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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Techno-Economic Analysis of Repurposing Natural Gas Transmission Pipeline Networks to Accommodate Hydrogen Blends

Blending hydrogen into natural gas infrastructure could supplement natural gas supply and increase resilience for applications such as ammonia production, peaking and load-following power plants, and heating. The United States has an extensive network of natural gas pipelines, but the feasibility of employing this infrastructure to transport hydrogen is unclear. We analyze the costs associated with repurposing three distinct natural gas transmission pipelines in different locations within the United States to carry blends of hydrogen up to 100% via three different pipeline network modification methods and compare against the cost of building a new dedicated hydrogen pipeline. We conduct a sensitivity analysis on the hoop stress limit of the existing pipe, techno-economic parameters, emissions, and relative capacity. The results show that the capital costs required to upgrade a pipeline can vary from tens of millions to billions of dollars depending on the length and capacity of the existing pipeline section, whether the existing pipeline already operates at or below its maximum allowable operating pressure, whether future demand is expected to increase or decrease, the network modification method selected, and pipe material costs. The delivered cost of energy to end users is impacted less by the levelized cost of transporting hydrogen blends than by the cost of the natural gas and hydrogen fuels being transported. The emissions impact of blending hydrogen into natural gas transmission networks scales proportionally with the amount of energy displaced with low-emission hydrogen (such as from natural gas with carbon capture and sequestration or electrolysis powered by nuclear, renewable, or geothermal electricity), therefore low blend ratios (e.g., < 20% vol. hydrogen) will result in low emissions impacts. Factors such as permitting and right-of-way costs, the proximity of the pipeline to hydrogen demand and production, and the compatibility of and/or retrofitting costs of end-use gas-fueled technologies will likely be greater drivers in determining whether converting a particular natural gas pipeline to carry hydrogen makes economic sense.

08 HYDROGEN↗
NASA NTRS2010

Empirical Method to Estimate Hydrogen Embrittlement of Metals as a Function of Hydrogen Gas Pressure at Constant Temperature

High pressure Hydrogen (H) gas has been known to have a deleterious effect on the mechanical properties of certain metals, particularly, the notched tensile strength, fracture toughness and ductility. The ratio of these properties in Hydrogen as compared to Helium or Air is called the Hydrogen Environment Embrittlement (HEE) Index, which is a useful method to classify the severity of H embrittlement and to aid in the material screening and selection for safety usage H gas environment. A comprehensive world-wide database compilation, in the past 50 years, has shown that the HEE index is mostly collected at two conveniently high H pressure points of 5 ksi and 10 ksi near room temperature. Since H embrittlement is directly related to pressure, the lack of HEE index at other pressure points has posed a technical problem for the designers to select appropriate materials at a specific H pressure for various applications in aerospace, alternate and renewable energy sectors for an emerging hydrogen economy. Based on the Power-Law mathematical relationship, an empirical method to accurately predict the HEE index, as a function of H pressure at constant temperature, is presented with a brief review on Sievert's law for gas-metal absorption.

Lee, Jonathan A.↗
DOE OSTI2020

Prediction of organic homolytic bond dissociation enthalpies at near chemical accuracy with sub-second computational cost

Bond dissociation enthalpies (BDEs) of organic molecules play a fundamental role in determining chemical reactivity and selectivity. However, BDE computations at sufficiently high levels of quantum mechanical theory require substantial computing resources. In this paper, we develop a machine learning model capable of accurately predicting BDEs for organic molecules in a fraction of a second. We perform automated density functional theory (DFT) calculations at the M06-2X/def2-TZVP level of theory for 42,577 small organic molecules, resulting in 290,664 BDEs. A graph neural network trained on a subset of these results achieves a mean absolute error of 0.58 kcal mol-1 (vs DFT) for BDEs of unseen molecules. We further demonstrate the model on two applications: first, we rapidly and accurately predict major sites of hydrogen abstraction in the metabolism of drug-like molecules, and second, we determine the dominant molecular fragmentation pathways during soot formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Divertor detachment in the pre-fusion power operation phase in ITER during application of resonant magnetic perturbations

Detachment of the divertor plasma during application of resonant magnetic perturbation (RMP) fields is evaluated for hydrogen H-mode plasma during the first pre-fusion power operation (PFPO-1) phase in ITER by 3D plasma boundary modelling with EMC3–EIRENE. Plasma response effects from a linearized, resistive, single fluid MHD model are discussed, which includes partial screening of the externally applied field—but also field amplification near the separatrix. Furthermore, this field amplification is found to play a pivotal role for the magnetic footprint on the divertor targets, but is sensitive to model parameters. Extensions of the footprint beyond the straight portions of the ITER vertical divertor targets, optimized for high stationary heat flux handling, may be possible depending on the level of toroidal rotation in the plasma. Exhaust from the bulk plasma is guided by the helical corrugations (lobes) of the perturbed separatrix, and this results in an upstream heat flux that is distributed over these lobes with lower peak values than in the typical radial heat flux profiles seen in the absence of magnetic perturbations. As a consequence, an earlier onset (with respect to the upstream density) of detachment is found in the traditional strike zone when RMPs are applied, but secondary, non-axisymmetric strike locations appear—and those remain attached at temperatures above 10 eV. Neon seeding can mitigate these non-axisymmetric heat loads, but this becomes less efficient for large magnetic footprints.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Turbine Aero-Thermal Technologies for 65% Combined Cycle Efficiency (Phase I Final Report)

GE Power (GEP), a division of General Electric Company, performed a gas turbine technology development program that integrated Aerodynamic and Heat Transfer advances as an important and innovative step towards the DOE goal of 65% combined cycle efficiency. Improved efficiency will also contribute towards the reduction in the cost of electricity identified by the DOE for the US through reduced fuel consumption, and through lowering the capital cost of the generating equipment. It is currently predicted that the result of this project will enable 0.40~0.65 pt in combined cycle efficiency improvement. This technology will be directly applicable to gas turbines utilizing coal gasification processes where hydrogen-rich coal-derived synthesis gas is produced with natural gas being the developmental fuel.

03 NATURAL GAS↗
DOE OSTI2021

Aluminization Coatings and Glass Seals for High Temperature System: CRADA 536 [Abstract Only]

The proposed work will demonstrate the suitability of PNNL Reactive Air Aluminization (RAA) coatings (US Patent Numbers 10,577,694, 10,378,094, and 9,481,923) for use in high-temperature systems. In particular, the Participant and Contractor will explore applicability of these coatings in Participant’s high-temperature hydrogen reactors where they would be used to prepare the sealing surfaces of the reactor technology. Utility Global will also instruct PNNL regarding their needs relating to the further development of glass seal technologies that are suitable for use in their systems. This effort will entail alkaline earth-based silicate glass development and characterization; evaluation and characterization of reliability and compatibility of the coatings with glass seals, working environments, and substrates; performance demonstrations of representative cells and intermediate cells sealed using the glass seals and/or coatings of interest; and incorporation of the aluminization coatings and glass seals into the reactor for full-scale testing.

08 HYDROGEN↗
DOE OSTI2022

Recent Progress on Emerging Applications of Hydrochar

Hydrothermal carbonization (HTC) is a prominent thermochemical technology that can convert high-moisture waste into a valuable product (called hydrochar) at a relatively mild treatment condition (180–260 °C and 2–10 MPa). With rapidly growing research on HTC and hydrochar in recent years, review articles addressing the current and future direction of this research are scarce. Hence, this article aims to review various emerging applications of hydrochars, e.g., from solid fuel to soil amendment, from electron storage to hydrogen storage, from dye adsorption, toxin adsorption, heavy metal adsorption to nutrient recovery, and from carbon capture to carbon sequestration, etc. This article further provides an insight in the hydrochar’s working mechanism for various applications and how the applications can be improved through chemical modification of the hydrochar. Finally, new perspectives with appropriate recommendations have been made to further unveil potential applications and its improvement through hydrochar and its modified version.

09 BIOMASS FUELS↗
DOE OSTI2021

One-Dimensional (1D) Nanostructured Materials for Energy Applications

At present, the world is at the peak of production of traditional fossil fuels. Much of the resources that humanity has been consuming (oil, coal, and natural gas) are coming to an end. The human being faces a future that must necessarily go through a paradigm shift, which includes a progressive movement towards increasingly less polluting and energetically viable resources. In this sense, nanotechnology has a transcendental role in this change. For decades, new materials capable of being used in energy processes have been synthesized, which undoubtedly will be the cornerstone of the future development of the planet. In this review, we report on the current progress in the synthesis and use of one-dimensional (1D) nanostructured materials (specifically nanowires, nanofibers, nanotubes, and nanorods), with compositions based on oxides, nitrides, or metals, for applications related to energy. Due to its extraordinary surface–volume relationship, tunable thermal and transport properties, and its high surface area, these 1D nanostructures have become fundamental elements for the development of energy processes. The most relevant 1D nanomaterials, their different synthesis procedures, and useful methods for assembling 1D nanostructures in functional devices will be presented. Applications in relevant topics such as optoelectronic and photochemical devices, hydrogen production, or energy storage, among others, will be discussed. The present review concludes with a forecast on the directions towards which future research could be directed on this class of nanostructured materials.

Machín, Abniel (ORCID:0000000341343344)↗
NASA NTRS1971

Shock tube technique for measuring opacities at high pressures for gaseous-core nuclear rockets.

A new method of opacity determination is described that uses an improved shock tube design and is applicable to measurements of Planck and Rosseland mean opacities in hydrogen or seeded hydrogen at hydrogen partial pressures of 500 atm, at temperatures from 2300 to 8000 K. The selection of seed materials to be added to the gases to make them semiopaque is discussed. Currently favored seeds are silicon and carbon or graphite for reactive seeds, and depleted uranium and tungsten 184 for nonreactive seeds.

Patch, R. W.↗
NASA NTRS1978

The 11th Annual Battery Workshop

The development, properties, and testing of nickel cadmium, metal hydrogen, and lithium systems are discussed, as well as their applications and related safety factors.

Source record↗
NASA NTRS1989

Advances in lightweight nickel electrode technology

Studies are currently underway to further the development of lightweight nickel electrode technology. Work is focused primarily on the space nickel-hydrogen system and nickel-iron system but is also applicable to the nickel-cadmium and nickel-zinc systems. The goal is to reduce electrode weight while maintaining or improving performance thereby increasing electrode energy density. Two basic electrode structures are being investigated. The first is the traditional nickel sponge produced from sintered nickel-carbonyl powder and the second is a new material for this application which consists of a non-woven mat of nickel fiber. Electrodes are being manufactured, tested and evaluated at the electrode and cell level.

Coates, Dwaine↗
NASA NTRS1989

Advances in lightweight nickel electrode technology

Studies are currently underway to further the development of lightweight nickel electrode technology. Work is focused primarily on the space nickel-hydrogen system and nickel-iron system but is also applicable to the nickel-cadmium and nickel-zinc systems. The goal is to reduce electrode weight while maintaining or improving performance, thereby increasing electrode energy density. Two basic electrode structures are being investigated. The first is the traditional nickel sponge produced from sintered nickel-carbonyl powder. The second is a new material for this application which consists of a non-woven mat of nickel fiber. Electrodes are being manufactured, tested, and evaluated at the electrode and cell level.

Coates, Dwaine↗
NASA NTRS1997

The Systematic Interpretation of Cosmic Ray Data (The Transport Project)

The Transport project's primary goals were to: (1) Provide measurements of critical fragmentation cross sections; (2) Study the cross section systematics; (3) Improve the galactic cosmic ray propagation methodology; and (4) Use the new cross section measurements to improve the interpretation of cosmic ray data. To accomplish these goals a collaboration was formed consisting of researchers in the US at Louisiana State University (LSU), Lawrence Berkeley Laboratory (LBL), Goddard Space Flight Center (GSFC), the University of Minnesota (UM), New Mexico State University (NMSU), in France at the Centre d'Etudes de Saclay and in Italy at the Universita di Catania. The US institutions, lead by LSU, were responsible for measuring new cross sections using the LBL HISS facility, analysis of these measurements and their application to interpreting cosmic ray data. France developed a liquid hydrogen target that was used in the HISS experiment and participated in the data interpretation. Italy developed a Multifunctional Neutron Spectrometer (MUFFINS) for the HISS runs to measure the energy spectra, angular distributions and multiplicities of neutrons emitted during the high energy interactions. The Transport Project was originally proposed to NASA during Summer, 1988 and funding began January, 1989. Transport was renewed twice (1991, 1994) and finally concluded at LSU on September, 30, 1997. During the more than 8 years of effort we had two major experiment runs at LBL, obtained data on the interaction of twenty different beams with a liquid hydrogen target, completed the analysis of fifteen of these datasets obtaining 590 new cross section measurements, published nine journal articles as well as eighteen conference proceedings papers, and presented more than thirty conference talks.

Guzik, T. Gregory↗
NASA NTRS2007

PillCam(TradeMark), a Noninvasive Endoscopic Device for the Measurement of Gastrointestinal Motility Changes

Introduction: Bioavailability and effectiveness of drugs given by mouth are governed in part by gastrointestinal (GI) motility and function. Microgravity has been shown to decrease GI motility as indicated by a 3 fold increase in gastrointestinal transit time (GITT). The PillCam(TradeMark), an endoscopic camera embedded in a capsule, is a novel noninvasive and unobtrusive device that is used for the diagnosis of GI pathology. The purpose of this study is to evaluate the usefulness of PillCam(TradeMark) as an alternative to the Lactulose Breath Hydrogen Test (LBHT) for estimating GI motility. The sensitivity and applicability of this device for detection and estimation of the effect of promethazine, a deterrent, and caffeine, a prokinetic, on GI motility were also examined. Method: In this semi-randomized cross-over design study, six male and six female subjects were administered the following 4 treatments: PillCam(TradeMark) alone, PillCam(TradeMark)+Lactulose (10g), PillCam(TradeMark)+caffeine (200mg), and PillCam(TradeMark)+Promethazine (50mg). Results: GITT ranged between 1:24 and 7:52 hr:min. Lactulose did not alter GITT. A significant increase in GITT was noticed after administration of PMZ when compared to values from PillCam(TradeMark) treatment alone or PillCam(TradeMark)+Lactulose treatment. No difference in GITT after caffeine treatment was noticed. While there were no gender related differences in GITT after administration of PillCam(TradeMark) or with lactulose, a significant difference (p<.05) between genders was observed after promethazine administration with mean GITT higher in males (5:50 hr:min) than females (4:15 hr:min). Conclusion: The PillCam(TradeMark) capsule is applicable for the determination of GITT using time stamped GI images. It can be successfully used for the assessment of drug induced changes in GI motility and therefore, may be applicable for microgravity and analog environment studies on GI motility and function.

Vaksman, Zahman↗
NASA NTRS2010

Combustion Stability Analyses for J-2X Gas Generator Development

The National Aeronautics and Space Administration (NASA) is developing a liquid oxygen/liquid hydrogen rocket engine for upper stage and trans-lunar applications of the Ares vehicles for the Constellation program. This engine, designated the J-2X, is a higher pressure, higher thrust variant of the Apollo-era J-2 engine. Development was contracted to Pratt & Whitney Rocketdyne in 2006. Over the past several years, development of the gas generator for the J-2X engine has progressed through a variety of workhorse injector, chamber, and feed system configurations. Several of these configurations have resulted in injection-coupled combustion instability of the gas generator assembly at the first longitudinal mode of the combustion chamber. In this paper, the longitudinal mode combustion instabilities observed on the workhorse test stand are discussed in detail. Aspects of this combustion instability have been modeled at the NASA Marshall Space Flight Center with several codes, including the Rocket Combustor Interaction Design and Analysis (ROCCID) code and a new lumped-parameter MatLab model. To accurately predict the instability characteristics of all the chamber and injector geometries and test conditions, several features of the submodels in the ROCCID suite of calculations required modification. Finite-element analyses were conducted of several complicated combustion chamber geometries to determine how to model and anchor the chamber response in ROCCID. A large suite of sensitivity calculations were conducted to determine how to model and anchor the injector response in ROCCID. These modifications and their ramification for future stability analyses of this type are discussed in detail. The lumped-parameter MatLab model of the gas generator assembly was created as an alternative calculation to the ROCCID methodology. This paper also describes this model and the stability calculations.

Hulka, J. R.↗
NASA NTRS2010

J-2X Gas Generator Development Testing at NASA Marshall Space Flight Center

NASA is developing a liquid oxygen/liquid hydrogen rocket engine for upper stage and trans-lunar applications of the Ares vehicles for the Constellation program. This engine, designated the J-2X, is a higher pressure, higher thrust variant of the Apollo-era J-2 engine. Development was contracted to Pratt & Whitney Rocketdyne in 2006. Over the past several years, two phases of testing have been completed on the development of the gas generator for the J-2X engine. The hardware has progressed through a variety of workhorse injector, chamber, and feed system configurations. Several of these configurations have resulted in combustion instability of the gas generator assembly. Development of the final configuration of workhorse hardware (which will ultimately be used to verify critical requirements on a component level) has required a balance between changes in the injector and chamber hardware in order to successfully mitigate the combustion instability without sacrificing other engine system requirements. This paper provides an overview of the two completed test series, performed at NASA s Marshall Space Flight Center. The requirements, facility setup, hardware configurations, and test series progression are detailed. Significant levels of analysis have been performed in order to provide design solutions to mitigate the combustion stability issues, and these are briefly covered. Also discussed are the results of analyses related to either anomalous readings or off-nominal testing throughout the two test series.

Reynolds, D. C.↗
DOE OSTI2024

Hydrogen Production and Li-Ion Battery Performance with MoS2-SiNWs-SWNTs@ZnONPs Nanocomposites

This study explores the hydrogen generation potential via water-splitting reactions under UV-vis radiation by using a synergistic assembly of ZnO nanoparticles integrated with MoS2, single-walled carbon nanotubes (SWNTs), and crystalline silicon nanowires (SiNWs) to create the MoS2-SiNWs-SWNTs@ZnONPs nanocomposites. A comparative analysis of MoS2 synthesized through chemical and physical exfoliation methods revealed that the chemically exfoliated MoS2 exhibited superior performance, thereby being selected for all subsequent measurements. The nanostructured materials demonstrated exceptional surface characteristics, with specific surface areas exceeding 300 m2 g−1. Notably, the hydrogen production rate achieved by a composite comprising 5% MoS2, 1.7% SiNWs, and 13.3% SWNTs at an 80% ZnONPs base was approximately 3909 µmol h−1g−1 under 500 nm wavelength radiation, marking a significant improvement of over 40-fold relative to pristine ZnONPs. This enhancement underscores the remarkable photocatalytic efficiency of the composites, maintaining high hydrogen production rates above 1500 µmol h−1g−1 even under radiation wavelengths exceeding 600 nm. Furthermore, the potential of these composites for energy storage and conversion applications, specifically within rechargeable lithium-ion batteries, was investigated. Composites, similar to those utilized for hydrogen production but excluding ZnONPs to address its limited theoretical capacity and electrical conductivity, were developed. The focus was on utilizing MoS2, SiNWs, and SWNTs as anode materials for Li-ion batteries. This strategic combination significantly improved the electronic conductivity and mechanical stability of the composite. Specifically, the composite with 56% MoS2, 24% SiNWs, and 20% SWNTs offered remarkable cyclic performance with high specific capacity values, achieving a complete stability of 1000 mA h g−1 after 100 cycles at 1 A g−1. These results illuminate the dual utility of the composites, not only as innovative catalysts for hydrogen production but also as advanced materials for energy storage technologies, showcasing their potential in contributing to sustainable energy solutions.

Chemistry↗
NASA NTRS1989

Nickel-hydrogen capacity loss on storage

Nickel-hydrogen batteries are rapidly becoming accepted for use in low-earth-orbit and geosynchronous orbit applications. With their increased use it has become evident that the storage procedures commonly used for nickel-cadmium cells are not adequate for the nickel-hydrogen system. The capacity loss exhibited by nickel electrodes from various manufacturers when exposed to different storage conditions was determined. A comprehensive test matrix was developed to evaluate capacity loss in nickel electrodes from four different manufacturers. Two types of tests were run; individual electrode tests, which involved flooded capacity and impedance measurements before and after storage under varied conditions of temperature, hydrogen pressure, and electrolyte concentration; and cell tests which primarily evaluated the effects of state-of-charge on storage. The cell tests evaluated capacity loss on cells stored open circuit, shorted and trickle charged at C/100 following a full charge. The results indicate that capacity loss varies with the specific electrode manufacturing process, storage temperature and hydrogen pressure. In general, electrodes stored at low temperatures or low hydrogen pressures exhibited a smaller loss in capacity over the twenty-eight day storage period than those stored at high pressure and high temperature. The capacity loss appears to correlate with the level of cobalt in the nickel electrode, with the most significant loss of capacity occurring in electrodes with higher cobalt levels. Impedance measurements appear to correlate well with the capacity loss observed for a given type of electrode but do not correlate well with the capacity loss between electrodes fabricated by different manufacturers. There was a definite correlation between the electrode potential measured immediately following storage and the measured capacity loss.

Manzo, Michelle A.↗