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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Efforts have resulted in the production of some trimethylsilyl-blocked diamines, which have been employed in a novel manner for the synthesis of polyimide model compounds. Three new silicon-containing diamides were prepared by reacting 1 mol of bis-/N, N prime-bis (trimethylsilyl) -4-aminophonyl/-disubstituted silanes with 2 mol of phthalic anhydride, thus establishing the reactivity of fully silylated diamides in imide formation.
Eigenvalue equations of the form D(lambda) = 0 are studied for acoustic modes in circular and annular ducts without flow. The ducts have locally reacting walls with arbitrary wall admittance. It is shown that circular ducts may have double eigenvalues, or wall admittances where both D(lambda) and D prime (lambda) are zero. These double eigenvalues are formed by the coalescence of the lowest-order eigenfunction with some higher-order eigenfunction. The eigenfunctions, or acoustic modes, associated with the double eigenvalues are found to be orthogonal to themselves so that the standard expansion formula for the acoustic field, which is obtained from a separation-of-variables analysis, is invalid. An alternate expansion formula for the acoustic field is derived. This alternate formula shows that the coalesced acoustic mode is linearly amplified by the transmission distance and exponentially attenuated at the expected rate. The expansion formula also reveals a new eigenfunction, or acoustic mode, which is exponentially attenuated at the same rate as the coalesced eigenfunction.
The objectives of the Skylab Program included observations of the earth, the sun, the stars, and a comet in addition to a variety of engineering and medical experiments. Attention is given to mission planning activities accomplished before the launch of the orbital workshop, during the manned missions, and between manned missions. Two major purposes of early experiments planning were related to the establishment of reasonable potential goals in terms of accomplishment and the discovery of potential problems in scheduling. Planning during the mission proceeded according to a scheme in which the planning was done on a daily basis. Experiences from the three Skylab missions are discussed separately. The results of the Skylab Program demonstrate the value of the daily experiment planning system that was capable of reacting to changing constraints.
Measurements of low-density dissociated arc-heated flows around low and high surface catalycity spheres are compared with numerical solutions to the full Navier-Stokes equations for reacting gas flow fields, taking into account slip and finite surface catalytic boundary conditions. A time-dependent finite difference solution technique developed by Li (1973, 1974) is used in the investigation and a simple transport model is employed for the flows considered. The correctness of the solution approach is demonstrated by the very good agreement obtained between experimental and computational data.
Formation of large particles on substrate is eliminated by actively exhausting reacted gases. Effluent gas backflow is prevented by pumping in curtain of nitrogen above fresh reactive gases from several directions.
Etherified polymer is made from modified cellulose derivative which is reacted with periodate. It will absorb 2 grams of urea per 100 grams of polymer. Indications are that polymers could be used to help remove uremic wastes in artificial kidneys, or they could be administered orally as therapy for uremia.
A clean source of high enthalpy air was obtained from the exothermic decomposition of nitric oxide in the presence of strongly heated nitrogen. A nitric oxide jet was introduced into a confined coaxial nitrogen stream. Measurements were made of the extent of mixing and reaction. Experimental results are compared with one- and two-dimensional chemical kinetics computations. Both analyses predict much lower reactivity than was observed experimentally. Inlet nitrogen temperatures above 2400 K were sufficient to produce experimentally a completely reacted gas stream of synthetic air.
Alternating field demagnetization experiments have been conducted on representative samples of the carbonaceous meteorites (carbonaceous chondrites and ureilites). The results indicate that many, if not all, of these meteorites possess an intense and stable magnetic moment of extraterrestrial origin. Thermomagnetic analyses have been conducted on samples of all known carbonaceous meteorites. In addition to yielding quantitative magnetite estimates, these studies indicate the presence of a thermally unstable component, troilite, which reacts with gaseous oxygen to form magnetite. It is proposed that the magnetite found in some carbonaceous chondrites resulted from the oxidation of troilite during the early history of the solar system. The formation of pyrrhotite is expected as a natural consequence of magnetite formation via this reaction. Consideration is given to the implications of magnetite formation on paleointensity studies.
Aerosols of KBr and AgNO3 were mixed, exposed to light in a glass tube and collected in the dark. About 15% of the collected material was reduced to silver upon development. Thus, two aerosols of particles that react to form a photo-reducible compound can be used to measure coagulation efficiency.
A parametric study of the heat transfer rate along the wall of a rocket nozzle is presented. The influences of different parameters; laminar and turbulent Lewis number, mixture ratio, initial wall temperature distribution, and eddy viscosity, were considered. The numerical evaluation of these influences on heat transfer rate was done by using three different compressible, reacting laminar and turbulent boundary layer computer programs; MABL (Mass Addition Boundary Layer Program), MABL-KE (MABL program is modified to include turbulent kinetic energy equation), and BLIMP (Boundary Layer Integral Matrix Procedure). This study also provided an excellent opportunity to evaluate the efficiencies of these three computer programs and to suggest one of them for future computational purposes.
Exposure to g-forces causes changes in the vascular systems of animals. The vessels are distorted and their contents may escape. Various parts of a given organ may react differently according to their structure, and arteries will undergo changes that depend on their position relative to the direction of the g-force vector.
Bonding across the interface for two solids in contact and the subsequent transfer of material from one surface to another is a direct result of the interfacial bonds being stronger than the cohesive bonds in either of the two solids. Surface tools such as LEED, Auger emission spectroscopy, field ion microscopy, and the atom probe are used to examine adhesive contacts and to determine the direction, nature, quantity of material transfer and properties of the solids which effect transfer and wear. The electronic nature, cohesive binding energies, surface structure, lattice disregistry and distribution of species in surface layers are all found to effect adhesion and transfer or transport for clean surfaces in solid state contact. The influence of adsorbed and reacted surface films from fractions of a monolayer to multilayer reactive films are considered. It is shown that even fractions of a monolayer of surface active species such as oxygen and sulfur can markedly inhibit adhesion and transport.
Chromium and/or nickel powders were milled in metal chlorides and in organic liquids representative of various functional groups. The powders always reacted with the liquid and became contaminated with elements from them. The milled powders had specific surface areas ranging from 0.14 to 37 sq m/g, and the total contamination with elements from the milling liquid ranged from 0.01 to 56 weight percent. Compounds resulting from substitution, addition, or elimination reactions formed in or from the milling liquid.
A theoretical and experimental study of acoustic propagation in an anechoically terminated multisectioned duct was performed. A unique source array consisting of two concentric rings of sources, providing phase and amplitude control in the radial as well as circumferential direction, was developed to generate plane waves and both spinning and non-spinning higher order modes. Measurement of attenuation and radial mode shapes were taken with various finite length liners inserted between the hard wall sections of a duct with an anechoic termination. A search technique was developed to find the complex eigenvalues for a liner under the assumption of a locally reacting boundary condition. The experimental results were compared with a theoretical analysis which includes the modal transmission and reflection at the interface of each duct section, and this indicated that the local reaction boundary condition is valid for three liner configurations.
Accurate predictions of the thrust loss due to boundary layer effects and of the wall heat flux are very important to the design and performance evaluation of rocket nozzles. A method used in analytical procedures for liquid fuel rocket engine performance prediction and evaluation is presented. A computer program is examined that is a fast and accurate procedure for solving the set of boundary layer equation (momentum, energy, and species) for laminar or turbulent, chemically reacting flows with a wide variety of boundary conditions. Results of comparison of the various turbulent models are presented. A summary of the modifications and additions to the program is examined.
A second-order uniform expansion is obtained for nonlinear wave propagation in a two-dimensional duct lined with a point-reacting acoustic material consisting of a porous sheet followed by honeycomb cavities and backed by the impervious wall of the duct. The waves in the duct are coupled with those in the porous sheet and the cavities. An analytical expression is obtained for the absorption coefficient in terms of the sound frequency, the physical properties of the porous sheet, and the geometrical parameters of the flow configuration. The results show that the nonlinearity flattens and broadens the absorption vs. frequency curve, irrespective of the geometrical dimensions or the porous material acoustic properties, in agreement with experimental observations.
A phenomenological model of the magnetospheric substorm has been developed which divides the substorm into three phases: a growth phase, an expansion phase, and a recovery phase. Current research is reviewed in the light of criticism of this model. The most important inadequacies of the model concern the fact that the tail lobe and the plasma sheet do not always react as single entities as previously supposed. Further research is needed on the problems of substorm variability, errors in onset time, the number of distinct spatial regions, and the dependence of magnetic activity on past history.
An analysis of the sound field in a circularly curved duct of rectangular cross-section is carried out for both rigid and locally-reacting absorbing walls. The field is excited by a piston source at one end of the duct section, and comparisons of the acoustic field and the net power flow along the duct axis are made with corresponding results for a straight duct section for various frequencies. It is found that in general the curved duct yields a significant increase in sound attenuation along the duct axis as compared to the straight duct.