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At least 937 records · Page 52

Antisoiling technology: Theories of surface soiling and performance of antisoiling surface coatings

Physical examination of surfaces undergoing natural outdoor soiling suggests that soil matter accumulates in up to three distinct layers. The first layer involves strong chemical attachment or strong chemisorption of soil matter on the primary surface. The second layer is physical, consisting of a highly organized arrangement of soil creating a gradation in surface energy from a high associated with the energetic first layer to the lowest possible state on the outer surfce of the second layer. The lowest possible energy state is dictated by the physical nature of the regional atmospheric soiling materials. These first two layers are resistant to removal by rain. The third layer constitutes a settling of loose soil matter, accumulating in dry periods and being removed during rainy periods. Theories and evidence suggest that surfaces that should be naturally resistant to the formation of the first two-resistant layers should be hard, smooth, hydrophobic, free of first-period elements, and have the lowest possible surface energy. These characteristics, evolving as requirements for low-soiling surfaces, suggest that surfaces or surface coatings should be of fluorocarbon chemistry. Evidence for the three-soil-layer concept, and data on the positive performance of candidate fluorocarbon coatings on glass and transparent plastic films after 28 months of outdoor exposure, are presented.

Cuddihy, E. F.↗

Kinetics of hydrogen release from lunar soil

With increasing interest in a lunar base, there is a need for extensive examination of possible lunar resources. Hydrogen will be needed on a lunar base for many activities including providing fuel, making water, and serving as a reducing agent in the extraction of oxygen from its ores. Previous studies have shown the solar wind has implanted hydrogen in the lunar regolith and that hydrogen is present not only in the outer layer of soil but to considerable depths, depending on the sampling site. If this hydrogen is to be mined and used on the lunar surface, a number of questions need to be answered. How much energy must be expended in order to release the hydrogen from the soil. What temperatures must be attained, and how long must the soil be heated. This study was undertaken to provide answers to practical questions such as these. Hydrogen was determined using a Pyrolysis/GC technique in which hydrogen was released by heating the soil sample contained in a quartz tube in a resistance wire furnace, followed by separation and quantitative determination using a gas chromatograph with a helium ionization detector. Heating times and temperatures were varied, and particle separates were studied in addition to bulk soils. The typical sample size was 10 mg of lunar soil. All of the soils used were mature soils with similar hydrogen abundances. Pre-treatments with air and steam were used in an effort to find a more efficient way of releasing hydrogen.

Bustin, Roberta↗

The chemistry and mineralogy of Mars soil and dust

A single geological unit consisting of fine, apparently weathered soil material is covering large portions of the surface of Mars. This soil material has been thoroughly homogenized by global dust storms and it is plausible to assume that Mars dust is strongly correlated with it. The chemical-elemental composition of the soil was directly measured by the Viking Landers. Positive detection of Si, Al, Fe, Mg, Ca, Ti, S, Cl, and Br was achieved. Analyses of the SNC meteorites, a group of meteorites that has been suggested to be ejected Martian rocks, supply additional elemental-concentration data, broadening considerably the chemical data-base on the surface materials. A composition model for Mars soil, giving selected average elemental concentrations of major and trace elements, was recently suggested. It was constructed by combining the Viking Lander data, the SNC meteorite analyses, and other analyses. The mineralogy of the surface materials on Mars has not been directly measured yet. By use of various indirect approaches, including chemical correspondence to the surface analyses, spectral analogies, simulations of Viking Lander experiments, analyses of the SNC meteorites and various modeling efforts, the mineralogical composition was constrained to some extent. No direct analyses of soil reactivity have been done yet. Indirect evidence, mostly from the Viking biology experimental results, suggests that the soil probably has a slightly acidic reaction and is generally oxidized. Unambiguous identification of the Mars soil minerals by direct mineralogical analyses, and non-disturbed or in-situ measurements of the soil's reactivity, are of primary importance in future Mars research.

Banin, A.↗

Investigation of soil influences in AVHRR red and near-infrared vegetation index imagery

The effects of soil optical properties on vegetation index imagery are analyzed with ground-based spectral measurements and both simulated and actual AVHRR data from the NOAA satellites. Soil effects on vegetation indices were divided into primary variations associated with the brightness of bare soils, secondary variations attributed to 'color' differences among bare soils, and soil-vegetation spectral mixing. Primary variations were attributed to shifts in the soil line owing to atmosphere or soil composition. Secondary soil variance was responsible for the Saharan desert 'artefact' areas of increased vegetation index response in AVHRR imagery.

Huete, A. R.↗

Magnetic Susceptibility Measurements for in Situ Characterization of Lunar Soil

Magnetic separation is a viable method for concentration of components of lunar soils and rocks for use as feedstocks for manufacture of metals, oxygen, and for recovery of volatiles such as He-3. Work with lunar materials indicates that immature soils are the best candidates for magnetic beneficiation. The magnetic susceptibility at which selected soil components such as anorthite, ilmenite, or metallic iron are separated is not affected by soil maturity, but the recovery of the concentrated components is. Increasing soil maturity lowers recovery. Mature soils contain significant amounts of glass-encased metallic iron. Magnetic susceptibility, which is sensitive to metallic iron content, can be used to measure soil maturity. The relationship between the ratio of magnetic susceptibility and iron oxide and the conventional maturity parameter, I(sub s)/FeO, ferromagnetic resonant intensity divided by iron oxide content is given. The magnetic susceptibilities were determined using apparatus designed for magnetic separation of the lunar soils.

Oder, R. R.↗

Detection of soil erosion within pinyon-juniper woodlands using Thematic Mapper (TM) data

Multispectral measurements collected by Landsat Thematic Mapper (TM) were correlated with field measurements, direct soil loss estimates, and Universal Soil Loss Equation (USLE) estimates to determine the sensitivity of TM data to varying degrees of soil erosion in pinyon-juniper woodland in central Utah. TM data were also evaluated as a predictor of the USLE Crop Management C factor for pinyon-juniper woodlands. TM spectral data were consistently better predictors of soil erosion factors than any combination of field factors. TM data were more sensitive to vegetation variations than the USLE C factor. USLE estimates showed low annual rates of erosion which varied little among the study sites. Direct measurements of rate of soil loss using the SEDIMENT (Soil Erosion DIrect measureMENT) technique, indicated high and varying rates of soil loss among the sites since tree establishment. Erosion estimates from the USLE and SEDIMENT methods suggest that erosion rates have been severe in the past, but because significant amounts of soil have already been eroded, and the surface is now armored by rock debris, present erosion rates are lower. Indicators of accelerated erosion were still present on all sites, however, suggesting that the USLE underestimated erosion within the study area.

Price, Kevin P.↗

Soil moisture retrieval in the Oberpfaffenhofen testsite using MAC Europe AIRSAR data

Soil moisture content is an important parameter in many disciplines of science like hydrology, meteorology, agriculture and others. Microwave remote sensing technique has a high potential in measuring the dielectric constant of soils, which is strongly governed by the soil moisture. Much excellent work has been done on investigating the relationship between backscattering coefficient and soil moisture. Most of these studies are measured in a laboratory or are carried out with a multitemporal data set. This means, that the variation in the backscattering coefficient is only related to the soil moisture because all other parameters influencing the backscattering like surface roughness, vegetation cover, plant geometry, phenology of plants and row direction are kept constant. In this study the sensitivity of the backscattering coefficient to soil moisture of corn fields is investigated. In the framework of the MAC-Europe Campaign in June 1991, the NASA/JPL three-frequency polarimetric AIRSAR system collected data over the test site Oberpfaffenhofen. The AIRSAR campaign in Oberpfaffenhofen was complemented with intensive ground truth measurements. The sampled corn fields are nearly in the range of the same incidence angle (approximately 20 deg) and belong to different soil types. The evaluation was carried out at a single data set. The results show that the backscattering, measured at P-band, can be described with only two parameters very well. The main parameter influencing the backscattering is the soil moisture content; the second subordinated parameter is the row direction.

Wever, Tobias↗

Soil Organic Carbon and Below Ground Biomass: Development of New GLOBE Special Measurements

A scientific consensus is building that changes in the atmospheric concentrations of radiatively active gases are changing the climate (IPCC, 1990). One of these gases CO2 has been increasing in concentration due to additions from anthropogenic sources that are primarily industrial and land use related. The soil contains a very large pool of carbon, estimated at 1550 Gt (Lal 1995) which is larger than the atmospheric and biosphere pools of carbon combined (Greenland, 1995). The flux between the soil and the atmosphere is very large, 60 Pg C/yr (Lal 1997), and is especially important because the soil can act as either a source or a sink for carbon. On any given landscape, as much as 50% of the biomass that provides the major source of carbon can be below ground. In addition, the movement of carbon in and out of the soil is mediated by the living organisms. At present, there is no widespread sampling of soil biomass in any consistent or coordinated manner. Current large scale estimates of soil carbon are limited by the number and widely dispersed nature of the data points available. A measurement of the amount of carbon in the soil would supplement existing carbon data bases as well as provide a benchmark that can be used to determine whether the soil is storing carbon or releasing it to the atmosphere. Information on the below ground biomass would be a valuable addition to our understanding of net primary productivity and standing biomass. The addition of these as special measurements within GLOBE would be unique in terms of areal extent and continuity, and make a real contribution to scientific understanding of carbon dynamics.

Levine, Elissa↗

Influence of Soil Heterogeneity on Mesoscale Land Surface Fluxes During Washita '92

The influence of soil heterogeneity on the partitioning of mesoscale land surface energy fluxes at diurnal time scales is investigated over a 10(exp 6) sq km domain centered on the Little Washita Basin, Oklahoma, for the period June 10 - 18, 1992. The sensitivity study is carried out using MM5/PLACE, the Penn State/NCAR MM5 model enhanced with the Parameterization for Land-Atmosphere-Cloud Exchange or PLACE. PLACE is a one-dimensional land surface model possessing detailed plant and soil water physics algorithms, multiple soil layers, and the capacity to model subgrid heterogeneity. A series of 12-hour simulations were conducted with identical atmospheric initialization and land surface characterization but with different initial soil moisture and texture. A comparison then was made of the simulated land surface energy flux fields, the partitioning of net radiation into latent and sensible heat, and the soil moisture fields. Results indicate that heterogeneity in both soil moisture and texture affects the spatial distribution and partitioning of mesoscale energy balance. Spatial averaging results in an overprediction of latent heat flux, and an underestimation of sensible heat flux. In addition to the primary focus on the partitioning of the land surface energy, the modeling effort provided an opportunity to examine the issue of initializing the soil moisture fields for coupled three-dimensional models. For the present case, the initial soil moisture and temperature were determined from off-line modeling using PLACE at each grid box, driven with a combination of observed and assimilated data fields.

Jasinski, Michael F.↗

Timescales of Soil Moisture Anomalies: Results from Two GCMs

Soil moisture anomalies dissipate over timescales that may span weeks to months. Characterizing the geographical and seasonal variations in these timescales can have important practical benefit; significant soil moisture "memory" allows long-lead forecasts of soil moisture, which have been found in recent studies to be essential for useful Ion--lead forecasts of precipitation in many regions. In this talk, we will present and compare the soil moisture timescales derived in two separate general circulation model (GCM) studies. Both studies employ multiple ensembles of short-term climate simulations. Timescales at a given point are effectively estimated by determining how quickly the soil moisture distribution generated in one ensemble of simulations (characterized by a unique set of initial soil moisture conditions) approaches that produced by another ensemble (characterized by a different set of initial soil moisture conditions). The talk will include a discussion of why the timescales produced by the two GCMs differ in some regions, and it will also describe the impact of soil moisture memory on simulated precipitation.

Koster, Randal D.↗

Southern Great Plains 1997 hydrology experiment: The spatial and temporal distribution of soil moisture within a quarter section pasture field

Understanding the spatial and temporal distribution of soil moisture near the soil surface is important to relate ground truth data to remotely sensed data using an electronically scanned thinned array radiometer (ESTAR). The research was conducted at the A-ARM EF site in the Little Washita Watershed in Chickasha Oklahoma. Soil moisture was measured on a 100 x 100-m grid on a quarter section (0.8 km by 0.8 km) size field where the DOE A-ARM SWATS is located. This site has several drainage channels and small ponds. The site is under four different land use practices, namely active pastureland, non-grazed pastureland covered with thick grass, forest area covered with trees, and a single residential area. Soil moisture was measured with a Time Domain Reflectometry (TDR) Delta-T 6-cm theta-probe and gravimetric soil moisture (GSM) technique for the top 6 cm of the soil depth. A fourth order polynomial equation was fitted to each probe calibration curve. The correlation between TDR and GSM measurement technique ranges from 0.81 to 0.91. Comparison of the spatial and temporal distribution of soil moisture measured by the TDR and GSM techniques showed very strong similarities. Such TDR probes can be used successfully to replace the GSM techniques to measure soil moisture content rapidly and accurately with site specific calibration.

Tsegaye, T.↗

Passive Microwave Observation of Diurnal Surface Soil Moisture

Microwave radiometers operating at low frequencies are sensitive to surface soil moisture changes. Few studies have been conducted that have involved multifrequency observations at frequencies low enough to measure a significant soil depth and not be attenuated by the vegetation cover. Another unexplored aspect of microwave observations at low frequencies has been the impact of diurnal variations of the soil moisture and temperature on brightness temperature. In this investigation, observations were made using a dual frequency radiometer (1.4 and 2.65 GHz) over bare soil and corn for extended periods in 1994. Comparisons of emissivity and volumetric soil moisture at four depths for bare soils showed that there was a clear correspondence between the 1 cm soil moisture and the 2.65-GHz emissivity and between the 3-5 cm soil moisture and the 1.4-GHZ emissivity, which confirms previous studies. Observations during drying and rainfall demonstrate that new and unique information for hydrologic and energy balance studies can be extracted from these data.

Jackson, Thomas J.↗

Ultrasound Algorithm Derivation for Soil Moisture Content Estimation

Soil moisture content can be estimated by evaluating the velocity at which sound waves travel through a known volume of solid material. This research involved the development of three soil algorithms relating the moisture content to the velocity at which sound waves moved through dry and moist media. Pressure and shear wave propagation equations were used in conjunction with soil property descriptions to derive algorithms appropriate for describing the effects of moisture content variation on the velocity of sound waves in soils with and without complete soil pore water volumes, An elementary algorithm was used to estimate soil moisture contents ranging from 0.08 g/g to 0.5 g/g from sound wave velocities ranging from 526 m/s to 664 m/s. Secondary algorithms were also used to estimate soil moisture content from sound wave velocities through soils with pores that were filled predominantly with air or water.

Belisle, W.R.↗

BOREAS TGB-12 Soil Carbon Data over the NSA

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites to estimate the rates of carbon accumulation and turnover in each of the major vegetation types. TGB-12 data sets include soil properties at tower and selected auxiliary sites in the BOREAS NSA and data on the seasonal variations in the radiocarbon content of CO2 in the soil atmosphere at NSA tower sites. The sampling strategies for soils were designed to take advantage of local fire chronosequences, so that the accumulation of C in areas of moss regrowth could be determined. These data are used to calculate the inventory of C and N in moss and mineral soil layers at NSA sites and to determine the rates of input and turnover (using both accumulation since the last stand-killing fire and radiocarbon data). This data set includes physical parameters needed to determine carbon and nitrogen inventory in soils. The data were collected discontinuously from August 1993 to July 1996. The data are stored in tabular ASCII files.

Trumbore, Susan↗

A Critical Examination of Relative Concentrations of Volume-correlated and Surface-correlated Submicron Globules of Pure Fe-0 in Lunar Soils

Impacts on lunar soils produce melt and vapor in an approximate proportion of 7:1. The melt scavenges soil grains of diverse size, quenches and forms agglutinates, thereby converting surface correlated components of soil grains as volume correlated components; simultaneously, parts of the vapor may condense or escape. Cumulative small impacts increase the maturity of the soils, increase the abundance of agglutinates, and increase the concentration of vapor condensated material. Since the discovery of vapor deposited crystalline Fe-0 in vugs of regolith breccias and the theoretical anticipation of amorphous vapor deposits of diverse composition coating lunar soils grains, empirical evidence is gathering in support of such deposits, now commonly called vapor deposited patina (VDP). In addition, submicron globules of Fe-0 are seen to be ubiquitous in VDP. The amorphous VDP lowers the albedo of lunar soils, affects magnetic properties of soils, changes the slopes of uv-vis-ir reflectance spectra, and potentially also alters the gamma and x-ray spectra of lunar soils, compromising compositional inferences from remote sensing.

Basu, A.↗

The Martian Soil as a Geochemical Sink for Hydrothermally Altered Crustal Rocks and Mobile Elements: Implications of Early MER Results

Hydrothermal and aqueous alteration can explain some of the exciting results from the MER team s analyses of the martian soil, including the major elements, mobile elements, and the nickel enrichment. Published results from the five lander missions lead to the following conclusions: 1) The soil appears to be globally mixed and basaltic with only small local variations in chemistry. Relative to martian basaltic meteorites and Gusev rocks the soils are depleted in the fluid-mobile element calcium, but only slightly enriched to somewhat depleted in iron oxide. 2) The presence of olivine in the soils based on M ssbauer data argues that the soil is only partly weathered and is more akin to a lunar regolith than a terrestrial soil. 3) The presence of bromine along with sulfur and chlorine in the soils is consistent with addition of a mobile element component to the soil.

Newsom, H. E.↗

Effect of Forest Canopy on Remote Sensing Soil Moisture at L-band

Global maps of soil moisture are needed to improve understanding and prediction of the global water and energy cycles. Accuracy requirements imply the use of lower frequencies (L-band) to achieve adequate penetration into the soil and to minimize attenuation by the vegetation canopy and effects of surface roughness. Success has been demonstrated over agricultural areas, but canopies with high biomass (e.g. forests) still present a challenge. Examples from recent measurements over forests with the L-band radiometer, 2D-STAR, and its predecessor, ESTAR, will be presented to illustrate the problem. ESTAR and 2D-STAR are aircraft-based synthetic aperture radiometers developed to help resolve both the engineering and algorithm issues associated with future remote sensing of soil moisture. ESTAR, which does imaging across track, was developed to demonstrate the viability of aperture synthesis for remote sensing. The instrument has participated several soil moisture experiments (e.g. at the Little Washita Watershed in 1992 and the Southern Great Plains experiments in 1997 and 1999). In addition, measurements have been made at a forest site near Waverly, VA which contains conifer forests with a variety of biomass. These data have demonstrated the success of retrieving soil moisture at L-band over agricultural areas and the response of passive observations at L-band to biomass over forests. 2D-STAR is a second generation instrument that does aperture synthesis in two dimensions (along track and cross track) and is dual polarized. This instrument has the potential to provide measurements at L-band that simulate the measurements that will be made by the two L-band sensors currently being developed for future remote sensing of soil moisture from space: Hydros (conical scan and real aperture) and SMOS (multiple incidence angle and synthetic aperture). 2D-STAR participated in the SMEX-03 soil moisture experiment, providing images from the NASA P-3 aircraft. Preliminary results include images of the experiment site area near Huntsville, AL that included a mixture of forest and agriculture. Changes during a rain event further illustrate the issues presented by forests. Work is continuing to reduce the 2D-STAR data and to support the two future remote sensing missions. Among the goals is to process the 2D-STAR data to create multiple looks (at the same pixel) with different incidence angles. Data in this format can be used to test algorithms for retrieving soil moisture and biomass such as are planned for SMOS. Also, the data are being processed to provide images at constant incidence angles such as will be obtained by Hydros. Although Hydros will have only one incidence angle, it will also carry an L-band radar, The goal is to use the radar to improve spatial resolution, an issue for remote sensing from space at the long wavelengths. Simultaneous observations with active and passive sensors also offers interesting prospects for treating areas of high biomass (forests) and irregular terrain and may be the challenge for the future.

LeVine, D. M.↗

Surface Soil Changes Following Selective Logging in an Eastern Amazon Forest

In the Brazilian Amazon, selective logging is second only to forest conversion in its extent. Conversion to pasture or agriculture tends to reduce soil nutrients and site productivity over time unless fertilizers are added. Logging removes nutrients in bole wood, enough that repeated logging could deplete essential nutrients over time. After a single logging event, nutrient losses are likely to be too small to observe in the large soil nutrient pools, but disturbances associated with logging also alter soil properties. Selective logging, particularly reduced-impact logging, results in consistent patterns of disturbance that may be associated with particular changes in soil properties. Soil bulk density, pH, carbon (C), nitrogen (N), phosphorus (P), calcium (Ca), magnesium (Mg), potassium (K), iron (Fe), aluminum (Al), delta(sup 3)C, delta(sup 15)N, and P fractionations were measured on the soils of four different types of loggingrelated disturbances: roads, decks, skids, and treefall gaps. Litter biomass and percent bare ground were also determined in these areas. To evaluate the importance of fresh foliage inputs from downed tree crowns in treefall gaps, foliar nutrients for mature forest trees were also determined and compared to that of fresh litterfall. The immediate impacts of logging on soil properties and how these might link to the longer-term estimated nutrient losses and the observed changes in soils were studied.

Olander, Lydia P.↗