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At least 955 records · Page 53

Dissolution of used nuclear fuel using recycled nitric acid

An evaluation was performed on the feasibility of using HB-Line anion exchange column waste streams from Alternate Feedstock 2 (AFS-2) processing for the dissolver solution for used nuclear fuel (UNF) processing. The targeted UNF for dissolution using recycled solution are fuels similar to the University of Missouri Research Reactor (MURR) fuel. Furthermore, the objectives of this experimental program were to validate the feasibility of using impure dissolver solutions with the MURR dissolution flowsheet to verify they would not significantly affect dissolution of the UNF in a detrimental manner.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Tc removal from the waste treatment and immobilization plant low-activity waste vitrification off-gas recycle

Vitrification of Low Activity Waste in the Hanford Waste Treatment and Immobilization Plant generates a condensate stream from the off-gas processes. Components in this stream are partially volatile and accumulate to high concentrations through recycling, which impacts the waste glass loading and facility throughput. The primary radionuclide that vaporizes and accumulates in the stream is 99 Tc. This program is investigating Tc removal via reductive precipitation with stannous chloride to examine the potential for diverting this stream to an alternate disposition path. As a result, research has shown stannous chloride to be effective, and this paper describes results of recent experiments performed to further mature the technology.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

THE SPECTRUM OF THE RECYCLED PSR J0437-4715 AND ITS WHITE DWARF COMPANION

We present extensive spectral and photometric observations of the recycled pulsar/white dwarf binary containing PSR J0437-4715, which we analyzed together with archival X-ray and gamma-ray data, to obtain the complete mid-infrared to gamma-ray spectrum. We first fit each part of the spectrum separately, and then the whole multi-wavelength spectrum. We find that the optical-infrared part of the spectrum is well fit by a cool white dwarf atmosphere model with pure hydrogen composition. The model atmosphere (T{sub eff} = 3950 {+-} 150 K, log g = 6.98 {+-} 0.15, R{sub WD} = (1.9 {+-} 0.2) Multiplication-Sign 10{sup 9} cm) fits our spectral data remarkably well for the known mass and distance (M = 0.25 {+-} 0.02 M{sub Sun }, d = 156.3 {+-} 1.3 pc), yielding the white dwarf age ({tau}{sub WD} = 6.0 {+-} 0.5 Gyr). In the UV, we find a spectral shape consistent with thermal emission from the bulk of the neutron star surface, with surface temperature between 1.25 Multiplication-Sign 10{sup 5} and 3.5 Multiplication-Sign 10{sup 5} K. The temperature of the thermal spectrum suggests that some heating mechanism operates throughout the life of the neutron star. The temperature distribution on the neutron star surface is non-uniform. In the X-rays, we confirm the presence of a high-energy tail which is consistent with a continuation of the cutoff power-law component ({Gamma} = 1.56 {+-} 0.01, E{sub cut} = 1.1 {+-} 0.2 GeV) that is seen in gamma rays and perhaps even extends to the near-UV.

79 ASTRONOMY AND ASTROPHYSICS↗

FROM PLANETESIMALS TO DUST: LOW-GRAVITY EXPERIMENTS ON RECYCLING SOLIDS AT THE INNER EDGES OF PROTOPLANETARY DISKS

Transporting solids of different sizes is an essential process in the evolution of protoplanetary disks and planet formation. Large solids are supposed to drift inward; high-temperature minerals found in comets are assumed to have been transported outward. From low-gravity experiments on parabolic flights, we studied the light-induced erosion of dusty bodies caused by a solid-state greenhouse effect and photophoresis within a dust bed's upper layers. The gravity levels studied were 0.16g, 0.38g, 1g, and 1.7g. The light flux during the experiments was 12 {+-} 2 kW m{sup -2} and the ambient pressure was 6 {+-} 0.9 mbar. Light-induced erosion is strongly gravity dependent, which is in agreement with a developed model. In particular for small dusty bodies ((sub)-planetesimals), efficient erosion is possible at the optically thin inner edges of protoplanetary disks. Light-induced erosion prevents significant parts of a larger body from moving too close to the host star and being subsequently accreted. The small dust produced continues to be subject to photophoresis and is partially transported upward and outward over the surface of the disk; the resulting small dust particles are observed over the disk's lifetime. The fraction of eroded dust participates in subsequent cycles of growth during planetesimal formation. Another fraction of dust might be collected by a body of planetary size if this body is already present close to the disk edge. Either way, light-induced erosion is an efficient recycling process in protoplanetary disks.

79 ASTRONOMY AND ASTROPHYSICS↗

HST/COS SPECTRA OF THREE QSOs THAT PROBE THE CIRCUMGALACTIC MEDIUM OF A SINGLE SPIRAL GALAXY: EVIDENCE FOR GAS RECYCLING AND OUTFLOW

We have used the Cosmic Origins Spectrograph (COS) to obtain far-UV spectra of three closely spaced QSO sight lines that probe the circumgalactic medium (CGM) of an edge-on spiral galaxy, ESO 157-49, at impact parameters of 74 and 93 h {sup -1} {sub 70} kpc near its major axis and 172 h {sup -1} {sub 70} kpc along its minor axis. H I Ly{alpha} absorption is detected at the galaxy redshift in the spectra of all three QSOs, and metal lines of Si III, Si IV, and C IV are detected along the two major-axis sight lines. Photoionization models of these clouds suggest metallicities close to the galaxy metallicity, cloud sizes of {approx}1 kpc, and gas masses of {approx}10{sup 4} M {sub Sun }. Given the high covering factor of these clouds, ESO 157-49 could harbor {approx}2 Multiplication-Sign 10{sup 9} M {sub Sun} of warm CGM gas. We detect no metals in the sight line that probes the galaxy along its minor axis, but gas at the galaxy metallicity would not have detectable metal absorption with ionization conditions similar to the major-axis clouds. The kinematics of the major-axis clouds favor these being portions of a 'galactic fountain' of recycled gas, while two of the three minor-axis clouds are constrained geometrically to be outflowing gas. In addition, one of our QSO sight lines probes a second more distant spiral, ESO 157-50, along its major axis at an impact parameter of 88 h {sup -1} {sub 70} kpc. Strong H I Ly{alpha} and C IV absorption only are detected in the QSO spectrum at the redshift of ESO 157-50.

79 ASTRONOMY AND ASTROPHYSICS↗

X-RAY OBSERVATIONS OF DISRUPTED RECYCLED PULSARS: NO REFUGE FOR ORPHANED CENTRAL COMPACT OBJECTS

We present a Chandra X-ray survey of the disrupted recycled pulsars (DRPs), isolated radio pulsars with P > 20 ms and B{sub s} < 3 Multiplication-Sign 10{sup 10} G. These observations were motivated as a search for the immediate descendants of the Almost-Equal-To 10 central compact objects (CCOs) in supernova remnants (SNRs), 3 of which have similar timing and magnetic properties as the DRPs, but are bright, thermal X-ray sources consistent with minimal neutron star (NS) cooling curves. Since none of the DPRs were detected in this survey, there is no evidence that they are ''orphaned'' CCOs, NSs whose SNRs has dissipated. Upper limits on their thermal X-ray luminosities are in the range of log L{sub x} [erg s{sup -1}] = 31.8-32.8, which implies cooling ages >10{sup 4}-10{sup 5} yr, roughly 10 times the ages of the Almost-Equal-To 10 known CCOs in a similar volume of the Galaxy. The order of a hundred CCO descendants that could be detected by this method are thus either intrinsically radio quiet or occupy a different region of (P, B{sub s} ) parameter space from the DRPs. This motivates a new X-ray search for orphaned CCOs among radio pulsars with larger B-fields, which could verify the theory that their fields are buried by the fall-back of supernova ejecta, but quickly regrow to join the normal pulsar population.

79 ASTRONOMY AND ASTROPHYSICS↗

THE IMACS CLUSTER BUILDING SURVEY. V. FURTHER EVIDENCE FOR STARBURST RECYCLING FROM QUANTITATIVE GALAXY MORPHOLOGIES

Using J- and K{sub s}-band imaging obtained as part of the IMACS Cluster Building Survey (ICBS), we measure Sérsic indices for 2160 field and cluster galaxies at 0.31 < z < 0.54. Using both mass- and magnitude-limited samples, we compare the distributions for spectroscopically determined passive, continuously star-forming, starburst, and post-starburst systems and show that previously established spatial and statistical connections between these types extend to their gross morphologies. Outside of cluster cores, we find close structural ties between starburst and continuously star-forming, as well as post-starburst and passive types, but not between starbursts and post-starbursts. These results independently support two conclusions presented in Paper II of this series: (1) most starbursts are the product of a non-disruptive triggering mechanism that is insensitive to global environment, such as minor mergers; (2) starbursts and post-starbursts generally represent transient phases in the lives of 'normal' star-forming and quiescent galaxies, respectively, originating from and returning to these systems in closed 'recycling' loops. In this picture, spectroscopically identified post-starbursts constitute a minority of all recently terminated starbursts, largely ruling out the typical starburst as a quenching event in all but the densest environments.

79 ASTRONOMY AND ASTROPHYSICS↗

Post-puff SOL broadening on MAST-U under high-recycling conditions: evidence consistent with cross-field transport changes

Transient broadening of the scrape-off layer (SOL) density profile can modify main-chamber first-wall particle fluxes and divertor loading, yet its control parameters remain debated between divertor-regime transitions, neutral dynamics and changes in cross-field transport. We investigate fueling-driven SOL density-profile evolution and post-fueling relaxation on MAST-Upgrade (MAST-U) in ohmic L-mode, using two otherwise similar double-null Conventional Divertor discharges (I p = 450 kA, B T = 0.33 T) with identical 50 ms low-field side gas puffs; the only intentional difference is the puff start time. Upstream Thomson scattering shows that both discharges develop a transient far-SOL density profile modification, expressed as an increased SOL-width metric λ n e and a far-SOL enhancement consistent with a shoulder-like signature. In the earlier-puff case, the SOL-width metric remains elevated after puff termination and the post-puff decay time scales are systematically longer across the analysed radii. Outer-target Langmuir probes indicate high-recycling conditions during the analysed window (few-eV T e with radially peaked j sat,∥ and q ∥ profiles, without signatures of deep detachment). The outer-divertor collisionality proxy Λ div is elevated in both cases and does not discriminate between the different post-puff persistence. The target-integrated ion flux proxy ∫ J sat dA evolves nearly identically in both discharges when aligned to the puff start. Taken together, these observations suggest that the late/post-puff upstream SOL evolution is not set by parallel exhaust to the outer targetalone and is more consistent with upstream cross-field redistribution, with a possible role for plasma–neutral coupling and fueling geometry.

MAST-U↗

Divertorlets concept for low-recycling fusion reactor divertor: experimental, analytical and numerical verification

The 'divertorlets' concept is a potential non-evaporative liquid metal solution for heat removal at low recycling regime. A toroidal divertorlets prototype was built and tested in LMX-U at Princeton Plasma Physics Laboratory to evaluate the performance of this configuration. Here, details of the design, experimental results, comparison with analytical theory and MHD numerical simulations of toroidal divertorlets are covered. Experiments, analytical model and simulations showed agreement and allowed the projection of operation properties at higher magnetic flux densities (reactor-like operation), proving the concept to be a compelling solution for divertor applications.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Reducing measurement costs by recycling the Hessian in adaptive variational quantum algorithms

Abstract Adaptive protocols enable the construction of more efficient state preparation circuits in variational quantum algorithms (VQAs) by utilizing data obtained from the quantum processor during the execution of the algorithm. This idea originated with Adaptive Derivative-Assembled Problem-Tailored variational quantum eigensolver (ADAPT-VQE), an algorithm that iteratively grows the state preparation circuit operator by operator, with each new operator accompanied by a new variational parameter, and where all parameters acquired thus far are optimized in each iteration. In ADAPT-VQE and other adaptive VQAs that followed it, it has been shown that initializing parameters to their optimal values from the previous iteration speeds up convergence and avoids shallow local traps in the parameter landscape. However, no other data from the optimization performed at one iteration is carried over to the next. In this work, we propose an improved quasi-Newton optimization protocol specifically tailored to adaptive VQAs. The distinctive feature in our proposal is that approximate second derivatives of the cost function are recycled across iterations in addition to optimal parameter values. We implement a quasi-Newton optimizer where an approximation to the inverse Hessian matrix is continuously built and grown across the iterations of an adaptive VQA. The resulting algorithm has the flavor of a continuous optimization where the dimension of the search space is augmented when the gradient norm falls below a given threshold. We show that this inter-optimization exchange of second-order information leads the approximate Hessian in the state of the optimizer to be consistently closer to the exact Hessian. As a result, our method achieves a superlinear convergence rate even in situations where the typical implementation of a quasi-Newton optimizer converges only linearly. Our protocol decreases the measurement costs in implementing adaptive VQAs on quantum hardware as well as the runtime of their classical simulation.

Ramôa, Mafalda (ORCID:0000000302187801)↗

CELLULOSE SYNTHASE INTERACTIVE1 Is Required for Fast Recycling of Cellulose Synthase Complexes to the Plasma Membrane in Arabidopsis

Plants are constantly subjected to various biotic and abiotic stresses and have evolved complex strategies to cope with these stresses. For example, plant cells endocytose plasma membrane material under stress and subsequently recycle it back when the stress conditions are relieved. Cellulose biosynthesis is a tightly regulated process that is performed by plasma membrane-localized cellulose synthase (CESA) complexes (CSCs). However, the regulatory mechanism of cellulose biosynthesis under abiotic stress has not been well explored. In this study, we show that small CESA compartments (SmaCCs) or microtubule-associated cellulose synthase compartments (MASCs) are critical for fast recovery of CSCs to the plasma membrane after stress is relieved in Arabidopsis thaliana. This SmaCC/MASC-mediated fast recovery of CSCs is dependent on CELLULOSE SYNTHASE INTERACTIVE1 (CSI1), a protein previously known to represent the link between CSCs and cortical microtubules. Independently, AP2M, a core component in clathrin-mediated endocytosis, plays a role in the formation of SmaCCs/MASCs. Together, our study establishes a model in which CSI1-dependent SmaCCs/MASCs are formed through a process that involves endocytosis, which represents an important mechanism for plants to quickly regulate cellulose synthesis under abiotic stress.

59 BASIC BIOLOGICAL SCIENCES↗

Preliminary Testing of a Continuous Cryopump for Primary Fusion Device Pumping and Direct Internal Recycling

Here, the concept of directly recirculating fusion machine exhaust gas, bypassing the tritium plant, to make fuel pellets was proposed in the 1990s and later termed direct internal recycling (DIR). In the DIR concept, the residual fusion fuel in the machine exhaust stream is separated from impurities locally and diverted directly to the fueling systems, bypassing isotopic separation and other processing equipment, and therefore significantly reducing the required size of the fuel processing plant, reducing plant inventory, and thus increasing the economic viability of fusion as an energy source. One concept for DIR consists of a series of cryogenic pumps to separate the impurities from the machine exhaust gas using different triple point temperatures and saturation curves of exhaust constituents. In this concept, the plasma exhaust is initially passed through an impurity trap operating at ~25–30 K to desublimate impurities such as hydrocarbons, argon, oxygen, and nitrogen. The resulting process stream will consist of DT fuel and helium. The process stream is then pumped by a continuous cryopump known as a “snail pump.” This pump is a steady-state continuous cryopump that desublimates all remaining exhaust gas constituents while allowing helium, a byproduct of the fusion reaction, to pass through. The helium is pumped to the tritium plant for processing while the desublimated material is continuously scraped off, heated up, and transported to the fueling system. This article will present the cryogenic DIR concept and outline the design and operation of the snail pump, along with results from preliminary testing. Tests to assess pumping and separation efficiency found that at D2 flows below 50.7 Pa ⋅ m3/s with 1% helium, the pump is capable of pumping and separating the gas with a resulting DIR fraction of >99%, with no helium entrained in the primary fuel exhaust stream. The main limitation is due to the thermal performance of the cryogenic circuits of the pump, which will be addressed in future testing.

Gebhart III, Trey E. [Oak Ridge National Laborator↗

A recyclable self-healing composite with advanced sensing property

Polymer-based composites frequently encounter damage, often lurking beneath the surface and proving challenges to their early detection and repair. While material-based sensors show promise for encoding self-sensing properties within these composites, their in situ healing and reprocessability remain significant challenges. Therefore, the overarching goal of this study is the creation of a reprocessable polymeric composite encoded with self-healing attributes and the ability to autonomously sense damage. At the core of this innovation are vitrimers, a polymeric material characterized by a covalently adaptive dynamic network responsive to external factors such as heat. They combine thermoset-like resilience with thermoplastic-like flowability on demand under external stimuli. We nanoengineer a polyester-based vitrimeric polymer by incorporating piezoresistive carbon nanotubes (CNTs) as reinforcing elements that not only enhance its mechanical strength but also create a percolation network within the composite, thereby enabling piezoresistive self-sensing properties, all the while preserving the intrinsic self-healing capabilities offered by the vitrimeric matrix. The fabrication process of the composite involves a solvent-free in situ polymerization method that combines epoxy and anhydride-containing monomers with ~ 0.1 wt.% of CNTs. Once it was established that the introduction of CNTs into the polymeric matrix did not compromise the mechanical properties of the composite, their strain-sensing properties were characterized by applying cyclic loading while measuring their electrical resistance. Strikingly, CNT-enhanced vitrimer composite consistently retains its mechanical and sensing properties through repeated cycles of reshaping and reprocessing, underscoring its potential as a robust distributed strain sensor. This polyester-based vitrimeric composite is also easily recyclable without harsh chemical treatments. Preliminary findings from this study conclusively demonstrate that the bulk composite boasts both self-sensing capabilities and in situ detect healing properties, charting a promising course towards the development of a mechanically resilient multifunctional composite that seamlessly integrates selfsensing and healing capabilities.

Rohewal, Sargun Singh↗

Chemically recyclable thermoplastics from reversible-deactivation polymerization of cyclic acetals

Identifying plastics capable of chemical recycling to monomer (CRM) is the foremost challenge in creating a sustainable circular plastic economy. Polyacetals are promising candidates for CRM but lack useful tensile strengths owing to the low molecular weights produced using current uncontrolled cationic ring-opening polymerization (CROP) methods. Here, we present reversible-deactivation CROP of cyclic acetals using a commercial halomethyl ether initiator and an indium(III) bromide catalyst. Using this method, we synthesize poly(1,3-dioxolane) (PDXL), which demonstrates tensile strength comparable to some commodity polyolefins. Depolymerization of PDXL using strong acid catalysts returns monomer in near-quantitative yield and even proceeds from a commodity plastic waste mixture. Our efficient polymerization method affords a tough thermoplastic that can undergo selective depolymerization to monomer.

Abel, Brooks A.↗

Evolution of isotopic composition of reprocessed uranium during the multiple recycling in light water reactors with natural uranium feed

A complex approach based on the consistent modeling of neutron-physics processes and processes of cascade separation of isotopes is applied for analyzing physical problems of the multiple usage of reprocessed uranium in the fuel cycle of light water reactors. A number of scenarios of multiple recycling of reprocessed uranium in light water reactors are considered. In the process, an excess absorption of neutrons by the {sup 236}U isotope is compensated by re-enrichment in the {sup 235}U isotope. Specific consumptions of natural uranium for re-enrichment of the reprocessed uranium depending on the content of the {sup 232}U isotope are obtained.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Neutral recycling effects on ITG turbulence

The effects of recycled neutral atoms on tokamak ion temperaturegradient (ITG) driven turbulence have been investigated in a steepedge pedestal, magnetic separatrix configuration, with the full-fedge gryokinetic code XGC1. Ion temperature gradient turbulence isthe most fundamental and robust edge plasma instability, having a longradial correlation length and an ability to impact other forms ofpedestal turbulence. The neutral atoms enhance the ITG turbulence,first, by increasing the ion temperature gradient in the pedestal viathe cooling effects of charge exchange and, second, by a relativereduction in the ExB shearing rate.

Tokamak↗