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At least 937 records · Page 52

Model of Operation-and-Maintenance Costs for Photovoltaic Systems

This article presents a method for calculating costs associated with operation and maintenance (O&M) of photovoltaic (PV) systems. It compiles details regarding the cost and frequency of multiple O&M services to estimate annual O&M costs ($\$$/year) for each year of an analysis period, the net present value ($\$$) of life cycle costs accumulated over the analysis period, and the reserve account amount ($\$$). Here we show that this method is an improvement over the previous averaged or levelized per-unit ($\$$/kW/year) valuations for estimating PV O&M costs, because it allows a detailed selection of services to perform based on system size, market served (e.g., residential, commercial, or utility), type and configuration of system components (e.g., micro-, string or central inverter) and site and environmental conditions (e.g., snow, pollen, bird populations). This model also distinguishes costs that vary from year to year and increase at different rates over time because of heuristic failure distributions (e.g. Weibull or Lognormal distribution) based on actuarial data for many of the services. This cost model was created by the PV O&M Working Group of researchers and industry, sponsored by DOE Solar Energy Technologies Office, and has been published in an on-line version hosted by SunSpec Alliance at apsuite.sunspec.org. A spreadsheet version is included with this paper as supplementary material.

14 SOLAR ENERGY↗

Hot Forging Options for Thick Castings

Uranium alloyed with 10 wt% molybdenum (U-10Mo) is a monolithic nuclear fuel relevant to the National Nuclear Security Administration’s nonproliferation efforts. Research has been underway to optimize processing techniques for the U-10Mo fuel. This study investigated the use of hot compression or “hot forging” on a thick (~1") cast and homogenized U-10Mo plate before standard hot and cold rolling procedures. After plates were cast and homogenized, six samples were cut and forged at 700°C at a strain rate of either 0.10 s –1 or 0.01 s –1 at six levels of reduction. After forging, all samples underwent hot and cold rolling followed by annealing to achieve a final foil thickness of about 0.0085". Samples were taken at each stage of the casting and thermomechanical processing to assess the microstructural evolution. Chemical composition, microstructure, and uranium carbide morphology are presented and assessed in this study. Upon hot forging, dislocations accumulate along the grain boundaries, which serve as nucleation sites for randomly oriented, strain-free grains during subsequent annealing steps. Hot forging and subsequent annealing produced very heterogeneous grain sizes. However, no molybdenum segregation was observed after forging. No obvious trend was observed between forging conditions (strain rate and reduction percentage) and the microstructure after final thermomechanical processing. Upon hot rolling to 0.04" and annealing (700°C for 45 min), the average grain diameters from OM was 17 ± 2 µm across the six different forged samples. The subsequent cold rolling to 0.0085" and then annealing (700°C for 45 min) resulted in an average of 13 ± 2 µm between the six samples. Thus, the starting, as-forged microstructure did not appear to significantly influence the final microstructure of the cold-rolled foil. These results will help with understanding and expanding hot working capabilities for thicker U-10Mo castings. They also provide useful information on the effects of hot forging and its potential use to minimize defects that can arise during subsequent hot and cold rolling procedures.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Medical vest broadens treatment capability

Universal sized vest, with specially tailored pockets designed to hold medical supplies, provides first aid/first care medical teams with broadened on-site capability. Vest is made of nylon, tough fibrous materials, and polyvinyl chloride. Design facilitates rapid donning, doffing, and adjustment.

Johnson, G. S.↗

Hubble Space Telescope Medium Deep Survey. 2: Deconvolution of Wide Field Camera field galaxy images in the 13 hour + 43 deg field

We present isophotal profiles of six faint field galaxies from some of the first deep images taken for the Hubble Space Telescope (HST) Medium Deep Survey (MDS). These have redshifts in the range z = 0.126 to 0.402. The images were taken with the Wide Field Camera (WFC) in `parallel mode' and deconvolved with the Lucy method using as the point-spread function nearby stars in the image stack. The WFC deconvolutions have a dynamic range of 16 to 20 dB (4 to 5 mag) and an effective resolution approximately less than 0.2 sec (FWHM). The multiorbit HST images allow us to trace the morphology, light profiles, and color gradients of faint field galaxies down to V approximately equal to 22 to 23 mag at sub-kpc resolution, since the redshift range covered is z = 0.1 to 0.4. The goals of the MDS are to study the sub-kpc scale morphology, light profiles, and color gradients for a large samole of faint field galaxies down to V approximately equal to 23 mag, and to trace the fraction of early to late-type galaxies as function of cosmic time. In this paper we study the brighter MDS galaxies in the 13 hour + 43 deg MDS field in detail, and investigate to what extent model fits with pure exponential disks or a(exp 1/4) bulges are justified at V approximately less than 22 mag. Four of the six field galaxies have light profiles that indicate (small) inner bulges following r(exp 1/4) laws down to 0.2 sec resolution, plus a dominant surrounding exponential disk with little or no color gradients. Two occur in a group at z = 0.401, two are barred spiral galaxies at z = 0.179 and z = 0.302, and two are rather subluminous (and edge-on) disk galaxies at z = 0.126 and z = 0.179. Our deep MDS images can detect galaxies down to V, I approximately less than 25 to 26 mag, and demonstrate the impressive potential of HST--even with its pre-refurbished optics--to resolve morphological details in galaxies at cosmologically significant distances (v approximately less than 23 mag). Since the median redshift of these galaxies is approximately less than 0.4, the HST resolution allows us to study sub kpc size scales at the galaxy, which cannot be done with stable images over wide fields from the best ground-based sites.

Windhorst, R. A.↗

Observing Solar Radio Bursts from the Lunar Surface

Locating low frequency radio observatories on the lunar surface has a number of advantages. Here, we describe the Radio Observatory for Lunar Sortie Science (ROLSS), a concept for a low frequency, radio imaging interferometric array designed to study particle acceleration in the corona and inner heliosphere. ROLSS would be deployed during an early lunar sortie or by a robotic rover as part of an unmanned landing. The prime science mission is to image type II and type III solar radio bursts with the aim of determining the sites at and mechanisms by which the radiating particles are accelerated. Secondary science goals include constraining the density of the lunar ionosphere by searching for a low radio frequency cutoff of the solar radio emissions and constraining the low energy electron population in astrophysical sources. Furthermore, ROLSS serves a pathfinder function for larger lunar radio arrays. Key design requirements on ROLES include the operational frequency and angular resolution. The electron densities in the solar corona and inner heliosphere are such that the relevant emission occurs below 10 MHz, essentially unobservable from Earth's surface due to the terrestrial ionospheric cutoff. Resolving the potential sites of particle acceleration requires an instrument with an angular resolution of at least 2 deg, equivalent to a linear array size of approximately 500 meters. Operations would consist of data acquisition during the lunar day, with regular data downlinks. The major components of the ROLSS array are 3 antenna arms arranged in a Y shape, with a central electronics package (CEP). Each antenna arm is a linear strip of polyimide film (e.g., Kapton (TM)) on which 16 single polarization dipole antennas are located by depositing a conductor (e.g., silver). The arms also contain transmission lines for carrying the radio signals from the science antennas to the CEP.

MacDowall, R. J.↗

Supersonic Retro-Propulsion for Future High-Mass Robotic Mars Lander Missions

A feasibility study was conducted to investigate the potential performance advantages of Supersonic Retro-Propulsion in support of future high-mass Mars robotic landing missions. A notional reference architecture for a potential future Mars Sample Return formed the basis for assuming a 4.7 m diameter SRP entry vehicle containing the Mars Ascent Vehicle element. Configuration analysis was conducted to ensure that the payload and required SRP components (including engines and propellant) fit within in the capsule volume. Optimized trajectory analysis highlighted several key performance sensitivities of SRP for ballistic coefficients of 150, 300, and 450 kg/m2. These results indicated a broad SRP ignition envelope (1-4 km altitude, 300-750 m/s velocity), as well as relatively small propellant mass fraction sensitivities to SRP thrust/weight, landing site elevation, and the application of a 4-g entry deceleration constraint (relevant for future crewed mission trajectories). Finally, mass-sizing was performed to assess sensitivities to ballistic coefficient and entry velocity, and showcased the ability of the SRP system to land payload masses on the order of twice that of MSL.

Whetsel, Charles↗

The Case for Comprehensive Spectroscopic Measurements of the Sun: Understanding Solar Flares and Coronal Heating

We discuss spectroscopic capabilities needed to resolve two important unresolved questions in solar physics, namely, ``What heats the solar corona?" and ``What causes the sudden, rapid release of energy that produces flares?" Spectroscopic capabilities needed to answer these questions include: (1) high spectral resolution, to enable measurement of unblended profiles of numerous emission lines; (2) high sensitivity with a wide dynamic range, to enable detection of faint line emission as well as weak wing components; (3) comprehensive temperature coverage, observing lines formed at log T separated by 0.1 or 0.2 dex between at least 20,000 K and 20 MK; (4) an absolute wavelength scale, to enable Doppler velocity measurements accurate to within 1 km/s or better; (5) simultaneous measurements over spatial area comparable in size to active regions (4' x 4'); (6) spatial resolution sufficient to resolve loop strands and the immediate vicinities of reconnection sites (<1''); (7) cadence short enough to monitor evolution of the solar atmosphere during periods of most rapid change (<1 s).

Jeffrey W Brosius↗

System and method for using ultramicroporous carbon for the selective removal of nitrate with capacitive deionization

The present disclosure relates to a flow through electrode, capacitive deionization (FTE-CDI) system which is able to adsorb nitrates from water being treated using the system. The system makes use of a pair of electrodes arranged generally parallel to one another, with a water permeable dielectric sandwiched between the electrodes. The electrodes receive a direct current voltage from an electrical circuit. At least one of the electrodes is formed from a carbon material having a hierarchical pore size distribution which includes a first plurality of pores having a width of no more than about 1 nm, and a second plurality of micro-sized pores. The micron-sized pores enable a flow of water to be pushed through the electrodes while the first plurality of pores form adsorption sites for nitrate molecules carried in the water flowing through the electrodes.

Campbell, Patrick↗

Hematite at Meridiani Planum and Gusev Crater as identified by the Moessbauer Spectrometer MIMOS II

The Moessbauer (MB) spectrometers on the MER rovers Opportunity and Spirit, which landed on Mars in January 2004, have identified the iron-containing mineral hematite (a-Fe2O3) at both landing sites. On Earth, hematite can occur either by itself or with other iron oxides as massive deposits, in veins , and as particles dispersed through a silicate or other matrix material. Hematite particle size can range from nanophase (superparamagnetic) to multidomain and particle shape ranges from equant to acicular to platy. Fine-grained hematite is red in color and is a pigmenting agent. Coarse-grained hematite can be spectrally neutral (gray) at visible wavelengths. Substitutional impurities, particularly Al, are common in hematite. Chemically pure, coarse-grained, and well-crystalline hematite has a magnetic transition (the Morin transition) at ~260 K. Moessbauer spectra, recorded as a function of temperature, provide a way to characterize Martian hematite with respect to some of the physical and chemical characteristics. At Meridiani Planum besides the iron-sulfate mineral jarosite also the Fe-oxide hematite has been identified by the Moessbauer spectrometer, mainly in three distinct types of reservoir: - outcrop matrix material dominated by the mineral jarosite in the MB spectrum, certain basaltic soils, and mm-sized spherules dubbed blueberries. Moessbauer spectra of each reservoir yield a distinct set of hyperfine parameters for hematite, suggesting different degrees of crystallinity and particle size. The hematite found by MB instrument MIMOS II in the outcrop material shows the Morin transition at relatively high temperatures (ca. 250 K) which is an indication of pure and well-crystallized hematite. The source of the hematite in the Blueberries as identified by Moessbauer spectroscopy, and also by MiniTES, is not known. These spherules, covering nearly the whole landing site area (Eagle crater, plains, Endurance crater), may be concretions formed in the outcrop involving aqueous processes. They are dispersed throughout the hematite containing jarositic outcrop material. According to Moessbauer analysis the dominating iron-bearing mineral in the spherules is hematite, and jarosite not been detected so far in significant amounts. But there are some places with hematite showing characteristics different from the hematite described above: (1) the soil at B023_HematiteSlope_Hema2 has some blueberries, but the MB did not seem to intercept any. The temperature dependence of its MB parameters are different from those of blueberries. (2) B049_RasberryNewton_Filling shows a unique Hm MB signature, as well as (3) B051_RealSharksTooth_Enamel1.

Klingelhoefer, G.↗

CROCUS Forward Scatter Disdrometer Data at Argonne National Laboratory Prairie Site

The Vaisala FD70 is a multi-parameter present weather and visibility sensor designed to measure precipitation type, intensity, and visibility with high accuracy in diverse environmental conditions. It uses a combination of forward-scatter measurement and optical disdrometer technologies to detect drop size, fall speeds, and optical properties, enabling the classification of various precipitation types such as rain, snow, sleet, and freezing rain along is visibility estimates. The FD70 provides quantitative estimates of liquid-equivalent precipitation rate and meteorological optical range (MOR), supporting applications in meteorological research, aviation, and road weather monitoring. These measurements are collected at the Argonne Testbed for Multiscale Observational Science (ATMOS), a 20 acre prairie site at Argonne National Lab, located in Lemont, IL. Data is available in netcdf format. Each file contains one second interval data, for approximately 24 hrs each day. File naming convention includes the project (CROCUS), location (ATMOS), instrument name, data level (raw, a1), and date (year, month, day).

54 ENVIRONMENTAL SCIENCES↗

Apollo 16 Mafic Glass: Geochemistry, Provenance, and Implications

Although the Apollo 16 mission landed in the feldspathic lunar highlands, mass-balance models suggest that there is a 5-6% mare component in the mature soils collected at the site. Only one mare basalt greater than 1 cm was found and two surveys of 2-4 mm particles found that less than 1% of this size fraction is mare basalt. Similar surveys of the less than 1 mm size fraction of A16 soils found very little lithic mare basalt, but several percent of basaltic green, yellow, and orange glass. The green glass beads were identified as VLT picritic glass and the orange/yellow glass shards were a mix of high and low Ti mare-like glass, high-Al basaltic glass, and KREEPy glasses. Most previous studies of glasses in the A16 regolith were surveys that identified a high proportion of feldspathic glass because most of the glass is produced by local impacts. Because the number of mafic glasses found was low, few compositional groupings were identified. As part of our ongoing study of the mafic components of the Apollo 16 site, we specifically targeted mafic glasses from Apollo 16, selecting against the more feldspathic glasses. In this way we were able to identify over 300 mafic glasses (greater than 10 wt % FeO). We present here the major- and trace-element chemistry of the main glass groups and discuss the likely provenance of each group.

Zeigler, R. A.↗

Frustrated Coulombic and Cation Size Effects on Nanoscale Boehmite Aggregation: A Tumbler Small- and Ultra-Small-Angle Neutron Scattering Study

To better understand the effects of solution chemistry on particle aggregation in the complex legacy tank wastes at the Hanford (WA) and Savannah River (SC) sites, we have performed a series of tumbler small- and ultra-small-angle neutron scattering experiments on 20 wt % solid slurries of nanoparticulate aluminum oxyhydroxide (boehmite) with M 1+ nitrates of various concentrations and radii. In this study, the solutes consisted of H, Li, Na, K, and Rb nitrates at 10 –5 , 10 –3 , 10 –1 , 2, and 4 molal (m) concentrations, as well as in pure H 2 O. Synthetic boehmite nanoparticles were used with a size range from ~20 to 30 nm. Tumbler cells were used to keep the solids from settling. Although particles initially form individual rhombohedral platelets, once placed in solution, they quickly form well-bonded stacks, primary aggregates, up to ~1500 Å long, and a second level of aggregates whose concentration and structure vary as a function of cation type and concentration. Aggregation generally increases with increased solute concentration and with cation radius up to a concentration somewhat above 10 –1 m, at which point the trend reverses. Primary aggregates become more rodlike and larger. The Kirkwood-like reversal probably reflects a change from Derjaguin–Landau–Verwey–Overbeek (DLVO)/Debye behavior controlled by surface chemistry to a frustrated Coulombic system controlled by the solution structure. These data suggest that an understanding of the effects of salt concentration and chemistry on nanoparticle aggregate structures provides useful physical insights into the microscopic origin of slurry rheology in the Hanford and Savannah River legacy wastes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Monte Carlo N-Particle Transport Performance of Predicting Digital Radiographic IQI Inspection

The identification of porosity, geometric noncompliance, and other defect types are critical to the qualification of materials and components. X-ray radiographic nondestructive testing is a common industrial inspection method for process quality control and component qualification and certification. Digital radiography provides a quick and efficient alternative when compared to traditional film-based inspection. The quality of radiographic inspection is dependent on equipment specifications, such as the source spot size and detector pixel size, and the specific parameters selected for use for the radiographic technique. To evaluate if an x-ray system and technique is sufficient for a given requirement, a radiographic image quality indicator (IQI) can be used. Radiographic IQIs in hard to machine materials or hard to manufacture defects can be time consuming and expensive to manufacture. This study was conducted to evaluate current Savannah River National Laboratory (SRNL) x-ray imaging systems with a custom tantalum IQI and using Monte Carlo simulations to predict the performance of future systems. The tantalum IQI was tested using a Siefert Isovolt 420 keV x-ray tube with a Perkin Elmer XRD 1611 flat panel with 100-micron pixels. Using the Monte Carlo N-Particle transport software, the radiographic tally was used to simulate the photon flux through an identical tantalum IQI. These simulations provided a benchmark as to the best theoretical identification on a given system using our tantalum IQI. The simulations were refined to match SRNL’s current systems’ noise levels, leading to confidence in their ability to predict the performance of other systems that may be purchased and deployed in the future at the Savannah River Site. Future studies will be conducted to prove this research can be extended to artificially evaluate the ability for systems to identify critical defect sizes through x-ray radiographic inspection, drastically reducing the cost and time burdens of producing high-fidelity radiographic test articles.

digital X-ray radiography↗

Frequency-Range Distribution of Boulders Around Cone Crater: Relevance to Landing Site Hazard Avoidance

Boulders represent a landing hazard that must be addressed in the planning of future landings on the Moon. A boulder under a landing leg can contribute to deck tilt and boulders can damage spacecraft during landing. Using orbital data to characterize boulder populations at locations where landers have safely touched down (Apollo, Luna, Surveyor, and Chang'e-3 sites) is important for determining landing hazard criteria for future missions. Additionally, assessing the distribution of boulders can address broader science issues, e.g., how far craters distribute boulders and how this distribution varies as a function of crater size and age. The availability of new Lunar Reconnaissance Orbiter Camera (LROC) Narrow Angle Camera (NAC) images [1] enables the use of boulder size- and range frequency distributions for a variety of purposes [2-6]. Boulders degrade over time and primarily occur around young or fresh craters that are large enough to excavate bedrock. Here we use NAC images to analyze boulder distributions around Cone crater (340 m diameter) at the Apollo 14 site. Cone crater (CC) was selected because it is the largest crater where astronaut surface photography is available for a radial traverse to the rim. Cone crater is young (approximately 29 Ma [7]) relative to the time required to break down boulders [3,8], giving us a data point for boulder range-frequency distributions (BRFDs) as a function of crater age.

Clegg-Watkins, R. N.↗

Nanoscale wetting controls reactive Pd ensembles in synthesis of dilute PdAu alloy catalysts

The performance of bimetallic dilute alloy catalysts is largely determined by the size of minority metal ensembles on the nanoparticle surface. By analyzing the synthesis of catalysts comprising Pd 8 Au 92 nanoparticles supported on silica using surface-sensitive techniques, we report that whether Pd overgrowth occurs before or after Au nanoparticle deposition onto the support controls the surface Pd ensemble size and abundance. These differences in Pd ensembles influence catalytic reactivity in H 2 –D 2 isotope exchange and benzaldehyde hydrogenation, which, in correlation with theoretical calculations, is used to elucidate the active site(s) in each reaction. To clarify how the synthetic sequence controls the formation of Pd ensembles, we combine numerical wetting calculations and molecular dynamics simulations (with a machine-learned force field) to visualize Pd deposition and migration on the nanoparticle surface, respectively. Our results suggest that the nanoparticle–support interface restricts nanoparticle accessibility to Pd deposition, which consequently controls the Pd ensemble size, illustrating the critical role of nanoscale wetting phenomena during bimetallic catalyst preparation.

36 MATERIALS SCIENCE↗

Characterizing inhibitors of human AP endonuclease 1

AP endonuclease 1 (APE1) processes DNA lesions including apurinic/apyrimidinic sites and 3´-blocking groups, mediating base excision repair and single strand break repair. Much effort has focused on developing specific inhibitors of APE1, which could have important applications in basic research and potentially lead to clinical anticancer agents. We used structural, biophysical, and biochemical methods to characterize several reported inhibitors, including 7-nitroindole-2-carboxylic acid (CRT0044876), given its small size, reported potency, and widespread use for studying APE1. Intriguingly, NMR chemical shift perturbation (CSP) experiments show that CRT0044876 and three similar indole-2-carboxylic acids bind a pocket distal from the APE1 active site. A crystal structure confirms these findings and defines the pose for 5-nitroindole-2-carboxylic acid. However, dynamic light scattering experiments show the indole compounds form colloidal aggregates that could bind (sequester) APE1, causing nonspecific inhibition. Endonuclease assays show the compounds lack significant APE1 inhibition under conditions (detergent) that disrupt aggregation. Thus, binding of the indole-2-carboxylic acids at the remote pocket does not inhibit APE1 repair activity. Myricetin also forms aggregates and lacks APE1 inhibition under aggregate-disrupting conditions. Two other reported compounds (MLS000552981, MLS000419194) inhibit APE1 in vitro with low micromolar IC50 and do not appear to aggregate in this concentration range. However, NMR CSP experiments indicate the compounds do not bind specifically to apo- or Mg 2+ -bound APE1, pointing to a non-specific mode of inhibition, possibly DNA binding. Our results highlight methods for rigorous interrogation of putative APE1 inhibitors and should facilitate future efforts to discover compounds that specifically inhibit this important repair enzyme.

59 BASIC BIOLOGICAL SCIENCES↗

Electrostatic Superlattices Beyond 1:1 Stoichiometry

ABSTRACT Exotic nanoparticle superstructures can be accessed by harnessing nanoparticle softness and charge regulation, features often viewed as obstacles to structural control. Here, we show that regulated charge mismatch in polymer‐grafted nanoparticles enables the assembly of high‐stoichiometry cubic superlattices. By co‐tuning grafting density, particle size, and bulk composition, we realize ionic‐lattice analogues, such as and , as well as single‐component and superlattices without atomic counterparts. The superlattice has recently been identified theoretically as a photonic band‐gap lattice. These phases emerge from a 1:1 “parent” lattice when local charge neutrality cannot be satisfied, driving either progressive interstitial filling or reorganization into a larger basis. For instance, the systematic occupation of ZnS tetrahedral sites yields , while ligand‐swapping symmetry breaking converts CsCl into . Upon heating, the assemblies exhibit reversible lattice contraction and pronounced negative thermal expansion. Furthermore, the energetic penalty for defects increases with nanoparticle size, facilitating the scalable production of high‐quality, open superlattices for photonic applications.

36 MATERIALS SCIENCE↗

Optimizing design and dispatch of a resilient renewable energy microgrid for a South African hospital

Lack of access to reliable energy is a major concern for countries in sub-Saharan Africa. The national grids are unable to consistently satisfy demand. Therefore, users turn to distributed generation systems in the form of back-up generators. However, such systems are usually designed based on a rule of thumb. We employ a mixed-integer linear programming model that considers several options such as renewable energy, combined heat and power, and storage technologies, in addition to those on-site, to provide optimal design and dispatch decisions that minimize total cost. We apply this model to a case study for a hospital in South Africa, considering its need for reliable electricity in light of multiple outages that might occur over the course of a year, as well as its high heating and cooling loads. Our results show that optimal design and dispatch decisions for the distributed generation system address reliability challenges, regardless of the time at which they occur. And, these solutions yield millions of dollars in savings, suggesting that technologies such as the absorption chiller may be overlooked in typical designs; its integration can reduce demand charges even in the absence of combined heat and power. We show that total cost is most sensitive to changes in site electrical demand, followed by capital cost, fuel cost, photovoltaic production, and monthly demand charges; changes in fuel cost primarily affect system sizes of combined heat and power and the absorption chiller, while photovoltaic system size is more sensitive to the changes in capital and fuel costs, photovoltaic resource availability, and hourly electrical demand. Finally, an outage simulator demonstrates the ability of our optimized system to sustain with no interruptions in power five-hour outages with probability 1.0 and ten-hour outages with probability 0.65, significant improvements over 0.5 and 0.0, respectively, under a business-as-usual case.

24 POWER TRANSMISSION AND DISTRIBUTION↗