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At least 937 records · Page 52

Core materials development for the fuel cycle R&D program

The Fuel Cycle Research and Development program is investigating methods of burning minor actinides in a transmutation fuel. One of the challenges of achieving this goal is to develop fuels capable of reaching extreme burnup levels (e.g. 40%). To achieve such high burnup levels’ fast reactor core materials (cladding and duct) must be able to withstand very high doses (>300 dpa design goal) while in contact with the coolant and the fuel. Thus, these materials must withstand radiation effects that promote low temperature embrittlement, radiation induced segregation, high temperature helium embrittlement, swelling, accelerated creep, corrosion with the coolant, and chemical interaction with the fuel (FCCI). To develop and qualify materials to a total fluence greater than 200 dpa requires development of advanced alloys and irradiations in fast reactors to test these alloys. Test specimens of ferritic/martensitic alloys (T91/HT-9) previously irradiated in the FFTF reactor up to 210 dpa at a temperature range of 350– 750 °C are presently being tested. This includes analysis of a duct made of HT-9 after irradiation to a total dose of 155 dpa at temperatures from 370 to 510 °C. Compact tension, charpy and tensile specimens have been machined from this duct and mechanical testing as well as SANS and Mossbauer spectroscopy are currently being performed. Initial results from compression testing and Charpy testing reveal a strong increase in yield stress (~400 MPa) and a large increase in DBTT (up to 230 °C) for specimens irradiated at 383 °C to a dose of 28 dpa. Less hardening and a smaller increase in DBTT was observed for specimens irradiated at higher temperatures up to 500 °C. Advanced radiation tolerant materials are also being developed to enable the desired extreme fuel burnup levels. Specifically, coatings are being developed to minimize FCCI, and research is underway to fabricate large heats of radiation tolerant oxide dispersion steels with homogeneous oxide dispersions.

Maloy, S. A.↗

Development of a Training Program for Commercial Building Technicians

This project focused on developing and deploying a comprehensive program of 22 training modules, including certification requirements, and accreditation standards for commercial building technicians, to help achieve the full savings potential of energy efficient buildings, equipment, and systems. This curriculum extended the currently available commercial building technician programs -- training a labor force in a growing market area focused on energy efficiency. The program helps to remove a major market impediment to low energy/zero energy commercial building system acceptance, namely a lack of operating personnel capable of handling more complex high efficiency systems. The project developed a training curriculum for commercial building technicians, with particular focus on high-efficiency building technology, and systems. In Phase 1, the project team worked collaboratively in developing a draft training syllabus to address project objectives. The team identified energy efficiency knowledge gaps in existing programs and plans and plans to address the gaps with either modified or new curricula. In Phase 2, appropriate training materials were developed to meet project objectives. This material was developed for alternative modes of delivery, including classroom lecture materials, e-learning elements, video segments, exercises, and hands-on training elements. A Certification and Accreditation Plan and a Commercialization and Sustainability Plan were also investigated and developed. The Project Management Plan was updated quarterly and provided direction on the management approaches used to accomplish the expected project objectives. GTI project management practices tightly coordinate project activities using management controls to deliver optimal customer value. The project management practices include clear scope definition, schedule/budget tracking, risk/issue resolution and team coordination.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Xcel Energy – LBNL ‘Beyond Widgets’ Project. Workstation Specific Lighting with Daylight Dimming Controls System Program Manual

This program manual was developed through a U.S. Department of Energy project to develop streamlined utility program approaches to the deployment of integrated systems in commercial offices. Integrated systems present deep opportunities for energy savings, however by nature these systems have additional levels of complexity and effort required for their design and energy savings assessment, which create barriers for utility incentive programs to develop streamlined cost effective incentive programs to capture these savings. This project worked with Xcel Energy in Colorado and Minnesota to select an integrated system and develop a streamlined approach to its deployment for small and large commercial offices. Xcel Energy worked with LBNL to select a workstation specific lighting system with daylight dimming controls, applied as a retrofit in commercial office spaces. Previous studies indicated a potential lighting annual energy savings of 28-63%, with an average of 47% for this system type, due to reduced fixture LPD and controls only, not including a full fixture replacement from a condition such as T8 to LED. Xcel also had a desire to incorporate this fixture replacement in their integrated system package, and as a result annual energy lighting savings are expected to be higher. FLEXLAB testing of the system for 500 lux minimum output conditions translated into a 94% annual energy savings for this system. Market analysis was developed for large and medium commercial office buildings in Xcel’s Minnesota and Colorado markets showing a potential for 48-295 and 120-672 GWh of energy savings potential for Colorado and Minnesota respectively. Total Resource Costs (TRC) vary by location and technology package used (enterprise versus non-enterprise lighting controls system), and vary from 0.29 to 1.27 and 0.06 and 0.44 for a Retrofit case, and 0.20 to 1.63 and 0.07 to 0.57 for a Replace on Burnout strategy for Colorado and Minnesota respectively. These results indicate good potential for demonstrating a strong technical and economic case for deployment of this system type in Xcel’s Colorado territory, while deployment in the Minnesota market may be advisable as well as part of a portfolio of programs, or as an effort to help shift the market into integrated systems deployment in general. It should be noted that the cost of avoided energy in both markets is significantly low ($0.07/kWh for Minnesota, $0.08/kWh for Colorado), and these TRC values would not be representative of deployment potential in other markets with higher utility rates. In addition, installation costs used for these systems may decrease with time, further enhancing their return on investment. Overall, workstation specific lighting systems with daylight dimming controls present a very strong potential for cost effective lighting energy savings, as demonstrated by the FLEXLAB test results and previous case studies. Further energy savings may be realized from the use of fixture-specific occupancy sensors as well, although this approach was not considered in this study.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Commercial Electric Vehicle (EV) Development and Manufacturing Program (Final Report)

Navistar with the Department of Energy’s assistance undertook this effort to achieve the project objectives as listed in the next section. A wholly owned subsidiary of Navistar, Workhorse Sales Corporation was the original grant awardee and upon their discontinuation as a standalone business entity, Navistar assumed the role of principal investigator. The intent of the effort, as part of the American Recovery and Reinvestment Act (ARRA) was to produce zero emission vehicles that could meet the needs of the marketplace while reducing carbon emissions to zero. This effort was predicated upon the assumption that concurrent development activities in the lithium ion battery industry investigations would significantly increase their production volumes thus leading to substantial reductions in their manufacturing costs. As a result of this development effort much was learned about the overall system compatibility between the electric motor, battery pack, and charging capabilities. The original system was significantly revised and improved during the execution of this development effort. The overall approach that was chosen was to utilize a British zero emissions, class 2 truck that had been developed for their market, homologate it and modify it to meet the product requirements as specified in the grant details. All of these specific goals were achieved. During the course of marketing and selling the product valuable information was obtained as relates to customer expectations, price points, and product performance expectations, specifically those customer expectations about range requirements in urban delivery situations. While the grant requirements specified a range of 100 miles on a single charge, actual customer usage logs indicate a range of 40 miles or less is typical for their applications. The price point, primarily due to battery pack costs, was significantly higher than the mass market could bear. From Navistar’s and the overall industry’s perspective, valuable insights and lessons into this all-electric vehicle propulsion were gained during the performance of this effort and can be revisited when battery chemistry and technology advance to the point of more suitable economic viability. Additionally, another goal of the ARRA act and this specific grant was to manufacture the product in the, at that time, economically depressed Northwest Indiana area. Navistar chose a location in Wakarusa, Indiana which fulfilled this requirement. Navistar was and continues to be committed to alternative fuel and propulsion options as an industry leader in the medium and heavy duty truck industry.

33 ADVANCED PROPULSION SYSTEMS↗

Cold Crucible Induction Melter (CCIM) Testing on Glass Ceramic and Ceramic Waste Forms

The U.S. Department of Energy Office of Nuclear Energy’s Fuel Cycle Research and Development (FCR&D) program is developing advanced high level waste (HLW) forms for the immobilization of the long-lived radionuclides resulting from future potential reprocessing of the used nuclear fuel from commercial reactors. One of the program’s goals is to have orders of magnitude improvements in durability (compared to the reference borosilicate glass waste form for HLW), to facilitate lower costs including less expensive and complex processing, to lower storage costs and to provide for final disposal of the waste in a deep geological repository. Both glass ceramic and ceramic waste forms are being developed and evaluated as possible improvements to borosilicate glass to achieve these objectives.

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Community-Scale Attic Retrofit and Home Energy Upgrade Data Mining - Hot Dry Climate

Retrofitting is an essential element of any comprehensive strategy for improving residential energy efficiency. The residential retrofit market is still developing, and program managers must develop innovative strategies to increase uptake and promote economies of scale. Residential retrofitting remains a challenging proposition to sell to homeowners, because awareness levels are low and financial incentives are lacking. The U.S. Department of Energy's Building America research team, Alliance for Residential Building Innovation (ARBI), implemented a project to increase residential retrofits in Davis, California. The project used a neighborhood-focused strategy for implementation and a low-cost retrofit program that focused on upgraded attic insulation and duct sealing. ARBI worked with a community partner, the not-for-profit Cool Davis Initiative, as well as selected area contractors to implement a strategy that sought to capitalize on the strong local expertise of partners and the unique aspects of the Davis, California, community. Working with community partners also allowed ARBI to collect and analyze data about effective messaging tactics for community-based retrofit programs. ARBI expected this project, called Retrofit Your Attic, to achieve higher uptake than other retrofit projects, because it emphasized a low-cost, one-measure retrofit program. However, this was not the case. The program used a strategy that focused on attics-including air sealing, duct sealing, and attic insulation-as a low-cost entry for homeowners to complete home retrofits. The price was kept below $4,000 after incentives; both contractors in the program offered the same price. The program completed only five retrofits. Interestingly, none of those homeowners used the one-measure strategy. All five homeowners were concerned about cost, comfort, and energy savings and included additional measures in their retrofits. The low-cost, one-measure strategy did not increase the uptake among homeowners, even in a well-educated, affluent community such as Davis. This project has two primary components. One is to complete attic retrofits on a community scale in the hot-dry climate on Davis, CA. Sufficient data will be collected on these projects to include them in the BAFDR. Additionally, ARBI is working with contractors to obtain building and utility data from a large set of retrofit projects in CA (hot-dry). These projects are to be uploaded into the BAFDR.

affordable housing↗

emPower 3.0 (Santa Barbara Final Technical Report)

This report serves as the Final Report for Santa Barbara County’s Energy Efficiency and Conservation Block Grant (EECBG) BetterBuildings Neighborhood Program (BBNP) award from the U.S. Department of Energy (DOE). This report explains how DOE BBNP funding was invested to develop robust program infrastructure designed to help property owners complete energy improvements, thereby generating substantial outcomes for the local environment and economy. It provides an overview of program development and design within the grant period, program accomplishments and challenges to date, and a plan for the future sustainability of emPower, the County’s innovative clean energy and building efficiency program.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Cementitious Barriers Partnership (CBP): Training and Release of CBP Toolbox Software, Version 1.0 - 13480

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the Office of Tank Waste Management within the Office of Environmental Management of U.S. Department of Energy (US DOE). The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that improve understanding and predictions of the long-term hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program are intended to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to or longer than 100 years for operating facilities and longer than 1,000 years for waste management purposes. CBP software tools were made available to selected DOE Office of Environmental Management and field site users for training and evaluation based on a set of important degradation scenarios, including sulfate ingress/attack and carbonation of cementitious materials. The tools were presented at two-day training workshops held at U.S. National Institute of Standards and Technology (NIST), Savannah River, and Hanford included LeachXS{sup TM}/ORCHESTRA, STADIUM{sup R}, and a CBP-developed GoldSim Dashboard interface. Collectively, these components form the CBP Software Toolbox. The new U.S. Environmental Protection Agency leaching test methods based on the Leaching Environmental Assessment Framework (LEAF) were also presented. The CBP Dashboard uses a custom Dynamic-link library developed by CBP to couple to the LeachXS{sup TM}/ORCHESTRA and STADIUM{sup R} codes to simulate reactive transport and degradation in cementitious materials for selected performance assessment scenarios. The first day of the workshop introduced participants to the software components via presentation materials, and the second day included hands-on tutorial exercises followed by discussions of enhancements desired by participants. Tools were revised based on feedback obtained during the workshops held from April through June 2012. The resulting improved CBP Software Toolbox, including evaluation versions of and LeachXS{sup TM}/ORCHESTRA and STADIUM{sup R} has been made available to workshop and selected other participants for further assessment. Inquiries about future workshops and requests for access to the Toolbox software can be made via the CBP web site [1]. (authors)

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The single-cell transcriptome program of nodule development cellular lineages in Medicago truncatula

Legumes establish a symbiotic relationship with nitrogen-fixing rhizobia by developing nodules. Nodules are modified lateral roots that undergo changes in their cellular development in response to bacteria, but the transcriptional reprogramming that occurs in these root cells remains largely uncharacterized. Here, we describe the cell-type-specific transcriptome response of Medicago truncatula roots to rhizobia during early nodule development in the wild-type genotype Jemalong A17, complemented with a hypernodulating mutant (sunn-4) to expand the cell population responding to infection and subsequent biological inferences. The analysis identifies epidermal root hair and stele sub-cell types associated with a symbiotic response to infection and regulation of nodule proliferation. Trajectory inference shows cortex-derived cell lineages differentiating to form the nodule primordia and, posteriorly, its meristem, while modulating the regulation of phytohormone-related genes. Gene regulatory analysis of the cell transcriptomes identifies new regulators of nodulation, including STYLISH 4, for which the function is validated.

Cell Biology↗

Specification of the near-Earth space environment with SHIELDS

Here, predicting variations in the near-Earth space environment that can lead to spacecraft damage and failure is one example of “space weather” and a big space physics challenge. A project recently funded through the Los Alamos National Laboratory (LANL) Directed Research and Development (LDRD) program aims at developing a new capability to understand, model, and predict Space Hazards Induced near Earth by Large Dynamic Storms, the SHIELDS framework. The project goals are to understand the dynamics of the surface charging environment (SCE), the hot (keV) electrons representing the source and seed populations for the radiation belts, on both macro- and micro-scale. Important physics questions related to particle injection and acceleration associated with magnetospheric storms and substorms, as well as plasma waves, are investigated. These challenging problems are addressed using a team of world-class experts in the fields of space science and computational plasma physics, and state-of-the-art models and computational facilities. A full two-way coupling of physics-based models across multiple scales, including a global MHD (BATS-R-US) embedding a particle-in-cell (iPIC3D) and an inner magnetosphere (RAM-SCB) codes, is achieved. New data assimilation techniques employing in situ satellite data are developed; these provide an order of magnitude improvement in the accuracy in the simulation of the SCE. SHIELDS also includes a post-processing tool designed to calculate the surface charging for specific spacecraft geometry using the Curvilinear Particle-In-Cell (CPIC) code that can be used for reanalysis of satellite failures or for satellite design.

54 ENVIRONMENTAL SCIENCES↗

Assessment of coated cladding impact on large-break LOCA with TRACE-DAKOTA

Since 2011, the U.S. Department of Energy has launched new research and development (R&D) programs for developing new accident tolerant fuels (ATFs). These new fuel concepts are expected to bring several advancements in terms of plant safety. However, development, licensing, as well as deployment of ATF require a substantial investment among fuel vendors, operating utilities, and regulatory authorities. For ATF to be economically feasible, credited safety benefits may be necessary to provide an economic incentive for transition of nuclear power plants from Zr/UO2-based fuel technologies to ATFs. As a result, it is essential to evaluate the economic viability of ATF by conducting a comprehensive safety benefits study informed by R&D and demonstration studies. In the present work, based on the best estimate plus uncertainty methodology, sensitivity analysis and uncertainty quantification for key safety quantities under LB-LOCA are performed for the Peach Bottom boiling water reactor (BWR) with GE14 nuclear fuel design adopting the ATF concepts. A coupled TRACE-DAKOTA analysis framework is adopted to perform the uncertainty quantification. Based on the computational results and obtained statistics, the coping time increase, fuel performance improvement as well as the most dominating phenomena during the accident for Cr-coated cladding are investigated in detail. Overall, the results obtained are useful for subsequent plant PRA study and support a move to more modernized performance-based regulatory requirements to realize plant economic benefits.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Program Final Report - Develop Thermoelectric Technology for Automotive Waste Heat Recovery

We conducted a vehicle analysis to assess the feasibility of thermoelectric technology for waste heat recovery and conversion to useful electrical power and found that eliminating the 500 W of electrical power generated by the alternator corresponded to about a 7% increase in fuel economy (FE) for a small car and about 6% for a full size truck. Electric power targets of 300 W were established for city and highway driving cycles for this project. We obtained critical vehicle level information for these driving cycles that enabled a high-level design and performance analysis of radiator and exhaust gas thermoelectric subsystems for several potential vehicle platforms, and we identified the location and geometric envelopes of the radiator and exhaust gas thermoelectric subsystems. Based on this analysis, we selected the Chevrolet Suburban as the most suitable demonstration vehicle for this project. Our modeling and thermal analysis assessment of a radiator-based thermoelectric generator (TEG), however, revealed severe practical limitations. Specifically the small temperature difference of 100°C or less between the engine coolant and ambient air results in a low Carnot conversion efficiency, and thermal resistance associated with air convection would reduce this conversion efficiency even further. We therefore decided not to pursue a radiator-based waste heat recovery system and focused only on the exhaust gas. Our overall approach was to combine science and engineering: (1) existing and newly developed TE materials were carefully selected and characterized by the material researcher members of our team, and most of the material property results were validated by our research partners, and (2) system engineers worked closely with vehicle engineers to ensure that accurate vehicle-level information was used for developing subsystem models and designs, and the subsystem output was analyzed for potential fuel economy gains. We incorporated material, module, subsystem, and integration costs into the material selection criteria in order to balance various materials, module and subsystem design, and vehicle integration options. Our work on advanced TE materials development and on TEG system design, assembly, vehicle integration, and testing proceeded in parallel efforts. Results from our two preliminary prototype TEGs using only Bi-Te TE modules allowed us to solve various mechanical challenges and to finalize and fine tune aspects of the design and implementation. Our materials research effort led us to quickly abandon work on PbTe and focus on the skutterudite materials due to their superior mechanical performance and suitability at automotive exhaust gas operating temperatures. We synthesized a sufficiently large quantity of skutterudite material for module fabrication for our third and final prototype. Our TEG#3 is the first of its kind to contain state-of-the-art skutterudite-based TE modules to be installed and tested on a production vehicle. The design, which consisted of 24 skutterudite modules and 18 Bi-Te modules, attempted to optimize electrical power generation by using these two kinds of TE modules that have their peak performance temperatures matched to the actual temperature profile of the TEG during operation. The performance of TEG#3 was limited by the maximum temperature allowable for the Bi-Te TE modules located in the colder end of the TEG, resulting in the operating temperature for the skutterudite modules to be considerably below optimum. We measured the power output for (1) the complete TEG (25 Watts) and (2) an individual TE module series string (1/3 of the TEG) operated at a 60°C higher temperature (19 Watts). We estimate that under optimum operating temperature conditions, TEG#3 will generate about 235 Watts. With additional improvements in thermal and electrical interfaces, temperature homogeneity, and power conditioning, we estimate TEG#3 could deliver a power output of about 425 Watts.

30 DIRECT ENERGY CONVERSION↗

Baseline Postirradiation Examination of the FUTURIX-FTA Experiments

Postirradiation Examination (PIE) results from the baseline examination of the FUTURIX-FTA irradiation experiment are presented in this report. The FUTURIX-FTA irradiation was designed to study the fuel performance of candidate transmutation fuels. The FUTURIX-FTA experiment was conducted in the true fast neutron spectrum conditions of the Phénix sodium fast test reactor in France. FUTURIX-FTA contained several compositions that were also irradiated as part of the AFC-1 test in cadmium filtered positions in the Idaho National Laboratory (INL) Advanced Test Reactor (ATR) that approximate the neutron spectrum of a fast reactor. This experiment was a joint collaboration between the Department of Energy (DOE) in the U.S. and the Commissariat á l'Energie Atomique et aux Energies Alternatives (CEA) in France. A joint agreement between DOE and CEA was established in 2004 to conduct an irradiation experiment of metallic and nitride fuels in the Phénix reactor at CEA. Both the FUTURIX-FTA tests and the AFC-1 tests were conducted for the DOE Advanced Fuels Campaign (AFC) that is part of Fuel Cycle Research & Development (FCRD) program. These programs seek to develop and demonstrate the technologies needed to transmute long-lived transuranic actinide isotopes contained in spent nuclear fuel via fast reactor technology. The long term goal of this work is to reduce the radiotoxicity of future high level waste repositories. Post-irradiation examination of irradiated fuels experiments provides data related to in reactor fuel performance and input into future fuel design choices. The compositions of the FUTURIX-FTA pins were designed to test if minor actinides could be incorporated into the fuel of a fast reactor without significantly changing fuel performance observed for previously well studied fuels. The fuel performance of metallic fuel in fast reactors has been well documented. Likewise the irradiation performance of nitride fuels in fast reactors has also been documented. However the existing database for nitride fuels is much smaller than the database for metal fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

RADWIND Project Final Technical Report

The Rural Area Distributed Wind Integration Network Development (RADWIND) Project (January 2020-April 2023) was undertaken by NRECA Research, a not-for-profit subsidiary of NRECA focused on underwritten research, with the support of DOE. The project was part of the Wind Energy Technologies Office’s (WETO’s) Wind Integration for Rural Economic Development (WIRED) program, which was developed out of an October 2018 workshop in which NRECA participated in. RADWIND’s end of project goal was “to raise awareness of distributed wind as a solution for the energy, resiliency, and economic development needs of electric cooperatives, and to provide resources and information that reduce barriers and lower costs for co-ops seeking to deploy distributed wind. Through this project, NRECA Research seeks to establish a national distributed wind presence for and by NRECA’s members that delivers these benefits and plans to communicate NRECA’s members that properly deployed distributed wind can be a bankable technology option for rural America.”

17 WIND ENERGY↗

The Cementitious Barriers Partnership (CBP) Software Toolbox Capabilities In Assessing The Degradation Of Cementitious Barriers

The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy (US DOE) Office of Tank Waste and Nuclear Materials Management. The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that help improve understanding and predictions of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program have been used to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to 100 years and longer for operating facilities and longer than 1000 years for waste disposal. The CBP Software Toolbox has produced tangible benefits to the DOE Performance Assessment (PA) community. A review of prior DOE PAs has provided a list of potential opportunities for improving cementitious barrier performance predictions through the use of the CBP software tools. These opportunities include: 1) impact of atmospheric exposure to concrete and grout before closure, such as accelerated slag and Tc-99 oxidation, 2) prediction of changes in Kd/mobility as a function of time that result from changing pH and redox conditions, 3) concrete degradation from rebar corrosion due to carbonation, 4) early age cracking from drying and/or thermal shrinkage and 5) degradation due to sulfate attack. The CBP has already had opportunity to provide near-term, tangible support to ongoing DOE-EM PAs such as the Savannah River Saltstone Disposal Facility (SDF) by providing a sulfate attack analysis that predicts the extent and damage that sulfate ingress will have on the concrete vaults over extended time (i.e., > 1000 years). This analysis is one of the many technical opportunities in cementitious barrier performance that can be addressed by the DOE-EM sponsored CBP software tools. Modification of the existing tools can provide many opportunities to bring defense in depth in prediction of the performance of cementitious barriers over time.

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