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At least 937 records · Page 52

Experimental investigation of the Marangoni effect on the stability of a double-diffusive layer

Stability experiments were carried out in 4-cm-thick, salt-stratified fluid layer by heating from below and cooling from above. The bottom boundary was rigid while the top was either free or rigid. The initial solute Rayleigh number varied from 2.5 x 10(exp 6) to 4.6 x 10(exp 7). For the rigid-free case, at initial solute Rayleigh numbers R(sub s) greater than 5.4 x 10(exp 6), thermal Marangoni instabilities were observed to onset along the free surface at a relatively low thermal Rayleigh number, R(sub t). The convection was very weak, and it had almost no effect on the concentration and temperature distributions. Double-diffusive instabilities along the top free surface were observed to onset at a higher R(sub t), with much stronger convection causing changes in the concentration and temperature distributions near the top. At a yet higher R(sub t), double-diffusive convection was observed to onset along the bottom boundary. Fluid motion in the layer then evolved into fully developed thermal convection of a homogeneous fluid without any further increase in the imposed Delta T. For layers with R(sub s) less than 5.4 x 10(exp 6), Marangoni and double-diffusive instabilities onset simultaneously along the free surface first, while double-diffusive instabilities along the bottom wall onset at a higher R(sub t).

Tanny, Josef↗

Three-Dimensional Surface Downwelling Longwave Radiation Clear-Sky Effects in the Upper Colorado River Basin

In complex terrain, non-parallel surfaces receive emitted radiation from adjacent surfaces. Qualitatively, where surface skin temperatures and lower tropospheric temperature and humidity are not uniform, the downwelling longwave radiation (DLR) will be determined not just by radiation from the atmosphere above a given location, but also by adjacent surface temperatures. We quantify this three-dimensional longwave radiative effect over the Upper Colorado River Basin in clear-sky conditions by calculating surface DLR with observed land-surface temperatures from ECOSTRESS. We find that this effect is due to terrain-subtended sky-view and represents ~22% of the surface longwave flux, rising to ~28% and ~24% in the East and Southeast of the Basin, respectively, and can be >50% in extreme cases. The common omission of this effect in atmospheric radiation models leads to an underestimation of DLR in complex terrain, especially at higher elevations, which has significant implications for mountainous ecohydrology simulations.

3-dimensional effects↗

Exchange bias and quantum anomalous nomalous Hall effect in the MnBi 2 Te 4 /CrI 3 heterostructure

The layered antiferromagnetic MnBi 2 Te 4 films have been proposed to be an intrinsic quantum anomalous Hall (QAH) insulator with a large gap. It is crucial to open a magnetic gap of surface states. However, recent experiments have observed gapless surface states, indicating the absence of out-of-plane surface magnetism, and thus, the quantized Hall resistance can only be achieved at the magnetic field above 6 T. We propose to induce out-of-plane surface magnetism of MnBi 2 Te 4 films via the magnetic proximity with magnetic insulator CrI 3 . A strong exchange bias of ~40 meV originates from the long Cr- e g orbital tails that hybridize strongly with Te p orbitals. By stabilizing surface magnetism, the QAH effect can be realized in the MnBi 2 Te 4 /CrI 3 heterostructure. Moreover, the high–Chern number QAH state can be achieved by controlling external electric gates. Thus, the MnBi 2 Te 4 /CrI 3 heterostructure provides a promising platform to realize the electrically tunable zero-field QAH effect.

36 MATERIALS SCIENCE↗

Surface Film Formation on Al-V Alloys with Far-From-Equilibrium Microstructure

Nanocrystalline supersaturated Al-V alloys produced by high-energy ball milling have been reported to exhibit enhanced corrosion resistance and mechanical properties compared to commercial Al alloys. Corrosion of passive alloys such as Al-V alloy relies on the characteristics of the surface film, which is studied using scanning/transmission electron microscopy and time-of-flight secondary ion mass spectrometry. The effect of microstructure and composition on the surface film has been investigated after different immersion periods (30 min, 2 h, and 1 day) in 0.1 M NaCl. The surface film was complex and composed of oxidized Al and V. The heterogeneous surface film was observed due to the presence of secondary phases and initiation of localized corrosion. The void formation was observed beneath the surface film that would potentially cause pitting corrosion. The generation of nano-sized voids was dependent on grain orientation. Compared to pure Al, the chloride penetration is suppressed in Al-V alloys. The effect of composition and microstructure on surface film formation and attendant corrosion behavior is discussed herein.

36 MATERIALS SCIENCE↗

Contrasting Trends in Colorado Fire Weather Index from Reanalysis and Observations

Recent wildfires in Colorado raise the question of whether rising global temperatures have increased fire weather occurrences in Colorado. The U.S. National Weather Service defines fire weather as when “forecast weather conditions will result in a significant threat for the ignition and/or spread of wildfires.” We use two datasets to address the question: “How has the occurrence of fire weather changed in Colorado?” Using 22 years of observed weather conditions from a meteorological tower at the National Renewable Energy Laboratory and 67 years of ERA5 reanalysis data, we assess changing trends in Colorado fire weather as defined by hot, dry, and windy conditions. Additionally, we explore if the difference in recorded wind speeds between observational data and reanalysis data can be explained by differences in spatial and temporal resolution and what are the implications in the context of quantifying fire weather occurrences. The observational data are limited in temporal extent and spatial representativeness, but they capture exact real-world conditions at a location in complex terrain. The reanalysis data are available for an extended period of time and for the entire state, but the data are of relatively coarse spatial and temporal resolution and may fail to capture extremes. To quantify fire risk, we calculate the hot–dry–windy index (HDWI), which relies on wind speed and vapor pressure deficit. No statistically significant trend in the HDWI appears in the observational dataset. However, according to the reanalysis data, strong increasing trends in HDWI values emerge across all of Colorado. This apparent conflict between observational and reanalysis data suggests that reanalysis data may not be representative. Further, more long-term observational datasets are required to assess fire risk.

17 WIND ENERGY↗

Calibrated Radar Wind Profiler (RWP) Moments

The SGP Central Facility (C1) radar wind profiler (RWP) was calibrated using nearby surface disdrometer observations. Between 2011 and 2019, the SGP C1 RWP operated in two modes. The vertically pointing mode (named the precipitation mode) transmitted a short and long pulse length to have two different range resolutions and the beam-swinging mode (named the wind mode) transmitted one pulse length into three different beam directions. The precipitation-mode observations were available and calibrated from April 2011 through mid-August 2019. The wind-mode observations were available and calibrated between April 2014 and March 2019. The RWP spectra were processed to account for Nyquist velocity aliasing and coherent integration filtering effects before calculating the spectrum moments. During intense precipitation events, the calculated signal-to-noise ratio (SNR) is biased low due to signal power being distributed across the velocity spectrum such that some signal power is erroneously included in the noise level estimate, causing the noise level to be biased high. To correct for the low SNR bias, a new noise level is estimated using observations without precipitation and the SNR is increased accordingly. The adjusted SNR was converted to radar reflectivity factor and then calibrated against a nearby surface disdrometer. The calibration methodology is fully described in: Williams, CR, J Barrio, PE Johnston, P Muradyan, and S Giangrande. 2023. “Calibrating radar wind profiler reflectivity factor using surface disdrometer observations.” Atmospheric Measurement Techniques, https://egusphere.copernicus.org/preprints/2023/egusphere-2022-1405/

54 ENVIRONMENTAL SCIENCES↗

Sapphire fiber interferometer for microdisplacement measurements at high temperatures

We report the use of a short-length, multimode sapphire rod as an extension to a Michelson configuration, but operated as a low-finesse Fabry-Perot cavity. We demonstrate the performance of such a device as an interferometric sensor, where the interference between the reflections from the sapphire-air interface and an air-metallic surface is observed for microdisplacement of the metallic surface which is placed close to the sapphire endface. We describe in detail the fabrication procedure and present results obtained from the detection of temperature changes, applied strain, and surface acoustic waves.

Murphy, Kent A.↗

Soot Surface Oxidation in Laminar Hydrocarbon/Air Diffusion Flames at Atmospheric Pressure

Soot surface oxidation was studied experimentally in laminar hydrocarbon/air diffusion flames at atmospheric pressure. Measurements were carried out along the axes of round fuel jets burning in coflowing dry air considering acetylene-nitrogen, ethylene, propyiene-nitrogen, propane and acetylene-benzene-nitrogen in the fuel stream. Measurements were limited to the initial stages of soot oxidation (carbon consumption less than 70%) where soot oxidation occurs at the surface of primary soot particles. The following properties were measured as a function of distance above the burner exit: soot concentrations by deconvoluted laser extinction, soot temperatures by deconvoluted multiline emission, soot structure by thermophoretic sampling and analysis using Transmission Electron Microscopy (TEM), concentrations of major stable gas species (N2, H2O, H2, O2, CO, CO2, CH4, C2H2, C2H6, C3H6, C3H8, and C6H6) by sampling and gas chromatography, concentrations of some radical species (H, OH, O) by deconvoluted Li/LiOH atomic absorption and flow velocities by laser velocimetry. For present test conditions, it was found that soot surface oxidation rates were not affected by fuel type, that direct rates of soot surface oxidation by O2 estimated from Nagle and Strickland-Constable (1962) were small compared to observed soot surface oxidation rates because soot surface oxidation was completed near the flame sheet where O2 concentrations were less than 3% by volume, and that soot surface oxidation rates were described by the OH soot surface oxidation mechanism with a collision efficiency of 0.14 and an uncertainty (95% confidence) of +/- 0.04 when allowing for direct soot surface oxidation by O2, which is in reasonably good agreement with earlier observations of soot surface oxidation rates in both premixed and diffusion flames at atmospheric pressure.

Xu, F.↗

Correction to "Influence of Dust and Black Carbon on the Snow Albedo in the NASA Goddard Earth Observing System Version 5 Land Surface Model"

The website information describing the forcing meteorological data used for the land surface model (LSM) simulation, which were observed at an Automated Meteorological Station CAWS) at the Sapporo District Meteorological Observatory maintained by the Japan Meteorological Agency (JMA), was missing from the text. The 1-hourly data were obtained from the website of Kisyoutoukeijouhou (Information for available JMA-observed meteorological data in the past) on the website of JMA (in Japanese) (available at: http://www.jma.go.jpijmaimenulreport.html). The measurement height information of 59.5 m for the anemometer at the Sapporo Observatory was also obtained from the website of JMA (in Japanese) (available at: http://www.jma.go.jp/jma/menu/report.html). In addition, the converted 10-m wind speed, based on the AWS/JMA data, was further converted to a 2-m wind speed prior to its use with the land model as a usual treatment of off-line Catchment simulation. Please ignore the ice absorption data on the website mentioned in paragraph [15] which was not used for our calculations (but the data on the website was mostly the same as the estimated ice absorption coefficients by the following method because they partially used the same data by Warren [1984]). We calculated the ice absorption coefficients with the method mentioned in the same paragraph, for which some of the refractive index data by Warren [1984] were used and then interpolated between wavelengths, and also mentioned in paragraph [20] for the visible (VIS) and near-infrared (NIR) ranges. The optical data we used were interpolated between wavelengths as necessary.

Yasunari, Teppei J.↗

VHF SoOp (Signal of Opportunity) Technology Demonstration for Soil Moisture Measurement Using Microwave Hydraulic Boom Truck Platform

A goal of this research is to test deployable VHF antennas for 6U Cubesat platforms to enable validation of root zone soil moisture (RZSM) estimation algorithms for signal of opportunity (SoOp) remote sensing over the 240-270 MHz frequency band. The proposed work provides a strong foundation for establishing a technology development path for maturing a global direct surface soil moisture (SM) and RZSM measurement system over a variety of land covers. Knowledge of RZSM up to a depth of 1 meter and surface SM up to a depth of 0.05 meter on a global scale, at a spatial resolution of 1-10 km through moderate-to-heavy vegetation, is critical to understanding global water resources and the vertical moisture gradient in the Earths surface layer which controls moisture interactions between the soil, vegetation, and atmosphere. Current observations of surface SM from space by L-band radiometers (1.4 GHz) and radars (1.26 GHz) are limited to measurements of surface SM up to a depth of 0.05 meter through moderate amounts of vegetation. This limitation is mainly due to the inability of L-band signals to penetrate through dense vegetation and deep into the soil column. Satellite observations of the surface moisture conditions are coupled to sophisticated models which extrapolate the surface SM into the root zone, thus providing an indirect estimate rather than a direct measurement of RZSM. To overcome this limitation, low-frequency airborne radars operating at 435 MHz and 118 MHz have been investigated, since these lower frequencies should penetrate denser vegetation and respond to conditions deeper in the soil.

SoOp↗

Initial Characterization of the Second A709 Commercial Heat

In fiscal year 2021, Idaho National Laboratory (INL) received the second commercial heat of A709 in the plate-product form, heat 529900. The chemistry, microstructure, and mechanical properties of this heat were characterized. Heat 529900 met the chemistry and mechanical property requirements specified for UNS S31025 in American Society for Testing and Materials (ASTM) A213 and American Society of Mechanical Engineers SA 213 for seamless tube which A709 was derived from. The microstructure of heat 529900 was comprised of equiaxed, recrystallized grains and elongated, unrecrystallized grains. The frequency of the unrecrystallized grains varied across the thickness of the plate with the highest frequency observed at the surface and none observed at the center. The equiaxed grain size of heat 529900 ranged from an ASTM grain size number 4 to an ASTM grain size number 6. The size of the equiaxed grains varied across the thickness of the plate with the coarsest grains located at the center of the plate. Additionally, the creep-fatigue properties of the second commercial heat were better than those of the first commercial heat.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Influence of annealing on the photodeposition of silver on periodically poled lithium niobate

The preferential deposition of metal nanoparticles onto periodically poled lithium niobate surfaces, whereby photogenerated electrons accumulate in accordance with local electric fields and reduce metal ions from solution, is known to depend on the intensity and wavelength of the illumination and the concentration of the solution used. Here, it is shown that for identical deposition conditions (wavelength, intensity, concentration), post-poling annealing for 10 h at 200 °C modifies the surface reactivity through the reorientation of internal defect fields. Whereas silver nanoparticles deposit preferentially on the +z domains on unannealed crystals, the deposition occurs preferentially along 180° domain walls for annealed crystals. In neither case is the deposition selective; limited deposition occurs also on the unannealed –z domain surface and on both annealed domain surfaces. The observed behavior is attributed to a relaxation of the poling-induced defect frustration mediated by Li{sup +} ion mobility during annealing, which affects the accumulation of electrons, thereby changing the surface reactivity. The evolution of the defect field with temperature is corroborated using Raman spectroscopy.

36 MATERIALS SCIENCE↗

Hydrogen desorption kinetics for aqueous hydrogen fluoride and remote hydrogen plasma processed silicon (001) surfaces

The desorption kinetics of molecular hydrogen (H{sub 2}) from silicon (001) surfaces exposed to aqueous hydrogen fluoride and remote hydrogen plasmas were examined using temperature programmed desorption. Multiple H{sub 2} desorption states were observed and attributed to surface monohydride (SiH), di/trihydride (SiH{sub 2/3}), and hydroxide (SiOH) species, subsurface hydrogen trapped at defects, and hydrogen evolved during the desorption of surface oxides. The observed surface hydride species were dependent on the surface temperature during hydrogen plasma exposure with mono, di, and trihydride species being observed after low temperature exposure (150 °C), while predominantly monohydride species were observed after higher temperature exposure (450 °C). The ratio of surface versus subsurface H{sub 2} desorption was also found to be dependent on the substrate temperature with 150 °C remote hydrogen plasma exposure generally leading to more H{sub 2} evolved from subsurface states and 450 °C exposure leading to more H{sub 2} desorption from surface SiH{sub x} species. Additional surface desorption states were observed, which were attributed to H{sub 2} desorption from Si (111) facets formed as a result of surface etching by the remote hydrogen plasma or aqueous hydrogen fluoride treatment. The kinetics of surface H{sub 2} desorption were found to be in excellent agreement with prior investigations of silicon surfaces exposed to thermally generated atomic hydrogen.

36 MATERIALS SCIENCE↗

Assessment of CMIP5 and CMIP6 AMIP Simulated Clouds and Surface Shortwave Radiation Using ARM Observations over Different Climate Regions

The simulations of clouds and surface radiation from 10 CMIP6 models and their CMIP5 predecessors are compared to the ARM ground-based observations over different climate regions. Compared to the ARM radar-lidar derived total cloud fractions (CFT) and cloud fraction vertical distributions over the six selected sites, both CMIP5 and CMIP6 significantly underestimated CFT and low-level CF over the Northern Hemispheric midlatitude sites (SGPC1 and ENAC1), although the biases are generally smaller in CMIP6. Over the tropical oceanic site (TWPC2), 5 out of 10 CMIP6 models better simulated low-level CF than their CMIP5 predecessors. CMIP6 simulations generally agreed well with the ARM observations in CFT and cloud fraction vertical distributions over the tropical continental (MAOM1) and coastal (TWPC3) sites but missed the transitions between dry and wet seasons, similar to CMIP5 simulations. The improvements in downwelling shortwave fluxes (SWdn) at the surface from the majority of CMIP6 compared to CMIP5 primarily resulted from the improved cloud fraction simulations, especially over the SGPC1, ENAC1, and TWPC3 sites. By contrast, both CMIP5 and CMIP6 models exhibited diverse performances of clouds and shortwave radiation over the Arctic site (NSAC1), where CMIP6 models produced more clouds than CMIP5 models, especially for the low-level clouds. The comparisons between observations and CMIP5 and CMIP6 simulations provide valuable quantitative assessments of the accuracy of mean states and variabilities in the model simulations and shed light on general directions to improve climate models in different regions.

54 ENVIRONMENTAL SCIENCES↗

NASA Spaceborne Radar Missions: CloudSat and QuickScat: To Observe Clouds and Sea Surface Winds

CloudSat is a joint US/Canadian spaceborne science mission for global measurements of atmospheric cloud structures. Cloud Profiling Radar (CPR) has already captured many stunning profiles of cloud/precipitation structures, some have not been seen before. Observation of storms' cloud formation, in conjunction with data from other remote sensors, will hopefully improve quality of natural hazards' forecasts.

CloudSat↗

The Surface Longwave Downward Fluxes of the NASA GEWEX SRB Release 4.0 IP Products: Validation Against the Surface-Based BSRN and PMEL Observed Data

Since the NASA Global Energy Water Exchanges (GEWEX) Surface Radiation Budget (SRB) project released its 3rd version of products in 2010, the GEWEX Data Assessments Panel (GDAP) has been working on integrating various data products to address issues in the closing of the global energy and water cycles. The 4th version of the SRB products, Rel. 4.0-IP, has integrated data products from the cloud, aerosol, atmosphere, ocean surface, and land surface projects, coordinating within GDAP, to produce a long-term time series of TOA and surface radiative estimates. The Rel. 4-IP shortwave products span 34 years continuously from July 1983 to June 2017 on a quasi-equal-area 1degree longitude by 1degree latitude grid system. The longwave products are for land only from 1983-07 to 1987-12; for both land and ocean from 1988-01 to 2009-12; and ocean only from 2010-01 to 2017-06. The data are provided at 3 hourly, 3-hourly-monthly, daily and monthly means. The ISCCP HXS clouds and radiances are the key cloud input of the current GEWEX SRB algorithms. In addition, the longwave algorithm has also made changes in cloud microphysical property, surface skin temperature input, surface emissivity, atmospheric profile, adding longwave aerosol optical properties, revising cloud overlap procedure, and so on. Details of changes in both inputs and algorithms are documented in a NASA Algorithm Theoretical Basis Document (ATBD). We have validated the surface longwave downward fluxes against the surface-based Baseline Surface Radiation Network (BSRN) and the Pacific Marine Environmental Laboratory (PMEL) buoy data. As of 2020, the BSRN archive has 12,116 site-months of observed records from 73 stations on all seven continents, and as of 2017, PMEL archive has 4389 buoy months of observed records from 64 buoys deployed in the tropics of Pacific, Atlantic and Indian Oceans. This paper presents how the SRB Rel. 4.0-IP surface longwave downward fluxes compare with these surface-based measurements and how the comparison statistics differ from that of Rel. 3.0.

GEWEX SRB↗

Global Surface Temperature Change and Uncertainties Since 1861

The objective of this talk is to analyze the warming trend and its uncertainties of the global and hemi-spheric surface temperatures. By the method of statistical optimal averaging scheme, the land surface air temperature and sea surface temperature observational data are used to compute the spatial average annual mean surface air temperature. The optimal averaging method is derived from the minimization of the mean square error between the true and estimated averages and uses the empirical orthogonal functions. The method can accurately estimate the errors of the spatial average due to observational gaps and random measurement errors. In addition, quantified are three independent uncertainty factors: urbanization, change of the in situ observational practices and sea surface temperature data corrections. Based on these uncertainties, the best linear fit to annual global surface temperature gives an increase of 0.61 +/- 0.16 C between 1861 and 2000. This lecture will also touch the topics on the impact of global change on nature and environment. as well as the latest assessment methods for the attributions of global change.

Shen, Samuel S. P.↗

Submillimeter and millimeter observations of solar system objects

Planetary atmospheres and satellite surfaces are observed with the three element array at Caltech's Owens Valley Radio Observatory, Caltech's submillimeter telescope on Mauna Kea and at the 12-meter telescope at Kitt Peak. Researchers are primarily interested in spectroscopy of the atmospheres of Venus, Mars and Titan and the continuum structure of Saturn Rings, Galilean satellites, Neptune and Uranus. During the last year researchers completed a supersynthesis of the Saturn system at 2.8 mm with spatial resolution of 3 arc sec. They just completed a 4-confuguration synthesis of Venus in the CO absorption line. They hope to recover the wind patterns in the altitude range from 60 to 100 km where winds have never been measured. Two important questions are being investigated: (1) how high in the Venus atmosphere do 4-day winds extend, and (2) can we produce experiment proof (or disproof) of the subsolar-to-anti-solar flow (Dickenson winds) predicted by general circulation models.

Muhleman, Duane O.↗