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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
NASA NTRS1970

Research on rechargeable oxygen electrodes.

A research program is described which consisted of studying the effects of electrode cycling in very pure KOH solutions, with and without controlled additions of impurities, on oxide formation, oxygen evolution kinetics, oxygen reduction kinetics (including hydrogen peroxide formation), and changes in electrode structure. Bright platinum, platinized platinum, and Teflon-bonded platinum black electrodes were studied. Three main problem areas are identified: the buildup of a refractory anodic layer on prolonged cycling, which leads to a degradation of performance; the dissolution and subsequent deposition of dendritic platinum in the separator, leading to short-circuit ing and loss of electrocatalyst; and the disruptive effect of bubbling during gas evolution on charge. Each of these problem areas is analyzed, and remedial solutions are proposed.

Giner, J.↗
NASA NTRS1984

Probe of the Nearby Interstellar Medium by the Vacant Line of Sight to Beta Cma

The line of sight to Beta CM a was probed by Copernicus observations. This particular line of sight is remarkable for the low mean densities. The density was found to be bar N sub H approximately .002/cu cm. Two separate regions were distinguished: (1) A local nearby HI region extends over a few parsecs from the Sun with a density of the order of 0.1/cu cm and a temperature of 11000 to 12500 K; (2) An HII region lies somewhere beyond the HI region and is spread over about 60pc. Its total hydrogen mean density is of the same order as the HI region, i.e., of approximately 0.1 cu cm and it contains only elements in low ionization state. All the ata are coherent with the picture of a cloud in ionization equilibrium at T approximately 23000 deg K.

Gry, C.↗
NASA NTRS1986

Initial performance of advanced designs for IPV nickel-hydrogen cells

Advanced designs for individual pressure vessel nickel-hydrogen cells have been conceived which should improve the cycle life at deep depths-of-discharge and improve thermal management. Features of the designs which are new and not incorporated in either of the contemporary cells (Air Force/Hughes, Comsat) are: (1) use of alternate methods of oxygen recombination, (2) use of serrated edge separators to facilitate movement of gas within the cell while still maintaining required physical contact with the wall wick, and (3) use of an expandable stack to accommodate some of the nickel electrode expansion. The designs also consider electrolyte volume requirements over the life of the cells, and are fully compatible with the Air Force/Hughes design.

Smithrick, John J.↗
NASA NTRSDate not supplied

Mass Economy Evaluation for Integrated ECLSS and Propulsion Architecture

As missions in Low Earth Orbit (LEO) lengthen and extend to deep space, minimizing resupply needs becomes vital for sustaining crewed operations. Traditional life support systems depend on consumables resupplied from Earth, a method that is increasingly impractical for missions beyond LEO, such as lunar outposts or Mars transit. Long-duration missions require more efficient, autonomous systems that can recycle essential resources, particularly water and oxygen, to minimize the frequency and mass of resupply missions. The Environmental Control and Life Support System (ECLSS) is essential to such missions, with the International Space Station (ISS) serving as a testbed for advanced water recovery and partial oxygen recycling via physico-chemical methods. Yet, ECLSS and propulsion subsystems generally operate independently, despite overlapping requirements and potential areas for synergy. For instance, ECLSS byproducts, water, CO₂, and hydrogen, could be repurposed for propulsion, potentially reducing dedicated propellant mass and increasing overall system efficiency. One promising approach is to develop shared-resource architectures that integrate ECLSS with propulsion systems. This study examines the potential of such integration through the Sabatier CO₂ reduction process, focusing on water management as a key factor in system mass trade-offs. The Sabatier reaction produces water and methane from metabolic CO₂ and electrolytic hydrogen, partially closing the life support loop and providing methane, which could serve as a propellant. This integration could minimize waste, reduce resupply requirements, and enhance mission mass efficiency. A dynamic modeling framework will be used to simulate resource flows over long missions, capturing interactions between life support and propulsion. By comparing integrated versus separate system configurations, the study aims to quantify mass benefits and penalties, informing future habitat designs and trade studies for missions prioritizing autonomy and mass efficiency.

ECLSS↗
NASA NTRS2026

Mass Economy Evaluation for Integrated ECLSS and Propulsion Architecture

As missions in low Earth orbit (LEO) lengthen and extend to deep space, minimizing resupply needs becomes vital for sustaining crewed operations. Traditional life support systems depend on consumables resupplied from Earth, a method that is increasingly impractical for missions beyond LEO, such as lunar outposts or Mars transit. Long-duration missions require more efficient, autonomous systems that can recycle essential resources, particularly water and oxygen, to minimize the frequency and mass of resupply missions. The Environmental Control and Life Support System (ECLSS) is essential to such missions, with the International Space Station (ISS) serving as a testbed for advanced water recovery and partial oxygen recycling via physico-chemical methods. Yet, ECLSS and propulsion subsystems generally operate independently, despite overlapping requirements and potential areas for synergy. For instance, ECLSS byproducts, water, CO 2 , and hydrogen, could be repurposed for propulsion, potentially reducing dedicated propellant mass and increasing overall system efficiency. One promising approach is to develop shared-resource architectures that integrate ECLSS with propulsion systems. This study examines the potential of such integration through the Sabatier CO₂ reduction process, focusing on water management as a key factor in system mass trade-offs. The Sabatier reaction produces water and methane from metabolic CO 2 and electrolytic hydrogen, partially closing the life support loop and providing methane, which could serve as a propellant. This integration could minimize waste, reduce resupply requirements, and enhance mission mass efficiency. A dynamic modeling framework will be used to simulate resource flows over long missions, capturing interactions between life support and propulsion. By comparing integrated versus separate system configurations, the study aims to quantify mass benefits and penalties, informing future habitat designs and trade studies for missions prioritizing autonomy and mass efficiency.

ECLSS↗
DOE OSTI2021

Assessing the Activity of Ni Clusters Supported on TiC(001) toward CO 2 and H 2 Dissociation

Small Ni particles supported on TiC(001) were shown to display a very high activity for the catalytic hydrogenation of CO 2 but the underlying chemistry is, to a large extent, unknown. Here, by means of periodic density functional theory (DFT) calculations with the BEEF–vdW functional, we explore the adsorption and subsequent dissociation of CO 2 and H 2 on several Ni n clusters ( n = 4, 9, 13, and 16) supported on TiC(001) and compare the results to those obtained for the bare Ni(111) and TiC(001) surfaces using exactly the same computational approach. The calculations reveal that the Ni n /TiC system exhibits stronger adsorption energies and lower dissociation energy barriers for CO 2 and H 2 than the bare Ni(111) and TiC(001) surfaces. Furthermore, this is in line with the experimental finding evidencing that the Ni/TiC system has a catalytic activity higher than that of the separated Ni and TiC constituents. In addition, the calculated results show that two-dimensional (2D) supported clusters adsorb CO 2 and H 2 stronger than the three-dimensional (3D) supported clusters and also the 2D clusters exhibit lower energy barriers for CO 2 dissociation. Within the 2D supported clusters, larger particles feature slightly stronger adsorption energies and lower CO 2 dissociation energy barriers. Finally, H 2 dissociation proceeds with a very low energy barrier on all of the studied models, which makes these novel systems potential good candidates for hydrogenation reactions.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Continuous caustic aqueous phase electrochemical reforming (CAPER) of ethanol for producing compressed hydrogen

Caustic Aqueous Phase Electrochemical Reforming (CAPER) of ethanol produces pure compressed H 2 at lower voltages, temperatures, and energy requirements than conventional electrolysis, while capturing carbonaceous products. The CAPER flow reactor consists of stainless steel endplates, stainless steel current collectors, and a Teflon flow field. The electrodes are prepared using commercial palladium nanoparticles on carbon support for the anode and platinum nanoparticles on carbon support for the cathode. The catalyst metal loading was 1 mgcm –2 on a 10cm 2 carbon cloth for both electrodes. Our CAPER reactor produces pure H 2 at 80bar and 80°C applying voltages at ≤0.5V. The only gas-phase product detected was H 2 and any carbonaceous products were contained in the liquid phase. The H 2 was produced with 97±4% faradaic efficiency. Further, operating at smaller electrode separation distances (4mm) and 80°C increased the current density. The highest lower heating value efficiency achieved was 28% at a flow rate of 0.05mLmin –1 and an applied voltage of 0.5V. The compressed H 2 was produced at ≤20 kWh kg –1 , which is much lower than electrolysis systems that require upwards of 50 kWh kg –1 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Roles of interaction between components in CZZA/HZSM-5 catalyst for dimethyl ether synthesis via CO 2 hydrogenation

The roles of interaction between two catalyst components in CuO–ZnO–ZrO 2 –Al 2 O 3 (CZZA)/HZSM-5 bifunctional catalyst for dimethyl ether (DME) synthesis via carbon dioxide hydrogenation were investigated. It was found that CZZA catalyst showed excellent stability during methanol (MeOH) synthesis for 100 h, while there was a severe loss of catalytic activity in the bifunctional catalyst for DME synthesis. So, the effects of different degrees of intimacy of two catalyst components were studied for DME synthesis, including mixed and separated modes. For the mixed mode, the particle size of catalysts and the amount of reaction intermediates were proven to influence the catalyst deactivation. For the separated mode, the catalysts showed rapid deactivation within a short time. Various characterizations indicated that the remarkable deactivation of separated mode was mainly caused by the decrease of copper active centers (e.g., sintering and oxidation) and blockage of acid sites via increased coke deposition on HZSM-5.

42 ENGINEERING↗
DOE OSTI2024

Removing Basis Set Incompleteness Error in Finite-Temperature Electronic Structure Calculations: Two-Electron Systems

We investigate the basis-set-size dependence for quantities related to interacting electrons in the canonical ensemble. Calculations are performed using exact diagonalization (finite temperature full configuration interaction method) on two-electron model systems–the uniform electron gas (UEG) and the helium atom. Our data reproduce previous observations of a competition for how the internal energy converges between the ground-state correlation energy and the high-temperature kinetic energy. We explore how this can be related to component parts of the internal energy including kinetic, exchange, and correlation energies and show there is surprising nuance in how this can be broken down into mostly monotonically converging quantities. We also show that separation of the free energy into a free energy with/without correlation allows for monotonic convergence with basis set size due to the variational principle. We find that the free energy convergence matches the previously observed convergence properties of the internal energy. We discuss the free energy divergence that happens when converging a finite basis analytical hydrogen atom to the complete basis set limit and compare this to the energies of a helium atom in a large periodic box. Reducing the box size, we saw convergence trends for the helium atom that were similar to the UEG.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1958

Effect of Target-type Thrust Reverser on Transonic Aerodynamic Characteristics of a Single-engine Fighter Model

A brief investigation of a target-type thrust reverser on a single-engine fighter model has been conducted in the Langley 16-foot transonic tunnel at Mach numbers from 0.20 to 1.05.At Mach numbers of 0.80, 0.92, and 1.05, a hydrogen peroxide turbojet-engine simulator was operated with the thrust reverser extended. The angle of attack was varied from 0 degrees to 5 degrees at these Mach numbers. The Reynolds number of the free stream, based on the mean aerodynamic chord, was about 5 x 10(6). It was estimated that reversed jet operations separated the model boundary-layer flow over the upper surface of the horizontal tail and upper part of the afterbody. This resulted in a positive pitch increment due to reversed jet operation. Jet-on operation also tended to stabilize the severe lateral oscillations which occurred with the reverser extended and the jet off. It appeared that these jet-off oscillations were the result of an alternating separation and reattachment of the flow on the rearmost portions of the fuselage afterbody.

Swihert, John M↗
NASA NTRS1995

Energization and transport of ions of ionospheric origin in the terrestrial magnetosphere

The work of this grant has been predominantly focused on ion outflows from two data sets: Prognoz 7 and Dynamics Explorer. The Prognoz analysis studied ion densities, temperatures, and flow velocities in the magnetotail. The work performed under this contract consisted of developing a program to load the raw data, computing the background subtraction of a strong sun pulse, and using the net count to calculate the low order moments of the distribution function. The study confirms the results of ISEE with regard to the supply of plasma from the cusp as a major source of plasmasheet plasma and goes beyond this to discuss the use of ion velocities as a way to examine the motions of the magnetotail. The abstract of the work to be reported is included as an appendix. The work on the DE/Retarding Ion Mass Spectrometer is separated into two categories: (1) classification of low-energy ion flows from high-latitudes, and (2) studies of the polar wind. Major publications resulting from this work are also included as an appendix to this report. The polar wind is in a category by itself as a result of the thermal escape of hydrogen and helium because of ambipolar diffusion through the heavier, oxygen-dominated topside ionosphere. The analysis of the polar wind reports the flux variability as a function of season, magnetic activity, etc. Much effort has been expended under this grant to complete a follow on study of the thermal structure of the polar wind. Extensive display tools and analysis software have been developed and used in an attempt to carry out this thermal analysis. The present work uses a constrained fit scheme that combines the ion densities and flow velocities derived from Chandler et al. and a spacecraft potential derived from an empirical relation to the total ion density to determine the remaining fit parameter, the ion temperature, via a least squares fit to the RIMS data.

Waite, J. Hunter JR.↗
NASA NTRS1994

Effects of the intense solar activity of March/June 1991 observed in the outer heliosphere

The properties of the large-scale global merged interaction region (GMIR) generated by the intense solar events of March and June 1991 are studied using the available solar wind, interplanetary magnetic field, and energetic particle data from the observing network of Pioneer 10 and Voyagers 1 and 2 in the outer heliosphere. At heliocentric distances extending to 55 AU the delayed effects of this enhanced solar activity are observed in the form of large inceases in the solar wind velocity and interplanetary magnetic field and significant decreases in the galactic cosmic ray intensity. For low-energy ions (5-MeV protons) there was a single long-lived event extending over a period of some 6 months. Near the strongest interplanetary disturbances the H and He spectra are best represented by similar exponentials in momentum/nucleon (i.e., particle velocity at these at these energies). Over the rest of the event the characteristic momentum for He, (P(sub 0))(sub He) is generally approximately 0.66 for hydrogen. These spectra and the consistently low H/He ratio (25.3) at 2 MeV/nucleon closely resemble that observed in corrotating interaction regions events. Despite the strong north/south asymmetry in the solar activity, the interplanetary disturbances produced the same net decrease in the galactic cosmic ray intensity of ions greater than 70 MeV at the three widely separated spacecraft when the effects of the long-term recovery are taken into account. A comparison of the relative intensity of MeV ions at these three spacecraft suggest that the most intense solar events occurred on the back side of the Sun in time periods adjacent to the March and June episodes of solar activity. It is argued that this GMIR as a system is responsible for the low-frequency radio emission observed by the Voyager Plasma Wave experiment some 1.46 years after the onset of the March 1991 activity.

Mcdonald, F. B.↗
NASA NTRS1998

Challenging Pneumatic Requirements for Acoustic Testing of the Cryogenic Second Stage for the New Delta 3 Rocket

The paper describes the unique pneumatic test requirements for the acoustic and shock separation testing of the Second Stage for the new Delta III Rocket at the Goddard Space Flight Center in Greenbelt, Maryland. The testing was conducted in the 45,000 cu ft (25-feet wide by 30-feet deep by 50-foot high) Acoustic Facility. The acoustic testing required that the liquid oxygen (LOX) and liquid hydrogen (LH2) tanks be filled with enough liquid nitrogen (LN2) to simulate launch fuel masses during testing. The challenge for this test dealt with designing, procuring, and fabricating the pneumatic supply systems for quick assembly while maintaining the purity requirements and minimizing costs. The pneumatic systems were designed to fill and drain the both LOX and LH2 tanks as well as to operate the fill/drain and vent valves for each of the tanks. The test criteria for the pneumatic sub-systems consisted of function, cleanliness, availability, and cost. The first criteria, function, required the tanks to be filled and drained in an efficient manner while preventing them from seeing pressures greater than 9 psig which would add a pressure cycle to the tank. An LN2 tanker, borrowed from another NASA facility, served as the pre-cool and drain tanker. Pre-cooling the tanks allowed for more efficient and cost effective transfer from the LN2 delivery tankers. Helium gas, supplied from a high purity tube trailer, was used to pressurize the vapor space above the LN2 pushing it into the drain tanker. The tube trailer also supplied high pressure helium to the vehicle for valve control and component purges. Cleanliness was maintained by proper component selection, end-use particle filtration, and any on-site cleaning determined necessary by testing. In order to meet the availability/cost juggling act, products designed for LOX delivery systems were procured to ensure system compatibility while off the shelf valves and tubing designed for the semiconductor industry were procured for the gas systems.

Webb, Andrew T.↗
NASA NTRS2017

Early Hydrodynamic Escape Limits Rocky Planets to Less Than or Equal to 1.6 Earth Radii

In the past decade thousands of exoplanet candidates and hundreds of confirmed exoplanets have been found. For sub-Neptune-sized planets, those less than approx. 10 Earth masses, we can separate planets into two broad categories: predominantly rocky planets, and gaseous planets with thick volatile sheaths. Observations and subsequent analysis of these planets show that rocky planets are only found with radii less than approx. 1.6 Earth radii. No rocky planet has yet been found that violates this limit. We propose that hydrodynamic escape of hydrogen rich protoatmospheres, accreted by forming planets, explains the limit in rocky planet size. Following the hydrodynamic escape model employed by Luger et al. (2015), we modelled the XUV driven escape from young planets (less than approx.100 Myr in age) around a Sun-like star. With a simple, first-order model we found that the rocky planet radii limit occurs consistently at approx. 1.6 Earth radii across a wide range of plausible parameter spaces. Our model shows that hydrodynamic escape can explain the observed cutoff between rocky and gaseous planets. Fig. 1 shows the results of our model for rocky planets between 0.5 and 10 Earth masses that accrete 3 wt. % H2/He during formation. The simulation was run for 100 Myr, after that time the XUV flux drops off exponentially and hydrodynamic escape drops with it. A cutoff between rocky planets and gaseous ones is clearly seen at approx. 1.5-1.6 Earth radii. We are only interested in the upper size limit for rocky planets. As such, we assumed pure hydrogen atmospheres and the highest possible isothermal atmospheric temperatures, which will produce an upper limit on the hydrodynamic loss rate. Previous work shows that a reasonable approximation for an upper temperature limit in a hydrogen rich protoatmosphere is 2000-3000 K, consistent with our assumptions. From these results, we propose that the observed dichotomy between mini-Neptunes and rocky worlds is simply explained by an early episode of thermally-driven hydrodynamic escape when host stars have saturated XUV fluxes.

Lehmer, O. R.↗
DOE OSTI2020

Stabilization of Photocatalytically Active Uranyl Species in a Uranyl–Organic Framework for Heterogeneous Alkane Fluorination Driven by Visible Light

When photoactivated, the uranyl ion is a robust oxidant capable of abstracting hydrogen atoms from nonactivated C–H bonds. Yet, the highly reactive singly reduced [U V O 2 ] + intermediate is unstable with respect to disproportionation to the uranyl dication and insoluble tetravalent uranium phases, which limits the usage of uranyl ions as robust photocatalysts. Herein, we demonstrate that photoactivated uranyl ions can be stabilized by immobilizing and separating them spatially in a uranyl–organic framework heterogeneous catalyst, NU-1301. The visible-light-photoactivated uranyl ions in NU-1301 demonstrated longer-lived U(V) and radicals than those in homogeneous counterparts, as evidenced by X-ray photoelectron spectroscopy and time-dependent electron paramagnetic resonance, leading to higher turnovers and enhanced stability for the fluorination of nonactivated alkanes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Influence of Added Salt on Chain Conformations in Poly(ethylene oxide) Melts: SANS Analysis with Complications

Poly(ethylene oxide) (PEO)-based electrolytes have gained increasing attention in both the rechargeable battery industry and fundamental research, but any influence of the ions on the polymer conformation is not fully understood. Small-angle neutron scattering (SANS) is a powerful means to determine single-polymer chain conformations. We conducted SANS experiments on 50:50 blends of perdeuterated PEO (dPEO) and hydrogenous PEO (hPEO) of two different molecular weights (20 and 40 kDa) doped with two different salts (LiTFSI and LiClO 4 ) at various concentrations. An additional measurement with LiI is also reported. The scattering profiles of salt-doped dPEO/hPEO blends were measured, and the incoherent scattering from dPEO and hPEO doped with salt was measured separately. A strong low q upturn was observed in some of the blends and in the pure dPEO homopolymers. The statistical segment lengths of PEO–salt mixtures were derived using a Kratky analysis. The segment length decreases modestly with increasing amounts of LiTFSI but apparently first increases then decreases with added LiClO 4 . At the highest salt concentration examined (r = [Li+]/[EO] = 0.125), a roughly 10% decrease in the statistical segment length was observed in both LiTFSI and LiClO 4 -doped PEOs, for both molecular weights. This work confirms that added salt causes a contraction of the PEO chain dimensions, but the effect appears slightly weaker than reported recently. Certain difficulties in data analysis are also discussed, including the unexplained low q scattering even in pure deuterated polymers, uncertainties in background subtraction, and inappropriate application of the Debye function.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Selective Photodimerization in a Cyclodextrin Metal–Organic Framework

For the most part, enzymes contain one active site wherein they catalyze in a serial manner chemical reactions between substrates both efficiently and rapidly. Imagine if a situation could be created within a chiral porous crystal containing trillions of active sites where substrates can reside in vast numbers before being converted in parallel into products. Here, we report how it is possible to incorporate 1-anthracenecarboxylate (1-AC – ) as a substrate into a γ-cyclodextrin-containing metal–organic framework (CD-MOF-1), where the metals are K + cations, prior to carrying out [4+4] photodimerizations between pairs of substrate molecules, affording selectively one of four possible regioisomers. One of the high-yielding regioisomers exhibits optical activity as a result of the presence of an 8:1 ratio of the two enantiomers following separation by high-performance liquid chromatography. The solid-state superstructure of 1-anthracenecarboxylate potassium salt (1-ACK), which is co-crystallized with γ-cyclodextrin, reveals that pairs of substrate molecules are not only packed inside tunnels between spherical cavities present in CD-MOF-1, but also stabilized—in addition to hydrogen-bonding to the C-2 and C-3 hydroxyl groups on the d-glucopyranosyl residues present in the γ-cyclodextrin tori—by combinations of hydrophobic and electrostatic interactions between the carboxyl groups in 1-AC– and four K + cations on the waistline between the two γ-cyclodextrin tori in the tunnels. Here, these non-covalent bonding interactions result in preferred co-conformations that account for the highly regio- and enantioselective [4+4] cycloaddition during photoirradiation. Theoretical calculations, in conjunction with crystallography, support the regio- and stereochemical outcome of the photodimerization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1982

The relationship between carbon monoxide abundance and visual extinction in interstellar clouds

Carbon monoxide column densities are compared to visual extinctions toward field stars in the rho Oph and Taurus molecular cloud complexes. The relationship of C(0-18) column density to extinction is established, and new determinations for (C-13)O column densities are given for a range of visual extinctions extended to beyond 20 mag. A prescription for determining hydrogen column densities and masses of molecular clouds from observations of CO isotopes is presented and discussed critically. These measurements agree well with the predictions of gas phase chemistry models which include chemical fractionation and selective isotopic photodestruction. The functional dependence of the C(O-18) column density on extinction is characterized by two different regimes separated by a distinct transition observed to occur at 4 mag in both molecular cloud complexes, whereas the functional dependence of (C-13)O is quite different in the two regions. Some saturation is found to occur for C(O-18) emission at high visual extinction and use the rarer isotopic species C(O-17) and (C-13)(O-18) to correct for it.

Frerking, M. A.↗