layers. The phenomenology of surface interactions with gases are considered, taking into account physical adsorption, chemisorption, and the oxidation of surfaces. Studies of the surface structure are discussed, giving attention to field emission microscopy, field-ion microscopy, electron diffraction techniques, Auger spectroscopy, scanning electron microscopy, electron probe microanalysis, ion microprobe methods, and low-energy backscattering spectroscopy. Investigations of semiconductor surfaces are also described.

Gatos, H. C.↗

NASA NTRS1975

Flame stability in combusting turbulent jets

A simplified theoretical model for turbulent methane/air flames from a subscale power plant burner is developed and applied to predict the stability of flames as a function of (1) ambient atmosphere temperature and composition, (2) initial preheat temperature, and (3) percentage of external product gas recirculation. The flame model equates the rate at which mass is supplied per unit volume to the rate it is chemically reacted per unit volume using a one-step reaction and a perfectly stirred reactor (PSR). The model contains a free parameter which is evaluated by comparing the theoretical results to experimental results available in the literature. The stability results show that premixed, turbulent flames are stable over a wide equivalence ratio range if the ambient gas is air; however, if combustion products are entrained, the stability is sharply reduced.

Nelson, H. F.↗

NASA NTRS1975

Wave propagation in a quasi-chemical equilibrium plasma

Wave propagation in a quasi-chemical equilibrium plasma is studied. The plasma is infinite and without external fields. The chemical reactions are assumed to result from the ionization and recombination processes. When the gas is near equilibrium, the dominant role describing the evolution of a reacting plasma is played by the global conservation equations. These equations are first derived and then used to study the small amplitude wave motion for a near-equilibrium situation. Nontrivial damping effects have been obtained by including the conduction current terms.

Fang, T.-M.↗

NASA NTRS1974

Composition of the gases associated with the magmas that produced rocks 15016 and 15065

Gases may be trapped in crystallizing minerals in many different ways but gas analyses can provide geologically meaningful information only if the gases can be related to their specific locations in the host mineral. The gases trapped in glass inclusions can be representative samples of the gases associated with the magma adjacent to the mineral at the time it crystallized. Analyses of the gases in glass inclusions in gabbro 15065,44 and basalt 15016,48 show that in both cases the gases in the parent magma started with a composition close to 46% oxygen, 42% carbon and 12% hydrogen and became more water-rich as crystallization progressed. This enrichment is probably due to a selective removal of the less soluble carbon compounds into the vapor phase. Some of the volatile components may react with the rock as temperature falls to give siderite and possibly hydrous phases.

Barker, C.↗

NASA NTRS1975

Preliminary assessment of the potential impact of solid-fueled rocket engines in the stratosphere

Free chlorine atoms produced from HCl deposited by solid-fueled rocket engines react to destroy odd oxygen in the stratosphere. Using a one-dimensional photochemical model, we have computed the reduction of ozone likely to be caused by long-term operation of such vehicles powered by large solid-fueled rocket engines. It is likely that ozone reduction will not be greater than a few tenths of a per cent, although the value is dependent upon ambient NO(x) concentrations.

Whitten, R. C.↗

NASA NTRS1976

Novel aminobenzyl and imidobenzyl benzenes

Compounds are useful as intermediates for several classes of polymers. Amines can function as cross-linking agents for epoxide and urethane polymers, as well as intermediates for synthesis of thermally-stable addition-type polyimides. Imide derivatives can be obtained by reacting amines with certain monoanhydrides containing olefinic unsaturation.

Bell, V. L.↗

NASA NTRS1976

Hot-wire probe

High-temperature platinum probe measures turbulence and Reynolds shear stresses in high-temperature compressible flows. Probe does not vibrate at high velocities and does not react like strain gage on warmup.

Mikulla, V.↗

NASA NTRS1977

Rapid kinetics

Hybrid program for chemical kinetics provides rapid solution to problems involving flowing or static, chemically reacting, gas mixtures.

Mclain, A. G.↗

NASA NTRS1975

NASA/FRC wake turbulence flight test program: Ride quality aspects

To determine how much the ride quality of the Shuttle Carrier (Boeing 747) Aircraft is affected at various spoiler settings, the PEMS II (Portable Environmental Measuring System) was used to measure onboard motion during a test flight October 15, 1975. The PEMS II measures acceleration in the vertical, transverse and longitudinal directions as well as angular rates of pitch, roll, and yaw. The data acquired by this instrument, combined with an airline passenger comfort model, gives an indication of how passengers would react to the motion induced by flying in a vortex alleviation configuration.

Deptula, D. A.↗

NASA NTRS1975

On possible interactions between upper and lower atmosphere

Geomagnetic data was compared with data on tropospheric and stratospheric circulation characteristics; a statistically significant shrinking was found in areal extent of the stratospheric vortex from the third to the eighth day following a 'geomagnetic storm' The meridionality of the 30 640-m contour line at 10 millibars increases markedly from 5 to 8 days after the storm. During the contraction of the polar vortex edge, the mean height of the vortex central contour decreases only slightly. This indicates that a stratospheric warming event is associated with a steepening of the contour gradient rather than a warming over the entire area of the stratospheric polar vortex. The troposphere reacts to these weak, but significant, stratospheric warming events by a shrinkage of the area of the 500-millibar cold air pool. This shrinkage commences about 3 days after the stratospheric warming. The investigation indicates that the energy input into the stratosphere that is received in conjunction with the geomagnetic disturbance has to come at a propitious time, when the stratospheric-tropospheric circulation system is not already undergoing a major readjustment because of an inherent dynamic instability.

Macdonald, B. C.↗

NASA NTRS1976

A Theoretical and Experimental Study of Acoustic Propagation in Multisectioned Circular Ducts

The propagation of plane waves and higher order acoustic modes in a circular multisectioned duct was studied. A unique source array consisting of two concentric rings of sources, providing phase and amplitude control in the radial, as well as circumferential direction, was developed to generate plane waves and both spinning and nonspinning higher order modes. Measurements of attenuation and radial mode shapes were taken with finite length liners inserted between the hard wall sections of an anechoically terminated duct. Materials tested as liners included a glass fiber material and both sintered fiber metals and perforated sheet metals with a honeycomb backing. The fundamental acoustic properties of these materials were studied with emphasis on the attenuation of sound by the liners and the determination of local versus extended reaction behavior for the boundary condition. A search technique was developed to find the complex eigenvalues for a liner under the assumption of a locally reacting boundary condition.

Wyerman, B. R.↗

NASA NTRS1976

Indicator providing continuous indication of the presence of a specific pollutant in air

A continuous HCl in-air indicator was developed which consists of a tube-like element with an inlet end through which a continuous stream of air containing HCl enters. The air flows downstream from the inlet end and exits the element's outlet end. Positioned between the element's inlet and outlet ends are first and second spaced apart photoelectric units, which are preferably positioned adjacent the inlet and outlet ends, respectively. Ammonia gas is injected into the air, flowing through the element, at a position between the two photoelectric units. The ammonia gas reacts with the HCl in the air to form ammonium chloride particles. The difference between the outputs of the two photoelectric units is an indication of the amount of HCl in the air stream.

Miller, C. G.↗

NASA NTRS1976

A thermoluminescent method for aerosol characterization

A thermoluminescent method has been used to study the interactions of aerosols with ozone. The preliminary results show that ozone reacts with many compounds found in aerosols, and that the thermoluminescence curves obtained from ozonated aerosols are characteristic of the aerosol. The results suggest several important applications of the thermoluminescent method: development of a detector for identification of effluent sources; a sensitive experimental tool for study of heterogeneous chemistry; evaluation of importance of aerosols in atmospheric chemistry; and study of formation of toxic, electronically excited species in airborne particles.

Long, E. R., Jr.↗

NASA NTRS1976

Chemical equilibrium

The entropy of a gas system with the number of particles subject to external control is maximized to derive relations between the thermodynamic variables that obtain at equilibrium. These relations are described in terms of the chemical potential, defined as equivalent partial derivatives of entropy, energy, enthalpy, free energy, or free enthalpy. At equilibrium, the change in total chemical potential must vanish. This fact is used to derive the equilibrium constants for chemical reactions in terms of the partition functions of the species involved in the reaction. Thus the equilibrium constants can be determined accurately, just as other thermodynamic properties, from a knowledge of the energy levels and degeneracies for the gas species involved. These equilibrium constants permit one to calculate the equilibrium concentrations or partial pressures of chemically reacting species that occur in gas mixtures at any given condition of pressure and temperature or volume and temperature.

Source record↗

NASA NTRS1976

Effect of ester impurities in PMR-polyimide resin

Spectral and chomatographic studies were conducted which established the presence of tri- and tetraester impurities in aged monomer solutions employed in fabrication of PMR-polyimide resin composites. The equilibrium constant and apparent rate of the esterification were determined. It was demonstrated, using differential scanning calorimetry, that the ortho-ester moiety of these impurities does not completely react at typical cure conditions. It is concluded that voids formed in composites fabricated with aged monomer solution are due to gaseous decomposition products evolved by ester impurities and/or unreacted amine during elevated temperature post-cure treatment.

Lauver, R. W.↗

NASA NTRS1976

The reactions of O(ID) and OH with CH3OH, oxidation of the HCO radial, and the photochemical oxidation of formaldehyde

An experimental, laboratory study of the various photochemical reactions that can occur in the mesosphere and stratosphere is presented. N2O was photolyzed at 2139 A in the presence of CH3OH and CO. The O(id) produced in the photolysis reacted with CH3OH to produce OH radicals, and thus the reactions of both O(id) and OH were able to be studied. Also considered was the oxidation of the HCO radical. Mixtures of Cl2, O2, H2CO, and sometimes N2 or He were irradiated at 3660 A at several temperatures to photodecompose the Cl2. The photochemical oxidation of formaldehyde was studied as follows: formaldehyde in the presence of N2 and/or O2 (usually dry air) was photolyzed with a medium pressure Hg lamp used in conjunction with various filters which transmit different relative amounts of Hg lines from 2894 A to 3660 A. Results are presented and discussed, along with a description of experimental procedures and apparatus, and chemical reaction kinetics.

Osif, T. L.↗