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At least 937 records · Page 52

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NASA NTRS1976

Remote sensing of soil moisture by a 21-cm passive radiometer

Microwave sensors on Skylab collected data as part of the Earth Resources Experiment Package. An investigation was designed to obtain field observations of soil moisture content for comparison with data from Skylab. The 21-cm radiometer has been shown to be highly responsive to the moisture content of the upper 2.5-cm layer of soil. A composite relationship between the radiometric temperature and soil moisture content has been determined from five data sets obtained over Kansas and Texas. This relationship, having a correlation index of -0.96, has been used as a basis for calculating the soil moisture content of large areas across the United States.

Eagleman, J. R.↗

DOE OSTI2021

Multifunctional Conjugated Ligand Engineering for Stable and Efficient Perovskite Solar Cells

Surface passivation is an effective way to boost the efficiency and stability of perovskite solar cells (PSCs). However, a key challenge faced by most of the passivation strategies is reducing the interface charge recombination without imposing energy barriers to charge extraction. Here, a novel multifunctional semiconducting organic ammonium cationic interface modifier inserted between the light-harvesting perovskite film and the hole-transporting layer is reported. It is shown that the conjugated cations can directly extract holes from perovskite efficiently, and simultaneously reduce interface non-radiative recombination. Together with improved energy level alignment and the stabilized interface in the device, a triple-cation mixed-halide medium-bandgap PSC with an excellent power conversion efficiency of 22.06% (improved from 19.94%) and suppressed ion migration and halide phase segregation, which lead to a long-term operational stability, is demonstrated. Finally, this strategy provides a new practical method of interface engineering in PSCs toward improved efficiency and stability.

36 MATERIALS SCIENCE↗

NASA NTRS2002

Thermal Examination of an Orbiting Cryogenic Fuel Depot

For many years NASA has been interested in the storage and transfer of cryogenic fuels in space. Lunar, L2 and other chemical propulsive space vehicle missions now have staged refueling needs that a fuel depot would satisfy. The depot considered is located in lower earth orbit. Many considerations must go into designing and building such a station. Multi-layer insulation systems, thermal shielding and low conductive structural supports are the principal means of protecting the system from excessive heat loss due to boiloff. This study focuses on the thermal losses associated with storing LH2 in a passively cooled fuel depot in a lower earth equatorial orbit. The corresponding examination looks at several configurations of the fuel depot. An analytical model has been developed to determine the thermal advantages and disadvantages of three different fuel depot configurations. Each of the systems consists of three Boeing rocket bodies arranged in various configurations. The first two configurations are gravity gradient stabilized while the third one is a spin-stabilized concept. Each concept was chosen for self-righting capabilities as well as the fuel settling capabilities, however the purpose of this paper is to prove which of the three concepts is the most efficient passively cooled system. The specific areas to be discussed are the heating time from the fusion temperature to the vaporization temperature and the amount of boiloff for a specific number of orbits. Each of the previous points is compared using various sun exposed surface areas of the tanks.

Hull, Patrick V.↗

DOE OSTI2023

Evaluating Scaling Effects of Steam Condensation Physics-based Model for Small Modular Reactor

This study focused on assessing condensation heat transfer (CHT) models for enhancing the passive safety of small modular reactors (SMRs). It also encompassed a review of the theoretical and semi-theoretical CHT models and correlations. Condensation models such as the degradation factor, heat and mass transfer analogy (HMTA), and boundary layer models are used to study advanced nuclear reactor PCCS. The previous CHT models were developed for small tube geometries, which differ from the containment of SMR. This study examined the scaled relations of a physics-based CHT model for analyzing laminar and turbulent film condensation downward flow conditions inside scaled tube geometries.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

DOE OSTI2023

Presentation: Evaluating scaling effects of steam condensation physics-based model for small modular reactors safety

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

NASA NTRS1993

Development of Leaky Wave Antennas for Layered Ridge Dielectric Waveguide

The millimeter wave, especially above 100 GHz, and the submillimeter wave frequency spectrum offers the possibility for narrow-beam, high-resolution antennas which are critical for high definition radars required for space debris tracking, airport ground avoidance radars, and missile tracking. In addition, the frequency which most atmospheric constituents may be detected lie in this part of the frequency spectrum. Therefore, the development of electronic components for millimeter/submillimeter wave passive sensors is required for environmental monitoring of the Earth's atmosphere. Typical microwave transmission lines such as microstrip and coplanar waveguide rely on two or more electrical conductors to concentrate and guide the electromagnetic energy. Unfortunately, the surface resistance of the conductors increases as the square root of frequency. In addition, the circuit dimensions must be decreased with increasing frequency to maintain a single mode transmission line which further increases the conductor loss. An alternative family of transmission lines are formed from two or more insulating materials and rely on the differences in the permittivities between the two materials to guide the wave. No metal conductors are required although some dielectric waveguides do utilize a metallic ground plane to facilitate the interconnections of active electrical elements or to reduce the transmission line size. Examples of such transmission lines are image guides, insulated image guides, trapped image guides, ridge guide, and layered ridge dielectric waveguide (LRDW). Although most dielectric waveguides have dimensions on the order of lambda to provide sufficient field confinement, the LRDW has been shown to provide good field confinement for electrically small lines. This offers an advantage in circuit integration. It has been shown that a periodic array of metallic strips placed either along or on top of a dielectric waveguide forms an effective radiator. This antenna is easy to fabricate and there is good background of microstrip type antenna design information in the literature. This paper reports the development of the first frequency scanning antenna fed by a LRDW.

Ponchak, George E.↗

NASA NTRS1999

Titanomagnetite-bearing Palagonitic Dust as an Analogue for Magnetic Aeolian Dust on Mars

The Mars Pathfinder magnetic properties experiment included two Magnet Arrays (MAs) which consist of five permanent magnets that have different strengths. Each magnet is a cylindrical and ring magnet arranged in a "bulls-eye" pattern beneath a thin surface layer. The design of the MA permits estimation of magnetic properties (saturation magnetization and magnetic susceptibility) of adhering material, principally by the number of magnets that have adhering material and the extent each magnet is saturated. The two MAs passively sample aeolian dust. Additional information is contained in the original extended abstract.

Morris, Richard V.↗

NASA NTRS2019

Exploring the Utility of Machine Learning-Based Passive Microwave Brightness Temperature Data Assimilation over Terrestrial Snow in High Mountain Asia

This study explores the use of a support vector machine (SVM) as the observation operator within a passive microwave brightness temperature data assimilation framework (herein SVM-DA) to enhance the characterization of snow water equivalent (SWE) over High Mountain Asia (HMA). A series of synthetic twin experiments were conducted with the NASA Land Information System (LIS) at a number of locations across HMA. Overall, the SVM-DA framework is effective at improving SWE estimates (~70% reduction in RMSE relative to the Open Loop) for SWE depths less than 200 mm during dry snowpack conditions. The SVM-DA framework also improves SWE estimates in deep, wet snow (~45% reduction in RMSE) when snow liquid water is well estimated by the land surface model, but can lead to model degradation when snow liquid water estimates diverge from values used during SVM training. In particular, two key challenges of using the SVM-DA framework were observed over deep, wet snowpacks. First, variations in snow liquid water content dominate the brightness temperature spectral difference (TB) signal associated with emission from a wet snowpack, which can lead to abrupt changes in SWE during the analysis update. Second, the ensemble of SVM-based predictions can collapse (i.e., yield a near-zero standard deviation across the ensemble) when prior estimates of snow are outside the range of snow inputs used during the SVM training procedure. Such a scenario can lead to the presence of spurious error correlations between SWE and TB, and as a consequence, can result in degraded SWE estimates from the analysis update. These degraded analysis updates can be largely mitigated by applying rule-based approaches. For example, restricting the SWE update when the standard deviation of the predicted TB is greater than 0.05 K helps prevent the occurrence of filter divergence. Similarly, adding a thin layer (i.e., 5 mm) of SWE when the synthetic TB is larger than 5 K can improve SVM-DA performance in the presence of a precipitation dry bias. The study demonstrates that a carefully constructed SVM-DA framework cognizant of the inherent limitations of passive microwave-based SWE estimation holds promise for snow mass data assimilation.

Kwon, Yonghwan↗

NASA NTRS1981

Radiative transfer theory for passive microwave remote sensing of random media

The radiative transfer theory is applied to a random medium for the case of passive remote sensing. A general numerical solution with Gaussian quadrature method is studied. For a medium with laminar structure or a medium with cylindrical structure, closed form solutions are obtained by solving the radiative transfer equations of a two-layer random medium. Numerical results for the general case and the two limiting cases are compared.

Chuang, S. L.↗

NASA NTRS1984

Wave approach to brightness temperature from a bounded layer of random discrete scatterers

By using the fluctuation-dissipation theorem, the strong fluctuation theory is applied to the calculation of brightness temperatures from a bounded layer of random discrete scatterers with the zeroth- and first-order approximations. Various functional dependences on wavelength, polarization, observation angle, medium depth, scatterer constituents, and other physical parameters are discussed. Theoretical results are favorably matched with experimental data for passive remote sensing of snowpacks.

Jin, Y.-Q.↗

NASA NTRS1993

AIAA/ASME/ASCE/AHS/ASC Structures, Structural Dynamics, and Materials Conference, 34th and AIAA/ASME Adaptive Structures Forum, La Jolla, CA, Apr. 19-22, 1993, Technical Papers. Pts. 1-6

Topics addressed include the prediction of helicopter component loads using neural networks, spacecraft on-orbit coupled loads analysis, hypersonic flutter of a curved shallow panel with aerodynamic heating, thermal-acoustic fatigue of ceramic matrix composite materials, transition elements based on transfinite interpolation, damage progression in stiffened composite panels, a direct treatment of min-max dynamic response optimization problems, and sources of helicopter rotor hub inplane shears. Also discussed are dynamics of a layered elastic system, confidence bounds on structural reliability, mixed triangular space-time finite elements, advanced transparency development for USAF aircraft, a low-velocity impact on a graphite/PEEK, an automated mode-tracking strategy, transonic flutter suppression by a passive flap, a nonlinear response of composite panels to random excitation, an optimal placement of elastic supports on a simply supported plate, a probabilistic assessment of composite structures, a model for mode I failure of laminated composites, a residual flexibility approach to multibody dynamics,and multilayer piezoelectric actuators.

Source record↗

NASA NTRS1998

35-GHz Measurements of Carbon Dioxide Crystals

In order to maximize our knowledge of the martian polar caps, it is important to compare and contrast the behavior of both frozen H2O and CO2 in different parts of the electromagnetic spectrum. Relatively little attention has been given, thus far, to observing the thermal microwave part of the spectrum. In this experiment, passive microwave radiation emanating from within a 33-cm snowpack was measured with a 35-GHz hand-held radiometer, and in addition to the natural snow measurements, the radiometer was used to measure the microwave emission and scattering from layers of manufactured CO2 (dry ice) crystals. A 1 square meter plate of aluminum sheet metal was positioned beneath the natural snow so that microwave emissions from the underlying soil layers would be minimized. 35 GHz measurements of this plate were made through the 33-cm snowpack. Layers of the snow were removed and measurements were repeated for the diminishing snowpack until the bare plate was in view. Then, 9 cm of CO2 crystals were deposited onto the sheet-metal plate, and as was the case for the natural snow, hand-held measurements were made each time the thickness of the deposit was altered. These CO2 crystals were -0.65 cm in diameter and were cylindrical. The temperature of the dry ice was -76 C, whereas the temperature at the top of the snowpack was -1.9 C (the air temperature was -3 C). Two additional 9-cm increments were placed on top of the existing CO2 crystals, resulting in a total thickness of 27 cm of dry ice. After this series of measurements was made, the CO2 crystals were then placed on top of the snowpack, and as before, measurements were made using the 35-GHz radiometer. As a final part of this experiment, soil particles were spread on top of the dry ice, and once again, microwave measurements were made with the 35-GHz radiometer.

Foster, J.↗

NASA NTRS1998

35 GHz Measurements of CO2 Crystals for Simulating Observations of the Martian Polar Caps

In order to learn more about the Martian polar caps, it is important to compare and contrast the behavior of both frozen H2O and CO2 in different parts of the electromagnetic spectrum. Relatively little attention has been given, thus far, to observing the thermal microwave part of the spectrum. In this experiment, passive microwave radiation emanating from within a 33 cm snowpack was measured with a 35 GHz hand-held radiometer, and in addition to the natural snow measurements, the radiometer was used to measure the microwave emission and scattering from layers of manufactured CO2 (dry ice). A 1 m x 2 m plate of aluminum sheet metal was positioned beneath the natural snow so that microwave emissions from the underlying soil layers would be minimized. Compared to the natural snow crystals, results for the dry ice layers exhibit lower' microwave brightness temperatures for similar thicknesses, regardless of the incidence angle of the radiometer. For example, at 50 degree H (horizontal polarization) and with a covering of 21 cm of snow and 18 cm of dry ice, the brightness temperatures were 150 K and 76 K, respectively. When the snow depth was 33 cm, the brightness temperature was 144 K, and when the total thickness of the dry ice was 27 cm, the brightness temperature was 86 K. The lower brightness temperatures are due to a combination of the lower physical temperature and the larger crystal sizes of the commercial CO2 Crystals compared to the snow crystals. As the crystal size approaches the size of the microwave wavelength, it scatters microwave radiation more effectively, thus lowering the brightness temperature. The dry ice crystals in this experiment were about an order of magnitude larger than the snow crystals and three orders of magnitude larger than the CO2 Crystals produced in the cold stage of a scanning electron microscope. Spreading soil, approximately 2 mm in thickness, on the dry ice appeared to have no effect on the brightness temperatures.

Foster, J. L.↗

DOE OSTI2024

In situ formation of pseudohalide anions induced by humid air and light passivates formamidinium‐based halide perovskites

Abstract Metal halide perovskites based on formamidinium (FA), or FA‐rich compositions have shown great promise for high‐performance photovoltaics. A deeper understanding of the impact of ambient conditions (e.g., moisture, oxygen, and illumination) on the possible reactions of FA‐based perovskite films and their processing sensitivities has become critical for further advances toward commercialization. Herein, we investigate reactions that take place on the surface of the FA 0.7 Cs 0.3 , mixed Br/I wide bandgap perovskite thin films in the presence of humid air and ambient illumination. The treatment forms a surface layer containing O, OH, and N‐based anions. We propose the latter originates from formamidine trapped at the perovskite/oxide interface reacting further to cyanide and/or formamidinate—an understudied class of pseudohalides that bind to Pb. Optimized treatment conditions improve photoluminescence quantum yield owing to both reduced surface recombination velocity and increased bulk carrier lifetime. The corresponding perovskite solar cells also exhibit improved performance. Identifying these reactions opens possibilities for better utilizing cyanide and amidinate ligands, species that may be expected during vapor processing of FA‐based perovskites. Our work also provides new insights into the self‐healing or self‐passivating of MA‐free perovskite compositions where FA and iodide damage could be partially offset by advantageous reaction byproducts. image

14 SOLAR ENERGY↗

DOE OSTI2020

Over 11% Efficient Eco-Friendly Kesterite Solar Cell: Effects of S-Enriched Surface of Cu2ZnSn(S,Se)4 Absorber and Band Gap Controlled (Zn,Sn)O Buffer

For high efficiency kesterite Cu2ZnSn(S,Se)4 (CZTSSe) solar cell, CdS thin film was usually used as a buffer layer. However, due to the toxicity of Cd and pollution problems involved from the solution-based chemical bath deposition, eco-friendly high efficiency CZTSSe solar cell with Cd-free buffer is necessary. As an Cd-free buffer layer, we investigated (Zn,Sn)O (ZTO) film deposited by sputtering method. In order to achieve high power conversion efficiency, we controlled energy band gaps of CZTSSe absorber as well as ZTO buffer, which was required to optimize conduction band offset (CBO) between the absorber and the buffer and to increase open circuit voltage (Voc) and fill factor (FF). The CBO was optimized by controlling the band gap of ZTO. By varying the Sn/(Zn + Sn) ratio and its deposition temperature, band gap of ZTO was successfully adjusted. Experimental and computational calculation results showed that solar cell performance was strongly affected by the CBO between absorber and buffer. Besides CBO matching, larger band gap of ZTO improved short circuit current density (Jsc) with enhanced external quantum efficiency value in blue photon spectrum range. As an additional way to improve power conversion efficiency of solar cell, band graded CZTSSe absorber was developed by using spray-based two-step process. The sprayed CZTSSe film was engineered to have S-enriched surface, which makes surface band gap widened and surface passivated, and resultantly increases Voc, Jsc and fill factor (FF). By controlling band gaps of both CZTSSe absorber and ZTO buffer, we obtained 11.22% environment-friendly CZTSSe solar cell without MgF2 anti-reflection coating.

(Zn↗

NASA NTRS1991

High resolution electrolyte for thinning InP by anodic dissolution and its applications to EC-V profiling, defect revealing and surface passivation

An extensive experimental study was conducted using various electrolytes in an effort to find an appropriate electrolyte for anodic dissolution of InP. From the analysis of electrochemical characteristics in the dark and under different illumination levels, x ray photoelectron spectroscopy and SEM/Nomarski inspection of the surfaces, it was determined that the anodic dissolution of InP front surface layers by FAP electrolyte is a very good choice for rendering smooth surfaces, free of oxides and contaminants and with good electrical characteristics. The FAP electrolyte, based on HF, CH3COOH, and H2O2 appears to be inherently superior to previously reported electrolytes for performing accurate EC-V profiling of InP at current densities of up to 0.3 mA/sq cm. It can also be used for accurate electrochemical revealing of either precipitates or dislocation density with application to EPD mapping as a function of depth, and for defect revealing of multilayer InP structures at any depth and/or at the interfaces.

Faur, Maria↗

DOE OSTI2022

A Many-Body Perturbation Theory Approach to Energy Band Alignment at the Crystalline Tetracene–Silicon Interface

Hybrid inorganic–organic semiconductor (HIOS) interfaces are of interest for new photovoltaic devices operating above the Shockley–Queisser limit. Predicting energy band alignment at the interfaces is crucial for their design, but represents a challenging problem due to the large scales of the system, the energy precision required and a wide range of physical phenomena that occur at the interface. To tackle this problem, many-body perturbation theory in the non-self-consistent GW approximation, orbital relaxation corrections for organic semiconductors, and line-up potential method for inorganic semiconductors which allows for tractable and accurate computing of energy band alignment in crystalline van-der-Waals hybrid inorganic–organic semiconductor interfaces are used. In this work, crystalline tetracene physisorbed on the clean hydrogen-passivated 1 × 2 reconstructed (100) silicon surface is studied. Using this computational approach, it is found that the energy band alignment is determined by an interplay of the mutual dynamic dielectric screening of two materials and the formation of a dipole layer due to a weak hybridization of atomic/molecular orbitals at the interface. The significant role of the exchange-correlation effects in predicting band offsets for the hybrid inorganic–organic semiconductor interfaces is also emphasized.

74 ATOMIC AND MOLECULAR PHYSICS↗

DOE OSTI2023

QES-Plume v1.0: a Lagrangian dispersion model

Low-cost simulations providing accurate predictions of transport of airborne material in urban areas, vegetative canopies, and complex terrain are demanding because of the small-scale heterogeneity of the features influencing the mean flow and turbulence fields. Common models used to predict turbulent transport of passive scalars are based on the Lagrangian stochastic dispersion model. The Quick Environmental Simulation (QES) tool is a low-computational-cost framework developed to provide high-resolution wind and concentration fields in a variety of complex atmospheric-boundary-layer environments. Part of the framework, QES-Plume, is a Lagrangian dispersion code that uses a time-implicit integration scheme to solve the generalized Langevin equations which require mean flow and turbulence fields. Here, QES-Plume is driven by QES-Winds, a 3D fast-response model that computes mass-consistent wind fields around buildings, vegetation, and hills using empirical parameterizations, and QES-Turb, a local-mixing-length turbulence model. In this paper, the particle dispersion model is presented and validated against analytical solutions to examine QES-Plume’s performance under idealized conditions. In particular, QES-Plume is evaluated against a classical Gaussian plume model for an elevated continuous point-source release in uniform flow, the Lagrangian scaling of dispersion in isotropic turbulence, and a non-Gaussian plume model for an elevated continuous point-source release in a power-law boundary-layer flow. In these cases, QES-Plume yields a maximum relative error below 6 % when compared with analytical solutions. In addition, the model is tested against wind-tunnel data for a uniform array of cubical buildings. QES-Plume exhibits good agreement with the experiment with 99 % of matched zeros and 59 % of the predicted concentrations falling within a factor of 2 of the experimental concentrations. Furthermore, results also emphasize the importance of using high-quality turbulence models for particle dispersion in complex environments. Finally, QES-Plume demonstrates excellent computational performance.

58 GEOSCIENCES↗