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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Enhancing the metal–insulator transition in VO 2 heterostructures with graphene interlayers

In this work, studies were conducted on epitaxial VO 2 thin films to assess to the effect of remote epitaxy on the metal–insulator transition (MIT). The epitaxial VO 2 heterostructures were synthesized on both bare Al 2 O 3 (0001) substrates and Al 2 O 3 substrates coated with two monolayer-thick graphene. While both systems exhibit the MIT, the film grown by remote epitaxy on graphene demonstrates improved transport properties. Electrical transport measurements show that the on/off ratio is enhanced by a factor of ~7.5 and the switching temperature window is narrower for VO 2 thin films grown on graphene. By characterizing the heterostructures with a suite of structural, chemical, and spectroscopic tools, we find that the graphene interlayer inhibits oxygen vacancy diffusion from Al 2 O 3 (0001) during the VO 2 growth, resulting in improved electrical behavior at the MIT.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Pressure-induced metallization and loss of surface magnetism in FeSi

Single-crystalline FeSi samples with a conducting surface state were studied under high pressure and magnetic field by means of electrical resistance measurements to explore how the bulk semiconducting state and the surface state are tuned by the application of pressure. Here, we found that the energy gap associated with the semiconducting bulk phase begins to close abruptly at a critical pressure of ~10 GPa and the bulk material becomes metallic with no obvious sign of any emergent phases or non-Fermi liquid behavior in temperature dependent electrical resistance in the neighborhood of the critical pressure above 3 K. Moreover, the metallic phase appears to remain at near-ambient pressure upon release of the pressure. Interestingly, the hysteresis in the electrical resistance vs magnetic field curve associated with the magnetically ordered conducting surface state decreases with pressure and vanishes at the critical pressure, while the slope of the electrical resistance vs magnetic field curve, which has a negative value for pressure below the critical pressure, decreases in magnitude with pressure and changes sign at the critical pressure. Thus the conducting surface state and the corresponding two-dimensional magnetic order collapse at the critical pressure where the energy gap of the bulk material starts to close abruptly, revealing the connection between the conducting surface state and the semiconducting bulk state in FeSi.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Low frequency electrical noise across contacts between a normal conductor and superconducting bulk YBa2Cu3O7

Virtually every device that makes use of the new ceramic superconductors will need normal conductor to supercondutor contacts. The current-voltage and electrical noise characteristics of these contacts could be become important design considerations. I-V and low frequency electrical noise measurements are presented on contacts between a normal conductor and superconducting polycrystalline YBa2Cu3O7. The contacts were formed by first sputtering gold palladium pads onto the surface of the bulk superconductor and then using silver epoxy to attach a wire(s) to each pad. Voltage across the contacts was found for small current densities. The voltage spectral density, S sub v(f), a quanity often used to characterize electrical noise, very closely followed an empirical relationship given by, S sub v(f) = C(VR)sq/f, where V is the DC voltage across the contact, R is the contact resistance, F is frequency, and C is a contant found to be 2 x 10(exp -10)/Omega sq at 78 K. This relationship was found to be independent of contact area, contact geometry, sample fabrication technique, and sample density.

Hall, J.↗
NASA NTRS1991

Low frequency electrical noise across contacts between a normal conductor and superconducting bulk YBa2Cu3O7

Virtually every device that makes use of the new ceramic superconductors will need normal conductor to superconductor contacts. The current-voltage and electrical noise characteristics of these contacts could become important design considerations. I-V and low frequency electrical noise measurements are presented on contacts between a normal conductor and superconducting polycrystalline YBa2Cu3O7. The contacts were formed by first sputtering gold palladium pads onto the surface of the bulk superconductor and then using silver epoxy to attach a wire(s) to each pad. Voltage across the contacts was found for small current densities. The voltage spectral density, S sub v(f), a quantity often used to characterize electrical noise, very closely followed an empirical relationship given by S sub v(f) = C(VR)sq/f, where V is the DC voltage across the contact, R is the contact resistance, F is frequency, and C is a contant found to be 2 x 10(exp -10)/Omega sq at 78 K. This relationship was found to be independent of contact area, contact geometry, sample fabrication technique, and sample density.

Hall, J.↗
NASA NTRS1995

A study of lightning in winter thunderstorms and the analysis of thunderstorm overflight data

Thunderstorms and the activities associated with them was the emphasis of this final report. The primary goal of the investigation of the dynamics, microphysics, and the electrical properties of tropical thunderstorms, was to understand the process or processes which initiate the precipitation in various convective clouds. A concept that the degree of atmospheric instability that determines the updraft velocity is different between those storms that generate electrical activity and those that do not. This is apparent in temperate latitudes, but in tropical regions, little knowledge of these interactions is available. Several ground monitoring stations have been set up and, along with a waveform recorder at one of the stations, the data collected from these stations will be analyzed in conjunction with other data collected from ship and airborne radars and airborne in situ measurements of electrical activity in coordination with the TOGA-COARE program.

Brook, Marx↗
DOE OSTI2020

Measurement of moisture-dependent ion diffusion constants in wood cell wall layers using time-lapse micro X-ray fluorescence microscopy

Our future bioeconomy depends on increased utilization of renewable lignocellulosic biomass. Controlling the diffusion of chemicals, such as inorganic ions, within secondary plant cell walls is central to many biomass applications. However, insufficient understanding of intra-cell-wall diffusion within secondary plant cell walls is hindering the advancement of many lignocellulosic biomass applications. In this work, X-ray fluorescence microscopy was used to measure diffusion constants of K + , Cu 2+ , and Cl - diffusing through loblolly pine (Pinus taeda) cell wall layers under 70%, 75%, or 80% relative humidity (RH). Results revealed that diffusion constants increased with RH, the larger Cu 2+ diffused more slowly than the K + , and the Cl - diffusion constant was the same as that for the counter cation, indicating cations and anions diffused together to maintain charge neutrality. Comparison with electrical conductivity measurements showed that conductivity is being controlled by ion mobility over these RH. The results further support that intra-cell-wall diffusion of inorganic ions is a Fickian diffusion process occurring through rubbery amorphous polysaccharides, which contradicts previous assertions that intra-cell-wall diffusion is an aqueous process occurring through water pathways. Researchers can now utilize polymer science approaches to engineer the molecular architecture of lignocellulosic biomass to optimize properties for specific end uses.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Magnetic field dependence of the martensitic transition and magnetocaloric effects in Ni 49 BiMn 35 In 15

The structural, magnetic, and magnetocaloric properties of the Bi-doped Heusler alloy Ni 49 BiMn 35 In 15 have been investigated using room temperature X-ray diffraction (XRD) and magnetization measurements in a temperature interval of 5-400 K. The alloy at room temperature was found to be in a mixture of a high temperature austenite phase (AP) and a low temperature martensite phase (MP). A drastic shift in the martensitic transition temperature at the rate of 16 K/T from 197 K to lower temperatures was observed. A kinetic arrest phenomenon of the AP was observed in the magnetization and electrical resistivity measurements during field-cooled (FC) measurements at 5T. A metamagnetic behavior characterized by a jump in magnetization in the isothermal M ( H ) curves near T M was observed. The maximum value of the magnetic entropy change and refrigerant capacity at Curie temperature were found to be 5.5 Jkg -1 K -1 and 312 Jkg -1 for μ o Δ H = 5T, respectively. A large magnetoresistance value of -56% was found near the martensitic transition.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Detecting Anomalies for Fire Prevention in Distribution Systems: Challenges and Analytical Techniques

Electric utilities in California have historically been linked to up to 10% of wildfires. To mitigate this risk, Southern California Edison has invested significantly in wildfire prevention strategies, including undergrounding cables and enhancing equipment inspections. This article explores a novel approach to fire prevention by detecting anomalies in the distribution system that may indicate potential fire hazards. The focus is on identifying arcing conditions through high-resolution point-on-wave (POW) measurements. Arcing, a precursor to fires, is challenging to detect due to its subtle transients and complex system topology. The article discusses the use of advanced signal processing and machine learning techniques, such as spectral correlation function and discrete wavelet transform, to extract features from POW data and accurately identify arcing events. The study demonstrates a high accuracy rate in detecting arcing, paving the way for improved fire prevention measures in electric distribution systems.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS1974

Electric and magnetic field observations during a substorm on February 24, 1970

Description of a series of electric field measurements obtained from the Injun 5 satellite and simultaneous magnetic disturbances observed in the interplanetary medium and on the ground during a magnetic substorm. The substorm analyzed took place on Feb. 24, 1970. Prior to the onset of the substorm, a greatly enhanced antisunward plasma flow was observed over the polar cap. The enhanced plasma flow occurred about 30 minutes after a switch in the direction of the interplanetary magnetic field from northward to southward. The electric fields across the polar cap immediately before and during the substorm were essentially unchanged, and it is thus indicated that an enhancement in the ionospheric conductivity rather than the electric field must be responsible for the large increase in the auroral electrojet current during the substorm.

Gurnett, D. A.↗
NASA NTRS1983

Electrodynamics of the stratosphere using 5000 cu m superpressure balloons

The Electrodynamics of the Middle Atmosphere research project encompasses the design of a microprocessor-controlled payload and the launch of up to eight small superpressure balloons in the 1982-1984 period. The primary payload instrument will measure the vector electric field from dc to 10 kHz, and the payloads will include instruments measuring local ionization, electrical conductivity, magnetic field, and temperature and pressure fluctuations. In addition, optical lightning will be recorded. The simultaneous measurement of these stratospheric parameters by several balloons, for periods extending over several solar rotations, will allow the study of electrical coupling between atmosphere and magnetosphere, of global current systems, and of global response to solar flares and magnetospheric storms.

Holzworth, R. H.↗
DOE OSTI2025

Spontaneous Formation of Single-Crystalline Spherulites in a Chiral 2D Hybrid Perovskite

In two-dimensional (2D) chiral metal-halide perovskites (MHPs), chiral organic spacers induce structural chirality and chiroptical properties in the metal-halide sublattice. This structural chirality enables reversible crystalline-glass phase transitions in (S-NEA) 2 PbBr 4 , a prototypical chiral 2D MHP where NEA + represents 1-(1-naphthyl)ethylammonium. Here, in this study, we investigate two distinct spherulite states of (S-NEA) 2 PbBr 4 , exhibiting either radial-like or stripe-like banded patterns depending on the annealing conditions of the amorphous film. Despite similarities in optical absorption and photoluminescence, the stripe-like, banded spherulite exhibits higher crystallinity and improved optical transparency compared to those of radial-like spherulite. X-ray nanoprobe measurements reveal tilting-angle modulations in the octahedral plane of stripe-like spherulites, correlating with the film’s surface geometry. Transfer matrix calculations indicate that the optical contrast in stripe-like patterns, seen in bright-field optical microscopy, arises from optical interference effects, differing from the contrast mechanism observed in polymer spherulites. Ultrafast carrier dynamics experiments suggest that the stripe-like spherulites resemble single crystals more closely than radial-like spherulites, while electrical conductivity measurements show enhanced charge carrier transport in stripe-like spherulites. These findings offer insights into MHP spherulite states with a single composition but different morphologies, previously observed only in polymers, highlighting their potential for optoelectronic applications.

36 MATERIALS SCIENCE↗
NASA NTRS1975

Investigation of electron dynamics in the magnetosphere with electron beams injected from sounding rockets

The Electron Echo experiments are described which were conducted with three sounding rockets to study the basic mechanisms by which electrons precipitate from the geomagnetic field to produce auroral X-rays during periods of geomagnetic activity. Echo I (1970) injected electron pulses at low latitude and successfully measured the returning pulses from the conjugate region. Echo II (1972) was launched from high latitude, studied the interaction of electron beams with background radiation as well as beam motion near the rocket, and obtained evidence for a beam plasma instability. Echo III (1974) detected a series of conjugate echoes during the presence of a strong convective field in the magnetosphere and conducted an unsuccessful search for beam bunching at the local plasma frequency. It is shown that the electric field measurement in the ionosphere, using incoherent backscatter radar and detectors on the rocket, was transferred to the equatorial plane as though field lines were equipotentials.

Winckler, J. R.↗
NASA NTRS1998

Exploring Carbon Nanotubes for Nanoscale Devices

Carbon nanotubes (CNTs) are shown to promise great opportunities in nanoelectronic devices and nanoelectromechanical systems (NEMS) because of their inherent nanoscale sizes, intrinsic electric conductivities, and seamless hexagonal network architectures. I present our collaborative work with Stanford on exploring CNTs for nanodevices in this talk. The electrical property measurements suggest that metallic tubes are quantum wires. Furthermore, two and three terminal CNT junctions have been observed experimentally. We have proposed and studied CNT-based molecular switches and logic devices for future digital electronics. We also have studied CNTs based NEMS inclusing gears, cantilevers, and scanning probe microscopy tips. We investigate both chemistry and physics based aspects of the CNT NEMS. Our results suggest that CNT have ideal stiffness, vibrational frequencies, Q-factors, geometry-dependent electric conductivities, and the highest chemical and mechanical stabilities for the NEMS. The use of CNT SPM tips for nanolithography is presented for demonstration of the advantages of the CNT NEMS.

Han, Jie↗
NASA NTRS1987

Joule heating in the mesosphere and thermosphere during the July 13, 1982, solar proton event

The solar proton event of July 13, 1982 produced considerable ionization in the polar-cap mesosphere. Energetic solar proton fluxes were measured by the NOAA-6 satellite. The DE-2 satellite measured the low-energy electrons, the ion drift velocity, and other atmospheric and ionospheric properties during the event in the region of the measured maximum electric field (189 mV/m at 2215 UT near 60 deg N), a Joule heating rate of 1-3 K/day is calculated between 70 and 80 km, exceeding the heating due to ozone absorption at noon in the summer hemisphere in that altitude range. The Joule heating rate above 90 km greatly exceeded 20 K/day. The calculated height-integrated Joule heating rate above 100 km in the same region exceeded 400 ergs/sq cm sec, and DE-2 near 350 km measured neutral winds of nearly 1000 m/s and neutral gas temperatures of over 2000 K. The overall ionospheric structure calculated below the DE-2 satellite is described.

Roble, R. G.↗
DOE OSTI2024

Imaging the Meissner effect in hydride superconductors using quantum sensors

By directly altering microscopic interactions, pressure provides a powerful tuning knob for the exploration of condensed phases and geophysical phenomena. Here, the megabar regime represents an interesting frontier, in which recent discoveries include high-temperature superconductors, as well as structural and valence phase transitions. However, at such high pressures, many conventional measurement techniques fail. Here we demonstrate the ability to perform local magnetometry inside a diamond anvil cell with sub-micron spatial resolution at megabar pressures. Our approach uses a shallow layer of nitrogen-vacancy colour centres implanted directly within the anvil; crucially, we choose a crystal cut compatible with the intrinsic symmetries of the nitrogen-vacancy centre to enable functionality at megabar pressures. We apply our technique to characterize a recently discovered hydride superconductor, CeH 9 . By performing simultaneous magnetometry and electrical transport measurements, we observe the dual signatures of superconductivity: diamagnetism characteristic of the Meissner effect and a sharp drop of the resistance to near zero. By locally mapping both the diamagnetic response and flux trapping, we directly image the geometry of superconducting regions, showing marked inhomogeneities at the micron scale. Our work brings quantum sensing to the megabar frontier and enables the closed-loop optimization of superhydride materials synthesis.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1974

Electric and magnetic field observations during a substorm of 24 February 1970

A series of electric field measurements is reported which was obtained from the Injun 5 satellite along with a simultaneous magnetic disturbance observed in the interplanetary medium and on the ground during a magnetic substorm. The substorm analyzed took place on February 24, 1970. Prior to the onset of the substorm a greatly enhanced anti-sunward plasma flow was observed over the polar cap. The enhanced plasma flow occurred about 30 minutes after a switch in the direction of the interplanetary magnetic field from northward to southward. The electric fields across the polar cap immediately before and during the substorm were essentially unchanged indicating that an enhancement in the ionospheric conductivity rather than the electric field must be responsible for the large increase in the auroral electrojet current during the substorm.

Gurnett, D. A.↗
NASA NTRS1987

Temperature dependence (4K to 300K) of the electrical resistivity of methane grown carbon fibers

Experimental measurements of the electrical resistivity vs temperature of methane vapor grown carbon fibers are presented. The fibers are heat treated from 1100 C (as-grown) to 3000 C. Data are fit to a standard two band model, which yields values for boundary scattering limited electron mobility, in-plane mean free path, energy band overlap, and total carrier density. The data are also fit to an ellipsoidal band model, where data fits yield effective masses, band overlap, Fermi velocity, phonon contributions to scattering, and ionized impurity scattering rates.

Woollam, John A.↗