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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 955 records · Page 53
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Assessment of Uncertainty in the Determination of Activation Energy for Polymeric Materials

An assessment of the experimental uncertainty in obtaining the kinetic activation energy from thermogravimetric analysis (TGA) data is presented. A neat phenolic resin, Borden SC1O08, was heated at three heating rates to obtain weight loss vs temperature data. Activation energy was calculated by two methods: the traditional Flynn and Wall method based on the slope of log(q) versus 1/T, and a modification of this method where the ordinate and abscissa are reversed in the linear regression. The modified method produced a more accurate curve fit of the data, was more sensitive to data nonlinearity, and gave a value of activation energy 75 percent greater than the original method. An uncertainty analysis using the modified method yielded a 60 percent uncertainty in the average activation energy. Based on this result, the activation energy for a carbon-phenolic material was doubled and used to calculate the ablation rate In a typical solid rocket environment. Doubling the activation energy increased surface recession by 3 percent. Current TGA data reduction techniques that use the traditional Flynn and Wall approach to calculate activation energy should be changed to the modified method.

Darby, Stephania P.↗
NASA NTRS1999

Tidal Energy Available for Deep Ocean Mixing: Bounds from Altimetry Data

Maintenance of the large-scale thermohaline circulation has long presented a problem to oceanographers. Observed mixing rates in the pelagic ocean are an order of magnitude too small to balance the rate at which dense bottom water is created at high latitudes. Recent observational and theoretical work suggests that much of this mixing may occur in hot spots near areas of rough topography (e.g., mid-ocean ridges and island arcs). Barotropic tidal currents provide a very plausible source of energy to maintain these mixing processes. Topex/Poseidon (T/P) satellite altimetry data have made precise mapping of open ocean tidal elevations possible for the first time. We can thus obtain empirical, spatially localized, estimates of barotropic tidal dissipation. These provide an upper bound on the amount of tidal energy that is dissipated in the deep ocean, and hence is available for deep mixing. We will present and compare maps of open ocean tidal energy flux divergence, and estimates of tidal energy flux into shallow seas, derived from T/P altimetry data using both formal data assimilation methods and empirical approaches. With the data assimilation methods we can place formal error bars on the fluxes. Our results show that 20-25% of tidal energy dissipation occurs outside of the shallow seas, the traditional sink for tidal energy. This suggests that up to 1 TW of energy may be available from the tides (lunar and solar) for mixing the deep ocean. The dissipation indeed appears to be concentrated over areas of rough topography.

Egbert, Gary D.↗
NASA NTRS1999

Tidal Energy Available for Deep Ocean Mixing: Bounds from Altimetry Data

Maintenance of the large-scale thermohaline circulation has long presented an interesting problem. Observed mixing rates in the pelagic ocean are an order of magnitude too small to balance the rate at which dense bottom water is created at high latitudes. Recent observational and theoretical work suggests that much of this mixing may occur in hot spots near areas of rough topography (e.g., mid-ocean ridges and island arcs). Barotropic tidal currents provide a very plausible source of energy to maintain these mixing processes. Topex/Poseidon satellite altimetry data have made precise mapping of open ocean tidal elevations possible for the first time. We can thus obtain empirical, spatially localized, estimates of barotropic tidal dissipation. These provide an upper bound on the amount of tidal energy that is dissipated in the deep ocean, and hence is available for deep mixing. We will present and compare maps of open ocean tidal energy flux divergence, and estimates of tidal energy flux into shallow seas, derived from T/P altimetry data using both formal data assimilation methods and empirical approaches. With the data assimilation methods we can place formal error bars on the fluxes. Our results show that 20-25% of tidal energy dissipation occurs outside of the shallow seas, the traditional sink for tidal energy. This suggests that up to 1 TW of energy may be available from the tides (lunar and solar) for mixing the deep ocean. The dissipation indeed appears to be concentrated over areas of rough topography.

Ray, Richard D.↗
NASA NTRS1999

Tidal Energy Available for Deep Ocean Mixing: Bounds From Altimetry Data

Maintenance of the large-scale thermohaline circulation has long presented a problem to oceanographers. Observed mixing rates in the pelagic ocean are an order of magnitude too small to balance the rate at which dense bottom water is created at high latitudes. Recent observational and theoretical work suggests that much of this mixing may occur in hot spots near areas of rough topography (e.g., mid-ocean ridges and island arcs). Barotropic tidal currents provide a very plausible source of energy to maintain these mixing processes. Topex/Poseidon satellite altimetry data have made precise mapping of open ocean tidal elevations possible for the first time. We can thus obtain empirical, spatially localized, estimates of barotropic tidal dissipation. These provide an upper bound on the amount of tidal energy that is dissipated in the deep ocean, and hence is available for deep mixing. We will present and compare maps of open ocean tidal energy flux divergence, and estimates of tidal energy flux into shallow seas, derived from T/P altimetry data using both formal data assimilation methods and empirical approaches. With the data assimilation methods we can place formal error bars on the fluxes. Our results show that 20-25% of tidal energy dissipation occurs outside of the shallow seas, the traditional sink for tidal energy. This suggests that up to 1 TW of energy may be available from the tides (lunar and solar) for mixing the deep ocean. The dissipation indeed appears to be concentrated over areas of rough topography.

Egbert, Gary D.↗
NASA NTRS1997

Surface Energy Heat Fluxes Using Remotely Sensed Parameters

Realistic estimates of surface energy heat fluxes are needed for the study of water and energy interactions between the land and atmosphere. The primary objective of this work is to study the estimation of surface heat energy fluxes using remote sensing derived parameters under different spatial and temporal conditions. Surface energy fluxes and remote sensing derived data from two sources were analyzed. First, we used surface heat flux, remote sensing, and ancillary data from the International Satellite Land Surface Climatology Project (ISLSCP), mapped at a 1 deg. x 1 deg. grid. Second, we used NOAA AVHRR (1 km), weather station, and ancillary data to derive estimates of surface latent and sensible heat energy fluxes over a 100 sq kilometers area for three test sites: 1) First ISLSCP Field Experiment (FIFE) grassland site, Konza Prairie, Kansas; 2) Howland, Maine Forest Ecosystem Dynamics Site; and 3) Walnut Gulch, scrubland site, surrounding Tombstone, Arizona. Satellite derived estimates of land surface temperature, surface albedo, and spectral vegetation index are used in selected models to provide estimates of surface heat fluxes. Analysis of results from the 1 deg. x 1 deg. grid for North America indicated there were similar, overall correlations between sensible and latent heat energy fluxes versus remotely sensed vegetation index and ground temperature during dry and wet year conditions. However, there were significant differences in correlations between years when stratified by land cover class. Analysis of 100 km x 100 km data (1 km resolution) indicated partitioning the areas in to primary versus secondary cover, with the secondary cover comprising less than 5% of the area, significantly improved surface heat energy flux estimates.

Toll, David L.↗
NASA NTRS2001

Potential Energy Curves and Transport Properties for the Interaction of He with Other Ground-state Atoms

The interactions of a He atom with a heavier atom are examined for 26 different elements, which are consecutive members selected from three rows (Li - Ne, Na - Ar, and K,Ca, Ga - Kr) and column 12 (Zn,Cd) of the periodic table. Interaction energies are determined wing high-quality ab initio calculations for the states of the molecule that would be formed from each pair of atoms in their ground states. Potential energies are tabulated for a broad range of Interatomic separation distances. The results show, for example, that the energy of an alkali interaction at small separations is nearly the same as that of a rare-gas interaction with the same electron configuration for the dosed shells. Furthermore, the repulsive-range parameter for this region is very short compared to its length for the repulsion dominated by the alkali-valence electron at large separations (beyond about 3-4 a(sub 0)). The potential energies in the region of the van der Waals minimum agree well with the most accurate results available. The ab initio energies are applied to calculate scattering cross sections and obtain the collision integrals that are needed to determine transport properties to second order. The theoretical values of Li-He total scattering cross sections and the rare-gas atom-He transport properties agree well (to within about 1%) with the corresponding measured data. Effective potential energies are constructed from the ab initio energies; the results have been shown to reproduce known transport data and can be readily applied to predict unknown transport properties for like-atom interactions.

Partridge, Harry↗
NASA NTRS2001

Energy Absorbing Protective Shroud

The present invention is a dissipating protection energy system designed to receive and safely dissipate the kinetic energy from high energy fragments. The energy dissipation system dissipates energy transferred to it by the incremental and progressive rupturing at an approximately constant force of strategically placed sacrificial stitching applied to a number of high strength straps, such as an aromatic polyimide fiber of extremely high tensile strength. Thus, the energy dissipation system provides a lightweight device for controlling and dissipating the dangerous and destructive energy stored in high strength fragments released by catastrophic failures of machinery minimizing damage to other critical components.

Schneider, William C.↗
NASA NTRS2002

A New Energy Source for Organic Synthesis in Europa's Surface Ice

Colored regions on Jupiter's satellite Europa and other icy bodies in the outer Solar System may be contaminated by organic macromolecular solid material that is produced when surface ices are exposed to electrical energy. Hypervelocity meteorite impacts and fracture release tidal and tectonic stresses in icy crusts in the form of electrical discharges, which provide the energy for in situ synthesis of the organic solids. We report measurements of electrical discharge, light emission, and magnetic phenomena in hypervelocity impacts into ice with projectiles with V approx. 5 km/s. Part of the projectile's kinetic energy is converted into electrical potential, while the mechanical disruption of the impact also releases stress energy as light, heat, electrical, and magnetic fields as secondary emissions. These newly recognized energy sources suggest that the dark material in the area of impact craters are tholins generated from the energy of the impacts and that well up from the fracture zone. Large pools of liquid water would persist under the meteorite crater for thousands of years, with the potential for prebiotic chemistry to take place at an accelerated rate due to energy pumped in from the secondary emissions.

Borucki, Jerome G.↗
NASA NTRS2002

Low-Energy Study of Gamma-Ray Bursts Using Two BATSE Spectroscopy Detectors

Gamma-ray bursts (GRBs) are energetic, short-duration emissions of gamma-rays from astronomical sources typically well beyond our galaxy. The Burst and Transient Source Experiment (BATSE) that was onboard NASA's Compton Gamma-Ray Observatory (CGRO) had detected an unprecedented 2704 GRBs during CGRO's nine-year mission. BATSE consisted of eight detector assemblies located at the corners of CGRO to give full sky coverage. Each assembly consisted of two detectors, a Large Area Detector (LAD) and a Spectroscopy Detector (SD). In determining the detail features of GRBs, the degree to which they possess a low-energy component (approx. 10 keV) is of interest. Preece have developed a method to study the low-energy characteristics and concluded that 14% of the 86 bright GRBs they studied had a definite low-energy component, referred to as a low-energy excess. Their study, and for the present study as well, needed to use SD data, because it extends down to the low-energy range when operating in a high-gain mode. For their study, low-energy data was used from just one SD. To better quantify the low-energy behavior, this study will consider bursts for which two SDs satisfy the same criteria as used by Preece.

Michael J. Pangia↗
NASA NTRS2002

Evidence for Temporally-Extended, High-Energy Emission from Gamma Ray Burst 990104

It is well known that high-energy emission (MeV - GeV) has been observed in several gamma ray bursts and temporally-extended emission from lower-energy gamma rays through radio wavelengths is well established. Observations of extended, high-energy emission are, however, scarce. Here we present evidence for a gamma ray burst emission that is both high-energy and extended, coincident with lower energy emissions. For the very bright and long burst, GRB 990104, we show light curves and spectra that confirm emission above 50 MeV, approximately 152 seconds after the BATSE (Burst and Transient Source Experiment) trigger and initial burst emission. Between the initial output and the main peak, seen at both low and high energy, there was a period of approx. 100 s during which the burst was relatively quiet. This burst was found as part of an ongoing search for high-energy emission in gamma ray bursts.

Wren, D. N.↗
NASA NTRS2003

Characterization of Downstream Ion Energy Distributions From a High Current Hollow Cathode in a Ring Cusp Discharge Chamber

The presence of energetic ions produced by a hollow cathodes operating at high emission currents (greater than 10 Angstroms) has been documented in the literature. As part of an ongoing effort to uncover the underlying physics of the formation of these ions, ion efflux from a high current hollow cathode operating in an ion thruster discharge chamber was investigated. Using a spherical sector electrostatic energy analyzer located downstream of the discharge cathode, the ion energy distribution over a 0 to 60 eV energy range was measured. The sensitivity of the ion energy distribution function to zenith angle was also assessed at 3 different positions: 0, 15, and 25 degrees. The measurements suggest that the majority of the ion current at the measuring point falls into the analyzer with an energy approximately equal to the discharge voltage. The ion distribution, however, was found to be quite broad. The high energy tail of the distribution function tended to grow with increasing discharge current. Sensitivity of the profiles to flow rate at fixed discharge current was also investigated. A simple model is presented that provides a potential mechanism for the production of ions with energies above the discharge voltage.

Foster, John E.↗
NASA NTRS2000

Atmospheric energy for subsurface life on Mars?

The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H(2) and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H(2) and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H(2)O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life.

NASA Center JPL↗
NASA NTRS2004

Characterizing the Energy Scale of the XRS on Astro-E2

The XRS on Astro-E2 consists of a microcalorimeter array with 31 active pixels. The XRS energy scale, which converts the measured pulse heights to the energies of the photons incident on the array, is a non-linear function of the thermal properties of the pixels and the power and noise conditions on the array. Each of the pixels operates independently and requires an individual energy scale. Analytic models of the XRS pulses are currently being developed that will be used to model the energy scale. However, because of the inherent complexity, a full empirical calibration of the energy scale is being conducted. The XRS energy scale has been calibrated for a range of operating conditions including variations in the detector temperature, bath temperatures, and photon flux. This allows us to characterize the functional dependence of the energy scale on these variables and to then generate a semi-empirical model that can be used to account for variations in operating conditions in space. We will present the results of the empirical characterization and comparisons to the analytic models.

Cottam, J.↗
NASA NTRS2005

Calculating the X-Ray Fluorescence from the Planet Mercury Due to High-Energy Electrons

The least-studied terrestrial planet is Mercury due to its proximity to the Sun, which makes telescopic observations and spacecraft encounters difficult. Our lack of knowledge about Mercury should change in the near future due to the recent launching of MESSENGER, a Mercury orbiter. Another mission (BepiColombo) is currently being planned. The x-ray spectrometer on MESSENGER (and planned for BepiColombo) can characterize the elemental composition of a planetary surface by measuring emitted fluorescent x-rays. If electrons are ejected from an atom s inner shell by interaction with energetic particles such as photons, electrons, or ions, electrons from an outer shell can transfer to the inner shell. Characteristic x-rays are then emitted with energies that are the difference between the binding energy of the ion in its excited state and that of the ion in its ground state. Because each element has a unique set of energy levels, each element emits x-rays at a unique set of energies. Electrons and ions usually do not have the needed flux at high energies to cause significant x-ray fluorescence on most planetary bodies. This is not the case for Mercury where high-energy particles were detected during the Mariner 10 flybys. Mercury has an intrinsic magnetic field that deflects the solar wind, resulting in a bow shock in the solar wind and a magnetospheric cavity. Electrons and ions accelerated in the magnetosphere tend to follow its magnetic field lines and can impact the surface on Mercury s dark side Modeling has been done to determine if x-ray fluorescence resulting from the impact of high-energy electrons accelerated in Mercury's magnetosphere can be detected by MESSENGER. Our goal is to understand how much bulk chemical information can be obtained from x-ray fluorescence measurements on the dark side of Mercury.

Burbine, T. H.↗
NASA NTRS2005

High-Resolution Electron Energy-Loss Spectroscopy (HREELS) Using a Monochromated TEM/STEM

A 200 keV FEI TF20 XT monochromated (scanning) transmission electron microscope funded by NASA's SRLIDAP program is undergoing installation at Lawrence Livermore National Laboratory. Instrument specifications in STEM mode are Cs =1.0 mm, Cc =1.2 mm, image resolution =0.18 nm, and in TEM mode Cs =1.3 mm, Cc =1.3 mm, information limit =0.14 nm. Key features of the instrument are a voltage-stabilized high tension (HT) supply, a monochromator, a high-resolution electron energy-loss spectrometer/energy filter, a high-resolution annular darkfield detector, and a solid-state x-ray energy-dispersive spectrometer. The high-tension tank contains additional sections for 60Hz and high frequency filtering, resulting in an operating voltage of 200 kV plus or minus 0.005V, a greater than 10-fold improvement over earlier systems. The monochromator is a single Wien filter design. The energy filter is a Gatan model 866 Tridiem-ERS high resolution GIF spec d for less than or equal to 0.15 eV energy resolution with 29 pA of current in a 2 nm diameter probe. 0.13 eV has already been achieved during early installation. The x-ray detector (EDAX/Genesis 4000) has a take-off angle of 20 degrees, an active area of 30 square millimeters, and a solid angle of 0.3 steradians. The higher solid angle is possible because the objective pole-piece allows the detector to be positioned as close as 9.47 mm from the specimen. The voltage-stabilized HT supply, monochromator and GIF enable high-resolution electron energy-loss spectroscopy (HREELS) with energy resolution comparable to synchrotron XANES, but with approximately 100X better spatial resolution. The region between 0 and 100 eV is called the low-loss or valence electron energy-loss spectroscopy (VEELS) region where features due to collective plasma oscillations and single electron transitions of valence electrons are observed. Most of the low-loss VEELS features we are detecting are being observed for the first time in IDPs. A major focus of our research is to understand the origin and significance of these features and how they might be exploited to gain insight about IDPs and other meteoritic materials.

Sai, Z. R.↗
NASA NTRS2005

Evolution of the Electron Yield Curves of Insulators as a Function of Impinging Electron Fluence and Energy

Electron emission and concomitant change accumulation near the surface of insulators in central to understanding spacecraft charging. We present a study of changes in electron emission yields as a result of internal charge build up due to electron dose. Evolution of total, backscattered and secondary yield results over a broad range of incident energies are presented for two representative insulators, Kapton(trademark) and Al2O3. Reliable yield curves for uncharged insulators are measured and quantifiable changes in yield are observed due to < 100 fC/sq mm fluences. We find excellent agreement with a phenomenological argument based on insulator charging predicted by the yield curve; this includes a decrease in the rate of change of the yield as incident energies approach the crossover energies and as accumulated internal charge reduces the landing energy to asymptotically approach a steady state surface charge and unity yield. We also find that the exponential decay of yield curves with fluence exhibit an energy dependent decay constant, alpha(E). Finally, we discuss physics based models for this energy dependence. To understand fluence and energy dependence of these charging processes requires knowledge of how charge is deposited within the insulator, the mechanisms for charge trapping and transport within the insulator, and how the profile of trapped charge affects the transport and emission of charges from insulators.

Sim, Alec↗
NASA NTRS2006

An Energy Balance Model to Predict Chemical Partitioning in a Photosynthetic Microbial Mat

Studies of biosignature formation in photosynthetic microbial mat communities offer potentially useful insights with regards to both solar and extrasolar astrobiology. Biosignature formation in such systems results from the chemical transformation of photosynthetically fixed carbon by accessory microorganisms. This fixed carbon represents a source not only of reducing power, but also energy, to these organisms, so that chemical and energy budgets should be coupled. We tested this hypothesis by applying an energy balance model to predict the fate of photosynthetic productivity under dark, anoxic conditions. Fermentation of photosynthetically fixed carbon is taken to be the only source of energy available to cyanobacteria in the absence of light and oxygen, and nitrogen fixation is the principal energy demand. The alternate fate for fixed carbon is to build cyanobacterial biomass with Redfield C:N ratio. The model predicts that, under completely nitrogen-limited conditions, growth is optimized when 78% of fixed carbon stores are directed into fermentative energy generation, with the remainder allocated to growth. These predictions were compared to measurements made on microbial mats that are known to be both nitrogen-limited and populated by actively nitrogen-fixing cyanobacteria. In these mats, under dark, anoxic conditions, 82% of fixed carbon stores were diverted into fermentation. The close agreement between these independent approaches suggests that energy balance models may provide a quantitative means of predicting chemical partitioning within such systems - an important step towards understanding how biological productivity is ultimately partitioned into biosignature compounds.

Hoehler, Tori M.↗
NASA NTRS2006

Energy Index For Aircraft Maneuvers

Method and system for analyzing, separately or in combination, kinetic energy and potential energy and/or their time derivatives, measured or estimated or computed, for an aircraft in approach phase or in takeoff phase, to determine if the aircraft is or will be put in an anomalous configuration in order to join a stable approach path or takeoff path. A 3 reference value of kinetic energy andor potential energy (or time derivatives thereof) is provided, and a comparison index .for the estimated energy and reference energy is computed and compared with a normal range of index values for a corresponding aircraft maneuver. If the computed energy index lies outside the normal index range, this phase of the aircraft is identified as anomalous, non-normal or potentially unstable.

Chidester, Thomas R.↗