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At least 937 records · Page 52

Time evolution of a viscous protoplanetary disk with a free geometry: Toward a more self-consistent picture

Observations of protoplanetary disks show that some characteristics seem recurrent, even in star formation regions that are physically distant such as surface mass density profiles varying as r {sup –1} or aspect ratios of about 0.03-0.23. Accretion rates are also recurrently found around 10{sup –8}-10{sup –6} M {sub ☉} yr{sup –1} for disks that have already evolved. Several models have been developed in order to recover these properties. However, most of them usually simplify the disk geometry if not its mid-plane temperature. This has major consequences for modeling the disk evolution over millions of years and consequently planet migration. In the present paper, we develop a viscous evolution hydrodynamical numerical code that simultaneously determines the disk photosphere geometry and the mid-plane temperature. We then compare our results of long-term simulations with similar simulations of disks with a constrained geometry along the Chiang and Goldreich prescription (d lnH/d lnr = 9/7). We find that the constrained geometry models provide a good approximation of the disk surface density evolution. However, they differ significantly regarding the temperature-time evolution. In addition, we find that shadowed regions naturally appear at the transition between viscously dominated and radiation-dominated regions that falls in the region of planetary formation. We show that χ (photosphere height to pressure scale height ratio) cannot be considered a constant, which is consistent with the findings of Watanabe and Lin. Comparisons with observations show that all disks naturally evolve toward a shallow surface density disk (Σ∝r {sup –1}). The mass flux across the disk typically stabilizes in about 1 Myr.

79 ASTRONOMY AND ASTROPHYSICS↗

Ion Migration Studies in Exfoliated 2D Molybdenum Oxide via Ionic Liquid Gating for Neuromorphic Device Applications

The formation of an electric double layer in ionic liquid (IL) can electrostatically induce charge carriers and/or intercalate ions in and out of the lattice which can trigger a large change of the electronic, optical, and magnetic properties of materials and even modify the crystal structure. Here, we present a systematic study of ionic liquid gating of exfoliated 2D molybdenum trioxide (MoO 3 ) devices and correlate the resultant electrical properties to the electrochemical doping via ion migration during the IL biasing process. A nearly 9 orders of magnitude modulation of the MoO 3 conductivity is obtained for the two types of ionic liquids that are investigated. In addition, notably rapid on/off switching was realized through a lithium-containing ionic liquid whereas much slower modulation was induced via oxygen extraction/intercalation. Time of flight–secondary ion mass spectrometry confirms the Li intercalation. Density functional theory (DFT) calculations have been carried out to examine the underlying metallization mechanism. Results of short-pulse tests show the potential of these MoO 3 devices as neuromorphic computing elements due to their synaptic plasticity.

2D materials↗

The role of hydrogen during Pt–Ga nanocatalyst formation

Hydrogen is a critical element during the in situ assembly of tailored catalytic materials, and serves as key ingredient in multifarious chemical reactions promoted by these catalysts. Despite intensive debate for several decades, the existence and nature of hydrogen-involved mechanisms – such as hydrogen-spillover, surface migration – have not been unambiguously proven and elucidated up to date. In this work, Pt–Ga alloy formation is used as a probe reaction to study the behavior and atomic transport of H and Ga, starting from Pt nanoparticles on hydrotalcite-derived Mg(Ga)(Al)O x supports. In situ XANES spectroscopy, time-resolved TAP kinetic experiments, HAADF-STEM imaging and EDX mapping are combined to probe Pt, Ga and H in a series of H 2 reduction experiments up to 650 °C. Mg(Ga)(Al)O x by itself dissociates hydrogen, but these dissociated hydrogen species do not induce significant reduction of Ga 3+ cations in the support. Only in the presence of Pt, partial reduction of Ga 3+ into Ga δ+ is observed, suggesting that different reaction mechanisms dominate for Pt- and Mg(Ga)(Al)O x -dissociated hydrogen species. This partial reduction of Ga 3+ is made possible by Pt-dissociated H species which spillover onto non-reducible Mg(Al)O x or partially reducible Mg(Ga)(Al)O x and undergo long-range transport over the support surface. Moderately mobile Ga δ+ O x migrates towards Pt clusters, where Ga δ+ is only fully reduced to Ga 0 on condition of immediate stabilization inside Pt–Ga alloyed nanoparticles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NaGaS 2 : An Elusive Layered Compound with Dynamic Water Absorption and Wide‐Ranging Ion‐Exchange Properties

Abstract Most ternary sulfides belonging to the MGaS 2 structure‐type have been known for many years and are well‐characterized. Surprisingly, there have been no reports of the NaGaS 2 composition, which contains Na, a monovalent cation slightly larger in size than Li, found in LiGaS 2 , a compound known for its non‐linear optical properties. Now it is demonstrated for the first time that the unique reversible water absorption in NaGaS 2 has resulted in its absence from previous reports owing to difficulties encountered when characterizing this compound by SC XRD. The layered structure of this compound coupled with uniquely easy migration of water molecules between the layers allows for ion exchange with 3d and 5f metal cations. Some cations, for example, Ni 2+ , facilitate exfoliation of the layers, providing a facile synthetic route to a new class of 2D chalcogenide materials and furthermore demonstrating that NaGaS 2 can readily uptake uranyl species from aqueous solutions.

Klepov, Vladislav V.↗

g-C3N4/UiO-66 nanohybrids with enhanced photocatalytic activities for the oxidation of dye under visible light irradiation

Highlights: • G-C{sub 3}N{sub 4}/UiO-66 heterojunctions were synthesized by a facile one-pot method. • G-C{sub 3}N{sub 4}/UiO-66 nanohybrids were used as an visible-light-driven photocatalysts. • G-C{sub 3}N{sub 4}/UiO-66 nanohybrids enhanced the separation of photoexcited carriers. • G-C{sub 3}N{sub 4}/UiO-66 nanohybrids were stable even after the four cycles. - Abstract: In this study, g-C{sub 3}N{sub 4} nanosheets coated UiO-66 nanohybrids were fabricated via a simple solvothermal method. The physicochemical parameters, structural and electrochemical properties of g-C{sub 3}N{sub 4}/UiO-66 nanohybrids (CNUO-x) were investigated. The nanohybrids were systematically characterized by XRD, FT-IR, TGA, TEM, SEM, EDS elemental mappings, XPS, N{sub 2} adsorption-desorption isotherms, PL and DRS. It was found that the addition of moderate g-C{sub 3}N{sub 4} could enhance the separation and migration rate of photo-induced charges, consequently leading to the increase of photocatalytic efficiency. The CNUO-1 nanohybrid exhibited better photocatalytic activity for the oxidation of Rh B under visible light irradiation, and displayed about 6.0 and 3.3 times faster than that of g-C{sub 3}N{sub 4} and UiO-66, respectively. Meanwhile, the nanohybrid showed excellent stability and reusability in four cyclic experiments. Finally, the increased photocatalytic reaction mechanism was also proposed. O{sub 2}{sup −}, h{sup +} and OH were further found to be the main active contributors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Weakly Solvating Electrolyte to Enable Lithium- and Manganese-Rich Cathode-Based Li-Ion Batteries

Traditional ethylene carbonate (EC)-based electrolytes exhibit strong solvation power at the surface of the layered transition metal oxide cathodes, which accelerates transition metal dissolution. The subsequent migration and deposition of dissolved transition metal species on the anode surface lead to significant capacity fading. To overcome this difficulty, we report a weakly solvating, all-fluorinated electrolyte designed to mitigate transition metal dissolution. For the first time, the role of electrolyte solvation in suppressing transition metal dissolution is systematically investigated. The tailored electrolyte significantly reduces transition metal dissolution and enhances the electrochemical performance of Li- and Mn-rich (LMR) cathode/graphite cells. This solvation-modulating strategy offers a broadly applicable framework for stabilizing interphases in other earth-abundant cathode chemistries, which similarly demand kinetic protection against interfacial degradation.

25 ENERGY STORAGE↗

The formation mechanisms and optical characteristics of GaSb quantum rings

The growth mechanisms and optical characteristics of GaSb quantum rings (QRs) are investigated. Although As-for-Sb exchange is the mechanism responsible for the dot-to-ring transition, significant height difference between GaSb quantum dots (QDs) and QRs in a dot/ring mixture sample suggests that the dot-to-ring transition is not a spontaneous procedure. Instead, it is a rapid transition procedure as long as it initiates. A model is established to explain this phenomenon. Larger ring inner diameters and heights of the sample with longer post Sb soaking time suggest that As-for-Sb exchange takes places in both vertical and lateral directions. The decreasing ring densities, enlarged ring inner/outer diameters and eventually flat GaSb surfaces observed with increasing growth temperatures are resulted from enhanced adatom migration and As-for-Sb exchange with increasing growth temperatures.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Model for radon diffusion through the lunar regolith.

Description of a model for radon diffusion through the lunar regolith in which the atom migrates by random walk. The regolith is represented by a system of randomly oriented baffles in which the mean distance which the atom travels between two collisions takes on the role of a mean free path. The effective mean time between two collisions depends on two entities: the actual mean time-of-flight and the mean sticking time on grain surfaces for one collision. The latter depends strongly on the temperature and the heat of adsorption of radon on regolith materials. Both the mean free path as well as the heat of adsorption are either poorly known or unknown for the lunar regolith; hence these quantities are treated as free parameters. Because of the greatly different mean lifetimes against radioactive decay of Rn219, Rn220, and Rn222, the regolith acts as a powerful 'filter' for these species. Rn222 escape is significant (32%) even for a mean free path of 1 micron, a heat of adsorption of 7.0 kcal/mole and a regolith depth of 4 m. Calculations of radon escape from a 4 m thick regolith, using mean free paths of 1, 10, and 80 microns and heats of adsorption of 4.0, 5.2, and 7.0 kcal/mole show that the Rn222/Rn220 escape ratio can be as small as 7.7 and as large as, or larger than 47. The small value of 7.7 is of particular interest, because it is nearly equal to the escape ratio inferred by Turkevich et al. (1970) from their Surveyor 5 results.

Friesen, L. J.↗

Low-velocity variability in the stellar wind of HD 152408 (O8: Iafpe)

We describe high-quality, spectroscopic time series observations of variability at low velocities in the stellar wind of the extreme O-supergiant HD 152408. These observations were obtained during a monitoring campaign coordinated between Australia and Chile in 1992 July. Systematic variability on hourly time scales is particularly apparent in the He I lambda 5876 P Cygni profile, which diagnoses the deeper, denser region of the wind. These changes indicate the presence of evolving wind structure, which takes the form of blueward-migrating, discrete optical depth enhancements. Four distinct features are identified over approximately 5 days, spanning a velocity range of about -50 km/s at formation to about -500 km/s (i.e., greater than or approximately equal to 0.5 of the terminal velocity) at the blue edge of the He I absorption trough. Sympathetic variations are also apparent in the Balmer emission lines of HD 152408. The characteristics of these features, including their widths, column densities, and accelerations, suggest similarities to discrete absorption components commonly seen at larger velocities in UV P Cygni profiles of other O-type stars. These optical results demonstrate that frequent, systematic wind variability is present down to very large depths, and provide constraints on the stability of the low-velocity regime of hot-star winds.

Prinja, Raman K.↗

High-resolution observations of the polar magnetic fields of the sun

High-resolution magnetograms of the solar polar region were used for the study of the polar magnetic field. In contrast to low-resolution magnetograph observations which measure the polar magnetic field averaged over a large area, we focused our efforts on the properties of the small magnetic elements in the polar region. Evolution of the filling factor (the ratio of the area occupied by the magnetic elements to the total area) of these magnetic elements, as well as the average magnetic field strength, were studied during the maximum and declining phase of solar cycle 22, from early 1991 to mid-1993. We found that during the sunspot maximum period, the polar regions were occupied by about equal numbers of positive and negative magnetic elements, with equal average field strength. As the solar cycle progresses toward sunspot minimum, the magnetic field elements in the polar region become predominantly of one polarity. The average magnetic field of the dominant polarity elements also increases with the filling factor. In the meanwhile, both the filling factor and the average field strength of the non-dominant polarity elements decrease. The combined effects of the changing filling factors and average field strength produce the observed evolution of the integrated polar flux over the solar cycle. We compared the evolutionary histories of both filling factor and average field strength, for regions of high (70-80 deg) and low (60-70 deg) latitudes. For the south pole, we found no significant evidence of difference in the time of reversal. However, the low-latitude region of the north pole did reverse polarity much earlier than the high-latitude region. It later showed an oscillatory behavior. We suggest this may be caused by the poleward migration of flux from a large active region in 1989 with highly imbalanced flux.

Lin, H.↗

Evolution of Information Management at the GSFC Earth Sciences (GES) Data and Information Services Center (DISC): 2006-2007

Increasingly sophisticated National Aeronautics and Space Administration (NASA) Earth science missions have driven their associated data and data management systems from providing simple point-to-point archiving and retrieval to performing user-responsive distributed multisensor information extraction. To fully maximize the use of remote-sensor-generated Earth science data, NASA recognized the need for data systems that provide data access and manipulation capabilities responsive to research brought forth by advancing scientific analysis and the need to maximize the use and usability of the data. The decision by NASA to purposely evolve the Earth Observing System Data and Information System (EOSDIS) at the Goddard Space Flight Center (GSFC) Earth Sciences (GES) Data and Information Services Center (DISC) and other information management facilities was timely and appropriate. The GES DISC evolution was focused on replacing the EOSDIS Core System (ECS) by reusing the In-house developed disk-based Simple, Scalable, Script-based Science Product Archive (S4PA) data management system and migrating data to the disk archives. Transition was completed in December 2007

Kempler, Steven↗

Advancements in the Aerosol Robotic Network (AERONET) Version 3 database – automated near-real-time quality control algorithm with improved cloud screening for Sun photometer aerosol optical depth (AOD) measurements

The Aerosol Robotic Network (AERONET) has provided highly accurate, ground-truth measurements of the aerosol optical depth (AOD) using Cimel Electronique Sun–sky radiometers for more than 25 years. In Version 2 (V2) of the AERONET database, the near-real-time AOD was semiautomatically quality controlled utilizing mainly cloud-screening methodology, while additional AOD data contaminated by clouds or affected by instrument anomalies were removed manually before attaining quality-assured status (Level 2.0). The large growth in the number of AERONET sites over the past 25 years resulted in significant burden to the manual quality control of millions of measurements in a consistent manner. The AERONET Version 3 (V3) algorithm provides fully automatic cloud screening and instrument anomaly quality controls. All of these new algorithm updates apply to near-real-time data as well as post-field-deployment processed data, and AERONET reprocessed the database in 2018. A full algorithm redevelopment provided the opportunity to improve data inputs and corrections such as unique filter-specific temperature characterizations for all visible and near-infrared wavelengths, updated gaseous and water vapor absorption coefficients, and ancillary data sets. The Level 2.0 AOD quality-assured data set is now available within a month after post-field calibration, reducing the lag time from up to several months. Near-real-time estimated uncertainty is determined using data qualified as V3 Level 2.0 AOD and considering the difference between the AOD computed with the pre-field calibration and AOD computed with pre-field and post-field calibration. This assessment provides a near-real-time uncertainty estimate for which average differences of AOD suggest a +0.02 bias and one sigma uncertainty of 0.02, spectrally, but the bias and uncertainty can be significantly larger for specific instrument deployments. Long-term monthly averages analyzed for the entire V3 and V2 databases produced average differences (V3–V2) of +0.002 with a ±0.02 SD (standard deviation), yet monthly averages calculated using time-matched observations in both databases were analyzed to compute an average difference of −0.002 with a ±0.004 SD. The high statistical agreement in multiyear monthly averaged AOD validates the advanced automatic data quality control algorithms and suggests that migrating research to the V3 database will corroborate most V2 research conclusions and likely lead to more accurate results in some cases.

David M. Giles↗

In Silico Methods for Space System Analysis: Optical Link Coding Performance and Lunar Terrain Masks

As deep space links migrate toward higher frequency bands like 𝐾𝑎 and optical, thor- ough trade-space exploration becomes increasingly valuable for designing reliable and efficient communications systems. In this contribution, we leveraged high-performance, concurrent simulations when the run-time complexity of simulation software overwhelms capabilities of ordinary desktop machines. The first part of this manuscript describes how to run error correcting code simulations concurrently on a high-performance supercomputer. The second part of this study describes a framework to produce azimuth and elevation terrain masks from imagery of the Lunar South Pole.

Michels, Dominik L↗

Mitigating cerium migration for perfluorosulfonic acid membranes using organic ligands

Improving the electrochemical stability of proton exchange membranes is a pressing priority for heavy-duty fuel cell vehicles. The lifetime of the most widely used perfluorosulfonic acid membranes is limited by reactive free radicals generated inside the system. Cerium has been found to reduce the chemical degradation of the membranes. However, cerium migration during fuel cell operation limits the chemical durability enhancement effect expected from the radical scavenging activity of cerium. Here we investigate a wide range of organic immobilizers for cerium, measuring their suitability concerning cerium retention, radical scavenging activity, and fuel cell performance. Further, we report that partially fluorinated phosphonic acids enhance cerium retention up to 45 times and reduce fluoride emission rate by 38% compared to the commercial Nafion™ XL membrane pre-impregnated with cerium. The energetics of cerium-phosphonic acid complex systems by density functional theory calculations rationalizes effective cerium immobilization.

25 ENERGY STORAGE↗

Circular RNA expression and circPTPRM promotes proliferation and migration in hepatocellular carcinoma

Circular RNAs (circRNAs) play a critical role during hepatocellular carcinoma (HCC) development. CircRNA PTPRM (circPTPRM) has not been reported to cause disease and its role in HCC is unclear. This study explored circRNA expression and the function of circPTPRM in HCC. RNA sequencing (RNA-seq) was performed on 3 randomly selected pairs of HCC tissues and their corresponding adjacent non-tumor tissues. Three differentially expressed circRNAs, circPTPRM, circSMAD2 and circPTBP3 were selected and verified by real-time quantitative reverse transcription-polymerase chain reactions in 30 pairs of tissue samples, In vitro cultured hepatoma cells, and normal liver cells. Clinical data analysis was performed to select target circRNAs. Anti-target circRNA siRNAs were transfected into hepatoma cell lines, and the biological behavior of hepatoma cells following silencing of the target circRNA were detected by cell proliferation, plate cloning, and transwell assays. There were 86 differentially expressed circRNAs from RNA-seq, of which 53 were significantly upregulated and 33 were significantly downregulated in HCC. CircPTPRM expression was significantly upregulated in HCC tissue (p = 0.023) based on the analysis of 30 paired samples. CircPTPRM expression positively correlated with HCC recurrence and metastasis (p = 0.039). CircPTPRM silencing reduced HCC cell proliferation, migration and invasion. CircRNAs were differentially expressed in HCC samples. CircPTPRM was significantly upregulated in HCC and may function during the tumorigenesis and metastasis of HCC.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Mitigating cerium migration for perfluorosulfonic acid membranes using organic ligands

Improving the electrochemical stability of proton exchange membranes is a pressing priority for heavy-duty fuel cell vehicles. The lifetime of the most widely used perfluorosulfonic acid membranes is limited by reactive free radicals generated inside the system. Cerium has been found to reduce the chemical degradation of the membranes. However, cerium migration during fuel cell operation limits the chemical durability enhancement effect expected from the radical scavenging activity of cerium. Here we investigate a wide range of organic immobilizers for cerium, measuring their suitability concerning cerium retention, radical scavenging activity, and fuel cell performance. We report that partially fluorinated phosphonic acids enhance cerium retention up to 45 times and reduce fluoride emission rate by 38% compared to the commercial Nafion™ XL membrane pre-impregnated with cerium. The energetics of cerium-phosphonic acid complex systems by density functional theory calculations rationalizes effective cerium immobilization.

30 DIRECT ENERGY CONVERSION↗

Noncontact temperature measurement: Requirements and applications for metals and alloys research

Temperature measurement is an essential capability for almost all areas of metals and alloys research. In the microgravity environment many of the science priorities that have been identified for metals and alloys also require noncontact temperature measurement capability. For example, in order to exploit the full potential of containerless processing, it is critical to have available a suitable noncontact temperature measurement system. This system is needed to track continuously the thermal history, including melt undercooling and rapid recalescence, of relatively small metal spheres during free-fall motion in drop tube systems. During containerless processing with levitation-based equipment, accurate noncontact temperature measurement is required to monitor one or more quasi-static samples with sufficient spatial and thermal resolution to follow the progress of solidification fronts originating in undercooled melts. In crystal growth, thermal migration, coarsening and other experiments high resolution thermal maps would be a valuable asset in the understanding and modeling of solidification processes, fluid flows and microstructure development. The science and applications requirements place several constraints on the spatial resolution, response time and accuracy of suitable instrumentation.

Perepezko, J. H.↗