DOE OSTI2017
Today's best permanent magnet materials, SmCo 5 and Nd 2 Fe 14 B, could likely be made signi fi cantly more powerful were it not necessary to dilute the strong magnetism of the rare earth ions (Sm, Nd) with the 3 d transition elements (Fe, Co). Since the rare-earth metals order magnetically at relatively low temperatures T o <= 292 K, transition elements must be added to bring T o to temperatures well above ambient. Under pressure T o (P) for the neighboring lanthanides Gd, Tb, and Dy follows a notably nonmonotonic, but nearly identical, dependence to similar to 60 GPa. At higher pressures, however, Tb and Dy exhibit highly anomalous behavior, T o for Dy soaring to temperatures well above ambient. In conclusion, we suggest that this anomalously high magnetic ordering temperature is an heretofore unrecognized feature of the Kondo lattice state.