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At least 937 records · Page 52

A Multi-Analysis Approach for Estimating Regional Health Impacts from the 2017 Northern California Wildfires

In the evening of October 8 and early hours of October 9, 2017, high winds in Northern California downed trees and power lines, igniting some of the most devastating wildfires the state had seen, and within hours unhealthy air quality impacted millions of people. We simulated these air quality conditions using fire detection information from the MODIS, VIIRS, and GOES-16 ABI satellite instruments, and applying a set of three WRF–CMAQ simulations, one data fusion, and three machine learning methods. We investigated using the 5-min available GOES-16 fire detection data to simulate timing of fire activity to allocate emissions hourly for the WRF-CMAQ air quality modeling system. Interestingly, this approach did not necessarily improve results compared to the baseline case, which used a default time profile. However, this approach was key to simulating the initial 12-hr explosive fire activity and smoke impacts. The WRF-CMAQ simulations compared well with observational data for the October 8-15 time period and tended to overestimate concentrations October 16-20. To improve these results, we applied three machine learning algorithms. We also had a unique opportunity to evaluate results with temporary monitors deployed specifically for wildfires, and performance was markedly different. For example, at the permanent monitoring locations, the WRF-CMAQ simulations had a Pearson correlation of 0.65, and the data fusion approach improved this (Pearson correlation = 0.95), while at the temporary monitor locations across the WRF-CMAQ, data fusion, and machine learning datasets, the best Pearson correlation was 0.5. The data fusion and machine learning results were biased low and WRF-CMAQ results were biased high. Finally, we applied the optimized PM2.5 exposure estimate in a short-term exposure-response function. Total estimated mortality attributable to PM2.5 exposure during the smoke episode was 83 (95% confidence interval: 0, 196) with 47% of these deaths attributable to wildland fire smoke.

O'Neill, Susan↗

Near-Critical CO 2 -Assisted Liquefaction-Extraction of Biomass and Wastes to Fuels and Value-Added Products

With the growing need for sustainable carbon-neutral liquid fuels, low-grade feedstocks, such as lignocellulosic biomass, and municipal solid wastes offer sufficient potential via thermochemical conversion. But the existing thermochemical means are limited in feed flexibility and scalability and require significant processing (energy and costs) of the intermediates. Bio-oil/biocrude intermediate from fast pyrolysis and hydrothermal techniques is impeded by issues of stability and oxygen content, along with hydrotreating viability. To address these issues, we investigated a novel pathway of near-critical CO 2 -assisted integrated liquefaction-extraction (NILE) technology in conceptual aspects for conversion of various biomass and municipal solid wastes into high-quality biocrude with high compatibility for co-hydrotreating with traditional fossil crude for liquid fuel needs in power and transportation sectors. Using supercritical CO 2 for dewatering wet feedstocks, for liquefaction, and extraction for lighter biocrude has produced biocrude with lower oxygen content by 50%, lowered metal content by 90%, stable viscosity, low acidity, and good aging stability compared to that produced from hydrothermal liquefaction along with higher hydrotreating and co-hydrotreating compatibility. Hydrotreating of the biocrude extract from supercritical CO 2 extraction also was feasible with no detected coke deposition, an oxygen content of 1%, and catalyst deactivation. Here, the validation and capabilities of the NILE concept urge for its further development to obtain sustainable liquid fuels with lower greenhouse gas emissions and costs.

09 BIOMASS FUELS↗

Water Network Tool for Resilience (WNTR)

The Water Network Tool for Resilience (WNTR) is an open source Python package designed to simulate and analyze resilience of water distribution networks. The United States Environmental Protection Agency, in partnership with Sandia National Laboratories, developed WNTR to integrate critical aspects of resilience modeling for water distribution networks into a single software framework. The software includes capability to: • Generate water network models • Modify network structure and operations • Assign fragility and survival curves to network components • Model disruptive events such as power outages, earthquakes, fires, pipe breaks, and contamination incidents • Model response and repair strategies • Simulate hydraulics and water quality • Evaluate resilience using a wide range of metrics • Integrate dependency with other critical infrastructure and supply chains • Analyze results and generate graphics SAND2019-450 M

Villa, Daniel↗

Ultra-Low SWaP CO 2 Sensing for Demand Control Ventilation (Final Report)

In this project PARC and Energy ETC aimed to develop an ultra-low cost, size, weight, and power (SWaP) printed CO 2 sensor system for occupancy detection to enable Demand Control Ventilation (DCV) on a per-room basis. The CO 2 sensor technology is based on the temperature variation when CO 2 reversibly physisorbs to a highly conductive and high surface area sorbent surface, and is compatible with integration with PARC innovations in printed sensors and flexible electronics, for which PARC is a globally leading research center. The printed CO 2 sensor itself is designed to be compatible with PARC’s “peel-and-stick” platform of ultra-low power, low-cost, distributed sensors, and to facilitate real-time DCV based on overall indoor air quality (IAQ). Previously, PARC has developed flexible hybrid electronics (FHE) compatible materials to measure humidity, temperature, light, strain, and gases such as carbon monoxide, methane, ammonia, and hydrogen sulfide. Through this project, PARC developed FHE-compatible materials to measure CO 2 . Thus, with one <$15 FHE “peel-and-stick” based sensor node, a building management system (BMS) will be able to capture a complete picture of the indoor environment. This includes IAQ, light, temperature, and other comfort factors that impact building operations. Combined with optimized DCV, this low-cost sensor capability can be a key enabler of annual primary energy savings of ~ 0.3-0.4 Quad in commercial buildings while ensuring healthy IAQ. Energy ETC is a leader in supplier-agnostic BMS deployments and will design the commissioning and deployment procedures to maximize system interoperability.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

National Energy Water Treatment and Speciation (NEWTS) Database & Dashboard

The Department of Energy's Office of Fossil Energy & Carbon Management (DOE/FECM) through the National Energy Technology Laboratory (NETL) has launched a free online tool, the National Energy Water Treatment and Speciation (NEWTS) Database and Dashboard, which can be utilized by community leaders and water researchers to better understand the composition of energy-related wastewater streams. The NEWTS Database and Dashboard provide public access to difficult-to-access datasets, including the original data sources and the processed data forms for input into aqueous chemistry modeling software. The data provided by the tool will help mitigate environmental risks and identify possible sources of valuable critical minerals (CM). The goal of this ASME Power presentation is to highlight the data and capabilities of this free online-tool for obtaining high quality water datasets in formats that are easy for modeling the treatment and recovery of valuable resources from effluent waste stream associated with energy operations.

Siefert, Nicholas↗

Capabilities of the Skylab-A spectrometer (S191) for remote sensing of surface targets in the thermal-infrared spectral region

The effects of some of the factors which fundamentally limit the amount of information which can be deduced from spectrometer (S191) measurements, made from the orbital altitude of Skylab-A, of the thermal-infrared power radiated into space from typical surface targets are discussed. The particular significance of this spectral region is that the power radiated at night is comparable in intensity to that in daylight. Calculations were made which simulate the quality of spectrometer data that could be expected from spectral measurements made in space, of the thermal-infrared radiation emitted from typical rocks on the surface. The results indicate that the reststrahlen structure in these spectra is not distinctive enough to permit reliable identification of the rocks. This conclusion is confirmed by relevant data which have already been obtained from aircraft and spacecraft.

Newsome, R. W., Jr.↗

Comparative evaluation of solar, fission, fusion, and fossil energy resources. Part 4: Energy from fossil fuels

The conversion of fossil-fired power plants now burning oil or gas to burn coal is discussed along with the relaxation of air quality standards and the development of coal gasification processes to insure a continued supply of gas from coal. The location of oil fields, refining areas, natural gas fields, and pipelines in the U.S. is shown. The technologies of modern fossil-fired boilers and gas turbines are defined along with the new technologies of fluid-bed boilers and MHD generators.

Williams, J. R.↗

Analytical study of ride smoothing benefits of control system configurations optimized for pilot handling qualities

An analytical study was conducted to evaluate the relative improvements in aircraft ride qualities that resulted from utilizing several control law configurations that were optimized for pilot handling qualities only. The airplane configuration used was an executive jet transport in the approach configuration. The control law configurations included the basic system, a rate feedback system, three command augmentation systems (rate command, attitude command, and rate command/attitude hold), and a control wheel steering system. Both the longitudinal and lateral directional axes were evaluated. A representative example of each control law configuration was optimized for pilot handling qualities on a fixed base simulator. The root mean square airplane responses to turbulence were calculated, and predictions of ride quality ratings were computed by using three models available in the literature.

Powers, B. G.↗

The Aerodynamic Characteristics of Four Full-Scale Propellers Having Different Plan Forms

Tests were made of four propellers, with diameters of 10 feet, having different blade plan forms. One propeller (Navy design no. 5868-r6) was of the usual present-day type and was used as a basis of comparison for the other three, which had unusual plan forms distinguished by the inward (toward the hub) location of the sections having the greatest blade width. It was found that propellers with points of maximum blade width occurring closer to the hub than on the present-day type of blade had higher peak efficiencies but lower take-off efficiencies. This results was found true for a "clean" liquid-cooled engine installation. It appears that some modification could be made to present plan forms which would produce propellers having more satisfactory aerodynamic qualities. The propellers with the inward location of the points of maximum blade width had lower thrust and power coefficients and stalled earlier than the present-day type.

Hartman, Edwin P↗

H2S data reduction

Calculating microwave opacity from a weakly absorbing gas mixture using a resonator requires measuring the quality factor of that resonator which necessitates accurately determining the center frequency (f(sub O)) and the half power bandwidth (Delta-f) of a noisy resonant line. The center frequency can be determined very accurately and varies very little over many measurements (a few kHz at GHz frequencies or a few hundredths of a percent). The greater source of error in estimating the Q of a resonator come from the bandwidth measurements. The half power bandwidth is determined essentially by eye-fitting a curve over a noisy resonant line and measuring with a spectrum analyzer.

Deboer, David↗

Measuring Q And f(sub r) Of A Microwave Cavity: Part I

Method of measuring quality factor (Q) and frequency of resonance (f(subr)) of microwave cavity exploits two inflection points of power-vs.-frequency resonance curve of cavity. Intended particularly for use with microwave cavity in which sample of lossy dielectric material heated to specified high temperature by microwave power at resonant frequency. Accurate measurement contributes to enhanced monitoring and control in contactless high-temperature processing of materials. Also used with small spherical sample to determine temperature dependence of complex dielectric constant.

Barmatz, Martin B.↗

Advanced Geosynchronous Imager

For improved understanding of chaotic processes and the diurnal cycle, an advanced GOES imager must also have the multi-spectral spectral bands used by low earth orbit (LEO) imagers, with on-orbit calibration for all bands. A synergy between GEO and LEO radiometry would enable earth system scientists to fuse the remote sensing data from all the spaceborne platforms. These additional radiometric capabilities are designed to observe important physical processes that vary rapidly and unpredicably: smoke, fires, precipitation, ozone, volcanic ash, cloud phase and height, and surface temperature. We believe the technology now exists to develop an imaging system that can meet future weather reporting and earth system science needs. To meet this need, we propose a design for a comprehensive geosynchronous atmospheric imager. This imager is envisioned to fly on a GOES-N class spacecraft, within the volume, weight and power constraints of a platform similar to GOES-N while delivering 100 times more data and radiometric quality than the GOES-N imager. The higher data rate probably requires its own ground station, which could serve as a systems prototype for NOAA's next generation of operational satellites. For operational compatibility, our proposed advanced GOES imaging system contains the GOES-R requirements as a subset, and the GOES-N imager capabilities (and the sounder's imaging channels) as a further subset.

Chesters, Dennis↗

Remote Sensing of Aircraft Contrails Using a Field Portable Digital Array Scanned Interferometer

With a Digital Array Scanned Interferometer (DASI), we have obtained proof-of-concept observations with which we demonstrate DASI capabilities for the determination of contrail properties. These include the measurement of the cloud and soot microphysical parameters, as well, the abundances of specific pollutant species such as SO(sub x) or NO(sub x). From high quality hyperspectral data and using radiative transfer methods and atmospheric chemistry analysis in the data reduction and interpretation, powerful inferences concerning cloud formation, evolution and dissipation can be made. Under this sub-topic, we will integrate DASI with computer controlled scanning of the field-of-view to direct the sensor towards contrails and exhaust plumes for tracking the emitting vehicles. The optimum DASI wavelength sensitivity range for sensing contrails is 0.35 - 2.5 micron. DASI deploys on the ground or from aircraft to observe contrails in the vicinity. This enables rapid, accurate measurement of the temporal, spatial, and chemical evolution of contrails (or other plumes or exhaust sources) with a low cost, efficient sensor.

Smith, William Hayden↗

A Compact X-Ray System for Macromolecular Crystallography

We describe the design and performance of a high flux x-ray system for macromolecular crystallography that combines a microfocus x-ray generator (40 gm FWHM spot size at a power level of 46.5Watts) and a 5.5 mm focal distance polycapillary optic. The Cu K(sub alpha) X-ray flux produced by this optimized system is 7.0 times above the X-ray flux previously reported. The X-ray flux from the microfocus system is also 3.2 times higher than that produced by the rotating anode generator equipped with a long focal distance graded multilayer monochromator (Green optic; CMF24-48-Cu6) and 30% less than that produced by the rotating anode generator with the newest design of graded multilayer monochromator (Blue optic; CMF12-38-Cu6). Both rotating anode generators operate at a power level of 5000 Watts, dissipating more than 100 times the power of our microfocus x-ray system. Diffraction data collected from small test crystals are of high quality. For example, 42,540 reflections collected at ambient temperature from a lysozyme crystal yielded R(sub sym) 5.0% for the data extending to 1.7A, and 4.8% for the complete set of data to 1.85A. The amplitudes of the reflections were used to calculate difference electron density maps that revealed positions of structurally important ions and water molecules in the crystal of lysozyme using the phases calculated from the protein model.

Gubarev, Mikhail↗

A Compact X-Ray System for Macromolecular Crystallography

We describe the design and performance of a high flux x-ray system for a macromolecular crystallography that combines a microfocus x-ray generator (40 micrometer full width at half maximum spot size at a power level of 46.5 W) and a collimating polycapillary optic. The Cu Ka lpha x-ray flux produced by this optimized system through a 500,um diam orifice is 7.0 times greater than the x-ray flux previously reported by Gubarev et al. [M. Gubarev et al., J. Appl. Crystallogr. 33, 882 (2000)]. The x-ray flux from the microfocus system is also 2.6 times higher than that produced by a rotating anode generator equipped with a graded multilayer monochromator (green optic, Osmic Inc. CMF24-48-Cu6) and 40% less than that produced by a rotating anode generator with the newest design of graded multilayer monochromator (blue optic, Osmic, Inc. CMF12-38-Cu6). Both rotating anode generators operate at a power level of 5000 W, dissipating more than 100 times the power of our microfocus x-ray system. Diffraction data collected from small test crystals are of high quality. For example, 42 540 reflections collected at ambient temperature from a lysozyme crystal yielded R(sub sym)=5.0% for data extending to 1.70 A, and 4.8% for the complete set of data to 1.85 A. The amplitudes of the observed reflections were used to calculate difference electron density maps that revealed positions of structurally important ions and water molecules in the crystal of lysozyme using the phases calculated from the protein model.

Gubarev, Mikhail↗

SPACE: the SPectroscopic, All-Sky Cosmic Explorer

We describe the scientific motivations, the mission concept and the instrumentation of SPACE, a class-M mission proposed for concept study at the first call of the ESA Cosmic-Vision 2015-2025 planning cycle. SPACE aims at producing the largest three-dimensional evolutionary map of the Universe over the past 10 billion years by taking near-IR spectra and measuring redshifts of more than half a billion galaxies at 0 < z < 2 down to AB approximately 23 over 37r sr of the sky. In addition, SPACE will also target a smaller sky field, performing a deep spectroscopic survey of millions of galaxies to AB approximately 26 and at 2 < z < l0+. Owing to the depth, redshift range, volume coverage and quality of its spectra, SPACE will reveal with unique sensitivity most of the fundamental cosmological signatures, including the power spectrum of density fluctuations and its turnover, the baryonic acoustic oscillations imprinted when matter and radiation decoupled, the distance-luminosity relation of cosmological supernovae, the evolution of the cosmic expansion rate, the growth rate of cosmic large-scale structure, the large scale distribution of galaxies. The datasets from the SPACE mission will represent a long lasting legacy that will be data mined for many years to come.

Cimatti, A.↗

Disorder to Order in Interface Patterns: Thermal Noise to Limit Cycle Transition in Dendrite Sidebranch Formation

Thin sample directional solidification experiments have been carried out in the model succinonitrile-camphor system to examine the origin of secondary branches in dendrite morphologies. Thermal noise at the dendrite tip creates interface instabilities which amplify to form sidebranches. This is accepted as the primary mode of sidebranching in dendritic growth from an undercooled melt and occurs in directional solidification of dendrites. The proposed limit cycle couples the growth of the tip with the initiation of the sidebranch. Directional solidification of curved interfaces is a driven dissipative system with the potential to form a limit cycle. Two sets of experiments were performed, the first holding velocity constant and evolving the gradient and the second imposing oscillating velocities around the natural period of sidebranching. Both experimental methods were found to characterize a transition from disordered sidebranching induced by thermal noise to ordered sidebranching produced by the limit cycle mechanisms. This is the first quantitative measurement of previously hypothesized limit cycle growth. These experiment sets have been quantitatively analyzed for dynamic behavior seen in limit cycles. High-quality data sets of the tip and instability enable the measurement of the FFT and analysis through a power spectrum. At low gradients, the sidebranches are found to be excited by thermal noise far away from the tip. As the gradient increases and velocity is held constant, the distance between the instability and tip decreases until limit cycle growth is found between the tip of the primary dendrite and the first forming sidebranch. An alternative to the deterministic limit cycles seen in experiments of gradient evolution is a limit cycle actively driven through the square wave oscillation of velocity. Crucial observations of the solidified microstructure conclude that this produced periodic interconnected bridges between the primary dendrites. This is a finding with potentially significant implications for commercial applications.

Trevor Lyons↗