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At least 937 records · Page 52

Projected Changes to Hydroclimate Seasonality in the Continental United States

Future changes to the hydrological cycle are projected in a warming world, and any shifts in drought risk may prove extremely consequential for natural and human systems. In addition to long-term moistening, drying, or warming trends, perturbations to the annual cycle of regional hydroclimate variables may also have substantial impacts. We analyze projected changes in several hydroclimate variables across the continental United States, along with shifts in the amplitude and phase of their annual cycles. We find that even in regions where no robust change in the annual mean is expected, coherent changes to the annual cycle are projected. In particular, we identify robust regional phase shifts toward earlier arrival of peak evaporation in the northern regions, and peak runoff and total soil moisture in the western regions. Changes in the amplitude of the annual cycle of total and surface soil moisture are also projected, and reflect changes to the annual cycle in surface water supply and demand. Whether changes become detectable above the background noise of internal variability depends strongly on the future scenario considered, and significant changes to the annual cycle are largely avoided in the lowest-forcing scenario.

drought↗

Predictive Integrated Stratigraphic Modeling Report, Center-wide Per- and Polyfluoroalkyl Substances, Potential Release Location 237, Kennedy Space Center, FL

The National Aeronautics and Space Administration (NASA) is investigating the occurrence of per- and polyfluoroalkyl substances (PFAS) Center-wide at Kennedy Space Center (KSC), Merritt Island, Florida (Figure 1-1) as Potential Release Location 237. AECOM Technical Services, Inc. (AECOM) conducted investigation activities in 2020 and 2021 to develop a better understanding of the fate and transport of PFAS in groundwater and surface water at KSC center-wide using PRedictive Integrated Stratigraphic Modeling (PRISM). PRISM uses best practices from the fields of geology, hydrology, and chemistry to acquire a holistic understanding of the subsurface and more accurately predict contaminant migration pathways. Based on the potential magnitude (frequency and areal distribution) of PFAS impacts at KSC, the analyses described herein were designed to provide tools to address the unique behavior of PFAS chemicals.

PFAS↗

Effects of Spaceflight Relevant Carbon Dioxide Levels on Pathogenesis Related Microbial Characteristics

BACKGROUND Multiple stressors in the spaceflight environment have the potential to alter microbial pathogenesis and virulence characteristics, including microgravity, radiation, and hostile/confined conditions. This combination of factors may lead to a stacking of risks, potentially creating unexpected increase in the risk of infectious disease. One understudied variable is the higher CO2 atmospheric concentration. The current Spaceflight Maximum Allowance Concentration (SMAC) for 24-hour average CO2 is 0.4% (3 mm Hg). These elevated ambient CO2 levels aboard the ISS could potentially influence the diversity and phenotypic responses of the resident microbial communities from both the spacecraft environment (air, surface, water) and crewmembers (gut, nasal, skin microbiomes). METHODS For these studies, we will evaluate the response of Staphylococcus aureus, Streptococcus pneumoniae and Enterobacter aerogenes, which are opportunistic pathogens that are of medical significance and have been or are likely to be found aboard spacecraft. These microorganisms will be cultured in both spaceflight analog and control conditions at CO2levels representing terrestrial atmospheric concentration of 0.04% (0.3 mmHg), ISS elevated concentration of 0.4% (3 mm Hg), and an unexpected elevated concentration of 1 % (7.6 mmHg) to represent a worst case scenario. DISCUSSION Overwhelming evidence from studies performed in food microbiology, marine biology and terrestrial environmental biology suggest altered gene expression, selective bacterial inhibition, increased growth and diversity, and increased antibiotic resistance of bacterial communities individually and in biofilm formation when exposed to increased levels of CO2. While many of these findings are based on levels of CO2 higher than would be found during spaceflight exploration missions, the potential for subtle changes in CO2 levels to exacerbate infectious disease risks warrants an evaluation of pathogen responses to spaceflight CO2 conditions. Our study will provide answers to spaceflight relevant atmospheric conditions, as described in the Risk of Adverse Health Effects Due to Host-Microorganism Interaction (GapMicro 103).

A A Medina-Colorado↗

Snow and Water Imaging Spectrometer: Final Instrument Characterization

The Snow and Water Imaging Spectrometer (SWIS) is a science-grade imaging spectrometer and telescope system suitable for CubeSat applications, spanning a 350-1700 nm spectral range with 5.7 nm sampling, a 10 degree field of view and 0.3 mrad spatial resolution. The system operates at F/1.8, providing high throughput for low-reflectivity water surfaces, while avoiding saturation over bright snow or clouds. The SWIS design utilizes heritage from previously demonstrated instruments on airborne platforms, while advancing the state of the art in compact sensors of this kind in terms of size and spectral coverage. Through frequent repeat observations from space at a moderate spatial resolution, SWIS can address key science questions concerning aquatic and terrestrial ecosystem changes, cryosphere warming and melt behavior, cloud and atmospheric science, and potential impacts of climate change and human activities on the environment. We review the optical design and innovations and key technologies developed for this instrument, as well as its measured optical performance. We discuss the radiometric calibration characterization, including detector linearity, flat field correction, and SNR. Finally, we discuss stray light modeling and the development of a focused ghost removal algorithm, which is tested and supported by laboratory results.

Bellardo, John↗

The Contribution of M-Dwarf Flares to the Thermal Escape of Potentially Habitable Planet Atmospheres

The habitability of planets around M dwarfs (. 0:5M ) can be a ected by the XUV (X rays + extreme UV) emission of these stars, with flares occasionally increasing the XUV flux by more than 2 orders of magnitude above quiescent levels. This wavelength range can warm and ionize terrestrial planets' upper atmospheres, which expands the planetary radius and promotes atmospheric loss. In this work, we study the contribution of the XUV flux due to flares on the atmospheric escape of Earth-like planets orbiting M dwarfs through numerical simulations. We considered the fi rst Gyr of planets with initial surface water abundances between 1 and 10 terrestrial oceans (TO), a small primordial hydrogen envelope ( 10􀀀3 M), and with host star masses between 0.2 and 0.6 M . In this parameter range, we fi nd that flares can remove up to two TO more than non flaring stars, which, in some cases, translates to a doubling of the total water loss. We also fi nd that flaring can increase atmospheric oxygen partial pressures by hundreds of bars in some cases. These results were obtained by adding a new module for flares to the VPLanet software package and upgrading its atmospheric escape module to account for Roche lobe overflow and radiation/recombination-limited escape.

Laura N R Do Amaral↗

Tracing the Path of Carbon Export in the Ocean though DNA Sequencing of Individual Sinking Particles

Surface phytoplankton communities were linked with the carbon they export into the deep ocean by comparing 18 S rRNA gene sequence communities from surface seawater and individually isolated sinking particles. Particles were collected in sediment traps deployed at locations in the North Pacific subtropical gyre and the California Current. DNA was isolated from individual particles, bulk-collected trap particles, and the surface seawater. The relative sequence abundance of exported phytoplankton taxa in the surface water varied across functional groups and ecosystems. Of the sequences detected in sinking particles, about half were present in large (>300 μm), individually isolated particles and primarily belonged to taxa with small cell sizes (<50 μm). Exported phytoplankton taxa detected only in bulk trap samples, and thus presumably packaged in the smaller sinking size fraction, contained taxa that typically have large cell sizes (>500 m). The effect of particle degradation on the detectable 18 S rRNA gene community differed across taxa, and differences in community composition among individual particles from the same location largely reflected differences in relative degradation state. Using these data and particle imaging, we present an approach that incorporates genetic diversity into mechanistic models of the ocean's biological carbon pump, which will lead to better quantification of the ocean’s carbon cycle.

Carbon Expert↗

Launch Complex 34, SWMU Cc054 2021 DNAPL Source Zone Operations, Maintenance, and Monitoring, and Hot Spot 6 Air Sparge System Annual Performance Monitoring Report Cape Canaveral Space Force Station, Florida

This Annual Performance Monitoring Report (PMR) for the Dense Non-Aqueous Phase Liquid (DNAPL) Source Zone (DSZ) and Hot Spot 6 (HS 6) Air Sparge (AS) System presents the results of Year 12 operation of the hydraulic containment (HC) Interim Measure (IM), the results of performance monitoring direct-push technology (DPT) sampling and monitoring well sampling conducted in the DSZ, and the results of operations and performance sampling of the HS 6 AS IM at Launch Complex 34 (LC34), located at Cape Canaveral Space Force Station (CCSFS), Florida. Site-wide biennial LTM sampling was not conducted during this reporting period and is scheduled to be conducted in December 2022. The timeframe for activities documented in this PMR extends from April 1, 2021 to March 31, 2022. LC34 has been designated Solid Waste Management Unit CC054 under the Kennedy Space Center (KSC) Resource Conservation and Recovery Act Corrective Action Program. The objective of the HC IM at LC34 is to contain the DSZ and deep dissolved-phase trichloroethene (TCE) high concentration plume via operation of a hydraulic containment system (HCS). The pre-IM design 300 micrograms per liter (μg/L) TCE groundwater contour was used to establish the deep zone capture area for deep recovery wells, and the shallow zone capture area was defined by the DSZ. The system began operating in 2010, and in 2015, the system was expanded to provide HC for areas within the 300 μg/L TCE groundwater isocontours of HS 3 and 4. In 2018 and 2019, an investigation was conducted to re-characterize the DSZ, which included investigating TCE mass in Layer 7. This data was subsequently used to optimize the pumping rates of the HCS to more adequately capture residual contaminant mass. The operational period for Year 12 of the HCS was from April 1, 2021 to March 31, 2022. Operational runtime for the system was 94 percent during Year 12, with downtime events attributed to planned maintenance, system repairs, and power outages. As of March 31, 2022, a total of 285,712,801 gallons of groundwater containing 84,933 pounds of VOCs have been removed by the HCS. Influent concentrations of TCE have decreased since startup from approximately 280,000 µg/L (January 2010) to 12,000 µg/L (March 2022). During the reporting period, all effluent concentrations from the HCS (aqueous and vapor) were below regulatory reporting limits, indicating the system continues to operate as intended. Performance monitoring was conducted in December 2021 within the DSZ to evaluate TCE contamination. Groundwater samples were collected via DPT at nine locations, consistent with previous events in 2017, 2018, 2019, and 2020. Full vertical profile sampling was completed at each DPT from 8 to 98 ft bls, at 5 foot intervals. The DPT performance monitoring results are summarized in this PMR. The results revealed TCE remains at concentrations greater than 11,000 µg/L in the DSZ (1-percent solubility, indicative of DNAPL) at eight of the nine DPT locations at depths ranging from 8 to 98 ft bls. An overall increasing trend of TCE concentrations was observed in DPT samples during this reporting period, which may be due to several recovery wells that were turned off during the AS Pilot Study in the DSZ that operated from July 2021 to February 2022 (documented separately from this report). The maximum TCE concentration in 2021 was 15,400,000 µg/L in the 58 ft bls depth interval at DPT597 (previous maximum result in 2020 was 1,690,000 at 48 ft bls at DPT596). During the 2021 DPT event, the overall majority of TCE contamination was identified in the 58 ft bls interval (below Layer 4), where in the previous year the majority of mass was observed in Layer 4. This trend appears to indicate continued mass discharge from Layer 4 (fine-grained unit). In addition to DPT sampling, monitoring well samples were collected from deep wells in the DSZ area (Layers 7 and 8) to verify vertical delineation. All monitoring well results were non-detect or below cleanup levels, with exception of one well (IW0162, screened 105 to 115 ft bls, which is below the existing recovery well capture zone) where TCE was identified above cleanup target levels. The HS 6 AS system remained operational during the reporting period covered under this report. The HS 6 AS IM was initiated in 2018 with 160 AS wells, and expanded in 2019 with an additional 140 AS wells. Quarterly performance monitoring was reduced to semi-annual prior to this operational period. The results of the HS 6 system operation and semi-annual performance monitoring are summarized in this report. Semi-annual monitoring results collected in April and October 2021 show concentrations of contaminants of concern (cis-1,2-dichloroethene, trans-1,2- dichloroethene, and vinyl chloride) are generally decreasing and not impacting the surface water drainage canal, indicating the HS 6 IM is meeting objectives. Overall, the tasks associated with Year 12 operation of the HC IM and operation of the HS 6 AS IM were performed in accordance with the recommendations of the 2020 LC34 (Year 11) Operations, Maintenance, and Monitoring Report for DNAPL Source Zone, Site Wide LongTerm Monitoring, and Hot Spot 6 Air Sparging System PMR (NASA, 2021c). Evaluation of results from the HC IM and HS 6 IM show that these systems are operating as designed and meeting performance objectives.

trichloroethene↗

Making Better Use of Satellite Data: The Satellite Needs Working Group

The U.S. Group on Earth Observations (USGEO) initiated in 2016 the Satellite Needs Working Group (SNWG) to identify and communicate the Earth observation needs of U.S. federal agencies. The SNWG identifies such needs through a biennial survey followed by interviews and follow-up discussions by the satellite Earth data providers of the U.S. Government: the National Aeronautics and Space Administration (NASA), the National Oceanic and Atmospheric Administration (NOAA), and the U.S. Geological Survey (USGS). Solutions and services are identified that leverage current or upcoming satellite missions to meet the identified needs; implementation of services that are estimated to significantly increase the level of satisfaction of multiple U.S. agencies are funded by NASA. The SNWG process has resulted in the implementation of numerous services that have impacted operations of not only U.S. agencies but of academic and international institutions as well. Notable examples include the Harmonized Landsat Sentinel-2 project that leverages European Space Agency (ESA) and NASA satellite assets to generate a global, analysis-ready, surface reflectance product with a temporal resolution of two days; the Airborne Data Management Group that curates and provides access to relevant resources, information and data from existing and past NASA field campaigns; and the Dynamic Surface Water Extent product which consists of harmonized but independent water extents derived from both from optical and radar data. These and other products are hosted at the NASA Distributed Active Archive Centers (DAACs) for free and open access. The SNWG Management Office at NASA’s Interagency Implementation and Advanced Concepts Team (IMPACT) manages the implementation of selected solutions and, importantly, NASA’s response to the needs of federal agencies through a Stakeholder Engagement Program. The impact of implemented services and solutions is hampered without efforts to build capacity around the use of the services. The Stakeholder Engagement Program ensures relevant training and outreach to SNWG agencies in collaboration with each solution implementation team.

remote sensing↗

InVEST Urban Development: Incorporating Earth Observation Data into the Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) Urban Flood Risk Mitigation Model Python API

Urban flooding poses as one of the biggest issues for cities today, as its impacts are amplified by both climate change and urbanization. The Natural Capital Project’s Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) Urban Flood Risk Mitigation (UFRM) model, which benefits from its simplicity and robustness, is commonly used in NASA DEVELOP projects for disaster mitigation, urban planning, and environmental justice issues. While InVEST UFRM model was able to produce the surface water runoff and retention map sufficient for the scopes of past projects, the model accuracy and spatial variability need improvement. Since the current InVEST UFRM model employs constant rainfall depth for all pixels in the area of interest (AOI), the model suffers from inaccurately estimating rainfall depth, runoff volume, and flood depth. Therefore, we adapted the model so that satellite-based precipitation raster datasets (i.e., Integrated Multi-satellitE Retrievals for Global Precipitation Measurement [GPM IMERG]) can be used instead of a single constant value. We simulated the flood events on August 21st and August 22nd, 2017 in Wyandotte County, Kansas using both our modified and the original InVEST UFRM model and then compared the results after incorporating the rainfall raster into the model. Areas with developed land on the land use map predicted moderate to high flood volume in the original volume regardless of the actual amount of precipitation. The modified model considered the rainfall depth’s spatial variation achieving less overestimation of flood runoff and volume at low-to-moderate rainfall area.

Son Do↗

SWOT and NISAR Boom Ground Deployment Test Challenges & Resolution

NASA’s Jet Propulsion Laboratory is developing two new spacecraft that use radar instruments to characterize temporal changes in the Earth’s surface with unprecedented precision (Figure 1). Both the Surface Water Ocean Topography (SWOT) and the NASA-ISRO Synthetic Aperture Radar (NISAR) spacecraft utilize large, precision flight deployable booms to properly position and support their instrument reflectors. The SWOT spacecraft includes two nearly identical reflector booms, each of which have similar flight deployable hinge designs. The NISAR spacecraft has a single reflector boom, with four unique hinge designs. These booms each undergo a multi-staged flight deployment sequence on orbit to transition from the launch stowed configuration to the science configuration within days of launch (Figure 2). The SWOT and NISAR Projects faced significant challenges relevant to requirement verification as well as hardware safety in their approach to ground testing these large flight deployables. This report summarizes flight deployable system design decisions that contributed to ground testing challenges. The report also summarizes the architecture trade study conducted for ground deployment testing. A summary of key issues encountered during flight deployable ground testing with the chosen common gravity offload system ensues, with discussion of the issues and mitigation measures implemented by both Projects that ultimately enabled successful flight subsystem-level full range of motion ground tests. Recommendations and lessons learned are offered to facilitate ground testability of future analogous large scale flight deployables.

Waters, Kyle C.↗

InVEST Urban Development: Incorporating Earth Observation Data into the Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) Urban Flood Risk Mitigation Model Python API

Urban flooding poses as one of the biggest issues for cities today as its impacts are amplified by both climate change and urbanization. The Natural Capital Project’s Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) Urban Flood Risk Mitigation (UFRM) model, which benefits from its simplicity and robustness, is commonly used in NASA DEVELOP projects for disaster mitigation, urban planning, and environmental justice issues. While the InVEST UFRM model was able to produce the surface water runoff and retention map sufficient for the scopes of past projects, the model’s accuracy and spatial variability need improvement. Since the current InVEST UFRM model employs constant rainfall depth for all pixels in the area of interest (AOI), the model suffers from inaccurately estimating rainfall depth, runoff volume, and flood depth. Therefore, we adapted the model so that satellite-based precipitation raster datasets (i.e., Integrated Multi-satellitE Retrievals for Global Precipitation Measurement [GPM IMERG]) can be used instead of a single constant value. We simulated the flood events on August 21st and August 22nd, 2017, in Wyandotte County, Kansas using both our modified and the original InVEST UFRM model and then compared the results after incorporating rainfall raster into the model. Areas with developed land on the land use map predicted moderate to high flood volume in the original volume regardless of the actual amount of precipitation. The modified model considered the rainfall depth’s spatial variation achieving less overestimation of flood runoff and volume at low-to-moderate rainfall area.

Urban flooding↗

Night Sky Testing of the Lunar Flashlight Star Tracker

Lunar Flashlight (LF) is a 6U, 14 kg spacecraft being built by the NASA Jet Propulsion Laboratory (JPL). The mission will use IR laser technology to search for volatiles and surface water ice deposits in the permanently shadowed regions (PSR) of the moon in preparation for future human lunar exploration. The fine pointing provided by the Guidance, Navigation and Control (GNC) system is crucial for the spacecraft to successfully reach the moon, enter a lunar orbit, and acquire scientific data. At the center of the GNC system’s ability to determine the spacecraft’s attitude is a star tracker. The LF star tracker is a commercial-off-the-shelf (COTS) unit built into the integrated GNC system provided by Blue Canyon Technologies. Blue Canyon tested the star tracker in a lab environment for basic functionality and attitude estimation capabilities; upon delivery of the hardware to JPL, further testing with a real night sky was desired to determine expected in-flight operational characteristics. JPL maintains the Table Mountain Facility with its suite of ground telescopes, including a 0.6m telescope with an equatorial mount. This stable platform provided a highly accurate method of providing slews and attitude holds akin to what the spacecraft will perform in flight. Therefore, by analyzing the data from these representative night-sky ground tests performed in March, 2021, it is possible to acquire expected flight performance of the star tracker, particularly in regard to the ability of the star tracker to maintain lock on the starfield during planned maneuver types. This paper presents the various tests that have been performed to ensure that the LF star tracker will function as part of the overall GNC system and integrated spacecraft once launched. Test data is included for several key tests, and a path forward towards future integration and testing at the spacecraft level is described.

Baker, John↗

Synergies Between Venus and Exoplanetary Observations

• How can Venus help inform Exoplanetary studies? 1. Volatile Cycling & Weathering on Venus Through Time (Foley, Höning) a) Weathering on Venus : surface water, land area, tectonic state i. Evidence for running water in tesserae? Khawja et al. 2020 ii. D/H Ratio? Hoffman et al. 1980 b) Volcanism & Outgassing: Is SO2 a proxy for on-going volcanism? c) Volatile in-gassing: Does subduction occur today? (Davaille et al.) 2. Venus’ Magnetic Field (O’Rourke) a) Is Venus’ slower interior cooling responsible for lack of magnetic field? b) Lack of a late energetic impactor (Jacobsson et al.): stable density gradients? c) Is mass a factor: larger super-Venus/Earth more likely to have magnetic field?

Exoplanets↗

Oregon Coast Range Ecological Conservation: Mapping Recent Logging Within Drinking Watersheds of Oregon’s Coastal Range to Support Future Resource Management Policies

Logging operations are widespread across the Oregon Coast Range and conventional logging practices pose a risk of contamination to surface water quality. The NASA DEVELOP Oregon Coast Ecological Conservation team partnered with nonprofit Oregon Wild to quantify the extent of clearcutting and commercial thinning in 80 Coast Range drinking watersheds between 2000 and 2022. This project used all available Landsat data from 1997 through June 2023 in Google Earth Engine. Sensors used include Landsat 5 Thematic Mapper, Landsat 7 Enhanced Thematic Mapper Plus, Landsat 8 Operational Land Imager, and Landsat 9 Operational Land Imager-2. The Continuous Change Detection and Classification (CCDC) algorithm was used with Landsat observations to identify clearcutting patches. Percent change in summer median Landsat Normalized Difference Vegetation Index (NDVI) images were used to identify areas of forest disturbance including commercial thinning. The team concluded that logging, including both clearcutting and commercial thinning, impacted 31% of forested area in drinking watersheds and the intensity of logging remained consistent from year to year. Clearcutting occurred primarily on private land while commercial thinning occurred primarily on state and federal lands. This study showed that CCDC effectively identifies clearcutting, and percent change in NDVI successfully identifies disturbances including commercial thinning. Key constraints included the lack of field validation data and the inability to attribute disturbances to logging with certainty. Ultimately, this study identified the drinking watersheds and communities most likely to be impacted by logging activity. These results can inform legislation aimed at balancing the commercial and environmental benefits of forestlands.

Logging↗

South Repeater Building (Swmu 121) Pilot Study Work Plan, Kennedy Space Center, Florida

This document is a Pilot Study Work Plan for a groundwater remediation system at the South Repeater Building (N6-1118) located at the John F. Kennedy Space Center (KSC), Florida. Aqueous fire-fighting foam was applied near the building in the late 1990s during a wildfire. Per- and polyfluoroalkyl substances (PFAS) are components of the foam. Sampling completed at and near the South Repeater Building identified PFAS in groundwater, surface water and soil. KSC is planning to design and install a groundwater remediation system to address the potential for off-Center migration of PFAS compounds in groundwater. This Pilot Study Work Plan outlines subsurface hydrogeologic data that will be collected to use in the construction of a groundwater flow model that will guide the design of a full-scale remediation system. This document was prepared by AECOM Technical Services, Inc., for NASA under Indefinite Delivery Indefinite Quantity Contract 80KSC019D0010, Task Order 80KSC019F0096.

PFAS↗

2024 IEEE GRSS Data Fusion Contest Flood Rapid Mapping

The Challenge Task As a result of climate change, extreme hydrometeorological events are becoming increasingly frequent. Flood rapid mapping products play an important role in informing flood emergency response and management. These maps are generated quickly from remote sensing data during or after an event to show the extent of flooding. They provide important information for emergency response, and damage assessment. The aim of this challenge is to develop data fusion algorithms that generate flood maps by processing spatial data from a variety of sources. The goal of this IEEE challenge (sponsored by NASA and CNES) is to design and develop an algorithm that will combine multi-source data to classify flood surface water extent–that is, water and non-water areas. Provided data sources include optical and SAR remote sensing images as well as a digital terrain model. The output is a gridded flood map where each grid cell is labeled water or non-water. The difficulty of detecting flooded areas can vary greatly depending on the conditions in the area of interest and the event. This data fusion challenge has two tracks representing this variance.

Jacqueline J Le Moigne-stewart↗

Zarr stores in NASA's EOSDIS

Data hosted by the National Aeronautics and Space Administration (NASA) are expected to increase to over 600 PB by the end of the decade (see Figure 1). This rapid increase is, in part, driven by the launch of new, high-data-volume Earth observing missions, such as the NASA-Indian Space Research Organisation (ISRO) Synthetic Aperture Radar (NISAR), Surface Water and Ocean Topography (SWOT), Tropospheric Emissions: Monitoring of Pollution (TEMPO) and Plankton, Aerosol, Cloud ocean Ecosystem (PACE) missions.

Owen Littlejohns↗

Launch Complex 34, SWMU CCO542022 DNAPL Source Zone Operations, Maintenance, and Monitoring, Site-Wide Long-Term Monitoring, and Hot Spot 6 Air Sparge System Annual Performance Monitoring Report Cape Canaveral Space Force Station, Florida

This Annual Performance Monitoring Report (PMR) for the Dense Non-Aqueous Phase Liquid (DNAPL) Source Zone (DSZ), Site-Wide Long-Term Monitoring (LTM), and Hot Spot (HS) 6 Air Sparge (AS) System presents the results of Year 13 operation of the hydraulic containment (HC) Interim Measure (IM), the results of performance monitoring direct-push technology (DPT) sampling and monitoring well sampling conducted in the DSZ, results of the biennial site-wide LTM event, and the results of operations and performance sampling of the HS 6 AS IM at Launch Complex 34 (LC34), located at Cape Canaveral Space Force Station (CCSFS), Florida. This site has been designated Solid Waste Management Unit (SWMU) CC054 under the Kennedy Space Center (KSC) Resource Conservation and Recovery Act (RCRA) Corrective Action Program. For the site-wide biennial LTM event, a total of 55 monitoring wells were sampled for volatile organic compounds (VOCs) in February 2023 and one well was sampled for polychlorinated biphenyls (PCBs) in December 2022. One well planned for VOC sampling was found to be destroyed and could not be sampled (CW0002). The LTM wells are screened in two lithologic zones: Layer 1 (0 to 25 feet below land surface [bls]) and Layer 2 (25 to 30 ft bls), and are located in the outlying areas of LC34 to monitor groundwater conditions within the Low-Concentration Plume (LCP), defined as concentrations exceeding Groundwater Cleanup Target Levels (GCTLs), and the High-Concentration Plume (HCP), defined as concentrations exceeding Natural Attenuation Default Concentrations (NADCs). Results from the biennial sampling event indicated overall plume stability and delineation for the plume, which extends over 300 acres. The operational period for Year 13 of the HCS was from April 1, 2022 to March 31, 2023. Operational runtime for the system was 90 percent during Year 13, with downtime events attributed to planned maintenance, system repairs, and power outages. As of March 31, 2023, a total of 313,673,241 cumulative gallons of groundwater containing 88,337 pounds of VOCs have been removed by the HCS. Influent concentrations of trichloroethene (TCE) have decreased since startup from approximately 280,000 μg/L (January 2010) to 12,000 μg/L (March 2023). During the reporting period, all effluent concentrations from the HCS (aqueous and vapor) were below regulatory reporting limits, indicating the system continues to operate as intended. Performance monitoring was conducted in December 2022 within the DSZ to evaluate TCE contamination. Groundwater samples were collected via DPT at nine locations, consistent with previous events between 2017 and 2021. Full vertical profile sampling was completed at each DPT from 8 to 98 feet bls, at 5-foot intervals. The DPT performance monitoring results are summarized in this PMR. The results revealed TCE remains at concentrations greater than 11,000 μg/L in the DSZ (1-percent solubility, indicative of DNAPL) at eight of the nine DPT locations and at depths ranging from 8 to 98 feet bls. In addition to DPT sampling, groundwater samples were collected from deep monitoring wells in the DSZ area (Layers 7 and 8) in December 2022 to verify vertical delineation. Layer 7/8 monitoring well results were non-detect in December 2022, with exception of three wells (IW0162, IW043D2, and IW044D2), where TCE, cis-1,2-dichloroethene (cDCE), and/or vinyl chloride (VC) were detected above GCTLs. These wells are screened 105 to 115 feet bls, which is below the existing recovery well capture zone. TCE was first detected in IW0162 in December 2021 and has since been sampled at least monthly to monitor TCE concentrations. The maximum TCE concentration during this operational period was 15,000 μg/L at IW0162 in March 2023. Because of the increased TCE concentrations in this well, a new recovery well (RW21D), screened 86 to 106 feet bls, was installed in January 2023 and incorporated into existing HCS operations. The HS 6 AS IM was initiated in 2018 with 160 AS wells, and expanded in 2019 with an additional 140 AS wells. Quarterly performance monitoring was reduced to semi-annual in 2020. The HS 6 AS system remained operational during the reporting period covered under this report. The results of the HS 6 system operation and semi-annual performance monitoring are summarized in this report. Semi-annual monitoring results collected in April and October 2022 show concentrations of contaminants of concern (cDCE, trans-1,2-dichloroethene, and vinyl chloride) are generally decreasing and not impacting the surface water drainage canal, indicating the HS 6 IM is meeting objectives. A Phase Two Expansion of the HS 6 AS IM was recently completed. As of the date of this report, the expansion became operational in August 2023 and the first quarter of monitoring was conducted in November 2023. Details of the construction, start-up, and performance monitoring will be included in a future Annual PMR. Overall, the tasks associated with Year 13 operation of the HC IM, operation of the HS 6 AS IM, and biennial site-wide sampling were performed in accordance with recommendations included in the previous 2021 LC34 (Year 12) annual report. Evaluation of results from the HC IM and HS 6 IM show that these systems are operating as designed and meeting performance objectives. Results from the site-wide biennial LTM program also show that the overall network of monitoring wells is adequate to continue monitoring plume-wide conditions.

Complex 34↗