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At least 937 records · Page 52

Distinguishing major lithologic types in rocks of precambrian age in central Wyoming using multilevel sensing, with a chapter on possible economic significance of iron formation discovered by use of aircraft images in the Granite Mountains of Wyoming

The author has identified the following significant results. Information obtained by remote sensing from three altitude levels: ERTS-1 (565 miles), U-2 (60,000 feet), and C-130 aircraft (15,000 feet) illustrates the possible application of multilevel sensing in mineral exploration. Distinction can be made between rocks of greenstone belts and rocks of granite-granite gneiss areas by using ERTS-1 imagery in portions of the Precambrian of central Wyoming. Study of low altitude color and color infrared photographs of the mafic terrain revealed the presence of metasedimentary rocks with distinct layers that were interpreted as amphibolite by photogeologic techniques. Some of the amphibolite layers were found to be iron formation when examined in the field. To our knowledge this occurrence of iron formation has not been previously reported in the literature.

Houston, R. S.↗

Technology utilization in a non-urban region: Further impact and technique of the Technology Use Studies Center

Updated information pertaining to clients who receive and use information disseminated by the Technology Use Studies Center (TUSC) is reported. Charts are provided which indicate TUSC's performance in information dissemination and technical assistance in terms of quantities of searches accomplished during several contract years. The faculty information service is described, along with details of cooperation with other agencies. Specific searches are listed according to subject, client, and client location, and a measure of client response to services provided is indicated by the included selection of transfer and impact reports. The impetus behind the formation of the general aviation news letter is also described.

Gold, C. H.↗

Jovian ionospheric models

This paper reports results obtained on ionosphere formation in the Jovian upper atmosphere with special reference to some of the recently available reaction rates, and to recent models of the Jovian neutral atmosphere based on the possibility of a warmer mesopause. In the older models of the Jovian ionosphere, the major ions were H+ which were lost only by pure radiative recombination. This led to high electron densities and practically no diurnal change. In contrast, recent models have relatively much smaller electron densities, especially in lower regions, and may be susceptible to significant diurnal variation.

Capone, L. A.↗

Laser ranging data analysis

Near real-time Lageos laser ranging data are analyzed in terms of range bias, time bias, and internal precision, and estimates for earth orientation parameters X(sub p), Y(sub p), and UT1 are obtained. The results of these analyses are reported in a variety of formats. Copies of monthly summaries from November, 1986 through November, 1987 are included.

Source record↗

Efficient spacecraft formationkeeping with consideration of ballistic coefficient control

The extent to which drag can be used to enhance retrieval and servicing of platforms in the Space Staion environment is investigated for the case when separations on the order of several hundred or even thousands of kilometers occur over extended, but predefined, periods of time. The nature of the problem is formulated, the analytical tools used are described, and the mathematical foundation of the analysis is presented. Results are reported for the cases of formation flying cycles without ballistic coefficient control, formation flying with controlled relative decay, and the effects of varying solar activity.

Mathews, Michael↗

Laser ranging data analysis

Results of the near real-time analysis of Lageos laser ranging data are reported. The data was analyzed in terms of range bias, time bias, and internal precision; and estimates for the Earth orientation parameters X sub p, Y sub p, and UT1 are obtained. The results of these analyses are reported in a variety of formats. Sample copies of the weekly summaries from the second half of 1988 are included along with an annotated distribution list of the weekly summaries. Annual summaries for 1987 and 1988 are also included.

Source record↗

GCS programmer's manual

A variety of instructions to be used in the development of implementations of software for the Guidance and Control Software (GCS) project is described. This document fulfills the Radio Technical Commission for Aeronautics RTCA/DO-178A guidelines, 'Software Considerations in Airborne Systems and Equipment Certification' requirements for document No. 4, which specifies the information necessary for understanding and programming the host computer, and document No. 12, which specifies the software design and implementation standards that are applicable to the software development and testing process. Information on the following subjects is contained: activity recording, communication protocol, coding standards, change management, error handling, design standards, problem reporting, module testing logs, documentation formats, accuracy requirements, and programmer responsibilities.

Lowman, Douglas S.↗

Ultraviolet Imaging Telescope observations of the ScI galaxy NGC 628 (M74)

Ultraviolet images of NGC 628 at 1520 and 2490 A show that the nucleus has an oblong appearance and that the arms and disk exhibit features not seen in blue or H-alpha images. Aperture photometry of the nucleus gives results that are compatible with observations in other bandpasses and with models. The spiral arms appear more symmetrical in the UV than in other colors; in particular, two gaps are seen on either side of the nucleus. Combined UV and radio data appear to support a large-scale collective phenomenon, perhaps a quasi-static spiral structure mechanism, as being the dominant mode of spiral formation in this galaxy. We report the detection of a low surface brightness object at a distance of 7.6 arcmin southwest of the nucleus.

Chen, Peter C.↗

Laser ranging data analysis

Center for Space Research efforts have focused on the near real-time analysis of Lageos laser ranging data and on the production of predictive ephemerides. The data are analyzed in terms of range bias, time bias, and internal precision, and estimates for the Earth orientation parameters X(sub p), Y(sub p) and UT1 are obtained. The results of these analyses are reported in a variety of formats. In addition several additional stations began sending not only quick-look observations but also normal points created on-site with new software. These normal points are transmitted in a new standard format different from either current quick-look or MERIT-II full-rate formats. Thus new preprocessing software was written and successfully tested on these data. Inspection of the Bendix produced Lageos full-rate normal points continued, with detailed analyses and filtering of all 1991 A and B release normal points for Lageos through the beginning of 1992. A summary of the combined full-rate and quick-look normal point data set created for 1991 is provided. New long-term ephemerides for Lageos satellite, as well as for Etalon-1 and Etalon-2 (the so-called high satellites used for laser ranging) were produced and distributed to the network stations in cooperation with the Crustal Dynamics Project and Eurolas. These predictions are used by essentially every laser ranging site obtaining regular returns from any of these three satellites.

Source record↗

LIDAR Remote Sensing Concepts

The primary goal of the NASA New Millennium Program (NMP) is to develop technology for use on future operational missions. The Program consists of two thrust areas, one oriented towards developing technologies for Deep Space Probes and one oriented towards developing technology for Earth Observing Probes. Each thrust area intends to fly several technology demonstrator spacecraft designated DS-X and EO-X respectively where X is the mission number. Each mission has an approximately $100 million cap on total mission cost. The EO-1 mission has been selected and is under development. The instrument discussed here was submitted by NASA MSFC as a potential candidate for the EO-2 or EO-3 missions due to launch in 2001 and late 2002 or early 2003 respectively. This report summarizes and follows the format of the material provided to NMP.

Spiers, Gary D.↗

LIDAR Remote Sensing Concepts

The primary goal of the NASA New Millennium Program (NMP) is to develop technology for use on future operational missions. The Program consists of two thrust areas, one oriented towards developing technologies for Deep Space Probes and one oriented towards developing technology for Earth Observing Probes. Each thrust area intends to fly several technology demonstrator space designated DS-X and EO-X respectively where X is the mission number. Each mission has an approximately $100 million cap on total mission cost. The EO-1 mission has been selected and is under development. The instrument discussed here was submitted by NASA MSFC as a potential candidate for the EO-2 or EO-3 missions due to launch in 2001 and late 2002 or early 2003 respectively. This report summarizes and follows the format of the material provided to NMP.

Spiers, Gary D.↗

Low Masses and High Redshifts: The Evolution of the Mass-Metallicity Relation

We present the first robust measurement of the high redshift mass-metallicity (MZ) relation at 10(exp 8) < M/Stellar Mass < or approx. 10(exp 10), obtained by stacking spectra of 83 emission-line galaxies with secure redshifts between 1.3 < or approx. z < or approx. 2.3. For these redshifts, infrared grism spectroscopy with the Hubble Space Telescope Wide Field Camera 3 is sensitive to the R23 metallicity diagnostic: ([O II] (lambda)(lambda)3726, 3729 + [OIII] (lambda)(lambda)4959, 5007)/H(beta). Using spectra stacked in four mass quartiles, we find a MZ relation that declines significantly with decreasing mass, extending from 12+log(O/H) = 8.8 at M = 10(exp 9.8) Stellar Mass to 12+log(O/H)= 8.2 at M = 10(exp 8.2) Stellar Mass. After correcting for systematic offsets between metallicity indicators, we compare our MZ relation to measurements from the stacked spectra of galaxies with M > or approx. 10(exp 9.5) Stellar Mass and z approx. 2.3. Within the statistical uncertainties, our MZ relation agrees with the z approx. 2.3 result, particularly since our somewhat higher metallicities (by around 0.1 dex) are qualitatively consistent with the lower mean redshift (z = 1.76) of our sample. For the masses probed by our data, the MZ relation shows a steep slope which is suggestive of feedback from energy-driven winds, and a cosmological downsizing evolution where high mass galaxies reach the local MZ relation at earlier times. In addition, we show that our sample falls on an extrapolation of the star-forming main sequence (the SFR-M∗ relation) at this redshift. This result indicates that grism emission-line selected samples do not have preferentially high star formation rates (SFRs). Finally, we report no evidence for evolution of the mass-metallicity-SFR plane; our stack-averaged measurements show excellent agreement with the local relation.

Hgih Redshifts↗

BioMoSS: ROS-generating Photocatalysts for the Disinfection of Potable Water Systems

With NASA’s desire to replace iodine as the biocide within the potable water system of future missions, we continue our development of the biocidal MoS2 (BioMoSS) system. BioMoSS is a visible-light activated photocatalyst based upon few-layered vertically aligned molybdenum disulfide (FLV-MoS2) for the production of reactive oxygen species (ROS) as a biocide. FLV-MoS2 has been reported to have a high bacterial kill rate. We report significant improvements in the vertical-alignment and biocidal efficacy of the FLV-MoS2 compared to our initial results reported last year. Furthermore, we report the results of peroxide formation with and without surface deposition using gold. Finally, we investigate the delamination of the FLV-MoS2 films under immersion in water.

Antiseptics↗

Coordination Chemistry as a Universal Strategy for a Controlled Perovskite Crystallization

The most efficient and stable perovskite solar cells (PSCs) are made from complex mixture of precursors, which are practically always dissolved in combinations of the volatile (and toxic) N, N-Dimethylformamide (DMF), and the non-volatile (and green) dimethyl sulfoxide (DMSO) solvents. Typically, to then form a thin film, an extreme oversaturation of the perovskite precursor is initiated to trigger nucleation sites, e.g. by vacuum, an airstream or a so-called antisolvent. Unfortunately, most such oversaturation triggers do not expel the lingering (and highly coordinating) DMSO, which is highly coordinating, from the thin films; this detrimentally affects long-term stability. Here, for the first time, we introduce (the green) dimethyl sulfide (DMS) as a novel nucleation trigger for perovskite films combining, uniquely, high coordination and high vapor pressure. More precisely, DMS coordinates more strongly than all currently used solvents, hence replacing them, including DMSO, effectively during film formation. Crucially, DMS also has among the highest vapor pressures reported in literature, thus effectively leaving the thin film shortly after formation. This gives DMS a universal scope: DMS replaces other solvents by coordinating more strongly and removes itself once the film formation is finished. To demonstrate this novel coordination chemistry approach, we process MAPbI 3 PSCs, typically dissolved in hard-to-remove (and green) DMSO achieving 21.6% efficiency, among the highest reported efficiencies for this system. To confirm the universality of our strategy, we tested DMS for FAPbI 3 as another composition, which showed higher efficiency of 23.5% compared to 20.9% for fabricated device with CB. Finally, this work provides a universal strategy to control perovskite crystallization using coordination chemistry heralding the revival of perovskite compositions with pure DMSO, such as MAPbI 3 .

36 MATERIALS SCIENCE↗

Extended emission and star formation in I Zw 18

The results of sky limited emission-line (H-alpha and forbidden O III 5007A) and line-free (6450 A and 5100 A) continuum imagery of the super-metal-poor blue compact galaxy I Zw 18 are reported. The main body of star formation in the galaxy is surrounded by a 3 kpc diameter extended envelope in H-alpha. In addition, there exist arcs of emission emanating from both central H II regions and winding around to the west, as well as a broader ridge of emission extending northward from the main body. The total mass of ionized material is estimated to be 3 x 10 to the 6th solar masses, or about 5 percent of the mass of the observed H I clouds. Several extended stellar continuum regions exist to the northwest of the main body, the brightest three forming a line along PA = 310 deg out to a 3 kpc distance from the central region of the galaxy. The correlation of the morphology and location of stellar continuum and emission regions with the distribution of H I is discussed. It is calculated that I Zw 18 has had previous, but disconnected, episodes of star formation, possibly from chance collisions of widely separated H I clouds.

Dufour, Reginald J.↗

Videos, photos, and AI-derived grain size data associated with “High-throughput AI Video Surveys Enable Reproducible Multiscale Sediment Size Mapping, with Implications for Hydrobiogeochemical Parameterization”

NOTE: The manuscript associated with this data package is currently in review. The data may be revised based on reviewer feedback. Upon manuscript acceptance, this data package will be updated with the final dataset and additional metadata. This data package is associated with the manuscript “High-throughput AI Video Surveys Enable Reproducible Multiscale Sediment Size Mapping, with Implications for Hydrobiogeochemical Parameterization” under review. This data package includes five data types: 1) raw photos and videos from drone survey and walking smartphone surveys; 2) images derived from raw videos; 3) manual labeling of reference scales; 4) metadata for all images and photo resolution derived from artificial intelligence (AI) models or manual labels, 5) grain size data obtained from AI models for all photos, 6) metadata and grain size data after quality control, 7) summaries of sample efficiency for all data, and 8) computational fluid dynamics (CFD) data used to support hydro-biogeochemical (HBGC) parameter estimation. Such data is used to 1) demonstrate significant improvements in accuracy, efficiency, and quality control for grain size data collection with the help of AI models, 2) study the spatial heterogeneity of grain size and observation reproducibility based on tens of thousands of data points generated by the AI models, and 3) evaluate the impacts of grain size heterogeneity on key HBGC parameters across sediment-to-reach and hourly-to-yearly scales. In particular, the data package contains 116 folders and 179696 files. The files include 41 videos in .mov format, 64047 photos in .jpg format, 13541 video-derived photos in .png format, 12747 segmentation mask data in .tif format, 12747 segmentation data in .json format, 24771 .csv files that with metadata and grain size for each individual photo as well as water depth and velocity data from CFD and observation, 51791 .txt files of raw AI predicted labels, and 11 flight record data in .srt format. The summary for all metadata and grain size statistics information is included in “Scales_V3_NG.csv” and “Statistics_V3_NG.csv”. The summary for data that pass data quality control (QC) level 0-2 is included in “QCStatistics_V3_NG.csv”. The QC level 0 represents photos whose photo resolution is positive, excluding photos that miss reference scale. The QC level 1 means reference scale circularity uncertainty is less than 5% for smartphone images while representing photo resolution is larger than 0.44 mm/pixel for drone images. The QC level 2 means excluding photos whose grain number is less than 100, a minimum number of grains recommended by classic literature. The summary for each video’s name, length, frame rates, survey area, grain number, survey efficiency, etc. can be found in “QCSummary_V3_NG.csv”. The summary for site name, GPS coordinates, and number of images at each site can be found in “SitesSummary_V3_*.csv” files. Overall computational efficiency summary is reported in Table 4 of accompanying manuscript. Additionally, the nitrate concentration data used in this work was downloaded from an existing dataset published on ESS-DIVE (Boat-Dragged Sensor Hanford Reach.csv; Conner A. et al., 2020). We thank the United States Forest Service, Washington Department of Fish and Wildlife, Washington Department of Natural Resources, Cowiche Canyon Conservatory, Port of Benton, and the Confederated Tribes and Bands of the Yakama Nation for access to field locations where the data were collected. We also thank the Yakama Nation Tribal Council and Yakama Nation Fisheries for working with us to facilitate data collection and optimization of data usage according to their values and worldview.

54 ENVIRONMENTAL SCIENCES↗

Active Thermochemical Tables: Enthalpies of Formation of Bromo- and Iodo-Methanes, Ethenes and Ethynes

Here, the thermochemistry of halocarbon species containing iodine and bromine is examined through an extensive interplay between new Feller–Peterson–Dixon (FPD) style composite methods and a detailed analysis of all available experimental and theoretical determinations using the thermochemical network that underlies the Active Thermochemical Tables (ATcT). From the computational viewpoint, a slower convergence of the components of composite thermochemistry methods is observed relative to species that solely contain first row elements, leading to a higher computational expense for achieving comparable levels of accuracy. Potential systematic sources of computational uncertainty are investigated, and, not surprisingly, spin-orbit coupling is found to be a critical component, particularly for iodine containing molecular species. The ATcT analysis of available experimental and theoretical determinations indicates that prior theoretical determinations have significantly larger uncertainties than originally reported, particularly in cases where molecular spin-orbit effects were ignored. Accurate and reliable heats of formation are reported for 38 halogen containing systems, based on combining the current computations with previous experimental and theoretical work via the ATcT approach.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗