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All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Escherichia coli Attenuation by Fe Electrocoagulation in Synthetic Bengal Groundwater: Effect of pH and Natural Organic Matter

Technologies addressing both arsenic and microbial contamination of Bengal groundwater are needed. Fe electrocoagulation (Fe-EC), a simple process relying on the dissolution of an Fe(0) anode to produce Fe(III) precipitates, has been shown to efficiently remove arsenic from groundwater at low cost. In this work, we investigated Escherichia coli (E. coli) attenuation by Fe-EC in synthetic Bengal groundwater as a function of Fe dosage rate, total Fe dosed, pH, and presence of natural organic matter (NOM). A 2.5 mM Fe dosage simultaneously achieved over 4-log E. coli attenuation and arsenic removal from 450 to below 10 μg/L. E. coli reduction was significantly enhanced at pH 6.6 compared to pH 7.5, which we linked to the decreased rate of Fe(II) oxidation at lower pH. 3 mg/L-C of NOM (Suwanee River fulvic acid) did not significantly affect E. coli attenuation. Live-dead staining and comparisons of Fe-EC with chemical coagulation controls showed that the primary mechanism of E. coli attenuation is physical removal with Fe(III) precipitates, with inactivation likely contributing as well at lower pH. Transmission electron microscopy showed that EC precipitates adhere to and bridge individual E. coli cells, resulting in large bacteria-Fe aggregates that can be removed by gravitational settling. Our results point to the promising ability of Fe-EC to treat arsenic and bacterial contamination simultaneously at low cost.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Mercury concentrations in urine of amerindian populations near oil fields in the peruvian and ecuadorian amazon

Background: Mercury is a global contaminant with toxic, persistent effects on human health. Petroleum extraction is an important source of elemental mercury; little is known about human exposure levels near oil fields in the Amazon basin. Objectives: To characterize mercury levels in people living near oil production sites in the Peruvian and Ecuadorian Amazon, controlling for fish consumption, occupation, source of water and socio-demographic characteristics. Methods: Analyze mercury levels in urine samples using cold vapour atomic fluorescence spectrometry from 76 indigenous men and women in eight riverine communities situated near oil wells or pipelines. Subjects answered a questionnaire soliciting socio-demographic, occupational and dietary information. Data were analyzed using multiple linear regression modeling. Results: The mean value of U-Hg was 2.61 μg/g creatinine (95% CI: 2.14–3.08), with 7% of the sample recording values above the global background standard suggested by The World Health Organization (5 μg/g creatinine). Women who used water from a surface source had two and a half times the amount of mercury in their urine (mean=3.70 μg/g creatinine, 95% CI: 2.26–5.15) compared with women who used other water sources (mean =1.39 μg/g creatinine, 95% CI: 0.51–2.25). Men who were involved in an oil clean-up operation had twice as much mercury in their urine (mean =3.07 μg/g creatinine, 95% CI: 1.97–4.16) as did those who worked on other tasks (mean =1.56 μg/g creatinine, 95% CI: 1.48–2.65). Mercury levels were not associated with the number of fish meals per week. Conclusions: Indigenous peoples of the Peruvian and Ecuadorian Amazon living near oil production sites generally had urine mercury levels within the global background standard suggested by the World Health Organization. Increased levels of mercury in urine were detected for men involved in oil spill remediation and for women who relied on surface water for household needs. These findings signal the need for strict safety measures to limit the amount of oil entering the waterways in Andean Amazonia so as to protect the health of indigenous people. - Highlights: • 7% of participants had levels of inorganic mercury at or exceeding levels suggested by WHO (5 μg/g creatinine). • U-Hg levels were 2.5 times higher among women using surface water than those who drew on water from a well, spring or rain. • Men who had worked cleaning up an oil spill had more than twice the amount of mercury in their urine as men who did not.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Behaviour of tritium in the vacuum vessel of JT-60U

The disassembly of the JT-60U torus started in 2010 after 18 years of deuterium plasma operations. The vessel is made of Inconel 625. Therefore, it was very important to study the hydrogen isotope (particularly tritium) behavior in Inconel 625 from the viewpoint of the clearance procedure. Inconel 625 specimen was exposed to the D{sub 2} (92.8 %) - T{sub 2} (7.2 %) gas mixture at 573 K for 5 hours. The tritium release from the specimen at 298 K was controlled for about 1 year. After that a part of tritium remaining in the specimen was released by heating up to 1073 K. Other part of tritium trapped in the specimen was measured by chemical etching method. Most of the chemical form of the released tritium was HTO. The contaminated specimen by tritium was released continuously the diffusible tritium under the ambient condition. In the tritium release experiment, the amount of desorbed tritium was about 99% during 1 year. It was considered that the tritium in Inconel 625 was released easily.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Facility Improvements and Modifications to Extend the Operational Life of the Modular Caustic-Side Solvent Extraction Process - 16082

Savannah River Remediation, LLC (SRR) is working to remove, stabilize, and dispose of approximately 36.7 million gallons (138.9 million liters) of liquid radioactive waste currently stored in 43 underground waste tanks, and ultimately close waste tanks. In 2008, as an interim salt treatment system to remove cesium from high level waste salt solutions prior to the Salt Waste Processing Facility start up, the Modular Caustic-Side Solvent Extraction Unit (MCU) initiated the removal of cesium from liquid radioactive salt waste prior to disposal. The MCU was designed and built for an expected three-year operational life and five-year design life. The first MCU cold runs began in June 2007 and hot startup was completed in April 2008. MCU remains in hot operation to this day, aiding in multiple, high-level tank closures. In an effort to continue liquid waste disposition at the Savannah River Site (SRS), equipment upgrades and operational improvements have been made to extend the life of the MCU beyond the original three years. Several pieces of fixed equipment have been converted into removable equipment which reduces the downtime associated with equipment change-outs and thereby reduces the dose to workers and processing impacts. Multiple pumps and filters have been upgraded to more robust designs. Process monitoring and controls have been upgraded to improve process performance. Redundant centrifugal contactor vibration equipment has been installed on each contactor in order to better assess the reliability, processing performance, and lifetime of the contactors. A new Solvent Hold Tank (SHT) Sampler has been installed to minimize the organic cross-contamination within the sampler, dose to workers, and sample analysis time. To increase processing availability and aid in visually obtained data, camera port has been added to the Salt Solution Feed Tank (SSFT). In order to decrease the overall background dose to the workers, the Process Vessel Ventilation (PVV) duct work now has the capability to be flushed to remove contamination. The caustic wash addition system has been modified to be a once-through system to improve equipment reliability, decrease downtime, and decrease dose to workers. In addition, the solvent that MCU utilizes to extract Cesium out of salt waste has been upgraded to Next Generation Solvent (NGS) which is based on MaxCalix extractant instead of a BobCalix extractant. Further, these upgrades and improvements have allowed MCU to be able to process at higher flow rates (up to 8.5 GPM) and with increased throughput (as high as 1.3 million gallons in FY13 and 5.3 million gallons since hot operations initiated) that have allowed SRR to continue the disposition of nuclear salt waste. The continued operation of MCU ensures more curies are stabilized into a glass matrix at SRS's Defense Waste Processing Facility (DWPF) and less curies are retained within South Carolina at SRS's Saltstone Disposal Facility (SDF). Unique challenges associated with modifying and improving a demonstration plant that is in hot operations and was designed to be temporary with a limited plant footprint have been successfully overcome. Further, creative strategies for removing old equipment have been utilized given the limited decontamination agents available for use that will not interfere with the organic solvent. This paper presents and discusses the deployment of these upgrades and operational improvements to MCU in order to allow continued, increased salt waste processing beyond the initial design life. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2013

2011 Mound Site Groundwater Plume Rebound Exercise and Follow-Up - 13440

The Mound Site facility near Miamisburg, Ohio, opened in 1948 to support early atomic weapons programs. It grew into a research, development, and production facility performing work in support of the U.S. Department of Energy (DOE) weapons and energy programs. The plant was in operation until 1995. During the course of operation, an onsite landfill was created. The landfill was located over a finger of a buried valley aquifer, which is a sole drinking water source for much of the Miami Valley. In the 1980's, volatile organic compounds (VOCs) were discovered in groundwater at the Mound site. The site was placed on the National Priorities List on November 21, 1989. DOE signed a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Federal Facility Agreement with the U.S. Environmental Protection Agency (EPA) and the Ohio Environmental Protection Agency. The agreement became effective in October 1990. The area that included the landfill was designated Operational Unit 1 (OU-1). In 1995, a Record of Decision was signed that called for the installation and operation of a pump and treatment (P and T) system in order to prevent the VOCs in OU-1 groundwater from being captured by the onsite water production wells. In addition to the P and T system, a soil vapor extraction (SVE) system was installed in 1997 to accelerate removal of VOCs from groundwater in the OU-1 area. The SVE system was successful in removing large amounts of VOCs and continued to operate until 2007, when the amount of VOCs removed became minimal. A rebound study was started in February 2003 to determine how the groundwater system and contaminants would respond to shutting down the P and T system. The rebound test was stopped in February 2004 because predetermined VOC threshold concentrations were exceeded down-gradient of the landfill. The P and T and SVE systems were restarted after the termination of the rebound test. In 2006, the remediation of the Mound site was completed and the site was declared to be protective of human health and the environment, as long as the institutional controls are observed. The institutional controls that apply to the OU-1 area include provisions that no soil be allowed to leave the site, no wells be installed for drinking water, and the site may be approved only for industrial use. The onsite landfill with the operating CERCLA remedy remained. However, the Mound Development Corporation lobbied Congress for funds to remediate the remaining onsite landfill to allow for property reuse. In 2007 DOE received funding from Congress to perform non-CERCLA removal actions at OU-1 to excavate the site sanitary landfill. In 2009, DOE received American Recovery and Reinvestment Act funding to complete the project. Excavation of the landfill occurred intermittently from 2006 through 2010 and the majority of the VOC source was removed; however, VOC levels near the P and T system remained greater than the EPA maximum contaminant levels (MCLs). Presently, groundwater is contained using two extraction wells to create a hydraulic barrier to prevent down-gradient migration of VOC-impacted groundwater. Since the primary contamination source has been removed, the feasibility of moving away from containment to a more passive remedy, namely monitored natural attenuation (MNA), is being considered. A second rebound study was started in June 2011. If contaminant and groundwater behavior met specific conditions during the study, MNA would be evaluated and considered as a viable alternative for the groundwater in the OU-1 area. From June through December 2011, the second rebound study evaluated the changes in VOC concentrations in groundwater when the P and T system was not in operation. As the study progressed, elevated concentrations of VOCs that exceeded predetermined trigger values were measured along the down-gradient boundary of the study area, and so the P and T system was restarted. It was determined that a discrete area with VOC concentrations greater than the MCLs was present in groundwater down-gradient of the extraction wells. The source was not identified, but the contamination was thought not to be caused by residually contaminated soil beneath the former landfill. The data collected so far supports the consideration of MNA as a viable alternative to hydraulic containment. Additional investigations are being performed to identify possible sources or pathways of VOCs in groundwater that may be contributing to the elevated VOC levels measured down-gradient of the extraction well system. Data from this additional investigation will be used to determine whether the VOCs detected down-gradient of the hydraulic boundary are the result of residual soil contamination, a previously unknown contribution of VOC-contaminated water entering the groundwater outside the capture zone of the extraction wells, or a pulse of VOC-contaminated groundwater from the OU-1 landfill that occurred during the rebound study. (authors)

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2012

Impacts of Environmental Nanoparticles on Chemical, Biological and Hydrological Processes in Terrestrial Ecosystems

This chapter provides insights on nanoparticle (NP) influence or control on the extent and timescales of single or coupled physical, chemical, biological and hydrological reactions and processes that occur in terrestrial ecosystems. Examples taken from the literature that show how terrestrial NPs may determine the fate of the aqueous and sorbed (adsorbed or precipitated) chemical species of nutrients and contaminants, are also included in this chapter. Specifically, in the first section, chapter objectives, term definitions and discussions on size-dependent properties, the origin and occurrence of NP in terrestrial ecosystems and NP toxicity, are included. In the second section, the topic of the binary interactions of NPs of different sizes, shapes, concentrations and ages with the soil solution chemical species is covered, focusing on NP formation, stability, aggregation, ability to serve as sorbents, or surface-mediated precipitation catalysts, or electron donors and acceptors. In the third section, aspects of the interactions in the ternary systems composed of environmental NP, nutrient/contaminant chemical species, and the soil/sediment matrix are discussed, focusing on the inhibitory and catalytic effects of environmental NP on nutrient/contaminant advective mobility and mass transfer, adsorption and desorption, dissolution and precipitation and redox reactions that occur in terrestrial ecosystems. These three review sections are followed by a short summary of future research needs and directions, the acknowledgements, the list of the references, and the figures.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

The SRNL technical assistance program: transferring lessons learned from two decades of remedial successes to the DOE complex - 15438

The Savannah River Site has an established history of developing implementable risk reduction strategies, developing and deploying innovative technological solutions, and collaboratively achieving realistic and protective environmental end states for complex environmental problems. Part of this success results from the strong historical collaboration between site environmental restoration groups and the Savannah River National Laboratory which results in the promulgation of innovative technical approaches and technologies from the laboratory to ongoing remediation campaigns. Much of the underlying research and development effort was funded by DOE's Office on Environmental Management through a series of applied technology demonstration projects (Integrated Demonstration Project, Integrated Programs and the Applied Field Research Site). Concomitant with the research efforts, SRNL has managed a dynamic and efficient national program that provides teams of technical experts with a broad experience base to recommend strategies that reduce risk and/or technical uncertainty for challenging environmental problems at other DOE facilities. At many of these sites, standard remedial approaches (e.g., excavation, pump and treat, soil vapor extraction) have either failed or proved to be too costly, inadequate, or ineffective. Alternatively, other sites struggle with implementation of innovative but less well understood approaches. The technical assistance teams use a structured process that based on several basic concepts, specifically, development of site specific technical frameworks, and careful matching of remedies to site-specific chemical, geological and physical conditions. Development of technical frameworks is a key strategy to apply basic science to an applied field problem. When directed toward understanding complex real-world environmental remediation challenges, frameworks are tools that support practical identification and incorporation of the key-controlling scientific processes and principles. Frameworks can also be used to minimize technical risks, encourage efficiency and effectiveness, and provide the basis for innovative and creative solutions. Efficient and effective environmental cleanup also requires matching the character of remediation and stabilization methods to the nature of the target zone of contamination as the nature of the target zone evolves through the life of the remedial project. A contaminant plume can be divided into the following zones: the source zone, the impact zone, and the transitional zone that then can be used to identify classes of technologies that are appropriate to that zone. For example, physical and chemical methods (e.g., trapping, immobilization, destruction, or isolation) that directly address the source contaminants are often appropriate for the disturbed zone during the remedial process. A variety of methods that include both active treatments (e.g., pump and treat or active bioremediation) and enhanced attenuation technologies (e.g., geochemical manipulation or reactive barriers) are often suitable for the primary contamination zone or impact zone. Various strategies based on natural attenuation processes may be applicable to the primary contamination zone and these methods are typically applied for the transition or baseline portions of the plume. Careful matching of remedies to site-specific conditions is critical to long-term success in environmental cleanup and restoration. The matching process facilitates selection of technologies with particular strengths that align with real-world needs and constraints, encourages strategic use of multiple or combined technologies to address major plume sub-domains, and supports transitioning technologies in space and time as remediation progresses. Since 2006, the SRNL Technical Assistance program has focused on providing support across the DOE complex. During this time, over 25 teams have visited eleven DOE sites and made recommendations that yielded an estimated cost savings of $100 M. Examples will be provided that illustrate key aspects and significant successes of the technical assistance program. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Hydraulic Testing of the Lost Lake Aquifer Near Recovery Well RWM 8

Groundwater beneath the M-Area HWMF is contaminated with chlorinated ethenes including trichloroethylene (TCE) and tetrachloroethylene (PCE). SRS operates a network of recovery wells designed to hydraulically contain and capture the high concentration VOC plume in the Lost Lake Aquifer Zone (LLAZ) (Figure 1). The recovery wells are connected to the M-1 Air Stripper and the system is permitted by the South Carolina Department of Environmental Control (SCDHEC) to operate at a total flow of 610 gpm. RWM 8, which is one of ten operational recovery wells, has historically operated at a flow rate of approximately 40 gpm. RWM 8 was installed with four separate 10-ft screens that spanned the LLAZ with a continuous gravel pack spaced as shown in Figure 2. The three uppermost screens are located within the LLAZ whereas the deepest screen is located within the middle sand of the Crouch Branch Confining Unit (CBCU). Area Closure Projects (ACP) installed a permanent packer in May 2019 to isolate the lowest screen from the pump with the goal being to target the zone of highest concentration in the LLAZ. ACP expressed concern that a substantial portion of the flow from RWM 8 comes from the lower screen. With this screen isolated from service, flow from the well may be below the desired operational envelope for the well. The reconfiguration of RWM 8 presented an opportunity to re-evaluate the performance characteristics of the well. Following placement of the packer and relocation of the pump, the well was redeveloped. To assess the effects of eliminating the lower screen, a step-drawdown test was planned. The purpose of this test was to establish new baseline well performance properties including specific capacity, well efficiency, and well loss coefficients. Data from the step-drawdown testing was also used to estimate a maximum pumping rate for RWM 8 under the new configuration. The setup for the step-drawdown test facilitated a subsequent constant rate aquifer pumping test aimed at determining aquifer hydraulic properties. Properties estimated for the LLAZ included transmissivity and storativity. Following shutdown of RWM 8, recovery data were also collected and analyzed to estimate aquifer properties. This report discusses the hydrologic tests conducted following the reconfiguration of RWM 8. The information provided in this report may serve as input to subsequent updates to the groundwater flow and contaminant transport model for A/M Area.

42 ENGINEERING↗
DOE OSTI2015

TECHNIQUES FOR HIGH-CONTRAST IMAGING IN MULTI-STAR SYSTEMS. I. SUPER-NYQUIST WAVEFRONT CONTROL

Direct imaging of extra-solar planets is now a reality with the deployment and commissioning of the first generation of specialized ground-based instruments (GPI, SPHERE, P1640, and SCExAO). These systems allow of planets 10{sup 7} times fainter than their host star. For space-based missions (EXCEDE, EXO-C, EXO-S, WFIRST), various teams have demonstrated laboratory contrasts reaching 10{sup −10} within a few diffraction limits from the star. However, all of these current and future systems are designed to detect faint planets around a single host star, while most non-M-dwarf stars such as Alpha Centauri belong to multi-star systems. Direct imaging around binaries/multiple systems at a level of contrast allowing detection of Earth-like planets is challenging because the region of interest is contaminated by the host star's companion in addition to the host itself. Generally, the light leakage is caused by both diffraction and aberrations in the system. Moreover, the region of interest usually falls outside the correcting zone of the deformable mirror (DM) with respect to the companion. Until now, it has been thought that removing the light of a companion star is too challenging, leading to the exclusion of many binary systems from target lists of direct imaging coronographic missions. In this paper, we will show new techniques for high-contrast imaging of planets around multi-star systems and detail the Super-Nyquist Wavefront Control (SNWC) method, which allows wavefront errors to be controlled beyond the nominal control region of the DM. Our simulations have demonstrated that, with SNWC, raw contrasts of at least 5 × 10{sup −9} in a 10% bandwidth are possible.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2011

Poly(dimethylsiloxane) microchip-based immunoassay with multiple reaction zones: Toward on-chip multiplex detection platform

In this work, a poly(dimethylsiloxane) (PDMS) microchip-based immuno-sensing platform with integrated pneumatic micro valves is described. The microchip was fabricated with multiple layer soft lithography technology. By controlling the activation status of corresponding valves, reagent flows in the microchannel network can be well manipulated so that immuno-reactions only take place at designated reaction zones (DRZs). Four DRZs are included in the prototype microchip. Since these DRZs are all isolated from each other by micro valves, cross contamination is prevented. Using the inner surface of the all-PDMS microchannel as immunoassay substrate, on-chip sandwich format solid phase immunoassay was performed to demonstrate the feasibility of this immuno-sensing platform. Mouse IgG and fluorescein isothiocyanate (FITC) were used as the model analyte and the signal reporter respectively. Only 10 ul sample is needed for the assay and low detection limit of 5 ng/ml (≈33 pM) was achieved though low-cost polyclonal antibodies were used in our experiment for feasibility study only. The encouraging results from mouse IgG immunoassay proved the feasibility of our microchip design. With slight modification of the assay protocol, the same chip design can be used for multi-target detection and can provide a simple, cost-effective and integrated microchip solution for multiplex immunoassay applications.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2024

Density of molten oxides measured in an aero-acoustic levitator

Knowing the thermophysical properties of high-temperature melts can aid the design of melt processes and validate atomic structural models, such as those used in studying glass formation. Property measurements on such melts are challenging, however, due to container-related contamination and heterogeneous nucleation. Containerless processing techniques that employ levitation can be used to avoid these obstacles. In that context, we demonstrate here the application of silhouette imaging to measure the density of molten oxides in an aero-acoustic levitation instrument (AAL). The AAL combines gas jet levitation with actively controlled acoustic positioning to enable full optical access to samples ca. 2–4 mm in diameter, which are laser beam heated and melted. The cross sections of molten drops are imaged using a monochromatic light source and narrowband-filtered camera. Melt volume is calculated from the cross sections and used to find density at several temperatures ranging 1530–1920 K, including up to 350 K of supercooling. We report densities for CaAl 2 O 4 , Ca 12 Al 14 O 33 , CaSiO 3 , their Fe 2 O 3 -bearing analogs, and 83TiO 2 -17RE 2 O 3 (RE = La or Nd). These provide important benchmarks of the capabilities, measurement uncertainties, and future outlook for this technique.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Cloud-Enabled Microscopy and Droplet Microfluidic Platform for Specific Detection of Escherichia coli in Water

We report an all-in-one platform – ScanDrop – for the rapid and specific capture, detection, and identification of bacteria in drinking water. The ScanDrop platform integrates droplet microfluidics, a portable imaging system, and cloud-based control software and data storage. The cloud-based control software and data storage enables robotic image acquisition, remote image processing, and rapid data sharing. These features form a “cloud” network for water quality monitoring. We have demonstrated the capability of ScanDrop to perform water quality monitoring via the detection of an indicator coliform bacterium, Escherichia coli, in drinking water contaminated with feces. Magnetic beads conjugated with antibodies to E. coli antigen were used to selectively capture and isolate specific bacteria from water samples. The bead-captured bacteria were co-encapsulated in pico-liter droplets with fluorescently-labeled anti-E. coli antibodies, and imaged with an automated custom designed fluorescence microscope. The entire water quality diagnostic process required 8 hours from sample collection to online-accessible results compared with 2–4 days for other currently available standard detection methods.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Model Package Report: Geoframework Model of the Hanford Site 100 Area

The purpose of the 100 Area Geoframework Model (GFM) is to provide a reasonable, consistent, and defensible three dimensional representation of the hydrostratigraphic units below the River Corridor at the Hanford Site to support contaminant fate and transport models. The GFM is a three dimensional representation of the subsurface geologic structure. From this, three dimensional geologic model-exported results, in the form of points or surfaces, are used as inputs to populate and assemble the various numerical model architectures. The objective of this report is to define the process used to produce a hydrostratigraphic model for the hydrostratigraphic units beneath the Hanford Site 100 Area. The GFM may support several other CH2M HILL Plateau Remediation Company project needs and objectives, including providing geologic information to support remedial investigations and actions and as a tool to present River Corridor geology and contaminant extents. The GFM was constructed based on information through 2019 available in the Integrated Data Management System, Hanford Environmental Information System, and the Hanford Site geologic contacts (GeoContacts) datasets. Revisions to the 100 Area GFM may occur to incorporate new data and information. Each version will be maintained in configuration control using date stamps for identifying supporting databases, figures, and interpretations. Supporting data include the final three dimensional geoframework surfaces, two dimensional structure and isopach maps, and all the geologic contact inputs and interpreted geologic log data. These final products provide a supporting set of geologic information that together allow the creation of the GFM. This information is managed, updated, and maintained via CH2M HILL Plateau Remediation Company under the Environmental Model Management Archive.

58 GEOSCIENCES↗
DOE OSTI2023

Using Geophysical Information to Investigate Subsurface Structure within the High-Hydraulic Conductivity Analysis Zone

Within the 200 East Area of the Central Plateau and southeastward toward the Columbia River, a high-hydraulic conductivity zone (HCZ) has been interpreted to extend through the 200-PO-1 and 200-BP-5 operable units on the Hanford Site. The HCZ is a controlling hydraulic feature that impacts groundwater flow out of the 200 East Area and the fate of eastwardly migrating plumes from the 200 West Area. The lateral extent of the HCZ is highly uncertain, and despite strong evidence for the existence of the HCZ based on water-level data and contaminant plume tracking, there is still a limited understanding of how to define its boundaries. To provide additional information on the nature and extent of the HCZ, three surface geophysical methods – electrical resistivity tomography (ERT), time-domain electromagnetics (TEM), and seismic methods – were used to collect data south of 200 East. In addition, existing data from 200 East, consisting of surface seismic data, a borehole check shot survey in 699-37-47A, and borehole stratigraphic interpretations, were used to aid interpretations of newly collected seismic data south of 200 East. This work presumed that the contrast in subsurface geophysical properties would be a first-order aid identifying a transmissive zone(s) within the HCZ analysis area by imaging contrasts and/or anomalies in geophysical properties. While seismic, ERT, and TEM methods have sensitivity to overlapping physical properties (porosity, moisture content, lithology), the resolution and physics used to acquire each of these datasets are different, and therefore the information can also be different. Figure S.1 shows the locations of the geophysical data considered in this report.

58 GEOSCIENCES↗
DOE OSTI2024

Soil Gas Survey Results Supporting Groundwater Correction Action Plan (GCAP) Development for the Moab Site

A soil gas survey was performed at the Moab Uranium Mill Tailings Remedial Action (UMTRA) Project Site during the week of November 6, 2023. Soil gas surveys are used to characterize residual subsurface sources of volatile contaminants, such as volatile organic compounds, as well as contaminants that generate a surrogate indicator gas or otherwise influence soil gas composition. The primary objective of the Moab soil gas survey was to confirm, identify, quantify, and refine secondary contaminant source area locations for uranium and ammonium/ammonia (NH 4 + /NH 3 ) in the vadose zone and shallow groundwater. The overarching goal was to provide information to assist in developing the technical basis for the Groundwater Compliance Action Plan (GCAP). Specifically, the soil gas data will support the deployment of source control technologies; e.g., where supplementary capping, removal actions, or amendments might be beneficial.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Soil Gas Survey Results Supporting Groundwater Correction Action Plan (GCAP) Development for the Moab Site

A soil gas survey was performed at the Moab Uranium Mill Tailings Remedial Action (UMTRA) Project Site during the week of November 6, 2023. Soil gas surveys are used to characterize residual subsurface sources of volatile contaminants, such as volatile organic compounds, as well as contaminants that generate a surrogate indicator gas or otherwise influence soil gas composition. The primary objective of the Moab soil gas survey was to confirm, identify, quantify, and refine secondary contaminant source area locations for uranium and ammonium/ammonia (NH 4 + /NH 3 ) in the vadose zone and shallow groundwater. The overarching goal was to provide information to assist in developing the technical basis for the Groundwater Compliance Action Plan (GCAP). Specifically, the soil gas data will support the deployment of source control technologies; e.g., where supplementary capping, removal actions, or amendments might be beneficial.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

A review of the behavior of radioiodine in the subsurface at two DOE sites

The 129 I isotope has a half-life of nearly 16 million years, creating a potential risk to receptors when 129I is present in groundwater and effective remedies are needed to mitigate its potential risk in the environment. This paper not only provides an in-depth review of various processes and reactions that control the fate and transport of iodine, but also describes how this information can be used for in situ management of iodine. The majority of the iodine fate and transport studies have been conducted at the US Department of Energy (DOE) Hanford and Savannah River sites, where radioisotopes of iodine were inadvertently released into the environment during weapons production. Site-specific remediation technologies are currently being evaluated as part of the DOE cleanup mission. The sites are markedly different in terms of climate (arid vs. sub-tropical), major geochemical parameters (pH ~ 7.5 vs. 4) and mineralogy (carbonate vs. Fe/Al oxide dominated), but they share the same network of processes and reactions that control iodine fate and transport. These include adsorption to minerals and sediments, interactions with organic matter, electron transfer reactions with minerals and microbes, and precipitation. In conclusion, this process-based network serves as basis for regional scale model calculations to predict plume spreading and/or dissipation, design efficient remediation techniques and conduct contamination management activities.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Production and Transformation of Mixed-Valent Nanoparticles Generated by Fe(0) Electrocoagulation

Mixed-valent iron nanoparticles (NP) generated electrochemically by Fe(0) electrocoagulation (EC) show promise for on-demand industrial and drinking water treatment in engineered systems. This work applies multiple characterization techniques (in situ Raman spectroscopy, XRD, SEM, and cryo-TEM) to investigate the formation and persistence of magnetite and green rust (GR) NP phases produced via the Fe(0) EC process. Current density and background electrolyte composition were examined in a controlled anaerobic system to determine the initial Fe phases generated as well as transformation products with aging. Fe phases were characterized in an aerobic EC system with both simple model electrolytes and real groundwater to investigate the formation and aging of Fe phases produced in a system representing treatment of arsenic-contaminated ground waters in South Asia. Two central pathways for magnetite production via Fe(0) EC were identified: (i) as a primary product (formation within seconds when DO absent, no intermediates detected) and (ii) as a transformation product of GR (from minutes to days depending on pH, electrolyte composition, and aging conditions). Furthermore, this study provides a better understanding of the formation conditions of magnetite, GR, and ferric (oxyhydr)oxides in Fe EC, which is essential for process optimization for varying source waters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗