Alkali-Activated Cement Composites for High Temperature Goethermal Wells
Under the Department of Energy, Energy Efficiency and Renewable Energy (DOE EERE) Geothermal Technologies Program (GTP), the scope of work at Brookhaven National Laboratory (BNL) was aimed at developing and characterizing multifunctional high-temperature geothermal well cement composites. These materials are suitable for both conventional hydrothermal reservoirs at temperature of 300°C and enhanced geothermal system (EGS) environments at heating temperatures up to 600°C. The multifunctional cements were being developed with the following five advanced properties: 1) thermal shock (TS) resistance under 5 cycle heatingcooling water quenching tests, where one cycle involved heating at 500 or 600°C for 24 h and then quenching in 25°C water; 2) improved compressive toughness; 3) enhanced protection of carbon steel (CS) against brine-induced corrosion; 4) superior durability of the bond between the CS and cement surfaces; and 5) good resistance to pH 0.5 H 2 SO 4 solution at 90°C, compared to two conventional geothermal well cements (Class G modified with SiO 2 and calcium aluminum phosphate (CaP)). The latter cement was originally formulated and developed at BNL as a CO 2 - resistant cement under the previous GTP project. Unlike Class G, CaP is classified as a chemically bonded cement; namely, chemical reactions are responsible for strengthening the cement at an earlier curing stage.