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On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

Perliski, Lori M.↗

Spectral bidirectional and hemispherical reflectance characteristics of selected sites in the Streletskaya steppe

Measurements of plant canopy bidirectional reflectance made by the PARABOLA (portable apparatus for rapid acquisition of bidirectional observations of the land and atmosphere) instrument in three spectral bands are analyzed for steppe grassland sites of differing productivity levels. The variation of spectral reflectance and the normalized difference vegetation index in the solar principal plane is presented. Comparisons are made with PARABOLA measurements from selected first ISLSCP field experiment (FIFE) grassland sites in the Konza prairie, Kansas. The Streletskaya steppe sites showed no strong hot spot reflectance, while this effect was present in some FIFE sites but absent in others. The hot spot effect seems to be dependent on canopy geometry and background reflectance characteristics of these sites. Spectral hemispherical reflectance was computed from the angular integration of the bidirectional measurements for the steppe sites. Total shortwave albedo was estimated from these hemispherical reflectance measurements and compared to albedo measured by pyranometers. The albedo estimates from PARABOLA were found to be approximately 12-17 percent higher than the pyranometer measurements.

Eck, Thomas F.↗

Nucleus properties of P/Schwassmann-Wachmann 1

Time series photometric measurements are presented of Comet P/Schwassmann-Wachmann 1 at a heliocentric distance of 5.886 AU when the comet possessed an extensive coma. The light curve shows a modulation caused by the rotation of the nucleus. The rotation period is considerably shorter than the 5 day period found by Whipple (1980), and we find substantial evidence that the nucleus may be in a complex spin state characterized by two periods 14.0 and 32.3 hr. Models of the rate at which the rotational light curve range decreases as a function of the amount of coma in the aperture have determined that the projected maximum to minimum axis ratio of the comet is 2.6 and that the product of the albedo times the rotationally averaged nucleus radius size is 9.54 +/- 0.3 sq km. Assuming a minimum geometric albedo of pR = 0.04, the maximum projected average nucleus radius is 15.44 +/-0.2 km, which is only 44 percent of the size estimated by Roemer (1966). However, using the albedo determined by Cruikshank & Brown (1983) of p = 0.13, the nucleus radius is only RN = 8.6 +/-0.l km. Because of the unknown nucleus orientation, these will be upper limits to the nucleus size. It appears that the nucleus of P/Schwassmann-Wachmann 1 is not the large nucleus that it has been believed to be for nearly 40 yr.

Meech, Karen J.↗

Spectral mixing models of S-Type asteroids

This paper presents the results of an attempt to determine S-Type asteroid mineralogies with the use of Hapke theory spectral mixing modelling. Previous attempts to understand the spectral variations present in this single class of asteroids have concentrated on spectral parameters such as absorption band center wavelengths, band area ratios, and geometric albedos. The procedure taken here is to utilize the Hapke spectral reflectance model to calculate single scatter albedo as a function of wavelength for a suite of candidate end-member materials. These materials are then mixed linearly in single scatter albedo space, and the mixture is converted, assuming intimate particle mixing, back to reflectance for the spectrum matching routine. A total of 39 S-Type asteroids selected from the Bell et al. survey have been matched with mixture model spectra.

Clark, Beth E.↗

Deucalionis Regio, Mars: Evidence for a unique mineralogic endmember and a crusted surface

A small equatorial region south of Sinus Meridiani, Deucalionis Regio, has been found spectrally distinct from other regions as seen in a high spectral resolution telescopic image of the meridian hemisphere of Mars. Analysis of Viking IRTM and other related data suggest that Deucalionis Regio has a crusted surface. The crust-bonding minerals may contribute to the spectral uniqueness of this region. Two independent analyses of spectral images, linear spectral mixing and supervised classification based on the spectral shapes, showed that in addition to the well-known spectral endmember regions in this image (western Arabia, south Acidalia, and Sinus Meridiani), Deucalionis Regio has spectral properties that are unique enough to make it a principle endmember unit. In those earlier works, Deucalionis Regio was referred to as 'Meridiani Border.' Analysis of thermal inertia, rock abundance, and albedo information derived from Viking images and Infrared Thermal Mapper (IRTM) data obtained 1977-80 also indicate that Deucalionis Regio has a surface of distinctly different physical properties when compared to Arabia, Sinus Meridiani, and Acidalia. Deucalionis Regio has a thermal inertia equivalent to the Martian average, a low rock abundance (less than 5 percent), and an intermediate albedo and color. Considerable effort by previous investigators has revealed a consistent model for the surface (upper few cm) properties of the endmember reigons Arabia, Sinus Meridiani, and Acidalia. Compared with these regions, we consider that Deucalionis Regio is not a region of either (1) unconsolidated, fine bright dust like Arabia, (2) considerable windblown unconsolidated sand like Sinus Meridiani, or (3) a rocky-and-sandy surface like Acidalia. Thus, we are forced to consider that either the surface of Deucalionis Regio is made of unconsolidated fine to medium sand (about 250 microns) of an unusual and previously unreported color and albedo, or that the surface is crusted, fine-grained weathered soil, and the thermal inertia is an indicator of the degree to which the surface sediments have become indurated. We favor the latter.

Merenyi, E.↗

Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) data products user's guide

Two tape products from the Total Ozone Mapping Spectrometer (TOMS) aboard the Nimbus-7 have been archived at the National Space Science Data Center. The instrument measures backscattered Earth radiance and incoming solar irradiance; their ratio -- the albedo -- is used in ozone retrievals. In-flight measurements are used to monitor changes in the instrument sensitivity. The algorithm to retrieve total column ozone compares the observed ratios of albedos at pairs of wavelengths with pair ratios calculated for different ozone values, solar zenith angles, and optical paths. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard-deviation random error is 2 percent, and the drift is +/- 1.5 percent over 14.5 years. The High Density TOMS (HDTOMS) tape contains the measured albedos, the derived total ozone amount, reflectivity, and cloud-height information for each scan position. It also contains an index of SO2 contamination for each position. The Gridded TOMS (GRIDTOMS) tape contains daily total ozone and reflectivity in roughly equal area grids (110 km in latitude by about 100-150 km in longitude). Detailed descriptions of the tape structure and record formats are provided.

Mcpeters, Richard D.↗

Particle sizes and composition of Mars atmospheric dust based upon Viking and Mariner 9 observations

Mars atmospheric dust can play an important role in the thermal structure of the Mars atmosphere during periods of high dust loading. However, the radiative properties of Mars atmospheric dust remain uncertain due to uncertain definitions of the dust composition and size distribution. The analysis by Toon et al., of Mariner 9 IRIS spectra during the 1971-1972 global dust storm indicated a reasonable match between the modeled 9-micron absorption of montmorillinite and the observed 9-micron absorption. Toon et al. also determined that an effective (cross-section weighted) mean radius of 2.5 microns (R(sub mode) = 0.4 microns) provided a consistent fit of montmorillinite to the IRIS dust spectra at 9 microns. Pollack et al. analyzed Viking lander observations of atmospheric extinction and scattering at visible-near IR wavelengths (0.5-1.0 microns), and obtained consistency with the Toon et al. dust size distribution when the effects of nonspherical particle shapes were included. An additional, minor (1 percent) component of visible-ultraviolet absorbing material was required to model the derived visible (0.86) and ultraviolet (0.4-0.6) single-scattering albedos of the dust, since montmorillinite does not absorb sufficiently in this wavelength region. A combined analysis of the Viking IRTM and Mariner 9 observations was conducted to reassess the model of Mars atmospheric ultraviolet-to-infrared measurements of dust absorption and scattering. The optical constants for palagonite are incorporated in a doubling-adding radiative transfer model of the Mars atmosphere to simulate Mariner 9 IRIS spectra as well as the Viking IRTM IR band observations. Visible and ultraviolet single-scattering albedos based on the Hansen and Travis Mie scattering code were also derived. A tentative conclusion is that smaller dust particles (R(sub mode) = 0.15 microns, cross-section weighted mean R = 1.2 microns) composed of palagonite provide a much improved fit to the Mariner 9 IRIS spectra; agreement with the observed ratio of visible-to-infrared extinction opacities; and ultraviolet and visible single-scattering albedos comparable to their observed values.

Clancy, R. T.↗

Impact of clouds on the shortwave radiation budget of the surface-atmosphere system for snow-covered surfaces

Recent data from the Earth Radiation Budget Experiment (ERBE) have raised the question as to whether or not the addition of clouds to the atmospheric column can decrease the top-of-the atmosphere (TOA) albedo over bright snow-covered surface. To address this issue, ERBE shortwave pixel measurements have been collected with surface insolation measurements made at two snow-covered locations: the South Pole and Saskatoon, Saskatchewan. Both collected datasets show a negative correlation (with solar zenith angle variability removed) between TOA albedo and surfaces insolation. Because increased cloudiness acts to reduce surface insolation, these negative correlations demonstrate that clouds increase the TOA albedo at both snow-covered locations.

Nemesure, Seth↗

Assessment of climate variability of the Greenland ice sheet: Integration of in situ and satellite data

The proposed research involves the application of multispectral satellite data in combination with ground truth measurements to monitor surface properties of the Greenland ice sheet which are essential for describing the energy and mass of the ice sheet. Several key components of the energy balance are parameterized using satellite data and in situ measurements. The analysis will be done for a ten year time period in order to get statistics on the seasonal and interannual variations of the surface processes and the climatology. Our goal is to investigate to what accuracy and over what geographic areas large scale snow properties and radiative fluxes can be derived based upon a combination of available remote sensing and meterological data sets. Data analysis showed the following results: (1)cloud classification based on longwave sky radiation revealed that overcast sky occurred for 25% of the time in winter, and for 15% in spring and summer respectively (winter and summer both show the same occurrence of clear sky of approximately 26%); (2) comparison of aerodynamic profile method with eddy correlation method to derive sensible and latent heat flux showed good agreement in the diurnal cycle and the turbulent fluxes were underestimated with the aerodynamic method by 10 - 30% as compared to the in situ eddy flux method; (3) the katabatic wind shows a distinct diurnal cycle with a maximum in the morning (7-9 h solar time) and a minimum in the later afternoon (18 h solar time); (4) snow grain size was modeled with a surface energy balance model (SNTHERM) and compared with in situ measurements. Sharp decreases in the modeled snow grain size, caused by accumulation events such as precipitation and deposition, could be verified with observational data; (4) radiative transfer modeling of firn supports our beliefs that the observed trends in 18 and 19 GHz passive microwave brightness temperatures are attributable to accumulation rate changes (modeling also indicates the above relationship is detectable because of the presence of depth hoar; (5) snow melt can be detected by a distinct signal in the passive microwave cross-polarized gradient ratio (19h-37v)/(19h+37v) and has been used for wet/dry snow classification; (6) top of the atmosphere (TOA) broadband albedos were derived from AVHRR visible and near infrared reflectances for the entire ice sheet from May 1990 - June 1991, and the highest albedo values are found along the southeast coast of the ice sheet which is consistent with the summer peak of precipitation due to onshore flow loaded with high water vapor content (TOA albedo values dropped to around 40% along the south-western coast during July and August due to bare ice surfaces); and (7) the net all-wave radiation balance at the top of the atmosphere is negative over the entire ice sheet except for the summer months - June-July-August (in June, the net radiation balance is slightly positive over the dry snow areas--15 W/m2).

Steffen, K.↗

Hubble Space Telescope UV spectral observations of Io passing into eclipse

Time-resolved spectra of Io have been obtained with the Faint Object Spectrograph on the Hubble Space Telescope in January 1992 at times centered on the passage of Io into Jupiter's shadow. Two different eclipse observations covered 1100-1600 A and 2250-3300 A. In the far ultraviolet(far-UV) range, emission lines of atomic sulfur and oxygen from Io's atmosphere (similar to those previously detected with the International Ultraviolet Explorer (IUE)) have been observed from Io in sunlight, and the spatial extent of the emitting region has been resolved for the first time: this is 0.5-1 Io radii (R(sub Io)) above the surface. The emission lines are typically 1kR in brightness while Io is in sunlight, and decrease to a few hundred Rayleighs within 20 min or less of Io's passing into shadow. If the emissions are produced in Io's ionosphere, the decrease in shadow appears consistent with the collisional slowing and recombination of photoelectrons in 100-1000 s, with recombination an important quenching process if the dominant ion is molecular (i.e., SO2(+)) condensation, with the residual emission in shadow due either to plasma impact of gas above the hot volcanic calderas or electron impact on S and O. In the near-UV range, we have not detected any airglow emissions from Io's atmosphere in shadow, with the main limitation being a high level of scattered light from Jupiter. We derive a 3 sigma upper limit to the 2560 A SO emission feature of 1 KR, which is close to what is expected from electron impact on SO2 based on the obs erved brightness of the FUV S and O lines in shadow. A high signal-to-noise spectrum of Io's albedo in sunlight reveals a spectral shape similar to laboratory spectra of SO2 frost reflectivity, and the relative albedo spectrum changed as Io passed into eclipse and part of the disk was in shadow. No specific SO2 gas absorption features appear in the albedo spectrum, although there could be substantial gas absorption near 2800 A if the individual lines are narrow and saturated. Finally, we present preliminary models for the near-UV spectrum of Io as functions of SO2 frost areal coverage and SO2 gas density.

Clarke, John T.↗

Pluto's lightcurve: Results from four oppositions

The rotational lightcurve, phase function, and orbital lightcurve of the Pluto-Charon system were measured in blue light over four consecutive oppositions spanning 1980 to 1983. Compared with observations made in the three previous decades, our lightcurve shows a higher amplitude of 0.29 mag, as well as a fainter rotationally averaged brightness, which provide constraints on the surface albedo distribution of the two bodies. The synodic rotational period of 6.38726 +/- 0.00007 days is consistent with the orbital period of Charon, which provides evidence for a completely tidally evolved system. The phase coefficient is 0.0372 +/- 0.0016 mag/deg, indicating a very shallow opposition surge compared with asteroids, but consistent with a high albedo surface. The orbital lightcurve shows substantially less fading than the earlier observations, which suggests that there is not a gross difference in average albedo between the southern and northern hemispheres.

Tholen, David J.↗

The effects of the nonsphericity and size distribution of ice crystals on the radiative properties of cirrus clouds

Hexagonal ice crystal and equivalent ice spheres have significantly different single-scattering properties. Although the extinction cross-section for spheres with equivalent surface areas is about the same as that for nonspherical ice crystals randomly oriented in space, equivalent spheres produce more forward scattering and have smaller single-scattering albedos. On the basis of broad-band radiative transfer calculations, in this note we will illustrate that the assumption that ice particles are spheres with equivalent surface areas leads to an underestimate to the solar albedo of cirrus clouds. Furthermore, we show that, for a given optical thickness, small ice particles reflect more solar flux than large ice particles. This implies that the ice crystal size distribution could be extremely important in the determination of the solar albedo of cirrus clouds due to external radiative forcing in climatic perturbation experiments. In the thermal infrared region, absorption by ice crystals predominates and the effects of the nonsphericity and size distribution of ice crystals on infrared radiative transfer appear to be secondary.

Kinne, Stefan↗

Calculation of surface and top of atmosphere radiative fluxes from physical quantities based on ISCCP data sets. 1: Method and sensitivity to input data uncertainties

The largest uncertainty in upwelling shortwave (SW) fluxes (approximately equal 10-15 W/m(exp 2), regional daily mean) is caused by uncertainties in land surface albedo, whereas the largest uncertainty in downwelling SW at the surface (approximately equal 5-10 W/m(exp 2), regional daily mean) is related to cloud detection errors. The uncertainty of upwelling longwave (LW) fluxes (approximately 10-20 W/m(exp 2), regional daily mean) depends on the accuracy of the surface temperature for the surface LW fluxes and the atmospheric temperature for the top of atmosphere LW fluxes. The dominant source of uncertainty is downwelling LW fluxes at the surface (approximately equal 10-15 W/m(exp 2)) is uncertainty in atmospheric temperature and, secondarily, atmospheric humidity; clouds play little role except in the polar regions. The uncertainties of the individual flux components and the total net fluxes are largest over land (15-20 W/m(exp 2)) because of uncertainties in surface albedo (especially its spectral dependence) and surface temperature and emissivity (including its spectral dependence). Clouds are the most important modulator of the SW fluxes, but over land areas, uncertainties in net SW at the surface depend almost as much on uncertainties in surface albedo. Although atmospheric and surface temperature variations cause larger LW flux variations, the most notable feature of the net LW fluxes is the changing relative importance of clouds and water vapor with latitude. Uncertainty in individual flux values is dominated by sampling effects because of large natrual variations, but uncertainty in monthly mean fluxes is dominated by bias errors in the input quantities.

Zhang, Y.-C.↗

Calibration of the NOAA 11 solar backscatter ultraviolet (SBUV/2) ozone data set from 1989 to 1993 using in-flight calibration data and SSBUV

Total ozone and ozone profiles are currently being measured by solar backscatter ultraviolet (SBUV/2) instruments onboard NOAA polar orbiting spacecraft using the backscattered ultraviolet technique. The NOAA 11 SBUV/2 operational data set, reprocessed from January 1989 to May 1993 (version 6), includes an updated algorithm and revised prelaunch and postlaunch calibrations of the geometrical albedo observations used to derive ozone values. The postlaunch calibration revisions remove time dependent errors in the ozone amounts due to instrument drift, while the revised prelaunch calibration corrects the absolute value of retrieved ozone. The prelaunch corrections are a result of calibration checks from in-orbit comparisons of ultraviolet geometric albedos measured by shuttle SBUV (SSBUV) and the NOAA 11 SBUV/2. Geometric albedo comparison data are further corrected using a radiative transfer code to account for the small difference in observing conditions between the two spacecraft. The postlaunch corrections rely on in-flight calibration and solar irradiance data to account for time dependent changes in instrument gain, thermal response, and instrument diffuser degradation over time. Comparison of data from three SSBUV flights, which occurred about one year apart, with concurrent SBUV/2 data provided an independent check of the time dependent change derived from the in-flight calibration data. Time independent corrections result in an increase of about 1% for total ozone, 5% for ozone at 1 mbar, and near 0% at 15 mbar. The time dependent corrections amount to an increase of 2% for total ozone, 10% for ozone near 1 mbar, and 3% at 15 mbar at the end of the current record in May 1993. Recent laboratory studies indicate that the absolute radiance calibrations may still be in error by a few percent which results in ozone profile values that are too low. The SBUV/2 total and ozone profile data are compared to the Nimbus SBUV data during the period when the data overlapped. Total ozone values agree to about 1%, while ozone profile differences range from -4% to +6%, depending on latitude and altitude, relative to SBUV. These differences are not statistically significant given the uncertainties of the two data sets.

Hilsenrath, E.↗

X-ray refelection from photoionized media in active galactic nuclei

We calculate the spectrum of X-ray radiation and reprocessed by a partly ionized optically thick medium in an active galactic nucleus. We self-consistently calculate the ionization balance and thermal balance in the medium along with the distribution of X-ray intensity with optical depth. In addition to absorption or scattering of the incident X-rays, we also compute the spectrum of X-rays emitted by the material, including lines, edges, and bremsstrahlung. The albedo of the medium depends primarily on the X-ray ionization parameter (ratio of incident flux to gas density, zeta(sub Chi), and secondarily on the UV flux generated by dissipation inside the disk; we locate the critical range of zeta(sub Chi) over which the albedo increases from small to nearly unity. While the continuum reflection is very weak below 10 keV when zeta(sub Chi) is small, significnat fluxes are emitted in atomic lines and edges in this energy range. In the limit of large zeta(sub Chi), the albedo below 10 keV increases, but reflection in this band is never gray: some photoelectric absorption remains up to rather large values of zeta(sub Chi), while at still higher values, inverse Compton scattering amplifies the soft X-ray flux. These features are sufficiently sharp that current and near-future X-ray experiments should permit diagnostic measures of zeta(sub Chi).

Zycki, Piotr T.↗

Analysis of Gaspra lightcurves using Galileo shape and photometric models

Galileo-based models for the shape of 951 Gaspra and the global-average photometric behavior of its surface have been used to model a representative subset of the asteroid's telescopic lightcurves. Fitting the synthetic lightcurves to the observed timing of lightcurve extrema, and knowing the orientation of Gaspra's axes at the time of the Galileo flyby, leads to a sidereal rotation period for the asteroid of 7.042024 +/- 0.000020 hr, a slight change from the period reported by Magnusson et al. (1992). Initially, the shapes, amplitudes, and absolute photometry of the synthetic and observed lightcurves agree with each other to within 0.05-0.1 mag. Small modifications to the Gaspra shape model on sides of the asteroid poorly imaged by Galileo (changes of 700 m or less in the southern hemisphere at longitudes 90 deg-270 deg W) reduce the typical discrepancies to approximately 0.05 mag in lightcurve shape and less than 0.03 mag in absolute photometry. The result demonstrates that Earth-based lightcurves can be used to refine the shape of a spacecraft-imaged irregular object in areas that are poorly constrained by the spacecraft observations. The consistency and phase-angle dependence of the Galileo-based model for Gaspra photometry, supports the accuracy of the absolute calibration of the Galileo SSI camera, and confirms the Earth-based determination of the V-filter geometric albedo of the asteroid (0.22 +/- 0.03; Tholen et al., submitted for publication). Remaining discrepancies between the synthetic and observed lightcurves show no indication of systematic latitudinal variations in albedo and also cannot be explained entirely by isolated albedo spots. These discrepancies are most likely caused by (1) small, remaining, hard-to-constrain errors in the Gaspra shape model and/or (2) moderate variations in macroscopic roughness across the asteroid's surface, in particular making longitudes 130 deg to 300 deg W moderately rougher than the opposite hemisphere.

Simonelli, Damon P.↗

Nonsphericity of dust-like tropospheric aerosols: Implications for aerosol remote sensing and climate modeling

T-matrix computations of light scattering by polydispersions of randomly oriented nonspherical aerosols and Mie computations for equivalent spheres are compared. Findings show that even moderate nonsphericity results in suubstantial errors in the retrieved aerosol optical thickness if satellite reflectance measurements are analyzed using Mie theory. On the other hand, the use of Mie theory for nonspherical aerosols produces negligible errors in the computation of albedo and flux related quantities, provided that the aerosol size distribution and optical thickness are known beforehand. The first result can be explained by large nonspherical-spherical differences in scattering phase function, while the second result follows from small nonspherical-spherical differences in single-scattering albedo and asymmetry parameter. No cancellation of errors occurs if one consistently uses Mie theory in the retrieval algorithm and then in computing the albedo for the retrieved aerosol optical thickness.

Mishchenko, M. I.↗

Neutron measurements in near-Earth orbit with COMPTEL

The fast neutron flux in near-Earth orbit has been measured with the COMPTEL instrument on the Compton Gamma Ray Observatory (CGRO). For this measurement one of COMPTEL's seven liquid scintillator modules was used as an uncollimated neutron detector with threshold of 12.8 MeV. The measurements cover a range of 4.8 to 15.5 GV in vertical cutoff rigidity and 3 deg to 177 deg in spacecraft geocenter zenith angle. One of the measurements occurred near the minimum of the deepest Forbush decrease ever observed by ground-level neutron monitors. After correction for solar modulation, the total flux is well fitted by separable functions in rigidity and zenith angle. With the spacecraft pointed near the nadir the flux is consistent with balloon measurements of the atmospheric neutron albedo. The flux varies by about a factor of 4 between the extremes of rigidity and a factor of 2 between the extremes of zenith angle. The effect of the spacecraft mass in shielding the detector from the atmospheric neutron albedo is much more important than its role as a source of additional secondary neutrons. The neutron spectral hardness varies little with rigidity or zenith angle and lies in the range spanned by earlier atmospheric neutron albedo measurements.

Morris, D. J.↗