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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 937 records · Page 52

Atomic-scale defects generated in the early/intermediate stages of dielectric breakdown in Si/SiO 2 transistors

In this study, electrically detected magnetic resonance and near-zero-field magnetoresistance measurements were used to study atomic-scale traps generated during high-field gate stressing in Si/SiO 2 MOSFETs. The defects observed are almost certainly important to time-dependent dielectric breakdown. The measurements were made with spin-dependent recombination current involving defects at and near the Si/SiO 2 boundary. The interface traps observed are P b0 and P b1 centers, which are silicon dangling bond defects. The ratio of P b0 /P b1 is dependent on the gate stressing polarity. Electrically detected magnetic resonance measurements also reveal generation of E' oxide defects near the Si/SiO 2 interface. Near-zero-field magnetoresistance measurements made throughout stressing reveal that the local hyperfine environment of the interface traps changes with stressing time; these changes are almost certainly due to the redistribution of hydrogen near the interface.

42 ENGINEERING↗

Measurement of Arcminute Scale Cosmic Microwave Background Anisotropy with the BIMA Array

We report the results of our continued study of arcminute scale anisotropy in the Cosmic Microwave Background (CMB) with the Berkeley-Illinois-Maryland Association (BIMA) array. The survey consists of ten independent fields selected for low infrared dust emission and lack of bright radio point sources. With observations from the VLA (Very Large Array) at 4.8 GHz, we have identified point sources which could act as contaminants in estimates of the CMB power spectrum and removed them in the analysis. Modeling the observed power spectrum with a single. flat band power with average multipole of l(sub eff) = 6864, we find Delta T = 14.2((sup +4.8)(sub -6.0)) micro K at 68% confidence. The signal in the visibility data exceeds the expected contribution from instrumental noise with 96.5% confidence. We have also divided the data into two bins corresponding to different spatial resolutions in the power spectrum. We find Delta T(sub 1) = 16.6((sup +5.3)(sub -5.9)) micro K at 68% confidence for CMB flat band power described by an average multipole of l(sub eff) = 5237 and Delta T(sub 2) is less than 26.5 micro K at 95% confidence for l(sub eff) = 8748.

Dawson, K. S.↗

Commercial-Scale Front-End Engineering Design (Feed) Study for MTR’s Membrane CO 2 Capture Process

This is the final report for a DOE sponsored project (DE-FE00031846) where MTR, Sargent & Lundy (S&L), Trimeric Corporation (Trimeric), in cooperation with Basin Electric Power Cooperative (BEPC), and Electric Power Research Institute (EPRI), completed a full-scale Front End Engineering and Design (FEED) study to evaluate the retrofit of MTR’s membrane-based post-combustion carbon dioxide (CO2) capture technology to the BEPC Dry Fork Station (DFS) Unit 1. The capture plant is designed to treat the entire flue gas flow from DFS; it is estimated that this system will capture 6,560 tonnes per day (TPD) of carbon dioxide. The overall goal of the project was to develop an AACE Level 2 Capital Cost Estimate with an accuracy of ±15% to demonstrate the economic feasibility of constructing and operating the MTR CO2 capture plant.

01 COAL, LIGNITE, AND PEAT↗

Input-output description of linear systems with multiple time-scales

It is pointed out that the study of systems evolving at multiple time-scales is simplified by studying reduced-order models of these systems valid at specific time-scales. The present investigation is concerned with an extension of results on the time-scale decomposition of autonomous systems to that of input-output systems. The results are employed to study conditions under which positive realness of a transfer function is preserved under singular perturbation. Attention is given to the perturbation theory for linear operators, the multiple time-scale structure of autonomous linear systems, the input-output description of two time-scale linear systems, the positive realness of two time-scale systems, and multiple time-scale linear systems.

Madriz, R. S.↗

Effect of inlet throttling on thermohydraulic instability in a large scale water-based RCCS: An experimental study

The objective of the present experimental study is to investigate the effect of inlet throttling on the thermohydraulic stability of a large scale water-based Reactor Cavity Cooling System (RCCS). The test was performed using the water-based Natural convection Shutdown heat removal Test Facility (NSTF) at Argonne, which represented a ½ axial scale and 12.5° sector slice of the full scale Framatome 625 MW t SC-HTGR RCCS concept. A two-phase steady state was first established through direct condensate refill, followed by increased inlet throttling over 10 stages, corresponding to a loss coefficient K over the range of 0.05–653. With the inlet throttling gradually increased, the system experienced a unique transition process between stabilization and destabilization. Through a stability analysis, three instability mechanisms were identified in the present test, including a compound mechanism due to both natural circulation oscillations (NCOs) and density wave oscillations (DWOs), Type-II DWOs, and geysering.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Validation of High Resolution Atmospheric and Dispersion Simulations

Weather models typically operate on averages of 1 km or more. This averages out fine scale turbulence. This results in smooth laminar flows and rapid vertical motions are usually averaged out. In this study, those fine scaled features were simulated for a 2013 field study of transport and diffusion of a tracer gas. Parameterized subgrid turbulence was required to produce dilution representative of observations. Despite this, the simulation with the finest grid and contained parameterized subgrid turbulence produced dilution that was consistent with observations.

THOMAS, ANDREW↗

Distant-acting Enhancers in Development and Disease

Multiple converging lines of evidence from experimental and human genetic studies indicate that both common and rare sequence variants involving enhancers play major roles in Mendelian and complex human disease phenotypes. We use a combination of sequence-based molecular approaches including chromatin mapping and synthesis-enabled modification of enhancer sequences, large-scale transgenic mouse studies (http://enhancer.lbl.gov), and CRISPR genome editing in the mouse model to study the in vivofunction of enhancers in developmental, evolutionary, and disease-related processes. Using examples from our ongoing work, I will illustrate how these methods provide insight into the function and evolution of distant-acting regulatory sequences and offer a starting point for understanding their role in human disease. I will discuss how improved in vivo mouse assays can be used to study candidate pathogenic human mutations in enhancers at scale, revealing the extent to which human genetic studies alone can be insufficient to identify truly causal mutations in enhancers. I will also show how such assays can be used to explore the sensitivity of enhancers that are extremely conserved ("ultraconserved") in evolution to mutations, revealing a remarkable functional robustness to sequence changes that contrasts with apparent evolutionary constraints.

Visel, A↗

Motion Dynamics of Motile Microbes in Pore-Networks and its Implications for Reactive Transport Processes

This report outlines new methods to improve simulations of microbial transport and microbially mediated reactions in porous media. A range of experimental, modeling, and machine learning tools are introduced to make these simulations faster, more reliable, and useful for real-world applications. At the microscopic level, the study investigates how different types of bacteria move through confined spaces. A new artificial intelligence tool called DeepTrackStat, is introduced to track motions dynamics as observed in videos of particles migrating through pore networks. This tool is especially helpful for studying fast-moving microbes and requires less computing power than traditional tracking methods. At larger scales, the research looks at how microbes and chemicals interact in zones where surface water and groundwater meet. To connect the small- and large-scale findings, the study presents a neural network model called STAMNet. This tool helps scale up detailed small-scale microbial motion behaviors to predict large-scale environmental changes more efficiently. By combining lab experiments, computer models, and artificial intelligence, the research presented supports smarter environmental decision-making, especially in bioremediation of contaminated groundwater and protection of water quality.

54 ENVIRONMENTAL SCIENCES↗

Theoretical study of various nonlinear phenomena in plasma systems and scaling of magneto-inertial-fusion targets

Plasma physics is an exciting field of study with a wide variety of nonlinear processes that come into play. Examples of such processes include the interaction of small-scale turbulence with large-scale plasma structures and the nonlinear saturation of plasma instabilities, for example those of magneto-hydrodynamical nature. During this Truman LDRD project, I studied a collection of nonlinear problems that are of interest to the field of plasma physics. This LDRD report summarizes four main research accomplishments. First, a new statistical model for describing inhomogeneous drift-wave turbulence inter- acting with zonal flows was developed. This new model includes the effects of nonlinear wave-wave collisions, which are expected to change the spectrum of the underlying DW turbulence and therefore the generation of zonal flows. Second, a new mathematical formalism was proposed to systematically apply the non- linear WKB approximation to general field theories, including those often used in fluid dynamics. This formalism represents an interesting tool for studying physical systems that show an explicit scale separation. Third, a weakly nonlinear model was developed to describe the magneto-Rayleigh-Taylor instability. This instability is of paramount importance to understand as it can reduce the performance of magnetic-inertial-fusion (MIF) platforms. The developed models captures the effects of harmonic generation and saturation of the linear growth of the instability. Finally, a framework was proposed for scaling magneto-inertial fusion (MIF) targets to larger pulsed-power drivers. From this framework, a set of scaling rules were derived that conserve the physical regimes of MIF systems when scaling up in peak current. By doing so, deleterious nonlinear processes that affect MIF performance may be kept at bay.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Optimization of nutrient utilization efficiency and productivity for algal cultures under light and dark cycles using genome-scale model process control

Abstract Algal cultivations are strongly influenced by light and dark cycles. In this study, genome-scale metabolic models were applied to optimize nutrient supply during alternating light and dark cycles of Chlorella vulgaris . This approach lowered the glucose requirement by 75% and nitrate requirement by 23%, respectively, while maintaining high final biomass densities that were more than 80% of glucose-fed heterotrophic culture. Furthermore, by strictly controlling glucose feeding during the alternating cycles based on model-input, yields of biomass, lutein, and fatty acids per gram of glucose were more than threefold higher with cycling compared to heterotrophic cultivation. Next, the model was incorporated into open-loop and closed-loop control systems and compared with traditional fed-batch systems. Closed-loop systems which incorporated a feed-optimizing algorithm increased biomass yield on glucose more than twofold compared to standard fed-batch cultures for cycling cultures. Finally, the performance was compared to conventional proportional-integral-derivative (PID) controllers. Both simulation and experimental results exhibited superior performance for genome-scale model process control (GMPC) compared to traditional PID systems, reducing the overall measured value and setpoint error by 80% over 8 h. Overall, this approach provides researchers with the capability to enhance nutrient utilization and productivity of cell factories systematically by combining genome-scale models and controllers into an integrated platform with superior performance to conventional fed-batch and PID methodologies.

59 BASIC BIOLOGICAL SCIENCES↗

Implementing Large-Scale CCS in Complex Geologic Reservoirs: Insights from Three Appalachian Basin Case Studies

This paper presents three design case studies for implementing large-scale geologic carbon storage in the Appalachian Basin region of the midwestern United States. While the Appalachian Basin has a challenging setting for carbon storage, the three case studies detailed in this article demonstrate that there are realistic options for implementing carbon storage in the basin. Carbonate rock formations, depleted hydrocarbon reservoirs, and moderate-porosity sandstones can be utilized as carbon-storage reservoirs in the Appalachian Basin. While these are not typical concepts for CO2 storage, the storage zones have advantages such as defined trapping mechanisms, multiple caprocks, and defined boundaries that are not always present in thick, permeable sandstones being targeted for many carbon-storage projects. The geologic setting, geotechnical parameters, and hydrologic setting for the three case studies are provided, along with the results of reservoir simulations of the CO2 injection-deployment strategies. The geological rock formations available for CO2 storage in the Appalachian Basin are more localized reservoirs with defined boundaries and finite storage capacities. Simulation results showed that accessing carbon-storage resources in these fields may require wellfields with 2–10 injection wells. However, these fields would have the capacity to inject 1–3 million metric tons of CO2 per year and up to 90 million metric tons of CO2 in total. The CO2 storage resources would fulfill decarbonization goals for many of the natural-gas power plants, cement plants, hydrogen plants, and refineries in the Appalachian Basin region.

Sminchak, Joel↗

Experimental study and demonstration of pilot-scale, dry feed, oxy-coal combustion under pressure

In this paper, we discuss how pressurized oxy-combustion is a promising technology for low-carbon, fossil fuel utilization. It has the potential of improved efficiency and economics compared with conventional atmospheric pressure oxy-combustion. Washington University in St. Louis has proposed a new pressurized oxy-combustion process, namely Staged Pressurized Oxy-Combustion, which has the potential to improve further the plant efficiency, operational flexibility, and economics. This process burns pulverized coal in a pressurized, oxy-combustion environment, which has not been demonstrated in a pilot-scale system before. To address this gap, a 100 kWth pressurized oxy-combustion facility was designed and constructed. This facility has a unique burner and furnace design featuring a co-axial, low-mixing flow field, which is drastically different from conventional coal-fired boiler designs where strong mixing is sought by introducing swirl or recirculating flows. This work aims to present the first pilot-scale experimental results of a dry-feed, pressurized oxy-combustion system. The tests focused on exploring flame stability and shape, char burnout, and fine particulate matter formation. Testing results suggest that the burner has excellent flame stability. The flame shape is consistent with the design philosophy and agrees with large eddy simulations. Importantly, complete char combustion can be achieved with an oxygen mole fraction in the flue gas of only 0.8%, as opposed to a required value of ~3% for conventional atmospheric pressure air-fired or oxyfuel combustion, which reduces the costs of both oxygen generation upstream and oxygen removal downstream. The testing results show promise for dry-feed, pressurized oxy-combustion, and the new burner and furnace design.

01 COAL, LIGNITE, AND PEAT↗

Genetic variation at transcription factor binding sites largely explains phenotypic heritability in maize

Abstract Comprehensive maps of functional variation at transcription factor (TF) binding sites (cis-elements) are crucial for elucidating how genotype shapes phenotype. Here, we report the construction of a pan-cistrome of the maize leaf under well-watered and drought conditions. We quantified haplotype-specific TF footprints across a pan-genome of 25 maize hybrids and mapped over 200,000 variants, genetic, epigenetic, or both (termed binding quantitative trait loci (bQTL)), linked tocis-element occupancy. Three lines of evidence support the functional significance of bQTL: (1) coincidence with causative loci that regulate traits, includingvgt1,ZmTRE1and the MITE transposon nearZmNAC111under drought; (2) bQTL allelic bias is shared between inbred parents and matches chromatin immunoprecipitation sequencing results; and (3) partitioning genetic variation across genomic regions demonstrates that bQTL capture the majority of heritable trait variation across ~72% of 143 phenotypes. Our study provides an auspicious approach to make functionalcis-variation accessible at scale for genetic studies and targeted engineering of complex traits.

Genetics & Heredity↗

Roadmap on exsolution for energy applications

Over the last decade, exsolution has emerged as a powerful new method for decorating oxide supports with uniformly dispersed nanoparticles for energy and catalytic applications. Due to their exceptional anchorage, resilience to various degradation mechanisms, as well as numerous ways in which they can be produced, transformed and applied, exsolved nanoparticles have set new standards for nanoparticles in terms of activity, durability and functionality. In conjunction with multifunctional supports such as perovskite oxides, exsolution becomes a powerful platform for the design of advanced energy materials. In the following sections, we review the current status of the exsolution approach, seeking to facilitate transfer of ideas between different fields of application. We also explore future directions of research, particularly noting the multi-scale development required to take the concept forward, from fundamentals through operando studies to pilot scale demonstrations.

25 ENERGY STORAGE↗

On an acoustic field generated by subsonic jet at low Reynolds numbers

An acoustic field generated by subsonic jets at low Reynolds numbers was investigated. This work is motivated by the need to increase the fundamental understanding of the jet noise generation mechanism which is essential to the development of further advanced techniques of noise suppression. The scope of this study consists of two major investigation. One is a study of large scale coherent structure in the jet turbulence, and the other is a study of the Reynolds number dependence of jet noise. With this in mind, extensive flow and acoustic measurements in low Reynolds number turbulent jets (8,930 less than or equal to M less than or equal to 220,000) were undertaken using miniature nozzles of the same configuration but different diameters at various exist Mach numbers (0.2 less than or equal to M less than or equal to 0.9).

Yamamoto, K.↗

A numerical study of the NOL large-scale test

The large-scale gap test was modeled numerically using the reactive hydrodynamics code 2DE with forest fire burn rates. The model gives good agreement between calculated and experimental critical gap values. The calibration of peak pressure in the gap versus gap length is obtained from these calculations, and is in good agreement with the published experiment curve. The two dimensional nature of the gap test is evident from the curvature of the shock wave in the gap and test sample, and from the observed distance of run to detonation in the test samples.

Bowan, A. L.↗