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At least 937 records · Page 52

Application of Machine Learning Techniques in Calibration and Data Reduction of Multi-Hole Probes

This work presents procedures to implement machine learning methods in the existing algorithms for multi-hole probe calibrations and data reduction. It is shown here, that utilizing artificial neural networks (ANNs) can reduce the amount of calibration data that needs to be acquired in order to obtain a specific calibration uncertainty, by more than 50% while simultaneously reducing data reduction times significantly. ANNs were used instead of the surface fitting methods, where first, the directional calibration coefficients related to the flow angles are calculated based on the pressure measurements, and then the flow angles are used as a set of the input parameters for the following ANNs to define Mach number and static and total pressure iteratively. In a second approach, novel calibration coefficients were used to directly relate the pressure measurements from five-hole probe to the quantities of interest thus, eliminating the need for iterative algorithms used in the conventional surface fitting methods. The advantageous features of this method are an average increase of less than 1% in the calibration uncertainty for flow angles and significant reduction of the data reduction times (few seconds). In addition, we confirmed the methodology to avoid over-fitting and under-fitting.

Machine Learning↗

Metal-Tuned Ligand Reactivity Enables CX 2 (X = O, S) Homocoupling with Spectator Cu Centers

Ligand non-innocence is ubiquitous in catalysis with ligands in synthetic complexes contributing as electron reservoirs or co-sites for substrate activation. The latter chemical non-innocence is manifested in H + storage or relay at sites beyond the metal primary coordination sphere. Reaction of a competent CO 2 -to-oxalate reduction catalyst, namely, [K(THF) 3 ](Cu 3 SL), where L 3– is a tris(β-diketiminate) cyclophane, with CS 2 affords tetrathiooxalate at long reaction times or at high CS 2 concentrations, where otherwise an equilibrium is established between the starting species and a complex–CS 2 adduct in which the CS 2 is bound to the C atom on the ligand backbone. X-ray diffraction analysis of this adduct reveals no apparent metal participation, suggesting an entirely ligand-based reaction controlled by the charge state of the cluster. Here, thermodynamic parameters for the formation of the aforementioned Cligand–CS 2 bond were experimentally determined, and trends with cation Lewis acidity were studied, where more acidic cations shift the equilibrium toward the adduct. Relevance of such an adduct in the reduction of CO 2 to oxalate by this complex is supported by DFT studies, similar effects of countercation Lewis acidity on product formation, and the homocoupled heterocumulene product speciation as determined by isotopic labeling studies. Taken together, this system extends chemical non-innocence beyond H + to effect catalytic transformations involving C–C bond formation and represents the rarest example of metal–ligand cooperativity, that is, spectator metal ion(s) and the ligand as the reaction center.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Model reduction in integrated controls-structures design

It is the objective of this paper to present a model reduction technique developed for the integrated controls-structures design of flexible structures. Integrated controls-structures design problems are typically posed as nonlinear mathematical programming problems, where the design variables consist of both structural and control parameters. In the solution process, both structural and control design variables are constantly changing; therefore, the dynamic characteristics of the structure are also changing. This presents a problem in obtaining a reduced-order model for active control design and analysis which will be valid for all design points within the design space. In other words, the frequency and number of the significant modes of the structure (modes that should be included) may vary considerably throughout the design process. This is also true as the locations and/or masses of the sensors and actuators change. Moreover, since the number of design evaluations in the integrated design process could easily run into thousands, any feasible order-reduction method should not require model reduction analysis at every design iteration. In this paper a novel and efficient technique for model reduction in the integrated controls-structures design process, which addresses these issues, is presented.

Maghami, Peiman G.↗

An SECM-Based Spot Analysis for Redoxmer-Electrode Kinetics: Identifying Redox Asymmetries on Model Graphitic Carbon Interfaces

The fundamental process in non-aqueous redox flow battery (NRFB) operation revolves around electron transfer (ET) between a current collector electrode and redox-active organic molecules (redoxmers) in solution. Here, we present an approach utilizing scanning electrochemical microscopy (SECM) to evaluate interfacial ET kinetics between redoxmers and various electrode materials of interest at desired locations. This spot-analysis method relies on the measurement of heterogeneous electron transfer rate constants (k f or k b ) as a function of applied potential (E-E 0 '). As demonstrated by COMSOL simulations, this method enables the quantification of Butler-Volmer kinetic parameters, the standard heterogeneous rate constant, k 0 , and the transfer coefficient, α. Our method enabled the identification of inherent asymmetries in the ET kinetics arising during the reduction of ferrocene-based redoxmers, compared to their oxidation which displayed faster rate constants. Similar behavior was observed on a wide variety of carbon electrodes such as multi-layer graphene, highly ordered pyrolytic graphite, glassy carbon, and chemical vapor deposition-grown graphite films. However, aqueous systems and Pt do not exhibit such kinetic effects. Our analysis suggests that differential adsorption of the redoxmers is insufficient to account for our observations. Displaying a greater versatility than conventional electroanalytical methods, we demonstrate the operation of our spot analysis at concentrations up to 100 mM of redoxmer over graphite films. Looking forward, our method can be used to assess non-idealities in a variety of redoxmer/electrode/solvent systems with quantitative evaluation of kinetics for applications in redox-flow battery research.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optimizing green infrastructure placement under precipitation uncertainty

Increased urbanization, infrastructure degradation, and climate change threaten to overwhelm stormwater systems across the nation, rendering them ineffective. Green Infrastructure (GI) practices are low cost, low regret strategies that can contribute to urban runoff management. However, questions remain as to how to best distribute GI practices through urban watersheds given precipitation uncertainty and the variable hydrological responses to them. We develop stochastic programming models to determine the optimal placement of GI practices across a set of candidate locations in a watershed to minimize the total expected runoff under medium-term precipitation uncertainties. Specifically, we first develop a two-stage stochastic programming model. Next, we reformulate this model using perturbed parameters to reduce the requisite computational time and extend it to multi-stage. In addition, we introduce constraints that allow for incorporating sub-catchment-level runoff reduction considerations. Furthermore, we account for hydrological connectivity in the watershed using an underlying acyclic connectivity graph of sub-catchments and incorporate various practical considerations into the models. In addition, we develop a systemic approach to downscale the existing daily precipitation projections into hourly units and efficiently estimate the corresponding hydrological responses. These advancements are brought together in a case study for an urban watershed in a mid-sized city in the U.S., where we perform sensitivity analyses, evaluate the importance of the considered constraints, and provide insights.

54 ENVIRONMENTAL SCIENCES↗

Multi-parametric analysis for mixed integer linear programming: An application to transmission upgrade and congestion management

Upgrading the capacity of existing transmission lines is essential for meeting the growing energy demands, facilitating the integration of renewable energy, and ensuring the security of the transmission system. This study focuses on the selection of lines whose capacities and by how much should be expanded from the perspective of the Independent System Operators (ISOs) to minimize the total system cost. We employ advanced multi-parametric programming and an enhanced branch-and-bound algorithm to address complex mixed-integer linear programming (MILP) problems, considering multi-period time constraints and physical limitations of generators and transmission lines. To characterize the various decisions in transmission expansion, we model the increased capacity of existing lines as parameters within a specified range. This study first relaxes the binary variables to continuous variables and applies the Lagrange method and Karush-Kuhn-Tucker (KKT) conditions to obtain optimal solutions and identify critical regions associated with active and inactive constraints. Moreover, we extend the traditional branch-and-bound (B&B) method by determining the problem’s upper and lower bounds at each node of the B&B decision tree, helping to manage computational challenges in large-scale MILP problems. Here, we compare the difference between the upper and lower bounds to obtain an approximate optimal solution within the decision-makers’ tolerable error range. In addition, the first derivative of the objective function on the parameters of each line is used to inform the selection of lines for easing congestion and maximizing social welfare. Finally, the capacity upgrades are selected by weighing the reductions in system costs against the expense of upgrading line capacities. The findings are supported by numerical simulations and provide transmission-line planners with decision-making guidance.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Effects of Absorber Near-Interface Compensation on Cd(Se,Te) Solar Cell Performance

Arsenic (As) has been shown to be an effective p-type dopant for CdTe, although high performance in As-doped devices remains difficult to achieve. Arsenic is prone to self-compensation in CdTe, as evidenced by the accumulation of dopant atoms in CdTe/Cd(Se,Te) near the interface with MgxZn1-xO (MZO). In this study, we use SCAPS 1D modeling software to investigate the effect of near-interface compensation, helping elucidate loss pathways in present-day As-doped devices and informing future growth directions. We consider three possible results of As accumulation: shallow donors, deep recombination centers, and a thin layer of excess acceptor accumulation. The reduction in near-interface carrier concentration caused by shallow donors is shown to improve open-circuit voltages (VOC), whereas deep levels are detrimental to all performance parameters. The thin charge layer affects capacitance-voltage (CV) measurements by reducing the depletion width while maintaining the same carrier concentration, replicating CV behavior that has been observed in actual devices. These results illustrate the importance of monitoring dopant accumulation within 100 nm of the interface, and suggest that reducing or eliminating the As concentration in this region would be beneficial. An undoped Cd(Se,Te) layer at the interface is suggested as a possible device structure to boost performance.

absorber↗

Noise reduction of EBF propulsive-lift systems

In a recently completed program, static and wind tunnel measurements have been made of the basic noise, noise reduction, and performance characteristics of externally blown flap (EBF) propulsive-lift systems. The static tests were performed on an outdoor model rig. Noise evaluations were made for parameters such as basic system geometry, flap slot dimension variation, elimination of flap slots, sweep angle variation, passive flap trailing edge modifications, active (blowing) trailing edge modifications, and for an ejector/decayer exhaust system. The wind tunnel evaluation determined forward speed effects on EBF systems noise characteristics. The results from the experimental programs are discussed as to their application to full scale short haul aircraft.

Gibson, J. S.↗

Application of the aerodynamic energy concept to flutter suppression and gust alleviation by use of active controls

The effects of active controls on flutter suppression and gust alleviation of the Arava twin turboprop STOL transport and the Westwind twinjet business transport are investigated. The active control surfaces are introduced in pairs which include, in any chosen wing strip, a 20-percent chord leading-edge control and a 20-percent chord trailing-edge control. Each control surface is driven by a combined linear-rotational sensor system located on the activated strip. The control law is based on the concept of aerodynamic energy and utilizes previously optimized control law parameters based on two-dimensional aerodynamic theory. The best locations of the activated system along the span of the wing are determined for bending-moment alleviation, reduction in fuselage accelerations, and flutter suppression. The effectiveness of the activated system over a wide range of maximum control deflections is also determined. Two control laws are investigated. The first control law utilizes both rigid-body and elastic contributions of the motion. The second control law employs primarily the elastic contribution of the wing and leads to large increases in the activated control effectiveness as compared with the basic control law. The results indicate that flutter speed can be significantly increased (over 70 percent increase) and that the bending moment due to gust loading can be almost totally eliminated by a control system of about 10 to 20 percent span with reasonable control-surface rotations.

Nissim, E.↗

The Application of Recent Techniques in Flight Flutter Testing

The relative merits of sinusoidal excitation versus random atmospheric turbulence was investigated. The randomdec and autocorrelation methods were used to analyze data from a Learjet flight test. A parameter identification digital program, using least squares approach, was developed to determine the aeroelastic characteristics of a two mode system. The flight test program, computer program, and data reduction procedure is presented. Final results of the two modes of excitation obtained by Randomdec method are discussed.

Abla, M. A.↗

Preliminary test results of the joint FAA-USAF-NASA runway research program. Part 1: Traction measurements of several runways under wet and dry conditions with a Boeing 727, a diagonal-braked vehicle, and a mu-meter

The stopping distance, brake application velocity, and time of brake application were measured for two modern jet transports, along with the NASA diagonal-braked vehicle and the British Mu-Meter on several runways, which when wetted, cover the range of slipperiness likely to be encountered in the United States. Tests were designed to determine if correlation between the aircraft and friction measuring vehicles exists. The test procedure, data reduction techniques, and preliminary test results obtained with the Boeing 727, the Douglas DC-9, and the ground vehicles are given. Time histories of the aircraft test run parameters are included.

Horne, W. B.↗

Noise characteristics of upper surface blown configurations: Summary

A systematic experimental program was conducted to develop a data base for the noise and related flow characteristics of upper surface blown configurations. The effect of various geometric and flow parameters was investigated experimentally. The dominant noise was identified from the measured flow and noise characteristics to be generated downstream of the trailing edge. The possibilities of noise reduction techniques were explored. An upper surface blown (USB) noise prediction program was developed to calculate noise levels at any point and noise contours (footprints). Using this noise prediction program and a cruise performance data base, aircraft design studies were conducted to integrate low noise and good performance characteristics. A theory was developed for the noise from the highly sheared layer of a trailing edge wake. Theoretical results compare favorably with the measured noise of the USB model.

Reddy, N. N.↗

Trajectory-Estimation Error Analysis

Orbital and Geodetic Parameter Estimation Error Analysis Program (ORAN) is Bayesian least-squares simulation program for orbital trajectories. ORAN does not process data; rather, computes accuracy of results of data reduction if measurements are processed by minimum-variance data-reduction program. Actual data used to provide time when given measurement was available and estimated noise on that measurement.

Putney, B.↗

Stability analysis of a buck regulator employing input filter compensation

The interaction between the input filter and the regulator often causes serious degradation of performance. The reduction in loop gain due to input filter interaction can result in system instability. An exact stability analysis of the buck regulator system is presented. The input filter parameter values are varied and system instability is predicted for the case without feedforward. The eigenvalues of the system can be brought back into the unit circle and the system thus stabilized with the addition of the feedforward loop. Measurements made for the cases with and without feedforward confirm the analytical prediction.

Kelkar, S. S.↗

Venus Gravity: Global Field Results

The Pioneer Venus Orbiter has provided a vast amount of gravity data, since March 1979. High resolution results have revealed the high correlation between topography and gravity. These data were acquired at relatively low spacecraft altitudes (150 km) where atmospheric effects and high frequency variations were significant and modelling with global spherical harmonics was difficult. During 1982 data were acquired over a complete Venus rotation where the lowest altitudes were 1000 km or more, thus removing atmospherics and high frequency gravity effects. These data that have been reduced to produce a tenth degree and order spherical harmonic model of the global gravity field of Venus. The reduction technique used a least squares where 78 independent arcs of data were combined in a simultaneous inversion. The tenth degree and order gravity field solution has 117 parameters describing the spherical harmonic coefficients. This provides approximately 1800 km feature resolution. These coefficients are presented as a geoid map.

Mottinger, N. A.↗

High-purity silicon crystal growth investigations

Information is given on evaporation and segregation contributions to impurity profiles of floating zone crystals (FZ); high-purity silicon float zoning (FZ); minority-carrier lifetime measurement of heavily doped silicon crystals; the effect of some crystal growth parameters on minority-carrier lifetime; and defect investigations by X-ray topography in graphical and tabular form. It was concluded that evaporation contributes substantially to impurity reduction when FZ or cold-crucible growth is conducted in a vacuum; boron and gallium may be more favorable dopants than indium or aluminum for obtaining high minority-carrier lifetimes; minority-carrier lifetimes greater than 100 microseconds are feasible at a 2 times 10 to the 17th power cm-3 doping level; minority-carrier lifetime decreases with increasing crystal cooling rate and also with the presence of dislocations; the method used to clean silicon feed rods affects lifetime; and microdefect densities in dislocation-free FZ crystals appear to be lower with Ga doping than with B doping.

Ciszek, T. F.↗

Constitutive modeling for isotropic materials

The first year of progress on a NASA-Lewis contract with the General Electric Co is documented. The purpose of this contract (NAS3-23927) is to develop and evaluate unified constitutive equations for applications to hot-path components of aircraft gas turbine engines such as high pressure turbine blades and vanes. To accomplish this goal, uniaxial, notched, and multiaxial specimens made of conventionally cast Rene 80 are being tested under conditions that simulate engine operating conditions. To reduce the raw data, automated data reduction techniques are being developed that produce computer files containing the information needed to analyze proposed constitutive theories. Described are the analytical methods being developed to determine the parameters for these nonlinear unified theories by using the reduced data files. In another activity, a dedicated finite-element computer code is being developed to use unified theories in the structural analysis of hot-section components. This code was extensively verified for one such theory by successfully predicting the strain histories measured experimentally at the notch root of complex specimens taken from complex laboratory specimens.

Ramaswamy, V. G.↗

Modeling and analysis of the space shuttle nose-gear tire with semianalytic finite elements

A computational procedure is presented for the geometrically nonlinear analysis of aircraft tires. The Space Shuttle Orbiter nose gear tire was modeled by using a two-dimensional laminated anisotropic shell theory with the effects of variation in material and geometric parameters included. The four key elements of the procedure are: (1) semianalytic finite elements in which the shell variables are represented by Fourier series in the circumferential direction and piecewise polynominals in the meridional direction; (2) a mixed formulation with the fundamental unknowns consisting of strain parameters, stress-resultant parameters, and generalized displacements; (3) multilevel operator splitting to effect successive simplifications, and to uncouple the equations associated with different Fourier harmonics; and (4) multilevel iterative procedures and reduction techniques to generate the response of the shell. Numerical results of the Space Shuttle Orbiter nose gear tire model are compared with experimental measurements of the tire subjected to inflation loading.

Kim, Kyun O.↗