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At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Effect of microgravity on stress ethylene and carbon dioxide production in sweet clover (Melilotus alba L.)

The study of higher plant growth and development in the microgravity (micro-g) environment continues to be a challenge. This is in part a result of the available flight qualified hardware with restrictive closed gas environments. This point is underscored by considering that gas exchange of seedlings grown in microgravity may be further limited owing to a thicker layer of water wicked onto the roots and to the absence of convective mixing. We hypothesized that seedlings grown under such conditions will experience greater hypoxia in microgravity than at Earth gravity, and thus produce greater stress ethylene. We compared flight and ground samples of sweet clover seedlings grown in the Fluid Processing Apparatus (FPA) during STS-57 and found them to contain extremely high levels of carbon dioxide (CO2) and stress ethylene. There were time dependent increases for both gases, and seedling growth was greatly inhibited. We repeated these experiments aboard STS-60 using modified chambers which increased, by fifty fold, the air available to the developing seedlings. Sweet clover seed germination and subsequent seedling growth to eight days within the FPA modified with a gas permeable membrane is not compromised by the microgravity environment.

Gallegos, Gregory L.↗
NASA NTRS1993

A Data Base of Crop Nutrient Use, Water Use, and Carbon Dioxide Exchange in a 20 Square Meter Growth Chamber: Wheat as a Case Study - Part 1

A data set is given describing the daily nutrient uptake, gas exchange, environmental conditions, and carbon (C), and nutrient partitioning at harvest for the entire canopy and root system of a wheat crop (Triticum aestivum, cv. Yecora Rojo). The data were obtained from a 20 sq m stand of wheat plants grown from planting to maturity in a closed, controlled environment, and include daily nutrient uptake [macronutrients, nitrogen (N), phosphorus (P), potassium (K), calcium (Ca), magnesium (Mg), and sulfur (S); and micronutrients, iron (Fe), boron (B), manganese (Mn), zinc (Zn), copper (Cu), and molybdenum (Mo)], canopy carbon dioxide (CO2) exchange rates, and transpiration. Environmental factors such as relative humidity, air temperature, nutrient solution temperature, pH and electrical conductivity, and photoperiod were controlled in the chamber to specific set points. A detailed description of biomass yield for each of the 64 plant growth trays comprising the 20 sq m of growth area is also provided, and includes dry weights of grain, straw, chaff, and roots, along with the concentration of nutrients in different plant tissues and the percent carbohydrate, fat, and protein. To our knowledge, this information represents one of the most extensive data sets available for a canopy of wheat grown from seed to maturity under controlled environmental and nutritional conditions, and thus may provide useful information for model development and validation. A methods section is included to qualify any assumptions that might he required for the use of the data in plant growth models, along with a daily event calendar indicating when adjustments in set points and occasional equipment or sensor failures occurred.

Wheeler, Raymond M.↗
NASA NTRS1997

Measurement of Carbon Dioxide Accumulation and Physiological Function in the Launch and Entry and Advanced Crew Escape Suits

The Launch and Entry Suit (LES) and Advanced Crew Escape Suit (ACES) are worn by astronauts for launch and entry. Previous work by Waligora, et al., 1992, Waligora and Gilbert, 1992, and Dalrymple 1996, have found that carbon dioxide (CO2) accumulation in the LES/ACES helmet may be problematic. CO2 accumulation is important because high inspired levels of CO2 reduce physical function and pose a safety hazard (e.g. levels of CO2 accumulation of 3.6% in the Extravehicular Mobility Unit are sufficient to terminate Extra Vehicular Activities). My task was to design a suitable test protocol for determining the important physiological aspects of LES/ACES use. Three basic issues arose. First was the determination of the astronaut's CO2 inspiration during visor-down use at rest and during walking at 3.5 mph. A sub-issue was the impact of a pneumotach on CO2 since it has been previously observed that when the Aerosport pneumotach was used, performance seemed improved, which might be attributable to a lowered respiration rate when using the pneumotach. The second issue was the energy costs of waLking in the LES/ACES with various G-suit inflation levels, since G-suit inflation increases metabolic costs and metabolic costs influence the C02 production in the LES/ACES helmet. Since G-suit inflation improves orthostatic tolerance after space flight, but likely increases the energy costs of walking, the balance between G-suit inflation and C02 accumulation is an important safety consideration. The third issue which arose from pilot work was the substantial reduction in physical function after a 10 min visor-down period prior to walk.

Bishop, Phillip↗
NASA NTRS1997

Flexible Pipes-Permeation of Methane, Carbon Dioxide and Water Through Tefzel ETFE: Experiments 1996

The permeation of a mixture of CH4 and CO2 (97% CH4 and 3% CO2) saturated with water vapour through Tefzel has been studied at 950 C and 25 and 50 bars. Tefzel is the Du Pont trademark of an ETFE (ethylenetetrafluorethylene) which is a copolymer of ethylene and tetrafluorethylene. This material might be used as inner plastic lining of flexible pipes. For methane and carbon dioxide, the permeability of Tefzel is higher than the deplasticized PVDF (Polyvinylidenefluoride), but lower than the plasticized PVDF. For water, the situation seems to be the other way round; Tefzel has a lower permeability than deplasticized PVDF. Whether the permeability tests on Tefzel at higher temperatures and pressures will be pursued or not, will be considered by the steering committee of the CAPP project in May.

Wang, Per Arne↗
NASA NTRS1998

Biochemical Capture and Removal of Carbon Dioxide

We devised an enzyme-based facilitated transport membrane bioreactor system to selectively remove carbon dioxide (CO2) from the space station environment. We developed and expressed site-directed enzyme mutants for CO2 capture. Enzyme kinetics showed the mutants to be almost identical to the wild type save at higher pH. Both native enzyme and mutant enzymes were immobilized to different supports including nylons, glasses, sepharose, methacrylate, titanium and nickel. Mutant enzyme could be attached and removed from metal ligand supports and the supports reused at least five times. Membrane systems were constructed to test CO2 selectivity. These included proteic membranes, thin liquid films and enzyme-immobilized teflon membranes. Selectivity ratios of more than 200:1 were obtained for CO2 versus oxygen with CO2 at 0.1%. The data indicate that a membrane based bioreactor can be constructed which could bring CO2 levels close to Earth.

Trachtenberg, Michael C.↗
NASA NTRS1997

The Oxidation of CVD Silicon Carbide in Carbon Dioxide

Chemically-vapor-deposited silicon carbide (CVD SiC) was oxidized in carbon dioxide (CO2) at temperatures of 1200-1400 C for times between 100 and 500 hours at several gas flow rates. Oxidation weight gains were monitored by thermogravimetric analysis (TGA) and were found to be very small and independent of temperature. Possible rate limiting kinetic laws are discussed. Oxidation of SiC by CO2 is negligible compared to the rates measured for other oxidants typically found in combustion environments: oxygen and water vapor.

Opila, Elizabeth J.↗
NASA NTRS1999

Fabrication and Performance of Zirconia Electrolysis Cells for Carbon Dioxide Reduction for Mars In Situ Resource Utilization Applications

The use of the Martian atmosphere (95% CO2) to produce oxygen (for propellant and life support) can significantly lower the required launch mass and dramatically reduce the total cost for Mars missions. Zirconia electrolysis cells are one of the technologies being considered for oxygen generation from carbon dioxide in Mars In Situ Resource Utilization (ISRU) production plants. The attractive features of the zirconia cell for this application include simple operation and lightweight, low volume system.

Minh, N. Q.↗
NASA NTRS1998

Oxidation of Chemically-Vapor-Deposited Silicon Carbide in Carbon Dioxide

Chemically-vapor-deposited silicon carbide (CVD SiC) was oxidized in carbon dioxide (CO2) at temperatures of 1200-1400 C for times between 96 and 500 h at several gas flow rates. Oxidation weight gains were monitored by thermogravimetric analysis (TGA) and were found to be very small and independent of temperature. Possible rate limiting kinetic mechanisms are discussed. Passive oxidation of SiC by CO2 is negligible compared to the rates measured for other oxidants that are also found in combustion environments, oxygen and water vapor.

Opila, Elizabeth J.↗
NASA NTRS2000

BOREAS TGB-12 Isotropic Carbon Dioxide Data over the NSA

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites to estimate the rates of carbon accumulation and turnover in each of the major vegetation types. This data set contains information on the carbon isotopic content of carbon dioxide sampled from soils in the NSA-OBS, NSA-YJP, and NSA-OJP sites. Data were collected from 14-Nov-1993 to 10-Oct-1996. The data are stored in tabular ASCII files.

Trumbore, Susan↗
NASA NTRS2001

The Impact of Increasing Carbon Dioxide on Ozone Recovery

We have used the GSFC coupled two-dimensional (2D) model to study the impact of increasing carbon dioxide from 1980 to 2050 on the recovery of ozone to its pre-1980 amounts. We find that the changes in temperature and circulation arising from increasing CO2 affect ozone recovery in a manner which varies greatly with latitude, altitude, and time of year. Middle and upper stratospheric ozone recovers faster at all latitudes due to a slowing of the ozone catalytic loss cycles. In the lower stratosphere, the recovery of tropical ozone is delayed due to a decrease in production and a speed up in the overturning circulation. The recovery of high northern latitude lower stratospheric ozone is delayed in spring and summer due to an increase in springtime heterogeneous chemical loss, and is speeded up in fall and winter due to increased downwelling. The net effect on the higher northern latitude column ozone is to slow down the recovery from late March to late July, while making it faster at other times. In the high southern latitudes, the impact of CO2 cooling is negligible. Annual mean column ozone is predicted to recover faster at all latitudes, and globally averaged ozone is predicted to recover approximately ten years faster as a result of increasing CO2.

Rosenfield, Joan E.↗
NASA NTRS2001

Combustion of Metals in Carbon Dioxide and Reduced-Gravity Environments

Ongoing exploration and future mission2001110444 s to Mars have given impetus to research on the use of natural resources of the planet. Since carbon dioxide (CO2) constitutes approximately 95% of the Mars atmosphere and since it reacts directly and vigorously with several metals, this investigation focuses on metal-CO2 reactions as a possible combination for rocket-propellant production and energy generation. Magnesium (Mg) has been initially selected as the metal fuel owing to its low ignition temperature and high specific impulse and burning rate in CO2. Our studies in this field started with low gravity (g) combustion tests of Mg in O2, CO2, and CO. Reduced gravity provided a clear picture of the burning phenomena by eliminating the intrusive buoyant flows in high-temperature metal reactions and by removing the destructive effect of gravity on the shape of molten metal samples. Suspended cylindrical metal samples of 2, 3, and 4-mm in diameter and length were radiatively ignited in low-g to generate free-floating samples exhibiting a spherically symmetric flame with increasing metal-oxide accumulation in an outer shell. For the Mg-CO2 combination, burning times twice as long as in normal-g and five times longer than in Mg-O2 flames were observed, revealing a diffusion-controlled reaction. The burning time is proportional to the square of the sample diameter. In tests conducted with pure CO, combustion was not possible without constant heating of the sample due to the formation of a thick carbon-containing coating around the Mg sample generated by surface reactions. The following work presents two new studies that attempt to explain some of the low-g experimental observations. First, a simplified one-dimensional, quasi-steady numerical model is developed to obtain temperature, species concentrations, and burning rates of the spherically symmetric diffusion flame around the Mg sample burning in O2 and CO2. Second, a Planar Laser Induced Fluorescence (PLIF) technique is implemented to provide spatially resolved measurements of magnesium oxide (MgO) in the reaction zone of Mg samples burning in O2 and CO2. These experiments reveal fundamental differences between the two combustion systems.

Branch, M. C.↗
NASA NTRS2001

An Assessment of the Ability of Potential Space-Borne Instruments to Resolve Spatial and Temporal Variability of Atmospheric Carbon Dioxide

Mounting concern regarding the possibility that increasing carbon dioxide concentrations will initiate climate change has stimulated interest in the feasibility of measuring CO2 mixing ratios from satellites. Currently, the most comprehensive set of atmospheric CO2 data is from the NOAA CMDL cooperative air sampling network, consisting of more than 40 sites where flasks of air are collected approximately weekly. Sporadic observations in the troposphere and stratosphere from airborne in situ and flask samplers are also available. Although the surface network is extensive, there is a dearth of data in the Southern Hemisphere and most of the stations were intentionally placed in remote areas, far from major sources. Sufficiently precise satellite observations with adequate spatial and temporal resolution would substantially increase our knowledge of the atmospheric CO2 distribution and would undoubtedly lead to improved understanding of the global carbon budget. We use a 3-D chemical transport model to investigate the ability of potential satellite instruments with a variety of orbits, horizontal resolution and vertical weighting functions to capture the variation in the modeled CO2 fields. The model is driven by analyzed winds from the Goddard Data Assimilation Office. Simulated CO2 fields are compared with existing surface and aircraft data, and the effects of the model convection scheme and representation of the planetary boundary layer are considered.

Andrews, Arlyn E.↗
NASA NTRS2001

Sensitivity Studies for Space-Based Global Measurements of Atmospheric Carbon Dioxide

Carbon dioxide (CO2) is well known as the primary forcing agent of global warming. Although the climate forcing due to CO2 is well known, the sources and sinks of CO2 are not well understood. Currently the lack of global atmospheric CO2 observations limits our ability to diagnose the global carbon budget (e.g., finding the so-called "missing sink") and thus limits our ability to understand past climate change and predict future climate response. Space-based techniques are being developed to make high-resolution and high-precision global column CO2 measurements. One of the proposed techniques utilizes the passive remote sensing of Earth's reflected solar radiation at the weaker vibration-rotation band of CO2 in the near infrared (approx. 1.57 micron). We use a line-by-line radiative transfer model to explore the potential of this method. Results of sensitivity studies for CO2 concentration variation and geophysical conditions (i.e., atmospheric temperature, surface reflectivity, solar zenith angle, aerosol, and cirrus cloud) will be presented. We will also present sensitivity results for an O2 A-band (approx. 0.76 micron) sensor that will be needed along with CO2 to make surface pressure and cloud height measurements.

Mao, Jian-Ping↗
NASA NTRS2002

Progress on Passive Sensor for Ultra-Precise Measurement of Carbon Dioxide from Space

Global measurements of atmospheric carbon dioxides (CO2) are needed to resolve significant discrepancies that exist in our understanding of the global carbon budget and, therefore, man's role in global climate change. The science measurement requirements for CO2 are extremely demanding (precision c .3%) No atmospheric chemical species has ever been measured from space with this precision. We are developing a novel application of a Fabry-Perot interferometer to detect spectral absorption of reflected sunlight by CO2 and O2 in the atmosphere. Preliminary design studies indicate that the method will be able to achieve the sensitivity and signal-to-noise required to measure column CO2 at the target specification. We are presently engaged in the construction of a prototype instrument for deployment on an aircraft to test the instrument performance and our ability to retrieve the data in the real atmosphere. In the first 6 months we have assembled a laboratory bench system to begin testing the optical and electronic components. We are also undertaking some measurements of signal and noise levels for actual sunlight reflecting from the ground. We shall present results from some of these ground based studies and discuss their implications for a space based system.

Heaps, William S.↗
NASA NTRS2003

Sensitivity Studies for Space-based Measurement of Atmospheric Total Column Carbon Dioxide Using Reflected Sunlight

A series of sensitivity studies is carried out to explore the feasibility of space-based global carbon dioxide (CO2) measurements for global and regional carbon cycle studies. The detection method uses absorption of reflected sunlight in the CO2 vibration-rotation band at 1.58 microns. The sensitivities of the detected radiances are calculated using the line-by-line model (LBLRTM), implemented with the DISORT (Discrete Ordinates Radiative Transfer) model to include atmospheric scattering in this band. The results indicate that (a) the small (approx.1%) changes in CO2 near the Earth's surface are detectable in this CO2 band provided adequate sensor signal-to-noise ratio and spectral resolution are achievable; (b) the radiance signal or sensitivity to CO2 change near the surface is not significantly diminished even in the presence of aerosols and/or thin cirrus clouds in the atmosphere; (c) the modification of sunlight path length by scattering of aerosols and cirrus clouds could lead to large systematic errors in the retrieval; therefore, ancillary aerosol/cirrus cloud data are important to reduce retrieval errors; (d) CO2 retrieval requires good knowledge of the atmospheric temperature profile, e.g. approximately 1K RMS error in layer temperature; (e) the atmospheric path length, over which the CO2 absorption occurs, must be known in order to correctly interpret horizontal gradients of CO2 from the total column CO2 measurement; thus an additional sensor for surface pressure measurement needs to be attached for a complete measurement package.

Mao, Jianping↗
NASA NTRS2003

Design and Development of an air-cooled Temperature-Swing Adsorption Compressor for Carbon Dioxide

The air revitalization system of the International Space Station (ISS) operates in an open loop mode and relies on the resupply of oxygen and other consumables from earth for the life support of astronauts. A compressor is required for delivering the carbon dioxide from a removal assembly to a reduction unit to recover oxygen and thereby closing the air-loop. We have a developed a temperature-swing adsorption compressor (TSAC) for performing these tasks that is energy efficient, quiet, and has no wearing parts. This paper discusses the design features of a TSAC hardware that uses air as the cooling medium and has Space Station application.

Mulloth, Lila M.↗
NASA NTRS2001

An Assessment of the Ability of Potential Spaceborne Instruments to Resolve Spatial and Temporal Variability of Atmospheric Carbon Dioxide

Mounting concern regarding the possibility that increasing carbon dioxide concentrations will initiate climate change has stimulated interest in the feasibility of measuring CO2 mixing ratios from satellites. Currently, the most comprehensive set of atmospheric CO2 data is from the NOAA CMDL cooperative air sampling network, consisting of more than 40 sites where flasks of air are collected approximately weekly. Sporadic observations in the troposphere and stratosphere from airborne in situ and flask samplers are also available. Although the surface network is extensive, there is a dearth of data in the Southern Hemisphere and most of the stations were intentionally placed in remote areas, far from major sources. Sufficiently precise satellite observations with adequate spatial and temporal resolution would substantially increase our knowledge of the atmospheric CO2 distribution and would undoubtedly lead to improved understanding of the global carbon budget. We use a 3-D chemical transport model to investigate the ability of potential satellite instruments with a variety of orbits, horizontal resolution and vertical weighting functions to capture the variation in the modeled CO2 fields. The model is driven by analyzed winds from the Goddard Data Assimilation Office. Simulated CO2 fields are compared with existing surface and aircraft data, and the effects of the model convection scheme and representation of the planetary boundary layer are considered.

Andrews, Arlyn E.↗
NASA NTRS2003

Sensitivity Studies for Space-based Measurements of Atmospheric Total Column Carbon Dioxide Using Reflected Sunlight

A series of sensitivity studies is carried out to explore the feasibility of space-based global carbon dioxide (CO2) measurements for global and regional carbon cycle studies. The detection method uses absorption of reflected sunlight in the CO2 vibration-rotation band at 1.58 micron. The sensitivities of the detected radiances are calculated using the line-by-line model (LBLRTM), implemented with the DISORT (Discrete Ordinates Radiative Transfer) model to include atmospheric scattering in this band. The results indicate that (a) the small (approx.1%) changes in CO2 near the Earth's surface are detectable in this CO2 band provided adequate sensor signal-to-noise ratio and spectral resolution are achievable; (b) the effects of other interfering constituents, such as water vapor, aerosols and cirrus clouds, on the radiance are significant but the overall effects of the modification of light path length on total back-to-space radiance sensitivity to CO2 change are minor for general cases, which means that generally the total column CO2 can be derived in high precision from the ratio of the on-line center to off-line radiances; (c) together with CO2 gas absorption aerosol/cirrus cloud layer has differential scattering which may result in the modification of on-line to off-line radiance ratio which could lead a large bias in the total column CO2 retrieval. Approaches to correct such bias need further investigation. (d) CO2 retrieval requires good knowledge of the atmospheric temperature profile, e.g. approximately 1K RMS error in layer temperature, which is achievable from new atmospheric sounders in the near future; (e) the atmospheric path length, over which the CO2 absorption occurs, should be known in order to correctly interpret horizontal gradients of CO2 from the total column CO2 measurement; thus an additional sensor for surface pressure measurement needs to be attached for a complete measurement package.

Mao, Jianping↗