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At least 937 records · Page 52

Inexpensive cross-linked polymeric separators made from water-soluble polymers

Polyvinyl alcohol (PVA), cross-linked chemically with aldehyde reagents, produces membranes which demonstrate oxidation resistance, dimensional stability, low ionic resistivity (less than 0.8 Ohms sq cm), low zincate diffusivity (less than 1 x 10 to the -7th mols/sq cm per min), and low zinc dendrite penetration rate (greater than 350 min) which make them suitable for use as alkaline battery separators. They are intrinsically low in cost, and environmental health and safety problems associated with commercial production appear minimal. Preparation, property measurements, and cell test results in Ni/Zn and Ag/Zn cells are described and discussed.

Hsu, L.-C.↗

Observer reference triad rotation, magnetic fields, and rotation in Euclidean cosmological models

It is shown that a cosmological model with Euclidean space sections admits fluid flows if a magnetic field is present. Further, if observer reference frames spin in their response to the universe, a vorticity may exist. Limits can be set on any present intergalactic magnetic field of less than 5.38 x 10 to the -10th gauss (for a model with the chosen symmetry and choice of initial field and fluid velocity components).

Fennelly, A. J.↗

International Ultraviolet Explorer observations of Alpha Scorpii

IUE observations of the absorption spectrum of Alpha-2 Sco B2.5 V are presented. These lines arise from matter being lost by the red supergiant primary, Alpha-1 Sco M1.5 Iab, which is passing in front of the B star. There is a factor of 30 spread in the hydrogen column densities derived from different elements on the assumption of solar abundance ratios. Possible causes are discussed - observational error, shell chemistry, and interstellar contributions. The mass loss rate from Alpha-1 Sco is dependent on the element chosen as giving the best hydrogen density; an unweighted mean gives a rate of 6.4 x 10 to the -6th solar mass/year.

Bernat, A. P.↗

Search for interstellar superheavy hydrogen

Models for fundamental physical interactions allow for the existence of stable or nearly stable elementary particles much heavier than the proton. Stellar spectra were searched for a positively charged superheavy particle, X(+), which, with a bound electron, should appear as apparently superheavy neutral hydrogen in the interstellar medium. An upper limit for the abundance of X relative to normal hydrogen in the line of sight toward the bright star gamma Cassiopeiae is 2 x 10 to the -8th.

Jura, M.↗

IUE observations of the X-ray burst source 4U/MXB 1735-44

The ultraviolet (1250-1950 A) energy distribution of the X-ray burst source 4U/MXB 1735-44 has been observed with the International Ultraviolet Explorer. The source was detected with an average flux of 1.1 x 10 to the -15th ergs/sq cm per sec per A. The similarity of the optical energy distribution of this source to that of Sco X-1 extends into the far-ultraviolet. Assuming that the optical and ultraviolet emission of MXB 1735-44 is due to reprocessing of X-rays in an accretion disk, the ratio of X-ray to bolometric (optical + ultraviolet) flux has been used to make an estimate of the thickness of the disk. For an assumed X-ray albedo of 0.5, it is found that the disk extends to less than approximately 6 deg from the orbital plane.

Hammerschlag-Hensberge, G.↗

Water absorption lines, 931-961 nm - Selected intensities, N2-collision-broadening coefficients, self-broadening coefficients, and pressure shifts in air

Intensities were measured for 97 lines of H2O vapor between 932 and 961 nm. The lines were selected for their potential usefulness for remote laser measurements of H2O vapor in the earth's atmosphere. The spectra were obtained with several different H2O vapor abundances and N2 broadening gas pressures; the spectral resolution was 0.046/cm FWHM. Measured H2O line intensities range from 7 x 10 to the -25th to 7 x 10 to the -22nd/cm per (molecules/sq cm). H2O self-broadening coefficients were measured for 13 of these strongest lines; the mean value was 0.5/cm per atm. N2-collision-broadening coefficients were measured for 73 lines, and the average was 0.11 cm per atm HWHM. Pressure shifts in air were determined for a sample of six lines between 948 and 950 nm; these lines shift to lower frequency by an amount comparable to 0.1 of the collision-broadened widths measured in air or N2. The measured intensities of many lines of 300-000 band are much larger than expected from prior computations, in some cases by over an order of magnitude. Coriolis interactions with the stronger 201-000 band appear to be the primary cause of the enhancement of these line intensities.

Giver, L. P.↗

Thermalization of starlight by elongated grains - Could the microwave background have been produced by stars

The possibility of the microwave background being produced by stars after the big bang is considered. The critical problem for this hypothesis is the source of the long-wavelength opacity for observed wavelengths greater than 10 cm. It is shown that free-free opacity cannot thermalize the background. Spherical dust grains also fail, but needle-shaped conducting grains can provide sufficient opacity to produce the observed spectrum with a metal abundance Z approximately equal to 10 to the -7th.

Wright, E. L.↗

Radio emission from AM Herculis-type binaries

A VLA search for 4.9 GHz radiation from the magnetic cataclysmic variable AM Her, along with the similar EF Eri binary, has led to the discovery of AM Her radio emission having a flux density of 0.67 + or - 0.052 mJy, where 1 mJy is equal to 10 to the -29th W/sq m per Hz. Neither AM Her circular polarization nor EF Eri were detected. The AM Her data are shown to be consistent with a model in which radiation is due to geosynchrotron emission from electrons of energies of a few hundred keV, which are trapped in the magnetosphere of the white dwarf element of the cataclysmic variable.

Chanmugam, G.↗

Dissipation of ionospheric irregularities by wave-particle and collisional interactions

The nonlinear dissipation of plasma irregularities aligned parallel to an ambient magnetic field is studied numerically using a model which employs both wave-particle and collisional diffusion. A wave-particle diffusion coefficient derived from a local theory of the universal drift instability is used. This coefficient is effective in regions of nonzero plasma gradients and produces triangular-shaped irregularities with spectra which vary as f to the -4th, where f is the spatial frequency. Collisional diffusion acts rapidly on the vertices of the irregularities to reduce their amplitude. The simultaneous action of the two dissipative processes is more efficient than collisions acting alone. In this model, wave-particle diffusion mimics the forward cascade process of wave-wave coupling.

Bernhardt, P. A.↗

Observations of Paschen alpha in the broad-line radio galaxy 3C 445

P alpha line flux measurements of the broad-line radio galaxy 3C 445 made at the NASA IR Telescope Facility in September 1981 are discussed. Broad-band measurements were obtained at H of 1.65 micron and K of 2.2 microns. A line flux of P alpha was found at 3.4 times 10 to the -13th ergs/sq cm sec. No discernable variation was detectable regarding measurements made in 1976. Substantial reddening was concluded to exist, although the H gamma lines observed were not due to reddening. The total H alpha luminosity was determined to be 4 x 10 to the 43rd ergs/sec. Steep Balmer line decrements are concluded to be due to interposed dust.

Rudy, R. J.↗

Petrology and petrogenesis of lunar breccia 12013

Sample 12013 is extremely rich in incompatible elements (K, P, U, Th, Pb, Ba, Rb, Zr, Nb, and rare earths) relative to other lunar samples, and it contains abundant granitic material composed of silica minerals and K-feldspar. The present investigation provides detailed petrologic and mineralogic descriptions of the rock and a discussion of its genesis and history. The sample is made up of two lithologies, including a mottled gray and white lithology, and a black lithology. A detailed petrology of the gray breccia is presented, taking into account lithic clasts, mineral clasts, deformation textures in clasts, the matrix, and felsite. A detailed petrology of the black breccia is also provided. Attention is given to a model for the formation of the breccia, an evaluation of the possible genetic relationships between the various components, and some constraints on the nature of the source area.

Quick, J. E.↗

The lunar regolith - Comparative studies of the Apollo and Luna sites. Chemistry of soils from Apollo 17, Luna 16, 20, and 24

The present investigation represents an extension of a comparative regolith study reported by Labotka et al. (1980) to the Apollo 17 site and to the east limb of the moon (Luna 16, 20, and 24 sites). Chemical systematics are considered, taking into account major and minor element characteristics, and large ion-lithophile patterns (K, REE, and Th). Attention is also given to chemical mixing calculations and the significance of the fine fraction. It is found that the chemistries of 1000-90, 90-20, and 20-10 micrometer size fractions are very similar to each other but quite different from the 'less than 10 micrometer' fine fractions. The 'less than 10 micrometer' fine fractions, which comprise about 5 to 20% of the bulk soils, are consistently more feldspathic and enriched in LIL-rich material relative to the coarse fractions in all soils. The KREEP type is different at each site and is largely derived locally.

Laul, J. C.↗

The relationship of the lunar regolith less than 10 micrometer fraction and agglutinates. I - A model for agglutinate formation and some indirect supportive evidence

The first part of a study of the 'less than 10 micrometer' soil fraction and agglutinates is concerned with the chemical systematics of the considered fraction of lunar soils, taking into account a model for agglutinate formation based on the fusion of the finest fraction (FFF). Attention is given to some evidence which supports the FFF model. The evidence is based on some indirect approaches to an estimation of the composition of the fused soil component. It is found that the 'less than 10 micrometer' soil fraction from all Apollo sites except Apollo 16 (which can be explained) is more feldspathic and enriched in incompatible elements (e.g., K and Th) than the bulk soil. It is concluded that these systematics result from simple comminution in which feldspar breaks down to finer sizes than pyroxene and olivine and the fine-grained incompatible-element-enriched mesostasis concentrates in the 'less than 10 micrometer' soil fraction.

Papike, J. J.↗

The Balmer basin - Regional geology and geochemistry of an ancient lunar impact basin

Photogeologic, geochemical and geophysical information is cited to support the contention that an ancient multi-ringed basin exists in the east limb region of the moon, centered at 15 deg S and 70 deg E. The inner ring of the basin, with a diameter of 225 km, is composed of isolated rugged mountains of pre-Nectarian terra; the less distinct outer ring, whose diameter is approximately 450 km, is made up of irregular segments of surrounding large craters. It is noted that two units of light plains material occur in this area and that they are confined for the most part to the region within the proposed outer basin ring. According to orbital geochemical data, the younger unit (Imbrian age plains) consists of a mare basalt not unlike others of the nearside. This unit possesses high Mg/Al concentration ratios as determined from X-ray fluorescence data; it is also relatively high in Th and Fe when compared with the surrounding highlands. It is thought that the relatively high albedo of the Balmer plains may derive from either a reworking by numerous secondary craters from the surrounding impacts or a basaltic composition with higher albedo and lower Fe than the nearside maria.

Maxwell, T. A.↗

Compositional variation in the Hadley Apennine region

Orbital geochemical data in the Hadley Apennine region are related to typical rock compositions and used in determining the distribution of soils derived from the rock types found in this region. Orbital XRF Mg/Si and Al/Si intensities are the orbital data that are used primarily. These data are corrected for spurious interorbit variation using a modification of a previously developed method. The corrected values are than converted to % MgO and % Al2O3, respectively, from theoretical considerations, and as such are compared with similar concentrations for typical lunar rocks and soils of the Apollo 15 landing site. The relationship of the XRF values to Fe, Ti, and Th concentrations, derived from gamma-ray observations, is also considered. It is established that the orbital geochemistry data for this region are consistent with the presence of a mixture of ANT suite and Fra Mauro basalt components frequently dominated by a KREEP basalt component toward the west and by a mafic pyroclastic component toward the east.

Clark, P. E.↗

On the contribution of a stochastic background of gravitational radiation to the timing noise of pulsars

The influence of a stochastic and isotropic background of gravitational radiation on timing measurements of pulsars is investigated, and it is shown that pulsar timing noise may be used to establish a significant upper limit of about 10 to the -10th on the total energy density of very long-wavelength stochastic gravitational waves. This places restriction on the strength of very long wavelength gravitational waves in the Friedmann model, and such a background is expected to have no significant effect on the approximately 3 K electromagnetic background radiation or on the dynamics of a cluster of galaxies.

Mashhoon, B.↗

IUE low-dispersion spectra of six luminous stars in symmetric nebulae

The stars and nebulae are HD 156738 and HDE 319703A, respectively centered in a pair of symmetric nebulae among the NGC 6334 group, AG Car in its nebula, HDE 250550 in nebula 8 of a catalog by Herbig, 209 BAC in Ml-67, and HD 89358 in NGC 3199. These include two O stars, two WN stars, an unstable B supergiant, and a ZAMS B star. Four of them are additions to a previous similar study, and the information about AG CAR and 209 BAC/Ml-67 is extended from that study. The objects are interpreted with Weaver et al.'s (1977) theory of the interaction of a stellar wind with the ambient interstellar medium, except where the short lifetime of the HDE 250550 nebula has forestalled such analysis. Spectral line identifications and types, and several parameters of mass loss, are tabulated. When the present mass loss rates are compared with previous results from other methods, there is an outstanding difference only for WN stars, since 1-3 x 10 to the -7th solar masses/year is derived here.

Johnson, H. M.↗

The photochemistry of the paleoatmosphere

Recent progress in the understanding of the chemistry and photochemistry of the paleoatmosphere is reviewed with emphasis on the application of photochemical models to the investigation of the evolution of the atmosphere. Photochemical calculations are presented which show that a primordial highly reducing atmosphere composed of methane and ammonia, if it formed at all, would be short-lived in the presence of solar ultraviolet radiation, giving way rapidly to a more mildly reducing atmosphere of carbon dioxide and nitrogen. Estimations of O2 produced from the photolysis of water vapor prior to the emergence of photosynthesis range from less than 10 to the -14th to 0.1 times the present atmospheric level, indicating the need for further research. A series of photochemical models of increasing complexity has been developed to study the evolution of atmospheric ozone taking into account reactions with O atoms, hydrogen oxides, nitrogen oxides, and chlorine as well as vertical transport, temperature and tropospheric chemistry so that the total content and vertical distribution of O3 may be determined for a specified level of paleoatmospheric O2.

Levine, J. S.↗