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At least 937 records · Page 52

Reaction Mechanisms and Particle Interaction in Burning Two-Phase Systems

The main objective of this research is to understand the mechanisms by which particle interactions affect ignition and combustion in the two-phase systems. Combustion of metal aerosols representing the two-phase systems is carried out in the microgravity environment enabling one to avoid the buoyant flows that mask the particle motion due to the particle-particle interaction effects. In addition, relatively large, e.g., 100 micron diameter particles can be used, that remain aerosolized (i.e., do not fall down as they would at normal gravity) so that their behavior ahead, behind, and within the propagating flame can be resolved optically. An experimental apparatus exploiting this approach has been designed for the 2.2-s drop tower microgravity experiments. A typical experiment includes fluidizing metal particles under microgravity in an acoustic field, turning off the acoustic exciter, and igniting the created aerosol at a constant pressure using a hot wire igniter. The flame propagation and details of the individual particle combustion and particle interactions are studied using high-speed movie and video cameras coupled with microscope lenses to resolve individual particles. Recorded flame images are digitized and various image processing techniques including flame position tracking, color separation, and pixel by pixel image comparisons are employed to understand the processes occurring in the burning aerosols. Condensed combustion products are collected after each experiment for the phase, composition, and morphology analyses. New experiments described in this paper address combustion of Ti and Al particle clouds in air and combustion of Mg particle clouds in CO2. In addition, microgravity combustion experiments have been conducted with the particles of the newly produced Al-Mg mechanical alloys aerosolized in air.

Dreizin, Edward L.↗

Hydrogeological Interpretation of Candidate Origin Sites for Martian Meteorite ALH84001

Barlow (this meeting) has identified two potential source craters for the martian meteorite ALH84001. The craters are at 11.7 deg S, 243.3 deg W (Mare Tyrrhenum site) and 14.0 deg S, 343.5 deg W (Sinus Sabaeus site). As noted by Barlow, both craters lie in the heavily cratered terrain (HCT) and are adjacent to fluvial valleys, Here I explore the fluvial history of these areas based upon the surrounding valley morphology. The most prominent valley network at the Sabaeus site is Evros Vallis. This wide, flat-floored valley is approximately 600 km long with an average width of 2.5 km and a depth of 220 m. The eroded volume of the entire Evros network is approximately 6 x 10(exp 11) cc. This is typical for networks located in the heavily cratered terrain (e.g. Warrego and Parana Valles). Evros is also an isolated valley system. No similar networks are found in the surrounding terrain. Thus it is unlikely that Evros formed as a result of widespread rainfall. A localized water source, such as discharge of a hydrothermal system or localized melting of snowfall, seems more consistent Previous modeling has demonstrated that only hydrothermal systems associated with high permeability subsurfaces can discharge sufficient water to form a valley network. The bulk of the discharge from such systems is consequently low temperature, slightly heated water Precipitation of calcium carbonate by low temperature fluids is consistent with most interpretations of the geochemistry of ALH84001. Available imagery at the Tyrrhenum site is of lesser quality. While eroded units of the HCT are nearby, there are no comparable well developed valley networks at this site. Erosion is instead manifested predominantly as gullies on slopes. This style of erosion suggests that water was not present at this site for the length of time as at the more integrated Sabaeus site. The superposition of fluidized ejecta blankets suggests however that ground water or ground ice was still present at this locality fairly recently, if the chosen crater is indeed correct.

Gulick, Virginia C.↗

Melting of the Martian Permafrost by Hydrothermal Convection Associated with Magmatic Intrusion

Many surface features on Mars are closely connected with the subsurface permafrost layer. The polygonal fractures and the possible thermokarsts are observed on the martian surface and they are analogous to the terrestrial features located on the permafrost. The rampart and/or fluidized ejecta morphology of martian craters is indicative of subsurface volatiles. Mars should stock much water in a form of ground ice. The suspected fluvial features on Mars would suggest water (or its mixture), which is coming from the subsurface aquifer or the ground ice. Such a martian hydrothermal system has been the alternative idea to the assumption of precipitation for forming observed fluvial-like features on Mars. The outflow channels, in particular, have characteristics unique to water erosion and clearly indicates the surface runoff of huge amount of water, which usual precipitations could not supply. The outflow channels potentially suggest the pre-existence of a substantial amount of liquid water very close to the martian surface to cause a large flood. The idea of supplying such massive liquid water near the ground might be still controversial, however, from many observational facts, we assume that the igneous melting of the martian permafrost layer should have played a significant role. We have numerically simulated the generation of meltwater and are proposing a consistent scenario of forming the outflow channels as well as the headwater regions; chaotic terrains.

Y Ogawa↗

Origin of Stability in Sedimentation

Velocity fluctuations and particle concentrations are studied in a liquid fluidized bed to investigate the origin of steady state sedimentation. Both the velocity fluctuations and the particle concentrations are found to strongly depend on height. A flux balance model shows why the bed is stable: velocity fluctuations drive a downward particle flux that is compensated by an upward particle flux stemming from an excess flow velocity due to the stratification in concentration. Our results show that in steady state the magnitudes of the fluctuations are related to the degree of stratification.

Segre, P. N.↗

Lithospheric Dynamics of Mars: Water, Flow, and Failure

Some of the largest Martian erosive features were influenced by groundwater, and include valley networks, outflow channels, and possibly landslides. We argue that hydrothermal systems attending crustal formation processes were able to drive sufficient groundwater to the surface to form the Noachian southern highlands valley networks, which show a spatial correlation to crustal magnetic anomalies, also results of crustal formation. Hydrothermal activity is quantified through numerical simulations of convection in a porous medium due to the presence of a hot intruded magma chamber. The parameter space includes magma chamber depth, volume, aspect ratio, and host rock permeability and porosity. For permeabilities as low as l0(exp -17) sq m and intrusion volumes as low as 50 km , the total discharge due to intrusions building that part of the southern highlands crust associated with magnetic anomalies spans a comparable range as the inferred discharge from the overlying valley networks. The Hesperian circum-Chryse outflow channels are further manifestations of groundwater discharge and Clifford and Parker (2001) suggest that the large volumes of water required for their formation flows beneath a confining cryosphere from the South Pole where meltwater beneath an ice cap recharges a global aquifer. We argue that recharge occurs instead over the nearby Tharsis aquifer at high obliquity, assisted by cryosphere melting due to volcanic activity. Numerical simulations quantify the strength and duration of outflow discharge given either South Polar or Tharsis recharge. The contribution of South Pole recharge given Clifford and Parker aquifer properties is negligible compared to that of the initial Tharsis inventory. Tharsis recharge, despite the restrictions of improved aquifer properties, makes a significant contribution and, unlike South Pole recharge under the same conditions, fulfills discharge requirements. Groundwater may have influenced long run-out landslide formation in the Valles Marineris. We present simulations of Martian, terrestrial, and lunar landslides that gauge the role of pore fluid pressure in reproducing accurate geometries and run-out with frictional, Bingham, and fluidization rheologies. The results indicate that pore fluid is a necessary component of Martian landslide formation and we suggest scenarios that might explain its presence.

Grimm, Robert E.↗

Granular Material Flows with Interstitial Fluid Effects

The research focused on experimental measurements of the rheological properties of liquid-solid and granular flows. In these flows, the viscous effects of the interstitial fluid, the inertia of the fluid and particles, and the collisional interactions of the particles may all contribute to the flow mechanics. These multiphase flows include industrial problems such as coal slurry pipelines, hydraulic fracturing processes, fluidized beds, mining and milling operation, abrasive water jet machining, and polishing and surface erosion technologies. In addition, there are a wide range of geophysical flows such as debris flows, landslides and sediment transport. In extraterrestrial applications, the study of transport of particulate materials is fundamental to the mining and processing of lunar and Martian soils and the transport of atmospheric dust (National Research Council 2000). The recent images from Mars Global Surveyor spacecraft dramatically depict the complex sand and dust flows on Mars, including dune formation and dust avalanches on the slip-face of dune surfaces. These Aeolian features involve a complex interaction of the prevailing winds and deposition or erosion of the sediment layer; these features make a good test bed for the verification of global circulation models of the Martian atmosphere.

Hunt, Melany L.↗

Lunar and Planetary Science XXXV: Impact-Related Deposits

The session "Impact-Related Deposits" included:Evidence for a Lightning-Strike Origin of the Edeowie Glass; 57Fe M ssbauer Spectroscopy of Fulgurites: Implications for Chemical Reduction; Ca-Metasomatism in Crystalline Target Rocks from the Charlevoix Structure, Quebec, Canada: Evidence for Impact-related Hydrothermal Activity; Magnetic Investigations of Breccia Veins and Basement Rocks from Roter Kamm Crater and Surrounding Region, Namibia; Petrologic Complexities of the Manicouagan Melt Sheet: Implications for 40Ar-39Ar Geochronology; Laser Argon Dating of Melt Breccias from the Siljan Impact Structure, Sweden: Implications for Possible Relationship to Late Devonian Extinction Events; Lunar Impact Crater, India: Occurrence of a Basaltic Suevite?; Age of the Lunar Impact Crater, India: First Results from Fission Track Dating; The Fluidized Chicxulub Ejecta Blanket, Mexico: Implications for Mars; Low Velocity Ejection of Boulders from Small Lunar Craters: Ground Truth for Asteroid Surfaces; Ejecta and Secondary Crater Distributions of Tycho Crater: Effects of an Oblique Impact; Potassium Isotope Systematics of Crystalline Lunar Spherules from Apollo 16; Late Paleocene Spherules from the North Sea: Probable Sea Floor Precipitates: A Silverpit Provenance Unproven; A Lithological Investigation of Marine Strata from the Triassic-Jurassic Boundary Interval, Queen Charlotte Islands, British Columbia, Including a Search for Shocked Quartz; Triassic Cratered Cobbles: Shock Effects or Tectonic Pressure?; Regional Variations of Trace Element Composition Within the Australasian Tektite Strewn Field; Cretaceous-Tertiary Boundary Microtektite-bearing Sands and Tsunami Beds, Alabama Gulf Coastal Plain; Sand Lobes on Stewart Island as Probable Impact-Tsunami Deposits; Distal Impact Ejecta, Uppermost Eocene, Texas Coastal Plain; and Continental Impact Debris in the Eltanin Impact Layer.

Source record↗

Martian Surface Properties: Inferences from Resolved Differences in Crater Geometries

Impact craters are a natural probe of planetary sub-surfaces, both from the excavated material and from crater geometries, which are sensitive to material properties of the target. One of the most intriguing aspects of Martian craters is the morphology of the ejecta blankets. All fresh and many older Martian craters larger than a few km are surrounded by ejecta blankets which appear fluidized, with morphologies believed to form by entrainment of liquid water. In addition to the ejecta morphology, quantitative information about the subsurface composition may be derived from geometrical measurements, e.g., rim uplift height and ejecta blanket volumes. In order to use craters to derive subsurface composition or test rampart morphology formation hypotheses, accurate measurements with quantified error estimates are required. We have developed and tested a toolkit for measurements of crater geometry using the MOLA altimetry data. Here, we present the results from geometry measurements on fresh craters in Lunae Planum and Utopia Planitia.

Valiant, G. J.↗

Application of a Planar Doppler Velocimetry System to a High Reynolds Number Compressible Jet

A Planar Doppler Velocimetry (PDV) system has been constructed and used to investigate the instantaneous turbulent velocity structure of a round high-speed compressible air jet with a low-speed co-flow. The exit condition was Mach=0.85 at ambient pressure, yielding a Reynolds number of about 650,000 on diameter. The PDV system was installed at NASA Langley Research Center in the Small Anechoic Jet Facility (SAJF), a chamber in which both the acoustic and aerodynamic properties of jets can be studied. For this test, the goal was to gather data which can be used to relate the turbulence structure of the jet to the levels and character of the acoustic noise produced by the jet. The current PDV system can acquire single-velocity-component, single-shot, planar images (15ns exposures) at 30 Hz. For this paper, the primary data set consists of 240 frames of velocity data acquired with both the jet and the low-speed co-flow seeded with light-scattering articles. Thus, velocities could be measured everywhere in the jet shear layer, both in the jet fluid and in the entrained co-flow. Some data were also taken with only the jet flow seeded. These provided mixing concentration images along with the reduced velocity fields. Other images were taken with only the co-flow seeded. These produced unique quantitative images of high speed entrainment. Optical "laser speckle" noise is the largest source of random noise in pulsed PDV systems. Components for the PDV imaging system were specifically selected to minimize speckle noise. To reduce systematic velocity errors due to laser drift, a frequency monitoring reference leg with a temperature-tuned reference iodine cell, was employed. In the course of this study, a novel flow seeder was developed. It enabled continuously variable seeding of the flow with particles of Sheared Pyrogenic Amorphous Hydrophobic Silica (SPAHS). The seeder comprised a dry fluidized bed hopper and a supersonic nozzle "pickup." Shearing action in the pickup dispersed the seed material in an exceptionally fine cloud (approximately 0.3 micron). These particles followed the flow well, did not clump or cake on screens or model surfaces, and were not susceptible to evaporation. Because of the refractory nature of the particles, SPAHS seeding should also be applicable to anticipated future testing at high temperatures.

Smith, Michael W.↗

Reclassification of Methanogenium tationis and Methanogenium liminatans as Methanofollis tationis gen. nov., comb. nov. and Methanofollis liminatans comb. nov. and description of a new strain of Methanofollis liminatans

Sequencing of 16S rRNA genes and phylogenetic analysis of Methanogenium tationis DSM 2702T (OCM 43T) (T = type strain) and Methanogenium liminatans GKZPZT (= DSM 4140T) as well as other members of the family Methanomicrobiaceae revealed that both species belong to a separate line of descent within this family. In addition, a new strain of Methanogenium liminatans, strain BM1 (= DSM 10196), was isolated from a butyrate-degrading, fluidized bed reactor and characterized. Cells of both species are mesophilic, highly irregular cocci that use H2/CO2 and formate for growth and methanogenesis. In addition, Methanogenium liminatans strains GKZPZT and BM1 used 2-propanol/CO2, 2-butanol/CO2 and cyclopentanol/CO2. Both species contained diether and tetraether lipids. The polar lipids comprised amino-phosphopentanetetrol derivatives, which appear to be characteristic lipids within the family Methanomicrobiaceae. The pattern of glycolipids, phosphoglycolipids and amino-phosphoglycolipids was consistent with the assignment of these two species to a taxon within the family Methanomicrobiaceae, but also permitted them to be distinguished from other higher taxa within this family. The G+C contents of the DNA of Methanogenium tationis and Methanogenium liminatans were 54 and 60 mol% (Tm and HPLC), respectively. On the basis of the data presented, the transfer of Methanogenium tationis and Methanogenium liminatans to the genus Methanofollis gen. nov. as Methanofollis tationis comb. nov. and Methanofollis liminatans comb. nov., respectively, is proposed, with Methanofollis tationis as the type species.

NASA Discipline Exobiology↗

Martian Impact Craters as Revealed by MGS and Odyssey

A variety of ejecta and interior morphologies were revealed for martian impact craters by Viking imagery. Numerous studies have classified these ejecta and interior morphologies and looked at how these morphologies correlate with crater diameter, latitude, terrain, and elevation [1, 2, 3, 4]. Many of these features, particularly the layered (fluidized) ejecta morphologies and central pits, have been proposed to result when the crater formed in target material containing high concentrations of volatiles. The Catalog of Large Martian Impact Craters was originally derived from the Viking 1:2,000,000 photomosaics and contains information on 42,283 impact craters 5-km diameter distributed across the entire martian surface. The information in this Catalog has been used to study the distributions of craters displaying specific ejecta and interior morphologies in an attempt to understand the environmental conditions which give rise to these features and to estimate the areal and vertical extents of subsurface volatile reservoirs [4, 5]. The Catalog is currently undergoing revision utilizing Mars Global Surveyor (MGS) and Mars Odyssey data [6]. The higher resolution multispectral imagery is resulting in numerous revisions to the original classifications and the addition of new elemental, thermophysical, and topographic data is allowing new insights into the environmental conditions under which these features form. A few of the new results from analysis of data in the revised Catalog are discussed below.

Barlow, N. G.↗

Development of a Reactor Model for Chemical Conversion of Lunar Regolith

Lunar regolith will be used for a variety of purposes such as oxygen and propellant production and manufacture of various materials. The design and development of chemical conversion reactors for processing lunar regolith will require an understanding of the coupling among the chemical, mass and energy transport processes occurring at the length and time scales of the overall reactor with those occurring at the corresponding scales of the regolith particles. To this end, a coupled transport model is developed using, as an example, the reduction of ilmenite-containing regolith by a continuous flow of hydrogen in a flow-through reactor. The ilmenite conversion occurs on the surface and within the regolith particles. As the ilmenite reduction proceeds, the hydrogen in the reactor is consumed, and this, in turn, affects the conversion rate of the ilmenite in the particles. Several important quantities are identified as a result of the analysis. Reactor scale parameters include the void fraction (i.e., the fraction of the reactor volume not occupied by the regolith particles) and the residence time of hydrogen in the reactor. Particle scale quantities include the time for hydrogen to diffuse into the pores of the regolith particles and the chemical reaction time. The paper investigates the relationships between these quantities and their impact on the regolith conversion. Application of the model to various chemical reactor types, such as fluidized-bed, packed-bed, and rotary-bed configurations, are discussed.

Hedge, uday↗

Methods and apparatus for using gas and liquid phase cathodic depolarizers

The invention provides methods for using gas and liquid phase cathodic depolarizers in an electrochemical cell having a cation exchange membrane in intimate contact with the anode and cathode. The electrochemical conversion of cathodic depolarizers at the cathode lowers the cell potential necessary to achieve a desired electrochemical conversion, such as ozone evolution, at the anode. When gaseous cathodic depolarizers, such as oxygen, are used, a gas diffusion cathode having the cation exchange membrane bonded thereto is preferred. When liquid phase cathodic depolarizers are used, the cathode may be a flow-by electrode, flow-through electrode, packed-bed electrode or a fluidized-bed electrode in intimate contact with the cation exchange membrane.

Murphy, Oliver J.↗

Integrated lunar materials manufacturing process

A manufacturing plant and process for production of oxygen on the moon uses lunar minerals as feed and a minimum of earth-imported, process materials. Lunar feed stocks are hydrogen-reducible minerals, ilmenite and lunar agglutinates occurring in numerous, explored locations mixed with other minerals in the pulverized surface layer of lunar soil known as regolith. Ilmenite (FeTiO.sub.3) and agglutinates contain ferrous (Fe.sup.+2) iron reducible by hydrogen to yield H.sub.2 O and metallic Fe at about 700.degree.-1,200.degree. C. The H.sub.2 O is electrolyzed in gas phase to yield H.sub.2 for recycle and O.sub.2 for storage and use. Hydrogen losses to lunar vacuum are minimized, with no net hydrogen (or any other earth-derived reagent) consumption except for small leaks. Feed minerals are surface-mined by front shovels and transported in trucks to the processing area. The machines are manned or robotic. Ilmenite and agglutinates occur mixed with silicate minerals which are not hydrogen-reducible at 700.degree.-1,200.degree. C. and consequently are separated and concentrated before feeding to the oxygen generation process. Solids rejected from the separation step and reduced solids from the oxygen process are returned to the mine area. The plant is powered by nuclear or solar power generators. Vapor-phase water electrolysis, a staged, countercurrent, fluidized bed reduction reactor and a radio-frequency-driven ceramic gas heater are used to improve thermal efficiency.

Gibson, Michael A.↗

Analysis of Thermal and Reaction Times for Hydrogen Reduction of Lunar Regolith

System analysis of oxygen production by hydrogen reduction of lunar regolith has shown the importance of the relative time scales for regolith heating and chemical reaction to overall performance. These values determine the sizing and power requirements of the system and also impact the number and operational phasing of reaction chambers. In this paper, a Nusselt number correlation analysis is performed to determine the heat transfer rates and regolith heat up times in a fluidized bed reactor heated by a central heating element (e.g., a resistively heated rod, or a solar concentrator heat pipe). A coupled chemical and transport model has also been developed for the chemical reduction of regolith by a continuous flow of hydrogen. The regolith conversion occurs on the surfaces of and within the regolith particles. Several important quantities are identified as a result of the above analyses. Reactor scale parameters include the void fraction (i.e., the fraction of the reactor volume not occupied by the regolith particles) and the residence time of hydrogen in the reactor. Particle scale quantities include the particle Reynolds number, the Archimedes number, and the time needed for hydrogen to diffuse into the pores of the regolith particles. The analysis is used to determine the heat up and reaction times and its application to NASA s oxygen production system modeling tool is noted.

Hegde, U.↗

Development of a Reactor Model for Chemical Conversion of Lunar Regolith

Lunar regolith will be used for a variety of purposes such as oxygen and propellant production and manufacture of various materials. The design and development of chemical conversion reactors for processing lunar regolith will require an understanding of the coupling among the chemical, mass and energy transport processes occurring at the length and time scales of the overall reactor with those occurring at the corresponding scales of the regolith particles. To this end, a coupled transport model is developed using, as an example, the reduction of ilmenite-containing regolith by a continuous flow of hydrogen in a flow-through reactor. The ilmenite conversion occurs on the surface and within the regolith particles. As the ilmenite reduction proceeds, the hydrogen in the reactor is consumed, and this, in turn, affects the conversion rate of the ilmenite in the particles. Several important quantities are identified as a result of the analysis. Reactor scale parameters include the void fraction (i.e., the fraction of the reactor volume not occupied by the regolith particles) and the residence time of hydrogen in the reactor. Particle scale quantities include the time for hydrogen to diffuse into the pores of the regolith particles and the chemical reaction time. The paper investigates the relationships between these quantities and their impact on the regolith conversion. Application of the model to various chemical reactor types, such as fluidized-bed, packed-bed, and rotary-bed configurations, are discussed.

Hegde, U.↗

Analysis of Thermal and Reaction Times for Hydrogen Reduction of Lunar Regolith

System analysis of oxygen production by hydrogen reduction of lunar regolith has shown the importance of the relative time scales for regolith heating and chemical reaction to overall performance. These values determine the sizing and power requirements of the system and also impact the number and operational phasing of reaction chambers. In this paper, a Nusselt number correlation analysis is performed to determine the heat transfer rates and regolith heat up times in a fluidized bed reactor heated by a central heating element (e.g., a resistively heated rod, or a solar concentrator heat pipe). A coupled chemical and transport model has also been developed for the chemical reduction of regolith by a continuous flow of hydrogen. The regolith conversion occurs on the surfaces of and within the regolith particles. Several important quantities are identified as a result of the above analyses. Reactor scale parameters include the void fraction (i.e., the fraction of the reactor volume not occupied by the regolith particles) and the residence time of hydrogen in the reactor. Particle scale quantities include the particle Reynolds number, the Archimedes number, and the time needed for hydrogen to diffuse into the pores of the regolith particles. The analysis is used to determine the heat up and reaction times and its application to NASA s oxygen production system modeling tool is noted.

Hegde, U.↗