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At least 937 records · Page 52

Vertical Distribution and Variability of Ozone During July 1999 Over Andenes, Norway

Ozonesonde measurements of the polar atmosphere obtained at Andenes, Norway during July 1999 showed unusual characteristics when compared with mid- or low-latitude ozone profiles. A minimum of two ozonesondes each day were released, one in late afternoon and one in early evening. A very well-defined ledge in the ozone profile corresponding to the tropopause appears to form as a result of transport. The ozone amount increases four to five times, from about 30 nb at the tropopause to 120 nb at a pressure about 10-20 hPa lower. The typical peak ozone value, although at a higher altitude than the ledge, appears at a much lower pressure (approx. 140 hPa) than found in midor low-latitudes (approx. 18-25 hPa), Total column ozone amounts are consistently higher than 300 DU. Analysis of the variation with regard to wind conditions will be discussed.

Schmidlin, F. J.↗

A Characterization of Vertical Ozonesonde Measurements at the Equatorial Locations of SHADOZ

Beginning in 1997 ozonesonde observations have been obtained from Equatorial locations participating in SHADOZ (Southern Hemisphere Additional Ozone) Project. Vertical ozone profiles are available from the western Pacific eastward to Kenya. Presently 10 stations provide vertical ECC ozonesonde measurements at least weekly. Statistical analysis shows the variation that occurs in the level of maximum ozone, the difference between integrated total ozone overburden from ECC and EP-TOMS observations, and with Dobson Spectrophotometers, when data are available.

Schmidlin, F. J.↗

The Evolution of Dendrite Morphology during Isothermal Coarsening

Dendrite coarsening is a common phenomenon in casting processes. From the time dendrites are formed until the inter-dendritic liquid is completely solidified dendrites are changing shape driven by variations in interfacial curvature along the dendrite and resulting in a reduction of total interfacial area. During this process the typical length-scale of the dendrite can change by orders of magnitude and the final microstructure is in large part determined by the coarsening parameters. Dendrite coarsening is thus crucial in setting the materials parameters of ingots and of great commercial interest. This coarsening process is being studied in the Pb-Sn system with Sn-dendrites undergoing isothermal coarsening in a Pb-Sn liquid. Results are presented for samples of approximately 60% dendritic phase, which have been coarsened for different lengths of times. Presented are three-dimensional microstructures obtained by serial-sectioning and an analysis of these microstructures with regard to interface orientation and interfacial curvatures. These graphs reflect the evolution of not only the microstructure itself, but also of the underlying driving forces of the coarsening process. As a visualization of the link between the microstructure and the driving forces a three-dimensional microstructure with the interfaces colored according to the local interfacial mean curvature is shown.

Alkemper, Jens↗

Impulsive Injection for Compressor Stator Separation Control

Flow control using impulsive injection from the suction surface of a stator vane has been applied in a low speed axial compressor. Impulsive injection is shown to significantly reduce separation relative to steady injection for vanes that were induced to separate by an increase in vane stagger angle of 4 degrees. Injected flow was applied to the airfoil suction surface using spanwise slots pitched in the streamwise direction. Injection was limited to the near-hub region, from 10 to 36 percent of span, to affect the dominant loss due to hub leakage flow. Actuation was provided externally using high-speed solenoid valves closely coupled to the vane tip. Variations in injected mass, frequency, and duty cycle are explored. The local corrected total pressure loss across the vane at the lower span region was reduced by over 20 percent. Additionally, low momentum fluid migrating from the hub region toward the tip was effectively suppressed resulting in an overall benefit which reduced corrected area averaged loss through the passage by 4 percent. The injection mass fraction used for impulsive actuation was typically less than 0.1 percent of the compressor through flow.

Culley, Dennis E.↗

THEMIS Observations of a Transient Event at the Magnetopause

This study focuses on Time History of Events and Macroscale Interactions During Substorms (THEMIS) observations of a long \duration transient event in the vicinity of the dayside magnetopause at approx.15:34 UT on 18 July 2008 that was characterized by features typical of a magnetospheric flux transfer event (FTE): a bipolar negative-positive 5-7 nT signature in the Bn component, a positive monopolar variation in the Bl and Bm components, a approx.5-7 nT enhancement in the total magnetic field strength, and a transient density and flow enhancement. The interplanetary magnetic field (IMF) was mostly radial and disturbed during the intervals studied; that is, it was favorable for the repeated formation, disappearance and reformation of the foreshock just upstream from the subsolar bow shock. We show that varying IMF directions and solar wind pressures created significant effects that caused the compressions of the magnetosphere and the bow shock and magnetopause motions and triggered the transient event. Global signatures of magnetic impulse events (MIEs) in ground magnetograms during the period suggest a widespread pressure pulse instead of a localized FTE as the cause of the event in the magnetosphere. The directions of propagation and the flow patterns associated with the event also suggest an interpretation in terms of pressure pulses.

Korotova, G. I.↗

From Space Weather Toward Space Climate Time Scales: Substorm Analysis from 1993 to 2008

Magnetic activity in the Northern Hemisphere auroral region was examined during solar cycles 22 and 23 (1993- 2008). Substorms were identified from ground-based magnetic field measurements by an automated search engine. On average, 550 substorms were observed per year, which gives in total about 9000 substorms. The interannual, seasonal and solar cycle-to-cycle variations of the substorm number (R(sub ss)), substorm duration (T(sub ss)), and peak amplitude (A(sub ss)) were examined. The declining phases of both solar cycles 22 and 23 were more active than the other solar cycle phases due to the enhanced solar wind speed. The spring substorms during the declining solar cycle phase (absolute value of A(sub ss,decl)) - 500 nT) were 25% larger than the spring substorms during the ascending solar cycle years ((absolute value of A(sub ss,asc) = 400 nT). The following seasonal variation was found: the most intense substorms occurred during spring and fall, the largest substorm frequency in the Northern Hemisphere winter, and the longest-duration substorms in summer. Furthermore, we found a winter-summer asymmetry in the substorm number and duration. which is speculated to be due to the variations in the ionospheric conductivity. The solar cycle-Io-cycle variation was found in the yearly substorm number and peak amplitude. The decline from the peak substorm activity in 1994 and 2003 to the following minima took 3 years during solar cycle 22, while it took 6 years during solar cycle 23.

Tanskanen, E. I.↗

Measurements and Modeling of Total Solar Irradiance in X-class Solar Flares

The Total Irradiance Monitor (TIM) from NASA's SOlar Radiation and Climate Experiment can detect changes in the total solar irradiance (TSI) to a precision of 2 ppm, allowing observations of variations due to the largest X-class solar flares for the first time. Presented here is a robust algorithm for determining the radiative output in the TIM TSI measurements, in both the impulsive and gradual phases, for the four solar flares presented in Woods et al., as well as an additional flare measured on 2006 December 6. The radiative outputs for both phases of these five flares are then compared to the vacuum ultraviolet (VUV) irradiance output from the Flare Irradiance Spectral Model (FISM) in order to derive an empirical relationship between the FISM VUV model and the TIM TSI data output to estimate the TSI radiative output for eight other X-class flares. This model provides the basis for the bolometric energy estimates for the solar flares analyzed in the Emslie et al. study.

Sun: chromosphere↗

The Nearby Evolved Stars Survey – I. JCMT/SCUBA-2 Submillimeter Detection of the Detached Shell of U Antliae

We present the highest resolution single-dish submillimetre observations of the detached shell source U Antliae to date. The observations were obtained at 450 and 850μm with SCUBA-2 instrument on the James Clerk Maxwell Telescope as part of the Nearby Evolved Stars Survey. The emission at 850μm peaks at 40 arcsec with hints of a second peak seen at ∼20 arcsec. The emission can be traced out to a radius of 56 arcsec at a 3σ level. The outer peak observed at 850μm aligns well with the peak observed at Herschel/PACS wavelengths. With the help of spectral energy distribution fitting and radiative transfer calculations of multiple-shell models for the circumstellar envelope, we explore the various shell structures and the variation of grain sizes along the in the circumstellar envelope. We determine a total shell dust mass of (2.0 ± 0.3) × 10−5 M⊙ and established that the thermal pulse that gave rise to the detached shell occurred 3500 ± 500 yr ago.

Dharmawardena, Thavisha E.↗

A New View of the Lunar South Pole from the Lunar Orbiter Laser Altimeter (LOLA)

Upcoming missions to the lunar south pole require detailed maps over large areas to fully characterize landing sites locally and regionally and to place their data into proper geologic context. To that end, we enhanced the Lunar Orbiter Laser Altimeter (LOLA) altimetry dataset for the south polar region, from which we produced new maps of topography, topographic roughness, and permanently shadowed regions (PSRs). The roughness maps reveal a diversity of terrains characterized by hectometer-scale roughness which is controlled in this region primarily by cratering and downslope mass transport. The south polar region is littered with linear roughness features of order ~1 – 10 km wide and ~10s – 100s of km long hypothesized to be secondary impacts within extended ejecta rays. Non uniformities in these features could reflect variations in secondary impactor properties and/or target terrain properties. Poleward of 80° S, the PSR cumulative size-frequency distribution (CSFD) shows an approximately power-law behavior whose exponent has a spatial variation of ~10%. PSRs with areas < 1 km2 contain 15 ± 5% of the total PSR area. Finally, we studied the effect of false positives and false negatives on the accuracy of the measured PSR cumulative size-frequency distribution (CSFD) and on the area for any individual PSR. The new maps presented here have many applications in the science and exploration of the lunar south polar region, such as geologic mapping and traverse planning.

Michael K. Barker↗

Satellite-Assisted Particulate Matter (SAPM) for the Models, In situ, and Remote Sensing of Aerosols (MIRA) Working Group

Models, In situ, and Remote sensing of Aerosols (MIRA) is an international working group that provides a forum for collaborations amongst these three atmospheric aerosol communities. MIRA consists of a collection of interdisciplinary and independently funded Topic/Project groups with clear goals and generally characterized by requests for additional scientific data. The Satellite-Assisted Particulate Matter (SAPM) Topic group focuses on the study of fine particulate matter (PM2.5), as it is a major contributor to air pollution and negatively impacts human health. Our group aims to provide intercomparisons of various methods and techniques for estimating surface PM2.5 assisted by satellite remote sensors (passive and active), global aerosol models, and in situ aerosol measurements. The overall motivation of our work is to enhance PM2.5 coverage beyond in situ ground stations, which can be limited. In this presentation, we provide an overview of various PM2.5 estimation approaches by current SAPM team members, as each approach has its own strengths and limitations. One approach uses near-surface aerosol extinction retrievals from the spaceborne Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and an assumed value of mass extinction efficiency to derive PM2.5 concentrations (Toth et al 2019). A study using this method found a promising agreement (R=0.60; slope=0.89) with U.S. Environmental Protection Agency (EPA) in situ PM2.5 measurements over the contiguous United States (CONUS) for a 12-year (2007-2018) period (Toth et al 2022). In a different approach combining spaceborne lidar and a model, the Cloud Aerosol Transport System (CATS) lidar and Goddard Earth Observing System (GEOS) model are blended in an ensemble variational assimilation scheme to retrieve aerosol extinction and convert speciated mass concentrations to total PM2.5. A recent study (Matus et al in prep.) found agreement within 2 μg/m3 over the CONUS on the 2016 annual mean when compared to EPA ground-based measurements. Another study explored trends in city aerosol optical depth (AOD) from a spaceborne passive remote sensor, Moderate Resolution Imaging Spectroradiometer (MODIS), and found that these trends agree well with trends in city surface PM2.5, which provides confidence in the use of city AOD for city PM2.5 trend studies (Vohra et al 2021). In a follow-on study, steep and significant trends (~2.5 to 7.8% a-1) in AOD are found for several South Asian cities (e.g., Bangalore and Hyderabad), suggesting rapid growth in PM2.5 (Vohra et al 2022). Also in this presentation, we report results on our current collective SAPM study of India, a country that exhibits high levels of PM2.5 pollution. We show the temporal (i.e., seasonal) and spatial variability of PM2.5 over India using the CALIOP and CATS+model approaches, comparisons between the estimated PM2.5 from the retrieval schemes, and validation with in situ PM2.5 ground-based observations from the Central Pollution Control Board in India. This region provides us with an excellent case study to test our PM2.5 retrievals in heavily polluted scenes and over a complex and varying topography. The SAPM Topic group actively seeks international participants/collaborators in our group, including those working with in situ aerosol measurements (e.g., ACTRIS). We are interested in aerosol datasets in order to either improve our PM2.5 estimates from various approaches (e.g., using in situ mass scattering/absorption coefficient and aerosol hygroscopic properties for various aerosol species) and/or validate the PM2.5 estimates (e.g., using in situ ground-based PM2.5 concentrations).

Travis D Toth↗

Spatial decomposition of magnetic anisotropy in magnets: Application to doped Fe 16 N 2

We propose a scheme of decomposition of the total relativistic energy in solids to intra- and interatomic contributions. The method is based on a site variation of such fundamental constant as the speed of light. As a practical illustration of the method, we tested such decomposition in the case of a spin-orbit interaction variation for the decomposition of the magnetic anisotropy energy (MAE) in CoPt. We further studied the α" - Fe 16 N 2 magnet doped by Bi, Sb, Co, and Pt atoms. It was found that the addition of Pt atoms can enhance the MAE by as much as five times while Bi and Sb substitutions double the total MAE. Using the proposed technique, we demonstrate the spatial distribution of these enhancements. Our studies also suggest that Sb, Pt, and Co substitutions could be synthesized by experiments.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Experimental investigation of turbulent wall-jets in the presence of adverse pressure gradients in a rectangular diffuser

An experimental study of wall static pressure distributions and mean velocity profiles along a duct and diffuser downstream of wall-jet injection was conducted over a range of diffuser total angles from 15 to 40 deg at injection to core flow mass flux ratios from 0 to 6. Pressure recovery in the diffuser increased with injection ratio and decreased with diffuser total angle. Peak velocities in the wall-jet decayed along the flow and the inner shear layer and outer mixing region grew in thickness along the flow. The inner layer was near similarity condition, but non-similar variations were found in the outer layer. Estimated wall shear stresses depended upon injection mass fluxes, downstream distance and diffuser total angle. Greater decay of peak velocity and larger friction coefficients were found in the diffuser than indicated by correlations from data for a wall-jet without a pressure gradient. At the largest diffuser total angle and the highest injection ratio flow reversal occurred in the core region.

Back, L.↗

Ozone measurements from the NOAA-9 and the Nimbus-7 satellites - Implications of short and long term variabilities

An overview of the measurements of total ozone and ozone profiles by the SBUV/2 instrument on the NOAA-9 spacecraft relative to similar measurements from the solar backscatter ultraviolet (SBUV) and TOMS instruments on Nimbus-7 is presented. During the three-year period from March 14, 1985 to February 28, 1988, when these data sets overlap, it is shown that there have been significant changes in the calibrations of the three instruments that may be attributed to diffuser plate degradation (for SBUV/TOMS) and to the drift of the NOAA-9 orbit to later equator crossing times (for SBUV/2). Though these instrument characteristic changes have effected the absolute values of the trends derived from the three instruments, their geophysical characteristics and response to short-term variations are accurate and correlate well among the three instruments. It is seen that the total column ozone measured by the three instruments shows good agreement with respect to its day-to-day, seasonal, and latitudinal variabilities.

Chandra, S.↗

Longitudinal and Seasonal Variations in Nighttime Plasma Temperatures in the Equatorial Topside Ionosphere During Solar Maximum

Latitude profiles of the ion and electron temperatures and total ion concentration across the equatorial region near 800 km altitude are routinely obtained from Defense Meteorological Satellite Program (DMSP) spacecraft. We have examined these profiles at 2100 hours local time to discover the influences of field-aligned plasma transport induced by F region neutral winds. Such dependencies are readily seen by contrasting observations at different seasons and different longitudes distinguished by different magnetic declinations. These data show strong evidence for adiabatic heating produced by interhemispheric plasma transport. This heating manifests itself as a local temperature maximum that appears in the winter hemisphere during the solstices and is generally absent during equinox. A longitudinal variation in the appearance of this maximum is consistent with the roles of meridional and zonal winds in modulating the field-aligned plasma velocities. The data also show a local temperature minimum near the dip equator. However, it is not so easy to attribute this minimum to adiabatic cooling since transport of plasma from below and the latitude variation in the flux tube content may also produce such a minimum.

Venkatraman, Sarita↗

A Climatology of Midlatitude Continental Clouds from the ARM SGP Site: Cloud Fraction and Surface Radiative Forcing - Part II

Data collected at the Department of Energy Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) Central Facility (SCF) are analyzed to determine the monthly and hourly variations of cloud fraction and radiative forcing between January 1997 and December 2002. Cloud fractions are estimated for total cloud cover and for single-layered low (0-3 km), middle (3-6 km), and high clouds (more than 6 km) using ARM SCG ground-based paired lidar-radar measurements. Shortwave (SW) and longwave (LW) fluxes are derived from up- and down-looking standard precision spectral pyranometers and precision infrared radiometer measurements with uncertainties of approximately 10 Wm(exp -2). The annual averages of total, and single-layered low, middle and high cloud fractions are 0.49, 0.11, 0.03, and 0.17, respectively. Both total and low cloud amounts peak during January and February and reach a minimum during July and August, high clouds occur more frequently than other types of clouds with a peak in summer. The average annual downwelling surface SW fluxes for total and low clouds (151 and 138 Wm(exp-2), respectively) are less than those under middle and high clouds (188 and 201 Wm(exp -2), respectively), but the downwelling LW fluxes (349 and 356 Wm(exp -2)) underneath total and low clouds are greater than those from middle and high clouds (337 and 333 Wm(exp -2)). Low clouds produce the largest LW warming (55 Wm(exp -2) and SW cooling (-91 Wm(exp -2)) effects with maximum and minimum absolute values in spring and summer, respectively. High clouds have the smallest LW warming (17 Wm(exp -2)) and SW cooling (-37 Wm(exp -2)) effects at the surface. All-sky SW CRF decreases and LW CRF increases with increasing cloud fraction with mean slopes of -0.984 and 0.616 Wm(exp -2)%(exp -1), respectively. Over the entire diurnal cycle, clouds deplete the amount of surface insolation more than they add to the downwelling LW flux. The calculated CRFs do not appear to be significantly affected by uncertainties in data sampling and clear-sky screening. Traditionally, cloud radiative forcing includes, not only the radiative impact of the hydrometeors, but also the changes in the environment. Taken together over the ARM SCF, changes in humidity and surface albedo between clear and cloudy conditions offset approximately 20% of the NET radiative forcing caused by the cloud hydrometeors alone. Variations in water vapor, on average, account for 10% and 83% of the SW and LW CRFs, respectively, in total cloud cover conditions. The error analysis further reveals that the cloud hydrometeors dominate the SW CRF, while water vapor changes are most important for LW flux changes in cloudy skies. Similar studies over other locales are encouraged where water and surface albedo changes from clear to cloudy conditions may be much different than observed over the ARM SCF.

Xi, B.↗

Variation in Coronal Activity from Solar Cycle 24 Minimum to Maximum Using Three-Dimensional Reconstructions of the Coronal Electron Density from STEREO/COR1

Three-dimensional electron density distributions in the solar corona are reconstructed for 100 Carrington rotations (CR 2054 - 2153) during 2007/03 - 2014/08 using the spherically symmetric method from polarized white-light observations with the inner coronagraph (COR1) onboard the twin Solar Terrestrial Relations Observatory (STEREO). These three-dimensional electron density distributions are validated by comparison with similar density models derived using other methods such as tomography and a magnetohydrodynamics (MHD) model as well as using data from the Solar and Heliospheric Observatory (SOHO)/Large Angle and Spectrometric Coronagraph (LASCO)-C2. Uncertainties in the estimated total mass of the global corona are analyzed based on differences between the density distributions for COR1-A and -B. Long-term variations of coronal activity in terms of the global and hemispheric average electron densities (equivalent to the total coronal mass) reveal a hemispheric asymmetry during the rising phase of Solar Cycle 24, with the northern hemisphere leading the southern hemisphere by a phase shift of 7 - 9 months. Using 14 CR (approx. equal to 13-month) running averages, the amplitudes of the variation in average electron density between Cycle 24 maximum and Cycle 23/24 minimum (called the modulation factors) are found to be in the range of 1.6 - 4.3. These modulation factors are latitudinally dependent, being largest in polar regions and smallest in the equatorial region. These modulation factors also show a hemispheric asymmetry: they are somewhat larger in the southern hemisphere. The wavelet analysis shows that the short-term quasi-periodic oscillations during the rising and maximum phases of Cycle 24 have a dominant period of 7 - 8 months. In addition, it is found that the radial distribution of the mean electron density for streamers at Cycle 24 maximum is only slightly larger (by approx. equal to 30%) than at cycle minimum.

Wang, Tongjiang↗

Partitioning Evapotranspiration in Semiarid Grassland and Shrubland Ecosystems Using Diurnal Surface Temperature Variation

The encroachment of woody plants in grasslands across the Western U.S. will affect soil water availability by altering the contributions of evaporation (E) and transpiration (T) to total evapotranspiration (ET). To study this phenomenon, a network of flux stations is in place to measure ET in grass- and shrub-dominated ecosystems throughout the Western U.S. A method is described and tested here to partition the daily measurements of ET into E and T based on diurnal surface temperature variations of the soil and standard energy balance theory. The difference between the mid-afternoon and pre-dawn soil surface temperature, termed Apparent Thermal Inertia (I(sub A)), was used to identify days when E was negligible, and thus, ET=T. For other days, a three-step procedure based on energy balance equations was used to estimate Qe contributions of daily E and T to total daily ET. The method was tested at Walnut Gulch Experimental Watershed in southeast Arizona based on Bowen ratio estimates of ET and continuous measurements of surface temperature with an infrared thermometer (IRT) from 2004- 2005, and a second dataset of Bowen ratio, IRT and stem-flow gage measurements in 2003. Results showed that reasonable estimates of daily T were obtained for a multi-year period with ease of operation and minimal cost. With known season-long daily T, E and ET, it is possible to determine the soil water availability associated with grass- and shrub-dominated sites and better understand the hydrologic impact of regional woody plant encroachment.

Moran, M. Susan↗

Microstructure‐Dependent Sodium Storage Mechanisms in Hard Carbon Anodes

Sustainable energy storage is essential to support the transition to renewables and meet the increasing demand for energy. Sodium‐ion batteries (NIBs) are attractive for grid‐scale energy storage due to the abundance and low cost of sodium, sustainability of other battery components, and electrochemical performance. Hard carbon (HC) is a leading anode material for NIBs, but its complex microstructure complicates the understanding of sodium storage mechanisms. Using X‐ray total scattering and density functional theory calculations, this study clarifies how HC's microstructural variations influence sodium storage across the slope (high potential) and plateau (low potential) regions of the potential capacity curve. In the slope region, sodium initially adsorbs at high‐binding energy defect sites and subsequently intercalates between graphene layers, adsorbing at low‐binding energy defect sites, correlating with different slopes observed during initial sodiation. Initial irreversibility arises from sodium trapping at surface defects and solid electrolyte interface formation. In the plateau region, sodium simultaneously intercalates and fills pores, influenced by pore size, interlayer spacing, and defect concentration. HCs with larger pore sizes form larger sodium clusters. In conclusion, the proposed mechanism underscores the role of microstructure engineering in enhancing HC performance and advancing NIBs for grid‐scale energy storage.

36 MATERIALS SCIENCE↗