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At least 955 records · Page 53

Structures of glasses created by multiple kinetic arrests

X-ray scattering has been used to characterize glassy itraconazole (ITZ) prepared by cooling at different rates. Faster cooling produces ITZ glasses with lower (or zero) smectic order with more sinusoidal density modulation, larger molecular spacing, and shorter lateral correlation between the rod-like molecules. We find that each glass is characterized by not one, but two fictive temperatures T f (the temperature at which a chosen order parameter is frozen in the equilibrium liquid). The higher T f is associated with the regularity of smectic layers and lateral packing, while the lower T f with the molecular spacings between and within smectic layers. This indicates that different structural features are frozen on different timescales. The two timescales for ITZ correspond to its two relaxation modes observed by dielectric spectroscopy: the slower δ mode (end-over-end rotation) is associated with the freezing of the regularity of molecular packing and the faster α mode (rotation about the long axis) with the freezing of the spacing between molecules. Finally, our finding suggests a way to selectively control the structural features of glasses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Insights into hyperbolic phonon polaritons in h – BN using Raman scattering from encapsulated transition metal dichalcogenide layers

Alternative techniques for probing hyperbolic phonon polaritons (HPPs) in two-dimensional materials will support the development of the emerging technologies in this field. Previous reports have shown that it is possible for W Se 2 monolayers in contact with the hexagonal boron nitride (h– BN) to generate HPPs in the h– BN via Raman scattering. In this paper, we set out our results on HPP Raman scattering induced in h– BN by W Se 2 and Mo Se 2 monolayers including multiple resonances at which the Raman scattering is enhanced. Analysis of the observed Raman line shapes demonstrates that Raman scattering allows HPPs with wave vectors with magnitudes significantly in excess of 15 000 cm –1 to be probed. Finally, we present evidence that the Raman scattering can probe HPPs with frequencies less than the expected lower bound on the reststrahlen band, suggesting new HPP physics still waits to be discovered.

2-dimensional systems↗

Scatter gather using key-value store

Scatter gather operation(s) are performed by accessing a shared memory that is shared amongst nodes interconnected through network(s) and having a CNS shared amongst the nodes. Data is gathered from multiple processes at corresponding multiple nodes into location(s) in the CNS, and tuple(s) having a same tuple name are created in the CNS. The tuple(s) have information referencing the gathered data in the location(s). Alternatively, data that has been gathered using the same tuple name is scattered to multiple processes participating in the CNS. The scattering uses the tuple(s) in the CNS, and is performed from the location(s) into other location(s) at one or multiple nodes for one or multiple processes at the corresponding one or multiple nodes. Both the gathering data and the scattering data may also be performed.

Jacob, Philip↗

Collision Tracking in OpenMC: Methods and Applications in Neutron Noise, Neutron Imaging, Time-of-Flight, and Multiplicity Counting

We present the development and application of a collision tracking feature within the OpenMC Monte Carlo particle transport code, designed for diverse applications such as neutron spectroscopy, scatter camera system, neutron noise, and multiplicity counting simulations. This feature enables the tracking of individual particle collisions, with potential applications in nuclear nonproliferation, reactor physics, and nuclear security. Additionally, the feature holds potential for the calibration of neutron detectors, specifically in converting light output into energy deposited within the detectors. The implementation consists of a set of filters—such as reaction type, energy, cell, and material—that constrain the set of collisions that are tracked, extensions to the Python API to enable simple input specification, and support for writing either OpenMC’s native HDF5-based format or the Monte Carlo particle list format. This feature was added to the official OpenMC release in version 0.15.3. In this work, the feature will be applied to showcase scenarios such as time-of-flight simulations, scatter-camera imaging for neutron source localization, neutron-noise analysis to extract integral kinetic parameters such as the prompt decay constant α, and multiplicity counting to estimate the mass of special nuclear materials. Ultimately, this feature aims to expand the application scope of open-source Monte Carlo particle transport codes such as OpenMC.

Monte Carlo code↗

X-ray scattering based scanning tomography for imaging and structural characterization of cellulose in plants

X-ray and neutron scattering have long been used for structural characterization of cellulose in plants. Due to averaging over the illuminated sample volume, these measurements traditionally overlooked the compositional and morphological heterogeneity within the sample. Here, a scanning tomographic imaging method is described, using contrast derived from the X-ray scattering intensity, for virtually sectioning the sample to reveal its internal structure at a resolution of a few micrometres. This method provides a means for retrieving the local scattering signal that corresponds to any voxel within the virtual section, enabling characterization of the local structure using traditional data-analysis methods. This is accomplished through tomographic reconstruction of the spatial distribution of a handful of mathematical components identified by non-negative matrix factorization from the large dataset of X-ray scattering intensity. Joint analysis of multiple datasets, to find similarity between voxels by clustering of the decomposed data, could help elucidate systematic differences between samples, such as those expected from genetic modifications, chemical treatments or fungal decay. The spatial distribution of the microfibril angle can also be analyzed, based on the tomographically reconstructed scattering intensity as a function of the azimuthal angle.

36 MATERIALS SCIENCE↗

Simplified spin dependence in dark matter direct detection

The interactions of dark matter with Standard Model particles can be systematically studied in the language of effective field theories. We investigate dark matter interactions with Standard Model particles, including spin-dependent interactions, for direct detection experiments and demonstrate that, although the scattering rate generally depends on multiple types of material response functions, certain linear combinations of these material response functions vanish if the initial and final electronic states share the same Hamiltonian. We also find that several other response functions vanish in parity-symmetric materials, making these systems as simple as isotropic detectors in some respects. Finally, we present the scattering rate for an anisotropic, possibly chiral detector, for generic dark matter-electron spin interactions. These relations reduce the number of independent response functions needed, thereby simplifying the computational complexity for a broad class of dark matter models. Our results provide a complete and efficient toolkit for analyzing electron recoil signals in diverse detector materials.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Modeling of the Molten Salt Reactor Experiment with SCALE

A SCALE model was developed for the Molten Salt Reactor Experiment (MSRE) benchmark that was recently added to the International Handbook of Evaluated Reactor Physics Benchmark Experiments. This SCALE model served as a basis for criticality calculations and nuclear data sensitivity and uncertainty analyses with the Monte Carlo code Shift and the TSUNAMI computational capabilities in the SCALE code system. The focus of this work is the assessment of the impact of nuclear data on the calculated eigenvalue results in support of the discussion of differences between the calculated and the experimental eigenvalue result. The differences in the eigenvalues obtained using the ENDF/B-VII.0, ENDF/B-VII.1, and ENDF/B-VIII.0 nuclear data libraries cover a relatively small range of ~230 pcm. Since eigenvalue sensitivity of the MSRE is dominated by the neutron multiplicity and neutron capture of 235 U and elastic scattering in graphite, relevant changes in the ENDF/B libraries for nuclear reactions (such as carbon capture) that caused large differences in other graphite-moderated systems did not have a significant impact. Propagation of nuclear data uncertainty results in an eigenvalue uncertainty of ~700 pcm with the major contributors being 235 U neutron multiplicity, graphite elastic scattering, and 7Li neutron capture. All calculations resulted in large differences of ~2000 pcm in eigenvalue compared to the benchmark experimental value. Several potential contributors to this difference—including uncertainties and gaps in the knowledge of the material, geometry, and nuclear data—were identified. Simplified models of the full MSRE core were developed, and similarity assessments were conduced with the full MSRE core model. It was found that simplified models can serve as adequate surrogates of the full-core model such that they can be used for performing selected nuclear data performance assessments with a lower computational burden.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Ratioed scatter diagrams - An erotetic method for phase identification on complex surfaces using scanning Auger microscopy

By ratioing multiple Auger intensities and plotting a two-dimensional occupational scatter diagram while digitally scanning across an area, the number and elemental association of surface phases can be determined. This can prove a useful tool in scanning Auger microscopic analysis of complex materials. The technique is illustrated by results from an anomalous region on the reaction zone of a SiC/Ti-6Al-4V metal matrix composite material. The anomalous region is shown to be a single phase associated with sulphur and phosphorus impurities. Imaging of a selected phase from the ratioed scatter diagram is possible and may be a useful technique for presenting multiple scanning Auger images.

Browning, R.↗

Interferometric Rayleigh Scattering Measurement System

A method and apparatus for performing simultaneous multi-point measurements of multiple velocity components in a gas flow is described. Pulses of laser light are directed to a measurement region of unseeded gas to produce Rayleigh or Mie scattered light in a plurality of directions. The Rayleigh or Mie scattered light is collected from multiple directions and combined in a single collimated light beam. The Rayleigh or Mie scattered light is then mixed together with a reference laser light before it is passed through a single planar Fabry-Perot interferometer for spectral analysis. At the output of the interferometer, a high-sensitivity CCD camera images the interference fringe pattern. This pattern contains the spectral and spatial information from both the Rayleigh scattered light and the reference laser light. Interferogram processing software extracts and analyzes spectral profiles to determine the velocity components of the gas flow at multiple points in the measurement region. The Rayleigh light rejected by the interferometer is recirculated to increase the accuracy and the applicability of the method for measurements at high temperatures without requiring an increase in the laser energy.

Bivolaru, Daniel↗

Super-resonant four-photon collinear laser frequency multiplication in plasma

Resonant four-photon scattering could nearly double frequencies of intense laser pulses in plasma. However, transverse slippage between pulses presents a technological challenge, while collinear four-photon scattering is forbidden for classical light dispersion in plasma. Nonlinear renormalization of intense laser pulses can enable collinear four-photon resonance. However, such a very intensity-sensitive resonance is difficult to maintain for evolving pulses. Remarkably, there is a lower-dimensionality submanifold of the resonant four-photon manifold where the evolving pulses stay in resonance. Furthermore this could enable an all-optical frequency doubling of mildly relativistic-intense laser pulses in collinear geometry, advantageously free of the transverse slippage challenges.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Current-enabled optical conductivity of superconductors

In most superconductors, optical excitations require impurity scattering or the presence of multiple bands. This is because in clean single-band superconductors, the combination of particle-hole and inversion symmetries prevents momentum-conserving transitions. In this Letter we show how the flow of supercurrent can lead to new contributions to optical conductivity. As the supercurrent breaks inversion symmetry, transitions across the superconducting gap become allowed even in clean superconductors and dominate over impurity-induced contributions for energies comparable to the gap width. Further, the response is dependent on the nature of the underlying normal state as well as on the type of superconducting order. Use of an external magnetic field to produce a screening supercurrent with controllable magnitude and direction, enables a detailed investigation of the superconducting state, allowing determination of the gap symmetry in unconventional superconductors for which other techniques have not been practicable.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Transversely Polarized Solid Target for Hall B at Jefferson Lab

The physics program for Hall B at Jefferson Lab includes multiple, high-impact experiments scattering electrons from transversely polarized protons. These experiments will measure, for example, the Transverse Momentum Distributions and the Generalized Parton Distribution for protons, using, respectively, semi-inclusive deep inelastic scattering and deeply virtual Compton scattering. In this talk I will discuss the technical challenges to implementing a polarized solid-state target in the Hall B experimental environment, examine potential solutions, and describe the current status of the target design.

Keith, Christopher↗

Coherent Anti-stokes Raman Spectroscopy (CARS) of gun propellant flames

Temperature measurements were made in a slightly fuel rich, premixed propane/air reference flame and nitrate ester propellant flames burning in air at atmospheric pressure using coherent anti-stokes raman scattering (CARS). Both single and multiple pulse VARS spectra of nitrogen in the reference flame were in good agreement with calculated and reported values. Single pulse CARS nitrogen spectra obtained in the propellant flames were analyzed to give temperatures consistent with values calculated using the NASA-Lewis thermochemical calculation. Comparison of a 0.1 second separated sequence of single pulse CARS spectra indicate turbulent air mixing in these propellant flames. The CARS spectral results demonstrate that temporal and spatially resolved temperature measurements could be determined in transient, turbulent flames.

Mcilwain, M. E.↗

Backscattering cascade of beam modes off ambient density fluctuations

The effects of a given nonthermal low-frequency density-fluctuation spectrum on the amplification of Langmuir waves by a 'bump-on-tail' beam of electrons are studied. The density-fluctuation spectrum is assumed to contain a uniform distribution of wavelengths ranging from much shorter than the beam mode wavelength to of the same order. This permits multiple large-angle (back) scattering to occur. One-dimensional numerical solutions of the kinetic equations are found which yield criteria for linear saturation of the beam instability of a cascade of backscattering to high wavenumber. The relevant time scales and spectral shapes are also determined in both the stable and unstable regions. Linear damping and Cerenkov emission by a possible nonthermal tail of electrons is taken into account. An application is made to the beam modes observed simultaneously with density fluctuations off the Jovian bow shock. It is shown that the observed level of density fluctuations is sufficient to saturate the unstable Langmuir waves, although nonthermal Landau damping may prevent a cascade to very high wavenumbers.

Russell, D. A.↗

A radar study of Comet IRAS-Araki-Alcock 1983d

Radar echoes from Comet IRAS-Araki-Alcock at wavelengths 3.54 and 12.9 cm indicate that the comet's nucleus is very rough on a scale larger than the radar wavelengths; however, the low polarization ratio (25 percent at 3.54 cm) indicates that the scattering is not dominated by multiple reflections, internal reflections, or large abundances of sharp edges, cracks, and pits. The shape of the nucleus probably departs greatly from a sphere with average radii near 3-4 km. The nucleus does not appear to look significantly different from a number of Apollo and Amor asteroids except that: (1) there is a suggestion that minor structure moves rapidly across the spectra, and (2) the debris not gravitationally bound to the comet was detected, and contributes 25 percent of the total radar cross section at the 12.9-cm wavelength. Other considerations suggest that the pole was at least 45 deg away from the line of sight on two days of observation, and that the rotation period is approximately 1-2 days.

Goldstein, R. M.↗

Development of deterministic transport methods for low energy neutrons for shielding in space

Transport of low energy neutrons associated with the galactic cosmic ray cascade is analyzed in this dissertation. A benchmark quality analytical algorithm is demonstrated for use with BRYNTRN, a computer program written by the High Energy Physics Division of NASA Langley Research Center, which is used to design and analyze shielding against the radiation created by the cascade. BRYNTRN uses numerical methods to solve the integral transport equations for baryons with the straight-ahead approximation, and numerical and empirical methods to generate the interaction probabilities. The straight-ahead approximation is adequate for charged particles, but not for neutrons. As NASA Langley improves BRYNTRN to include low energy neutrons, a benchmark quality solution is needed for comparison. The neutron transport algorithm demonstrated in this dissertation uses the closed-form Green's function solution to the galactic cosmic ray cascade transport equations to generate a source of neutrons. A basis function expansion for finite heterogeneous and semi-infinite homogeneous slabs with multiple energy groups and isotropic scattering is used to generate neutron fluxes resulting from the cascade. This method, called the FN method, is used to solve the neutral particle linear Boltzmann transport equation. As a demonstration of the algorithm coded in the programs MGSLAB and MGSEMI, neutron and ion fluxes are shown for a beam of fluorine ions at 1000 MeV per nucleon incident on semi-infinite and finite aluminum slabs. Also, to demonstrate that the shielding effectiveness against the radiation from the galactic cosmic ray cascade is not directly proportional to shield thickness, a graph of transmitted total neutron scalar flux versus slab thickness is shown. A simple model based on the nuclear liquid drop assumption is used to generate cross sections for the galactic cosmic ray cascade. The ENDF/B V database is used to generate the total and scattering cross sections for neutrons in aluminum. As an external verification, the results from MGSLAB and MGSEMI were compared to ANISN/PC, a routinely used neutron transport code, showing excellent agreement. In an application to an aluminum shield, the FN method seems to generate reasonable results.

Ganapol, Barry↗

Particle Acceleration in Active Galactic Nuclei

The investigation of stochastic particle acceleration through resonant interactions with plasma waves that populate the magnetosphere surrounding an accreting black hole is presented. Stochastic acceleration has been successfully applied to the problem of ion and electron energization in solar flares, and is capable of accounting for a wide range of both neutral and charged particle emissions. It is also a component in diffusive shock acceleration, since pitch-angle scattering (which is necessary for multiple shock crossings) is accompanied by diffusion in momentum space, which in turn yields a net systematic energy gain; however, stochastic energization will dominate the first-order shock process only in certain parameter regimes. Although stochastic acceleration has been applied to particle energization in the lobes of radio galaxies, its application to the central regions of AGNs (active galactic nuclei) has only recently been considered, but not in detail. We proposed to systematically investigate the plasma processes responsible for stochastic particle acceleration in black hole magnetospheres along with the energy-loss processes which impede particle energization. To this end, we calculated acceleration rates and escape time scales for protons and electrons resonating with Alfven waves, and for electrons resonating with whistlers. We also considered the "hot" topic of gamma-ray line emission from the Orion complex. We proposed that the observed gamma-ray lines are produced by energetic ions that are stochastically accelerated by cascading Alfven waves in the accretion plasma near a black hole. Related research papers that were published in journals are listed.

Miller, James A.↗

Particle Acceleration in Active Galactic Nuclei

The high efficiency of energy generation inferred from radio observations of quasars and X-ray observations of Seyfert active galactic nuclei (AGNs) is apparently achieved only by the gravitational conversion of the rest mass energy of accreting matter onto supermassive black holes. Evidence for the acceleration of particles to high energies by a central engine is also inferred from observations of apparent superluminal motion in flat spectrum, core-dominated radio sources. This phenomenon is widely attributed to the ejection of relativistic bulk plasma from the nuclei of active galaxies, and accounts for the existence of large scale radio jets and lobes at large distances from the central regions of radio galaxies. Reports of radio jets and superluminal motion from galactic black hole candidate X-ray sources indicate that similar processes are operating in these sources. Observations of luminous, rapidly variable high-energy radiation from active galactic nuclei (AGNs) with the Compton Gamma Ray Observatory show directly that particles are accelerated to high energies in a compact environment. The mechanisms which transform the gravitational potential energy of the infalling matter into nonthermal particle energy in galactic black hole candidates and AGNs are not conclusively identified, although several have been proposed. These include direct acceleration by static electric fields (resulting from, for example, magnetic reconnection), shock acceleration, and energy extraction from the rotational energy of Kerr black holes. The dominant acceleration mechanism(s) operating in the black hole environment can only be determined, of course, by a comparison of model predictions with observations. The purpose of the work proposed for this grant was to investigate stochastic particle acceleration through resonant interactions with plasma waves that populate the magnetosphere surrounding an accreting black hole. Stochastic acceleration has been successfully applied to the problem of ion and electron energization in solar flares, and is capable of accounting for a wide range of both neutral and charged particle emissions. It is also a component in diffusive shock acceleration, since pitch-angle scattering (which is necessary for multiple shock crossings) is accompanied by diffusion in momentum space, which in turn yields a net systematic energy gain; however, stochastic energization will dominate the first-order shock process only in certain parameter regimes. Although stochastic acceleration has been applied to particle energization in the lobes of radio galaxies, its application to the central regions of AGNs has only recently been considered, but not in detail. We proposed to systematically investigate the plasma processes responsible for stochastic particle acceleration in black hole magnetospheres along with the energy-loss processes which impede particle energization. To this end we calculated acceleration rates and escape time scales for protons and electrons resonating with Alfven waves, and for electrons resonating with whistlers. Assuming either a Kolmogorov or Kraichnan wave spectrum, accretion at the Eddington limit, magnetic field strengths near equipartition, and turbulence energy densities approx. 10% of the total magnetic field energy density, we find that Alfven waves accelerate protons to Lorentz factors approx, equals 10(exp 4) - 10(exp 6) before they escape from the system. Acceleration of electrons by fast mode and whistler waves can produce a nonthermal population of relativistic electrons whose maximum energy is determined by a competition with radiation losses.

Miller, James A.↗