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At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Numerical case study of the aerosol–cloud interactions in warm boundary layer clouds over the eastern North Atlantic with an interactive chemistry module

The presence of warm boundary layer stratiform clouds over the eastern North Atlantic (ENA) region is commonly influenced by the Azores High, especially during the summer season. To investigate comprehensive aerosol–cloud interactions, this study employs the Weather Research and Forecasting model coupled with a chemistry component (WRF-Chem), incorporating aerosol chemical components that are relevant to the formation of cloud condensation nuclei (CCN) and accounting for aerosol spatiotemporal variation. This study focuses on aerosol indirect effects, particularly the long-range transport of aerosols, in the ENA region under three different weather regimes: a ridge with a surface high-pressure system, a post-trough with a surface high-pressure system, and a weak trough. The WRF-Chem simulations conducted at a near-large-eddy scale offer valuable insights into the model's performance, especially in terms of its ability to use high spatial resolution to capture mesoscale cloud features across various weather regimes. Our result shows that introducing 5 times more aerosols to either non-precipitating or precipitating clouds significantly increases ambient CCN numbers, resulting in, to varying degrees, higher liquid water path (LWP) values. The substantial aerosol–cloud interaction especially occurs in the precipitating clouds and demonstrates the susceptibility of the LWP to changes in CCN under different regimes. Conversely, thin, non-rain clouds at the edges of a cloud system are prone to evaporation, exhibiting an aerosol drying effect. The aerosols released during this process transition back to the accumulation mode, facilitating future activation. This dynamic behavior is not adequately represented in prescribed-aerosol simulations.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1993

The correlation of alkalis and aluminum during high-temperature volatilization of albite and nepheline

Our previous study of high-temperature evaporation of mafic targets has shown a systematic enrichment of newly-formed condensates in silicon and alkalis and depletion in refractory elements (Al, Ca, Ti). This effect, which is consistent with the volatility of the elements, was also tested for several experiments with acidic targets. In one case it was the impact evaporation of granite targets using a light-gas gun facility. Analyses of the condensate which was collected during the impact show that it was enriched in Al and Na so that the composition of the condensate became close to nepheline. In the work of Nagahara, an incongruent evaporation of alkali feldspars under stationary conditions has been also proposed. These discoveries required a more detailed study of high-temperaure evaporation of monomineralic Al-silicate targets. In these experiments, we have used samples of oligoclase and of nepheline. Vaporization of samples was performed in a hermetic cell filled with helium at normal temperature and pressure using a powerful Nd-laser focused on the sample. Laser pulses had the following parameters: luminous energy approximately 600 J, duration approximately 10(exp -3) s, density of luminosity was approximately 5 x 10(exp 6) W/sq cm, the temperature of vaporization is about 3000-4000 K. About 4 cm from the sample, a nickel foil was placed on which the condensate was collected. Films of condensate were analyzed using X-Ray Photo-Electron spectrometer ES-2401. The measurement of internal chemical composition and of the charging state of elements through the whole depth of the condensed films was made layer by layer with argon-ion etching of 200 A of the film per step. Results of this study are given. The bottom layers of condensed film correspond to the front parts of the evaporated cloud or to condensation at the beginning of the evaporative process and surface layers to condensation at the end of the process.

Dikov, Yu. P.↗
NASA NTRS1994

Constraints on chondrule and CAI origins from vapor-liquid-solid experiments

It has been widely accepted that evaporation played an important role in the formation of chondritic constituents and elemental and isotopic fractionation in the solar nebula. Although many workers consider that evaporation is just the opposite of condensation, it is true only when the process is in equilibrium. When the process is not in equilibrium, e.g., local evaporation, where generated gas moves away from the residual solids, the fractionation path is quite different from the opposite of condensation of the gas with the solar system elemental abundances. The degree of elemental, particularly isotopic, fractionation is strongly dependent on the evaporation rate of the element when evaporation takes place from solid materials. The phase relations and the rate of evaporation of chondrite-forming minerals give constraints on partial pressure of the dust components, total pressure of the nebular gas, and heating rate of the materials.

Nagahara, H.↗
NASA NTRS1997

Solar Cells for Lunar Application

In this work a preliminary study of the vacuum evaporation of silicon extracted from the lunar regolith has been undertaken. An electron gun vacuum evaporation system has been adapted for this purpose. Following the calibration of the system using ultra high purity silicon deposited on Al coated glass substrates, thin films of lunar Si were evaporated on a variety of crystalline substrates as well as on glass and lightweight 1 mil (25 microns) Al foil. Extremely smooth and featureless films with essentially semiconducting properties were obtained. Optical absorption analysis sets the bandgap (about 1.1 eV) and the refractive index (n=3.5) of the deposited thin films close to that of crystalline silicon. Secondary ion mass spectroscopy and energy dispersive spectroscopy analysis indicated that these films are essentially comparable to high purity silicon and that the evaporation process resulted in a substantial reduction of impurity levels. All layers exhibited a p-type conductivity suggesting the presence of a p-type dopant in the fabricated layers. While the purity of the 'lunar waste material' is below that of the 'microelectronic-grade silicon', the vacuum evaporated material properties seems to be adequate for the fabrication of average performance Si-based devices such as thin film solar cells. Taking into account solar cell thickness requirements (greater than 10 microns) and the small quantities of lunar material available for this study, solar cell fabrication was not possible. However, the high quality of the optical and electronic properties of evaporated thin films was found to be similar to those obtained using ultra-high purity silicon suggest that thin film solar cell production on the lunar surface with in situ resource utilization may be a viable approach for electric power generation on the moon.

Freundlich, Alex↗
NASA NTRS1999

The Question of Future Droughts in a CO2-Warmed World

Increased droughts are to be expected in a warmer world, and so are increased floods. A warmer atmosphere can hold more moisture, and evaporate more water from the surface. Thus, when it is not raining, available soil water should be reduced. When it is raining, it could very well rain harder. Most researchers agree then that a warmer world will have greater hydrologic extremes. In addition, there is a basic imbalance that develops as climate warms, between the loss of moisture from the soil by evaporation and replenishment via precipitation. The land has a smaller heat capacity than the ocean, so it should warm faster. Evaporation from the land proceeds at the rate of its warming, while precipitation derives primarily from evaporation at the ocean surface. As the latter is increasing more slowly, in a warmer world, precipitation will not increase as rapidly as evaporation due to the fact that the oceans warm more slowly than the land surface (evaporation over the ocean is slower than over the land). Hence, more droughts are anticipated in a warmer world, but the specific location of such droughts is somewhat uncertain. To address the question of where droughts are likely to occur, one first needs to have a reasonable sense of what the future magnitude of warming will be, and what the latitudinal distribution of warming will be. For example, the greater the warming at high latitudes relative to low latitudes, the more likely there will be increased drought over the U.S. in summer. In contrast, substantial tropical warming could give us El Nino-like precipitation, with intensified flooding along the southern tier of the U.S. All of these conditions are likely to intensify as the global temperature rises.

Rind, David↗
NASA NTRS1998

Carbon-Water-Energy Relations for Selected River Basins

A biophysical process-based model was run using satellite, assimilated and ancillary data for four years (1987-1990) to calculate components of total evaporation (transpiration, interception, soil and snow evaporation), net radiation, absorbed photosynthetically active radiation and net primary productivity over the global land surface. Satellite observations provided fractional vegetation cover, solar and photosynthetically active radiation incident of the surface, surface albedo, fractional cloud cover, air temperature and vapor pressure. The friction velocity and surface air pressure are obtained from a four dimensional data assimilation results, while precipitation is either only surface observations or a blended product of surface and satellite observations. All surface and satellite data are monthly mean values; precipitation has been disaggregated into daily values. All biophysical parameters of the model are prescribed according to published records. From these global land surface calculations results for river basins are derived using digital templates of basin boundaries. Comparisons with field observations (micrometeorologic, catchment water balance, biomass production) and atmospheric water budget analysis for monthly evaporation from six river basins have been done to assess errors in the calculations. Comparisons are also made with previous estimates of zonal variations of evaporation and net primary productivity. Efficiencies of transpiration, total evaporation and radiation use, and evaporative fraction for selected river basins will be presented.

Choudhury, B. J.↗
NASA NTRS2020

Ohio River Basin Water Resources: Monitoring Flash Drought Potential and Quantifying the Hydrologic Impacts in the Ohio River Basin

Flash drought conditions emerge in a matter of weeks following persistent weather anomalies, such as high temperatures or large vapor pressure deficits, that drive increased evaporative demand. Vegetation response rapidly depletes soil moisture, threatening surface water supplies, triggering significant crop loss, and increasing wildfire risk. Drought indices sensitive to flash drought are currently not included in drought forecast models in the Ohio River Basin (ORB). The team assessed and compared drought indices, gauge-based data, and satellite measurements over the course of the September 2019 flash drought event in the Ohio River Basin to investigate environmental fingerprints throughout flash drought evolution. Potential leading flash drought indicators were compared to the Standardized Precipitation Index (SPI) to aid the National Weather Service (NWS) Ohio River Forecast Center and Kentucky Climate Center in producing early warning flash drought forecasts. These drought indices included Evaporative Demand Drought Index (EDDI), Standardized Precipitation Evapotranspiration Index (SPEI), and Landscape Evaporative Response Index (LERI) (derived from Terra Moderate Resolution Imaging Spectroradiometer (MODIS)). Drought index behavior inherently varies based on parameters incorporated - EDDI measures evaporative demand through potential evapotranspiration, and demonstrates more variations due to sensitivity to seasonal changes in evaporative demand throughout the 2010-2019 study period. Conversely, LERI measures evaporative response through actual evapotranspiration, representing different environmental changes. Soil moisture response was evaluated using Soil Moisture Active Passive (SMAP) L-band radiometer data and Kentucky Mesonet gauge-based measurements. This analysis enables climatologists and weather forecasters to keep decision-makers and stakeholders better informed about drought risks, and to implement the appropriate actions for preparation of drought onset.

Adelaide Schmid↗
NASA NTRS2020

Ohio River Basin Water Resources: Monitoring Flash Drought Potential and Quantifying the Hydrologic Impacts in the Ohio River Basin Utilizing NASA Earth Observations

Flash drought conditions emerge in a matter of weeks following persistent weather anomalies, such as high temperatures or large vapor pressure deficits, that drive increased evaporative demand. Vegetation response rapidly depletes soil moisture, threatening surface water supplies, triggering significant crop loss, and increasing wildfire risk. Drought indices sensitive to flash drought are currently not included in drought forecast models in the Ohio River Basin (ORB). The team assessed and compared drought indices, gauge-based data, and satellite measurements over the course of the September 2019 flash drought event in the Ohio River Basin to investigate environmental fingerprints throughout flash drought evolution. Potential leading flash drought indicators were compared to the Standardized Precipitation Index (SPI) to aid the National Weather Service (NWS) Ohio River Forecast Center and Kentucky Climate Center in producing early warning flash drought forecasts. These drought indices included Evaporative Demand Drought Index (EDDI), Standardized Precipitation Evapotranspiration Index (SPEI), and Landscape Evaporative Response Index (LERI) (derived from Terra Moderate Resolution Imaging Spectroradiometer (MODIS)). Drought index behavior inherently varies based on parameters incorporated -EDDI measures evaporative demand through potential evapotranspiration, and and demonstrates more variations due to sensitivity to seasonal changes in evaporative demand throughout the 2010-2019 study period. Conversely, LERI measures evaporative response through actual evapotranspiration, representing different environmental changes. Soil moisture response was evaluated using Soil Moisture Active Passive (SMAP) L-band radiometer data and Kentucky Mesonet gauge-based measurements. This analysis enables climatologists and weather forecasters to keep decision-makers and stakeholders better informed about drought risks to implement the appropriate actions for preparation of drought onset.

DEVELOP Project Summary↗
NASA NTRS2021

NASA’s MODIS/VIIRS Global Water Reservoir Product Suite from Moderate Resolution Remote Sensing Data

Global reservoir information can not only benefit local water management but can also improve our understanding of the hydrological cycle. This information includes water area, elevation, and storage; evaporation rate and volume values; and other characteristics. However, operational wall-to-wall reservoir storage and evaporation monitoring information is lacking on a global scale. Here we introduce NASA’s new MODIS/VIIRS Global Water Reservoir product suite based on moderate resolution remote sensing data—the Moderate Resolution Imaging Spectroradiometer (MODIS), and the Visible Infrared Imaging Radiometer Suite (VIIRS). This product consists of 8-day (MxD28C2 and VNP28C2) and monthly (MxD28C3 and VNP28C3) measurements for 164 large reservoirs (MxD stands for the product from both Terra (MOD) or Aqua (MYD) satellites). The 8-day product provides area, elevation, and storage values, which were generated by first extracting water areas from surface reflectance data and then applying the area estimations to the pre-established Area–Elevation (A–E) relationships. These values were then further aggregated to monthly, with the evaporation rate and volume information added. The evaporation rate and volume values were calculated after the Lake Temperature and Evaporation Model (LTEM) using MODIS/VIIRS land surface temperature product and meteorological data from the Global Land Data Assimilation System (GLDAS). Validation results show that the 250 m area classifications from MODIS agree well with the high-resolution classifications from Landsat (R^(2) = 0.99). Validation of elevation and storage products for twelve Indian reservoirs show good agreement in terms of R^(2) values (0.71–0.96 for elevation, and 0.79–0.96 for storage) and normalized root-mean-square error (NRMSE) values (5.08–19.34% for elevation, and 6.39–18.77% for storage). The evaporation rate results for two reservoirs (Lake Nasser and Lake Mead) agree well with in situ measurements (R^(2) values of 0.61 and 0.66, and NRMSE values of 16.25% and 21.76%). Furthermore, preliminary results from the VIIRS reservoir product have shown good consistency with the MODIS based product, confirming the continuity of this 20-year product suite. This new global water reservoir product suite can provide valuable information with regard to water-sources-related studies, applications, management, and hydrological modeling and change analysis such as drought monitoring.

Yao Li↗
DOE OSTI2022

Control rod drive mechanism with heat pipe cooling

A representative cooling system for a nuclear reactor control rod drive mechanism (CRDM) includes an evaporation section located within or next to the CRDM and a condensation section fluidly coupled to the evaporation section. The cooling system includes a set of heat fins coupled to drive coils in the CRDM and heat pipes that extend through the drive coils and heat fins. A fluid evaporates while in the evaporation section of the heat pipes from heat generated by the CRDM and moves out of the evaporation section into the condensation section in the heat fins. The fluid cools and condensates while in the condensation section, recirculating back into the evaporation section. This passive natural circulation cooling system reduces or eliminates the number of water hoses, piping, and other water pumping equipment typically used for cooling a CRDM thereby increasing nuclear reactor reliability and simplifying nuclear reactor operation and maintenance.

Lobscheid, Christian↗
DOE OSTI2024

Experimental and modeling study of the effect of confinement on the thermal decomposition of organic materials

Simultaneous Thermal Analysis is widely used to study thermal decomposition of a variety of organic materials, and the choice of experimental conditions is very important to obtain reliable mass loss and heat flow curves. Here in this work we investigate the effect of confinement on the thermal decomposition of organic materials. As an example, we explore high-density polyethylene (HDPE) and one of its pyrolysis products, namely eicosane (C 20 H 42 ), through experiments and modeling in open crucibles and crucibles closed with a pierced lid. A new model is developed for evaporation and sublimation from open and pinhole thermal-analysis pans. It considers the kinetic resistance of evaporation at the liquid-vapor interface, inhibition of evaporation by buildup of vapor inside the pan, thermal expansion of vapor inside the pan, and diffusion of vapor from the pan. The model is validated using simultaneous heat-flow and mass-loss measurements of n-eicosane evaporation for various pinhole sizes, down to 50 µm. The importance of product evaporation inhibition for measuring polymer decomposition was demonstrated using HDPE. This study sheds light on the effect of confinement on the mass loss rate of organic materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

On-Demand Selection of the Latent Domain Orientation in Spray-Deposited Block Copolymer Thin Films

With their ability to self-assemble spontaneously into well-defined nanoscale morphologies, block copolymer (BCP) thin films are a versatile platform to fabricate functional nanomaterials. An important challenge to wider deployment of BCPs in nanofabrication is combining precise control over the nanoscale domain orientation in BCP assemblies with scalable deposition techniques that are applicable to large-area, curved, and flexible substrates. Here, in this study, we show that spray-deposited smooth films of a nominally disordered BCP exhibit latent orientations, which can be prescriptively selected by controlling solvent evaporation during spray casting. Subsequent solvent vapor annealing triggers assembly toward highly ordered cylindrical morphologies along the pathway determined by solvent evaporation in the prior spray deposition stage. Faster evaporation promotes assembly of vertically oriented cylinders spanning the entire film thickness (100–300 nm). In comparison, slow solvent evaporation permits intermicellar aggregation and incipient cylinder formation in solution, which induces horizontal cylinder assembly upon annealing. The evaporatively controlled latent orientation mechanism presented herein elucidates how nonequilibrium phenomena during casting govern successive self-assembly pathways and facilitates a versatile method to dictate the domain orientation of BCP thin films on demand on flexible and highly curved substrates or in distinct pattern areas on the same substrate.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Alternative Treatment of Defense Waste Processing Facility Recycle via Reuse of Existing Liquid Waste Facilities - 20097

The Defense Waste Processing Facility (DWPF) at Savannah River Site (SRS) has been immobilizing high level waste since 1996. The chemical process within DWPF generates a large volume of condensate, which is recycled to the SRS H-Area Tank Farm. The recycle stream includes a small quantity of sludge solids, as well as soluble cesium that is volatilized during melter operation. The recycle waste is currently received into a large, underground waste tank that separates insoluble solids via decanting. The supernate is treated by an evaporator with a concentrate stream that is stored for future processing. The evaporator overheads are collected and sent to the Effluent Treatment Project (ETP) for final polishing and testing prior to discharge to local surface water. Recycle storage and treatment as described above complicates the overall mission within the tank farms, which are primarily engaged in waste retrieval and preparation activities that support sludge and salt disposition, as well as tank characterization and closure. The need to devote a portion of available storage space to recycle treatment limits operational flexibility, and ultimately the DWPF recycle stream must be diverted to fully close all the SRS waste tanks. An alternative treatment process is being explored to decouple the recycle stream from the tank farm. The proposed treatment process will accomplish solids separation via crossflow filtration and will utilize a wiped film evaporator to volume-reduce the filtrate stream. Evaporator overheads will continue to be further processed in ETP while the solids stream and evaporator concentrate stream will be returned for reprocessing with the DWPF and Salt Waste Processing Facility (SWPF). This process will utilize existing facilities within DWPF and the tank farm that were previously dedicated to Interim Salt Disposition (ISD), but no longer have an identified mission with the startup of SWPF. The reuse of these facilities will remove several constraints from the current Liquid Waste (LW) System Plan without expanding the current footprint of Department of Energy Environmental Management (EM) infrastructure within LW. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Sustainble dropwise condensation enabled ultraefficient heat pipes

Heat pipes play a critical role in determining the operations, safety, and energy efficiency of electronics. The main focus to improve the heat pipe performance is on the evaporator design or wicking structures. However, the intrinsic limitation comes from the condenser, which is fundamentally constrained by inefficient filmwise condensation (FWC). In this study, we successfully achieved a peak effective thermal conductivity (k eff ) of ~140 kW/(m·K) on widely used groove heat pipes by implementing sustainable dropwise condensation (DWC) and integrating with enhanced evaporator. To better understand the working mechanisms of the ultraefficient heat pipe, both the evaporator and condenser of the heat pipes have been modified accordingly. Our results show that up to 296% enhancements on the k eff can be achieved under various inclination angles by only inducing DWC in the condenser section. The drawback of temperature fluctuations induced by DWC in smooth heat pipes appears to be effectively solved using the grooves-wicking structure. Furthermore, by integrating the nanostructured evaporator, the k eff of the heat pipe can be boosted up to 517% compared to conventional groove heat pipes. This study, for the first time, demonstrates the huge potential of engineering both the condenser and evaporator simultaneously in developing ultraefficient heat pipes.

42 ENGINEERING↗
DOE OSTI2024

Design and Analysis of Liquid Lithium Plasma Facing Components

In this study, liquid metal (LM) on plasma-facing components (PFCs) creates a renewable protective cover enhancing power exhaust and protecting the solid substrate. Additionally, energy confinement improvement through particle pumping can be achieved in the case of liquid lithium (LL). A new variant of PFCs was recently introduced at Princeton Plasma Physics Laboratory (PPPL) where a porous wall is used to stabilize the LM surface, while using magnetohydrodynamic (MHD) drive to push the LM flow inside the component. This arrangement allows efficient heat exhaust, and enhanced control of the LM surface temperature, leading to spatial control of evaporation and condensation of LL on the plasma interface. This feature is particularly attractive when vapor shielding is introduced to allow heat flux redistribution. This system has the advantage that as the heat flux increases, the evaporation rate will increase, while decreasing heat flux will decrease the evaporation rate of lithium, ideally creating a feedback effect which could self-regulate the amount of lithium evaporated. Analytical and numerical models for LL PFCs were developed in PPPL. To calculate the target temperature distribution for the case of evaporation from the divertor, we apply an iterative process allowing two-way coupling between the fluid-kinetic analysis of plasma using SOLPS-ITER code and the flow and heat transfer analysis of the PFC using an analytical model. In the last stage, the results are validated using computational fluid dynamics (CFD) analysis with customized version of the CFX code from ANSYS. CFX was modified at PPPL to allow MHD analysis at the high magnetic field typical for fusion applications. Results of the analysis for NSTX-U tokamak conditions will be presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

A tandem radiative/evaporative cooler for weather-insensitive and high-performance daytime passive cooling

Radiative cooling and evaporative cooling with low carbon footprint are regarded as promising passive cooling strategies. However, the intrinsic limits of continuous water supply with complex systems for evaporative cooling, and restricted cooling power as well as the strict requirement of weather conditions for radiative cooling, hinder the scale of their practical applications. Here, we propose a tandem passive cooler composed of bilayer polymer that enables dual-functional passive cooling of radiation and evaporation. Specifically, the high reflectivity to sunlight and mid-infrared emissivity of this polymer film allows excellent radiative cooling performance, and its good atmospheric water harvesting property of underlayer ensures self-supply of water and high evaporative cooling power. Consequently, this tandem passive cooler overcomes the fundamental difficulties of radiative cooling and evaporative cooling and shows the applicability under various conditions of weather/climate. It is expected that this design can expand the practical application domain of passive cooling.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Tank Waste LDR Organics Data Summary for Sample-and-Send (Rev.1A)

The presence of organic chemicals regulated under the Resource Conservation and Recovery Act (RCRA) Land Disposal Restrictions (LDR) adds complexity to treating and disposing of the low activity fraction of Hanford tank waste if a low temperature treatment method such as grouting is used (SRNL-STI-2020-00228). The complexity arises from the fact that the baseline vitrification method is considered by the Washington State Department of Ecology (Ecology) as providing adequate thermal treatment for organics; a status not automatically extended to a lowtemperature process, such as solidifying the waste in a cementitious waste form. In addition, the Environmental Protection Agency (EPA) LDR program is intended to ensure that wastes are properly treated prior to disposal. Proper treatment makes hazardous waste less harmful to groundwater by reducing the mobility and/or toxicity of the hazardous constituents in the waste. EPA guidance indicates that stabilization/solidification of waste for organics could be considered impermissible dilution under the LDR dilution prohibition. In addition, waste storage activities at Hanford have required transferring and blending waste within the tank system and these activities have potentially altered the concentrations of the hazardous constituents. The LDR dilution prohibition found in 40 Code of Federal Regulations (CFR) 268.3 states that “… no generator, transporter, handler, or owner or operator of a treatment, storage, or disposal facility shall in any way dilute a restricted waste or the residual from treatment of a restricted waste as a substitute for adequate treatment …”. Hence, if LAW is to be treated using low temperature stabilization (such as cementation), then it is important to demonstrate both how past storage activities have contributed to the removal (by vacuum evaporation), or destruction (by in situ decomposition) of the LDR organics and how future retrieval and waste feed preparation will contribute to their removal (by filtration and ion exchange). Demonstrating these processes helps validate that cementation without additional organic treatment does not necessarily represent impermissible dilution. To aid in implementing cementitious solidification of Low Activity Waste (LAW), WRPS has been developing a regulatory and processing LDR treatment variance strategy termed “Sampleand-Send” that relies, in part, on demonstrating that in situ decomposition reactions along with historic evaporation of tank waste has destroyed or removed most of the LDR organics possibly associated with Hanford Tank Waste (SRNL-STI-2020-00582, SRNL-STI-2021-00453, SRNL-STI-2022-00391). Under the Sample-and-Send concept, Hanford tank waste would be retrieved, processed through a Tank-Side Cesium Removal-like system, and staged as a candidate feed that would then be sampled to confirm the waste acceptance criteria is met for solidification in an LAW cementitious treatment facility. If it can be shown that LDR organics are at concentrations below the waste acceptance criteria (WAC) for cementitious stabilization and have been sufficiently removed (by historic evaporation or by filtration and ion exchange during Cs removal), destroyed (by historic in situ decomposition), or are not soluble in LAW above the WAC then additional organic treatment is not needed prior to creating a cementitious final waste form and the concept of Sample-and-Send would be proposed to establish a non-rulemaking site-specific treatment variance using the specified method of treatment “STABL” to remove sampling requirements of the waste form after treatment. Waste not meeting the WAC could either be routed to the Hanford Waste Treatment and Immobilization Plant for LAW vitrification, or further processed by evaporation or chemical oxidation before solidifying in a cementitious waste form. A key component in implementing the Sample-and-Send strategy is identifying which of the 207 LDR organic compounds associated with the RCRA Part A permit application waste codes for the Double Shell Tanks (DSTs) and Single Shell Tanks (SSTs) and any applicable Underlying Hazardous Constituents (UHCs) from 40 CFR 268.48 should be considered as potentially present and thus subject to regulation. In addition, it is also necessary to understand the solubility volatility, and reactivity of these compounds in LAW to identify which of the potentially present LDR organic compounds are not soluble above regulatory levels or are likely to have been removed by historic evaporation or destroyed by in situ decomposition reactions. If there are potentially present LDR organic compounds that have not been removed or destroyed and are soluble above regulatorily significant concentrations then a treatability variance may be needed for these species to eliminate any concerns pertaining to impermissible dilution. The spreadsheet accompanying this calculation report contains the data and logic computations needed to screen the list of 207 LDR organics associated with Hanford tank waste to identify those potentially present and to indicate which compounds may need to be included in a treatability variance.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Field Validation of a Pilot-scale Black Liquor Membrane for Water Removal at Ahlstrom-Munksjö Paper Mill in Mosinee, WI

Project Background: The Industrial Technology Validation (ITV) program aims to identify and demonstrate the performance of new, emerging, and underutilized technologies in the industrial sector to help inform decisions towards accelerating commercialization and deployment. Pulp and paper is considered one of the most energy-intensive industries in the manufacturing sector. There are several methodologies for converting wood into pulp in the paper-making industry. The kraft process is a chemical method for producing wood pulp. The kraft process generates black liquor as a byproduct of pulp production. Traditionally, water is evaporated from the liquor by a set of multi-effect evaporators (MEEs), which concentrate weak black liquor (WBL) into strong black liquor (SBL) to support efficient combustion in a recovery boiler. Concentrating black liquor is an energy-intensive step in recovering pulping chemicals and generating high-pressure steam from dissolved wood solids. About 7% of pulp and paper energy usage, or nearly 164 trillion Btu, is used to remove water from black liquor in U.S. kraft pulp mills per year. The U.S. DOE’s IEDO is interested in the black liquor membrane technology evaluated in this report because it offers the potential for a more energy-efficient and less carbon-intensive kraft pulping process across 99 kraft pulp mills in 24 states (Agenda 2020 Technology Alliance 2016). This ITV project validates an innovative black liquor membrane technology for kraft pulp mills to understand its impact and benefits. Via Separations is a technology vendor that developed a graphene oxide membrane system to remove water from WBL before entering the evaporator set. High-pressure positive displacement (HPR) pumps move the black liquor through membranes that separate water and create a more concentrated black liquor. The vendor claims their pre-commercial technology reduces evaporator steam consumption by dewatering WBL before entering the evaporators. They also claim their technology has non-energy benefits such as enhanced soap collection and improved pulp throughput. This evaluation focuses on validating the energy and carbon dioxide (CO 2 e) emissions benefits associated with the membrane system.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗