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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

The effects of magnetic nozzle configurations on plasma thrusters

Plasma thrusters have been operated at power levels from 10kW to 0.1MW. When these devices have had magnetic fields applied to them which form a nozzle configuration for the expanding plasma, they have shown marked increases in exhaust velocity which is in direct proportion to the magnitude of the applied field. Further, recent results have shown that electrode erosion may be influenced by applied magnetic fields. This research is directed to the experimental and computational study of the effects of applied magnetic field nozzles in the acceleration of plasma flows. Plasma source devices which eliminate the plasma interaction in normal thrusters are studied as most basic. Normal thruster configurations will be studied without applied fields and with applied magnetic nozzle fields. Unique computational studies will utilize existing codes which accurately include transport processes. Unique diagnostic studies will support the experimental studies to generate new data. Both computation and diagnostics will be combined to indicate the physical mechanisms and transport properties that are operative in order to allow scaling and accurate prediction of thruster performance.

York, Thomas M.↗
DOE OSTI2019

Low cost modular plasma system for reforming of natural gas

The initial aim of this project was to develop a low-cost compact, modularly scalable, point of use, on demand production system for the reforming of natural gas (NG) into products such as acetylene, hydrogen and other related hydrocarbons. Based on a pulsed dielectric barrier discharge (DBD), the fast rising voltage pulses produced by the system causes the dielectric breakdown of the gas to lag behind the rapid voltage increase so that a voltage greater than the static breakdown voltage of the gas, called an overvoltage, is briefly attained. The century long commercial use of the DBD discharge to push the highly endothermic oxygen to ozone reaction served as an additional motivation. The project meets the recommendations of the National Research Council 2007 report on plasma science for a greater investment in low temperature plasma science and engineering. An important finding is that the method investigated has a high specific energy requirement (SER) of the order of 1,000 to 5,000 kWh per kg of hydrogen, and a corresponding low efficiency of only ~0.1 to 0.5% of converting electrical into chemical (ΔH, ΔG) energy. This compares unfavorably with 52 kWh/kgH 2 required for NG thermal plasma reforming, or a pulsed spark discharge, Lotfalipour et. al, and Gao et. al. (For comparison electrolysis of water into hydrogen and oxygen gas requires only 45 to 80kWh/kgH 2 ). This project garnered data with different reactor configurations, materials, gases and mixtures including NG, methane, hydrogen, propane, argon, nitrogen and air, gap sizes ranging from 0.5 to 4.1 mm, electrode areas from 5 to 460 cm, voltages to 27 kV, pulse frequencies to 20 kHz and peak currents into the hundreds of amperes, temperatures to 625 °C and pressures from 15 mbar to 2 bar. An SRS 300 residual gas analyzer (RGA) yielded quadrupole mass spectrometry (QMS) data on the reformate. To analyze the data we extended the public domain software OpenChrom®, Wenig, to QMS data, yielding accurate identification and quantitative data on reformate products. This extension of OpenChrom® is applicable beyond this project and is a significant contribution to the general community of researchers. The documentation is available on the internet, see Whitlock, and a copy has been appended to this report. The main product of methane and natural gas plasma reforming is hydrogen, constituting ~90% of the products, followed by 1% to 10% ethane, propane, ethylene, acetylene and isobutene. Neopentane, propene, butane and pentane constitute less than 1 % of product. Adding a nickel catalyst increases the selectivity for hydrogen. Carbon nanosheets (graphene), a product of commercial interest, were synthesized by plasma reforming of acetylene at low pressure. The reformate analysis shows hat saturated and branched hydrocarbons are favored compared with unsaturated and linear hydrocarbons. For example, ethane, propane, iso-butane, 2-methyl butane, and 2-methyl pentane are produced in higher amounts compared with unsaturated and linear components. At low pressure acetylene and ethylene production rate is higher and propane production lower. We developed a recirculating system in which hydrogen is removed through a permeable membrane as fast as it is being produced by the reactor and the remaining products are recirculated at a high flow rate of several liters per minute. This keeps the concentration of H 2 in the reactor low, while achieving a total output concentration of 79%, high enough for pressure swing adsorption to be used for further purification. The recirculating system could be used with other gas reforming technologies. We report on four different reactors,1) a spark discharge reactor, 2) a standard DBD cylindrical reactor, 3) a small DBD reactor where catalyst powder can be quickly loaded onto a carrier to investigate the effect of the plasma on the catalyst and the effectiveness of the of the catalyst in promoting gas reformation and 4) a configurable DBD reactor to study the performance effects of dielectric selection, electrode gap distance, and electrode/dielectric interface on plasma reactor operation. This project achieved a commercializable 1kW plasma system including reactors a plasma pulse generator and a gas supply module.

03 NATURAL GAS↗
DOE OSTI2020

SiO 2 Is Wasted Space in Single-Nanometer-Scale Silicon Nanoparticle-Based Composite Anodes for Li-Ion Electrochemical Energy Storage

The electrode processing conditions of silicon-based composite anodes play a pivotal role in the resulting interfacial chemical speciation and, thus, the electrochemical cycling behavior of the electrode. Systematically investigating how small chemical changes to the surface of the silicon nanoparticle (NP) affect larger, electrode-level properties is a strategy that will inform design principles to maximize electrode energy density and extend electrode lifetime. Here, we incorporate silicon nanoparticles (NPs) with an average diameter of 5.5 nm synthesized from the gas phase through a nonthermal plasma method into composite anode half-cell coin cells. We perform chemistry to functionalize the native hydride-terminated silicon NP surface with N-methylpyrrolidone (NMP) to improve slurry properties and reduce the silicon reactivity prior to composite electrode fabrication. We construct composite electrodes from these silicon NPs and observe an 86% capacity retention over 100 cycles at a rate of C/5, with an initial silicon specific capacity of 2600 mAh/g. We expose the same Si NPs to water that completely oxidizes these small-diameter NPs to SiO 2 and find that the SiO 2 NPs in the same electrode configuration exhibit no obvious lithium alloying capacity in the electrochemical potential range of lithium silicide alloy formation. As this result stands in contrast to existing literature, we provide a discussion on the origin of the discrepancies.

25 ENERGY STORAGE↗
NASA NTRS1990

The effects of magnetic nozzle configurations on plasma thrusters

Plasma thrusters have been operated at power levels from 10 kw to 0.1 MW. When these devices have had magnetic fields applied to them which form a nozzle configuration for the expanding plasma, they have shown marked increases in exhaust velocity which is in direct proportion to the magnitude of the applied field. Further, recent results have shown that electrode erosion may be influenced by applied magnetic fields. This research effort is directed to the experimental and computational study of the effects of applied magnetic field nozzles in the acceleration of plasma flows. Plasma source devices which eliminate the plasma interaction in normal thrusters are studied as most basic. Normal thruster configurations were studied without applied fields and with applied magnetic nozzle fields. Unique computational studies utilize existing codes which accurately include transport processes. Unique diagnostic studies supported the experimental studies to generate new data. Both computation and diagnostics were combined to indicate the physical mechanisms and transport properties that are operative in order to allow scaling and accurate prediction of thruster performance.

York, Thomas M.↗
NASA NTRS1972

Quasi-steady plasma accelerators

Results are reported from a continued study of MPD thrusters operating in the quasi-steady mode and using electrode vapor as the propellant. Testing methods were refined, and performance data is now available for a fairly wide range of thruster geometries. Performance was found to be strongly dependent on thruster geometry, with some designs showing approximately twice the efficiency obtained during the preceding contract period. The radial clearance between electrodes, the attachment point of the arc on the cathode, and the electrical resistance of the electrodes appear to be important design variables.

Ducati, A. C.↗
DOE OSTI2013

A dielectric-barrier discharge enhanced plasma brush array at atmospheric pressure

This study developed a large volume cold atmospheric plasma brush array, which was enhanced by a dielectric barrier discharge by integrating a pair of DC glow discharge in parallel. A platinum sheet electrode was placed in the middle of the discharge chamber, which effectively reduced the breakdown voltage and working voltage. Emission spectroscopy diagnosis indicated that many excited argon atoms were distributed almost symmetrically in the lateral direction of the plasma. The concentration variations of reactive species relative to the gas flow rate and discharge current were also examined.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2019

Plasma-enabled healing of graphene nano-platelets layer

Graphene platelet networks (GPNs) were deposited onto silicon substrates by means of anodic arc discharge ignited between two graphite electrodes. Here, substrate temperature and pressure of helium atmosphere were optimized for the production of the carbon nanomaterials. The samples were modified or destroyed with different methods to mimic typical environments responsible of severe surface degradation. The emulated conditions were performed by four surface treatments, namely thermal oxidation, substrate overheating, exposition to glow discharge, and metal coating due to arc plasma. In the next step, the samples were regenerated on the same substrates with identical deposition technique. Damaging and re-growth of GPN samples were systematically characterized by scanning electron microscopy and Raman spectroscopy. Furthermore, the full regeneration of the structural and morphological properties of the samples has proven that this healing method by arc plasma is adequate for restoring the functionality of 2D nanostructures exposed to harsh environments.

42 ENGINEERING↗
DOE OSTI2016

Investigation on the electron flux to the wall in the VENUS ion source

The long-term operation of high charge state electron cyclotron resonance ion sources fed with high microwave power has caused damage to the plasma chamber wall in several laboratories. Porosity, or a small hole, can be progressively created in the chamber wall which can destroy the plasma chamber over a few year time scale. A burnout of the VENUS plasma chamber is investigated in which the hole formation in relation to the local hot electron power density is studied. First, the results of a simple model assuming that hot electrons are fully magnetized and strictly following magnetic field lines are presented. The model qualitatively reproduces the experimental traces left by the plasma on the wall. However, it is too crude to reproduce the localized electron power density for creating a hole in the chamber wall. Second, the results of a Monte Carlo simulation, following a population of scattering hot electrons, indicate a localized high power deposited to the chamber wall consistent with the hole formation process. Finally, a hypervapotron cooling scheme is proposed to mitigate the hole formation in electron cyclotron resonance plasma chamber wall.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2012

Interactions of chlorine plasmas with silicon chloride-coated reactor walls during and after silicon etching

The interplay between chlorine inductively coupled plasmas (ICP) and reactor walls coated with silicon etching products has been studied in situ by Auger electron spectroscopy and line-of-sight mass spectrometry using the spinning wall method. A bare silicon wafer mounted on a radio frequency powered electrode (-108 V dc self-bias) was etched in a 13.56 MHz, 400 W ICP. Etching products, along with some oxygen due to erosion of the discharge tube, deposit a Si-oxychloride layer on the plasma reactor walls, including the rotating substrate surface. Without Si-substrate bias, the layer that was previously deposited on the walls with Si-substrate bias reacts with Cl-atoms in the chlorine plasma, forming products that desorb, fragment in the plasma, stick on the spinning wall and sometimes react, and then desorb and are detected by the mass spectrometer. In addition to mass-to-charge (m/e) signals at 63, 98, 133, and 168, corresponding to SiCl{sub x} (x = 1 - 4), many Si-oxychloride fragments with m/e = 107, 177, 196, 212, 231, 247, 275, 291, 294, 307, 329, 345, 361, and 392 were also observed from what appear to be major products desorbing from the spinning wall. It is shown that the evolution of etching products is a complex 'recycling' process in which these species deposit and desorb from the walls many times, and repeatedly fragment in the plasma before being detected by the mass spectrometer. SiCl{sub 3} sticks on the walls and appears to desorb for at least milliseconds after exposure to the chlorine plasma. Notably absent are signals at m/e = 70 and 72, indicating little or no Langmuir-Hinshelwood recombination of Cl on this surface, in contrast to previous studies done in the absence of Si etching.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Transient photoresponse of nitrogen-doped ultrananocrystalline diamond electrodes in saline solution

Beyond conventional electrically-driven neuronal stimulation methods, there is a growing interest in optically-driven approaches. In recent years, nitrogen-doped ultrananocrystalline diamond (N-UNCD) has emerged as a strong material candidate for use in electrically-driven stimulation electrodes. This work investigates the electrochemical activity of N-UNCD in response to pulsed illumination, to assess its potential for use as an optically-driven stimulation electrode. Whilst N-UNCD in the as-grown state exhibits a weak photoresponse, the oxygen plasma treated film exhibits two orders of magnitude enhancement in its sub-bandgap open circuit photovoltage response. The enhancement is attributed to the formation of a dense network of oxygen-terminated diamond nanocrystals at the N-UNCD surface. Electrically connected to the N-UNCD bulk via sub-surface graphitic grain boundaries, these diamond nanocrystals introduce a semiconducting barrier between the sub-surface graphitic semimetal and the electrolyte solution, leading to a photovoltage under irradiation with wavelengths of λ = 450 nm and shorter. Within the safe optical exposure limit of 2 mW mm{sup −2}, charge injection capacity of 0.01 mC cm{sup −2} is achieved using a 15 × 15 μm electrode, meeting the requirements for extracellular and intercellular stimulation. The nanoscale nature of processes presented here along with the diamond's biocompatibility and biostability open an avenue for the use of oxygen treated N-UNCD as optically driven stimulating electrodes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Probing local electron temperature and density inside a sheared flow stabilized Z-pinch using portable optical Thomson scattering

We report the first optical Thomson scattering measurements inside a high electron temperature (≳1 keV) and moderate electron density (mid 10 16 cm –3 ) plasma. This diagnostic has been built to provide critical plasma parameters, such as electron temperature and density, for Advanced Research Projects Agency-Energy-supported fusion-energy concepts. It uses an 8 J laser at 532 nm in 1.5 ns to measure the high frequency feature of the Thomson scattering profile at 17 locations along the probe axis. It is able to measure electron density from 5 × 10 17 cm –3 to several 10 19 cm –3 and electron temperatures from tens of eV to several keV. Here, in this paper, we describe the design, deployment, and analysis on the sheared flow stabilized Z-pinch machine at Zap Energy named FuZE. The probe beam is aimed at an axial distance of 20 cm from the central electrode and is timed within the temporal envelope of neutron emission. The high temperature and moderate density plasmas generated on FuZE lie in an unconventional regime for Thomson scattering as they are between tokamaks and laser-produced plasmas. We described the analysis considerations in this regime, show that the electron density was below 5 × 10 16 cm –3 at all times during these measurements, and present a sample shot where the inferred electron temperature varied from 167 ± 16 eV to 700 ± 85 eV over 1.6 cm.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

Multiscale Cryo Electron Microscopy Reveals Interfacial Degradation and Stabilization in Battery Electrodes

Electrochemical interfaces are dynamic systems, evolving based on their local environment and reactant surface structures. The electrode-electrolyte interface in Li-ion batteries can be protective, limiting parasitic reactions with the electrolyte to passivate the surface [1]. Additionally, this interphase has an impact on the Li-ion transport through that layer based on its composition, bonding environment, and thickness. These parameters are challenging to collect and may vary depending on the electrode surface site investigated relative to its spatial position in a coin cell. This study will detail a multiscale cryogenic electron microscopy approach where millimeter-scale cross-sections through the coin cell batteries were made using a cryogenic stage within a fs-laser plasma focused ion beam (laser PFIB) with complementary energy dispersive X-ray spectroscopy able to detect variations in the composition at electrode interfaces [2]. Microscale cross-sectioning and lamella sample preparation of battery electrodes was conducted at the Center for Integrated Nanotechnologies using a Ga-ion focused ion beam (FIB) with air-free and cryo-transfer [3], followed by nanoscale mapping of composition and bonding within the CEI through cryo-scanning transmission electron microscopy (cryo-STEM) electron energy loss spectroscopy [4]. This multiscale approach enabled identification of millimeter-scale features of a battery stack with visualization of degradation in electrodes such as cracks in cathode particles, gas evolution, and SEI evolution; microscale interfacial characteristics, such as heterogeneity in the SEI or barrier layer and identification of electrolyte networks to the electrode surfaces; and nanoscale measurement of the CEI thickness, mapping of transition metal bonding within the cathode particles to identify loss of active materials, and identification of beneficial electrolyte additives incorporated into the CEI structure. This multiscale approach allows for a statistical understanding of the primary mechanisms and parasitic degradation pathways that impact performance by limiting the ion transport pathways within Li+ batteries.

36 MATERIALS SCIENCE↗
NASA NTRS2002

Barium light source method and apparatus

Visible light emission is obtained from a plasma containing elemental barium including neutral barium atoms and barium ion species. Neutral barium provides a strong green light emission in the center of the visible spectrum with a highly efficient conversion of electrical energy into visible light. By the selective excitation of barium ionic species, emission of visible light at longer and shorter wavelengths can be obtained simultaneously with the green emission from neutral barium, effectively providing light that is visually perceived as white. A discharge vessel contains the elemental barium and a buffer gas fill therein, and a discharge inducer is utilized to induce a desired discharge temperature and barium vapor pressure therein to produce from the barium vapor a visible light emission. The discharge can be induced utilizing a glow discharge between electrodes in the discharge vessel as well as by inductively or capacitively coupling RF energy into the plasma within the discharge vessel.

Curry, John J.↗
DOE OSTI2013

3D active edge silicon sensors: Device processing, yield and QA for the ATLAS-IBL production

3D silicon sensors, where plasma micromachining is used to etch deep narrow apertures in the silicon substrate to form electrodes of PIN junctions, were successfully manufactured in facilities in Europe and USA. In 2011 the technology underwent a qualification process to establish its maturity for a medium scale production for the construction of a pixel layer for vertex detection, the Insertable B-Layer (IBL) at the CERN-LHC ATLAS experiment. The IBL collaboration, following that recommendation from the review panel, decided to complete the production of planar and 3D sensors and endorsed the proposal to build enough modules for a mixed IBL sensor scenario where 25% of 3D modules populate the forward and backward part of each stave. The production of planar sensors will also allow coverage of 100% of the IBL, in case that option was required. This paper will describe the processing strategy which allowed successful 3D sensor production, some of the Quality Assurance (QA) tests performed during the pre-production phase and the production yield to date.

47 OTHER INSTRUMENTATION↗
DOE OSTI2015

Investigation of the flickering of La{sub 2}O{sub 3} and ThO{sub 2} doped tungsten cathodes

Short-arc lamps are equipped with tungsten electrodes due to their ability to withstand a high thermal load during operation. Nominal currents of more than one hundred amperes lead to a cathode tip temperature near the melting point of tungsten. To reduce the electrode temperature and, thereby, to increase the maintenance of such lamps, ThO{sub 2} or tentatively La{sub 2}O{sub 3} are added to the electrode material. They generate a reduced work function by establishing a monolayer of emitter atoms on the tungsten surface. Emitter enrichments on the lateral surface of doped cathodes are formed. They are traced back to transport mechanisms of emitter oxides in the interior of the electrode and on the electrode surface in dependence of the electrode temperature and to the redeposition of vaporized and ionized emitter atoms onto the cathode tip by the electric field in front. The investigation is undertaken by means of glow discharge mass spectrometry, scanning electron microscope images, energy dispersive x-ray spectroscopy, and through measurements of the optical surface emissivity. The effect of emitter enrichments on the stability of the arc attachment is presented by means of temporally resolved electrode temperature measurements and by measurements of the luminous flux from the cathode-near plasma. They show that the emitter enrichments on the lateral surface of the cathode are attractive for the arc attachment if the emitter at the cathode tip is depleted. In this case, it moves along the lateral surface from the cathode tip to sections of the cathode with a reduced work function. It induces a temporary variation of the cathode tip temperature and of the light intensity from the cathode-near plasma, a so-called flickering. In particular, in case of lanthanated cathodes, strong flickering is observed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Optimization of Si:H films at the onset of nanocrystallinity for applications in silicon solar cells

The Si:H films at the onset of nanocrystallinity has proved to be an extremely useful material for stable a-Si:H based solar cells. In the present work it has been targeted to grow the improved a-Si:H matrix at the onset of nanocrystallization at a high growth rate. By optimizing the electrode separation in the RF glow discharge reactor and the effective gas pressure in the plasma, a significantly conducting (σ{sub D} ∼10{sup −5} S.cm{sup −1}), optically absorbing, low H-content (C{sub H} ∼2.2 at%) Si:H material at the onset of nanocrystallinity (X{sub C} ∼53%) has been obtained at a relatively high growth rate (r{sub d} = 102 Å/min), suitable for the desired technological applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

A simple novel device for air sampling by electrokinetic capture

A variety of different sampling devices are currently available to acquire air samples for the study of the microbiome of the air. All have a degree of technical complexity that limits deployment. Here, we evaluate the use of a novel device, which has no technical complexity and is easily deployable. An air-cleaning device powered by electrokinetic propulsion has been adapted to provide a universal method for collecting samples of the aerobiome. Plasma-induced charge in aerosol particles causes propulsion to and capture on a counter-electrode. The flow of ions creates net bulk airflow, with no moving parts. A device and electrode assembly have been re-designed from air-cleaning technology to provide an average air flow of 120 lpm. This compares favorably with current air sampling devices based on physical air pumping. Capture efficiency was determined by comparison with a 0.4 μm polycarbonate reference filter, using fluorescent latex particles in a controlled environment chamber. Performance was compared with the same reference filter method in field studies in three different environments. For 23 common fungal species by quantitative polymerase chain reaction (qPCR), there was 100 % sensitivity and apparent specificity of 87%, with the reference filter taken as “gold standard.” Further, bacterial analysis of 16S RNA by amplicon sequencing showed equivalent community structure captured by the electrokinetic device and the reference filter. Unlike other current air sampling methods, capture of particles is determined by charge and so is not controlled by particle mass. We analyzed particle sizes captured from air, without regard to specific analyte by atomic force microscopy: particles at least as low as 100 nM could be captured from ambient air. This work introduces a very simple plug-and-play device that can sample air at a high-volume flow rate with no moving parts and collect particles down to the sub-micron range. In conclusion, the performance of the device is substantially equivalent to capture by pumping through a filter for microbiome analysis by quantitative PCR and amplicon sequencing.

47 OTHER INSTRUMENTATION↗