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At least 937 records · Page 52

Non-Contact Thermal Properties Measurement with Low-Power Laser and IR Camera System

As shown by the Phoenix Mars Lander's Thermal and Electrical Conductivity Probe (TECP), contact measurements of thermal conductivity and diffusivity (using a modified flux-plate or line-source heat-pulse method) are constrained by a number of factors. Robotic resources must be used to place the probe, making them unavailable for other operations for the duration of the measurement. The range of placement is also limited by mobility, particularly in the case of a lander. Placement is also subject to irregularities in contact quality, resulting in non-repeatable heat transfer to the material under test. Most important from a scientific perspective, the varieties of materials which can be measured are limited to unconsolidated or weakly-cohesive regolith materials, rocks, and ices being too hard for nominal insertion strengths. Accurately measuring thermal properties in the laboratory requires significant experimental finesse, involving sample preparation, controlled and repeatable procedures, and, practically, instrumentation much more voluminous than the sample being tested (heater plates, insulation, temperature sensors). Remote measurements (infrared images from orbiting spacecraft) can reveal composite properties like thermal inertia, but suffer both from a large footprint (low spatial resolution) and convolution of the thermal properties of a potentially layered medium. In situ measurement techniques (the Phoenix TECP is the only robotic measurement of thermal properties to date) suffer from problems of placement range, placement quality, occupation of robotic resources, and the ability to only measure materials of low mechanical strength. A spacecraft needs the ability to perform a non-contact thermal properties measurement in situ. Essential components include low power consumption, leveraging of existing or highly-developed flight technologies, and mechanical simplicity. This new in situ method, by virtue of its being non-contact, bypasses all of these problems. The use of photons to both excite and measure the thermal response of any surface material to a high resolution (estimated footprint = 10 square centimeters) is a generational leap in physical properties measurements. The proposed method consists of spot-heating the surface of a material with a low (less than 1 W) power laser. This produces a moderate (5-10 K) temperature increase in the material.

Hudson, Troy L.

High performance alloy electroforming

Electroformed copper and nickel are used in structural applications for advanced propellant combustion chambers. An improved process has been developed by Bell Aerospace Textron, Inc. wherein electroformed nickel-manganese alloy has demonstrated superior mechanical and thermal stability when compared to previously reported deposits from known nickel plating processes. Solution chemistry and parametric operating procedures are now established and material property data is established for deposition of thick, large complex shapes such as the Space Shuttle Main Engine. The critical operating variables are those governing the ratio of codeposited nickel and manganese. The deposition uniformity which in turn affects the manganese concentration distribution is affected by solution resistance and geometric effects as well as solution agitation. The manganese concentration in the deposit must be between 2000 and 3000 ppm for optimum physical properties to be realized. The study also includes data regarding deposition procedures for achieving excellent bond strength at an interface with copper, nickel-manganese or INCONEL 718. Applications for this electroformed material include fabrication of complex or re-entry shapes which would be difficult or impossible to form from high strength alloys such as INCONEL 718.

Malone, G. A.

Lidar Measurements of On-Shore Wind Diffusion

The concept to place electric power generating stations on the oceans off the coast of the United States has instilled new efforts in research for improved understanding of the diffusion properties of the atmosphere in the ocean-air interface. The Atomic Energy Commission has instigated a program by the Meteorology Group at Brookhaven National Laboratory to investigate the low level, on-shore wind systems that dominate many of the coastal regions. Analytical techniques and specialized instrumentation from previous studies at Brookhaven are being used in this new program. The Brookhaven Lidar system is used to measure some of the physical properties of the oil-fog plume originating from a portable smoke generator on a boat off the coast. The oil-fog plume is used as a tracer which can be observed, photographed and measured to determine the diffusive power of the atmosphere associated with the ocean-air interface and the discontinuities found in the ocean-land boundary. This paper will describe the program rather briefly and the oil-fog scattering measurements that have been made with the Lidar system.

Brown, R. M.

Cirrus cloud properties derived from coincident GOES and lidar data during the 1986 FIRE Cirrus Intensive Field Observations (IFO)

One of the main difficulties in detecting cirrus clouds and determining their correct altitude using satellite measurements is their nonblackness. In the present algorithm (Rossow et al., 1985) used by the International Satellite Cloud Climatology Project (ISCCP), the cirrus cloud emissivity is estimated from the derived cloud reflectance using a theoretical model relating visible (VIS, 0.65 micron) optical depth to infrared (IR, 10.5 micron) emissivity. At this time, it is unknown how accurate this approach is or how the derived cloud altitude relates to the physical properties of the cloud. The First ISCCP Regional Experiment (FIRE) presents opportunities for determining how the observed radiances depend on the cloud properties. During the FIRE Cirrus Intensive Field Observations (IFO, see Starr, 1987), time series of cloud thickness, height, and relative optical densities were measured from several surface-based lidars. Cloud microphysics and radiances at various wavelengths were also measured simultaneously over these sites from aircraft at specific times during the IFO (October 19 to November 2, 1986). Satellite-observed radiances taken simultaneously can be matched with these data to determine their relationships to the cirrus characteristics. The first step is taken toward relating all of these variables to the satellite observations. Lidar-derived cloud heights are used to determine cloud temperatures which are used to estimate cloud emissivities from the satellite IR radiances. These results are then correlated to the observed VIS reflectances for various solar zenith angles.

Minnis, Patrick

Properties of Single Crystalline Semiconducting CoSb3

A study of the thermoelectric properties of the skutterudite compound CoSb3 was carried out on single crystals grown by the Bridgman gradient freeze technique. p- and n-type samples were obtained over a wide range of carrier concentration. Undoped As-grown crystals show p-type conductivity while n-type samples were obtained by addition of Te or Pd. Samples were characterized by x-ray diffractometry, electron microprobe analysis, and density measurements. The physical properties of CoSb3 such as linear thermal expansion coefficient, sound velocity, and Debye temperature were also determined and are presented. Seebeck coefficient, electrical resistivity, thermal conductivity, and Hall effect measurements were performed between room temperature and about 900 K. Exceptionally high Hall mobilities were obtained on p-type samples with a maximum room-temperature Hall mobility of 3300 sq cm/V.s at a carrier concentration of 1 x 10(exp 17)/cc. The results of the transport property measurements are discussed and are in agreement with some recent predictions based on band structure calculations. The potential of CoSb3 for thermoelectric applications is evaluated.

Caillat, T.

Discovery of Associated Absorption Lines in an X-Ray Warm Absorber: Hubble Space Telescope Faint Object Spectrograph Observations of MR 2251-178

The presence of a 'warm absorber' was first suggested to explain spectral variability in an X-ray spectrum of the radio-quiet quasi-stellar object (QSO) MR 2251-178. A unified picture, in which X-ray warm absorbers and 'intrinsic' UV absorbers are the same, offers the opportunity to probe the nuclear environment of active galactic nuclei. To test this scenario and understand the physical properties of the absorber, we obtained a UV spectrum of MR 2251-178 with the Faint Object Spectrograph on board the Hubble Space Telescope (HST). The HST spectrum clearly shows absorption due to Lyalpha, N v, and C IV, blueshifted by 300 km s(exp -1) from the emission redshift of the QSO. The rarity of both X-ray and UV absorbers in radio-quiet QSOs suggests these absorbers are physically related, if not identical. Assuming the unified scenario, we place constraints on the physical parameters of the absorber and conclude the mass outflow rate is essentially the same as the accretion rate in MR 2251-178.

Monier, Eric M.

Organic/Inorganic Polymeric Composites for Heat-Transfer Reduction

Organic/inorganic polymeric composite materials have been invented with significant reduction in heat-transfer properties. Measured decreases of 20-50 percent in thermal conductivity versus that of the unmodified polymer matrix have been attained. These novel composite materials also maintain mechanical properties of the unmodified polymer matrix. The present embodiments are applicable, but not limited to: racing applications, aerospace applications, textile industry, electronic applications, military hardware improvements, and even food service industries. One specific application of the polymeric composition is for use in tanks, pipes, valves, structural supports, and components for hot or cold fluid process systems where heat flow through materials is problematic and not desired. With respect to thermal conductivity and physical properties, these materials are superior alternatives to prior composite materials. These materials may prove useful as substitutes for metals in some cryogenic applications. A material of this type can be made from a blend of thermoplastics, elastomers, and appropriate additives and processed on normal polymer processing equipment. The resulting processed organic/inorganic composite can be made into fibers, molded, or otherwise processed into useable articles.

Smith, Trent

Global Variations in Regolith Properties on Asteroid Vesta from Dawn's Low-Altitude Mapping Orbit

We investigate the depth, variability, and history of regolith on asteroid Vesta using data from the Dawn spacecraft. High-resolution (15-20 m pixel(sup -1)) Framing Cameraimages are used to assess the presence of morphologic indicators of a shallow regolith,including the presence of blocks in crater ejecta, spur-and-gully-type features in crater walls,and the retention of small (less than 300 m) impact craters. Such features reveal that the broad,regional heterogeneities observed on Vesta in terms of albedo and surface composition extend to the physical properties of the upper approx. 1 km of the surface. Regions of thin regolithare found within the Rheasilvia basin and at equatorial latitudes from approx. 0-90 deg. E and approx.260-360 deg. E. Craters in these areas that appear to excavate material from beneath the regolithhave more diogenitic (Rheasilvia, 090 deg. E) and cumulate eucrite (260-360 deg. E) compositions.A region of especially thick regolith, where depths generally exceed 1 km, is found from approx.100-240 deg. E and corresponds to heavily cratered, low-albedo surface with a basaltic eucritecomposition enriched in carbonaceous chondrite material. The presence of a thick regolithin this area supports the idea that this is an ancient terrain that has accumulated a larger component of exogenic debris. We find evidence for the gardening of crater ejecta towardmore howarditic compositions, consistent with regolith mixing being the dominant form of "weathering" on Vesta.

asteroid

Measuring the Coronal Properties of IC 4329A with NuSTAR

We present an analysis of an approximately 160 ks NuSTAR observation of the nearby bright Seyfert galaxy IC 4329A. The highquality broadband spectrum enables us to separate the effects of distant reflection from the direct coronal continuum, and to therefore accurately measure the high-energy cutoff to be E(sub cut) = 178 (+74 / −40) keV. The coronal emission arises from accretion disk photons Compton up-scattered by a thermal plasma, with the spectral index and cutoff being due to a combination of the finite plasma temperature and optical depth. Applying standard Comptonization models, we measure both physical properties independently using the best signal to noise obtained to date in an active galactic nucleus over the 3 - 79 keV band. We derive kT(sub e) = 37(+7 /−6) keV with tau = 1.25(+0.20 / −0.10) assuming a slab geometry for the plasma, and kT(sub e) = 33(+6 / −6) keV with tau = 3.41(+0.58 / −0.38) for a spherical geometry, with both having an equivalent goodness-of-fit.

finite plasma temperature

Characterizing the impact of water uptake on light absorption by aerosol particles

Absorbing aerosols (AA) have an important impact on the global radiation budget. The composition and properties of AA can vary substantially throughout the atmosphere, depending on the particle source and the influence of chemical aging. Uncertainties associated with the radiative effects of AA remain substantial. A key contributor to this uncertainty is understanding the extent to which water uptake alters absorption by AA particles and how this depends on particle composition. We have used new and existing experimental tools to systematically characterize the relationship(s) between AA chemical and physical characteristics, relative humidity, and mixing of AA with other aerosol components through a combination of laboratory and field measurements. We have developed fundamental understanding through laboratory experiments that will enable interpretation of field observations at DOE ARM sites and facilitate process-based improvements in the simulation of absorption by carbonaceous aerosols in climate models. In the laboratory experiments we have considered a variety of different AA types, including fullerene soot (a surrogate for refractory black carbon, or BC) and nigrosine (a surrogate for partially soluble brown carbon, or BrC). By examining a range of AA types we will develop insight into how the chemical and physical properties of AA particles (e.g. whether they are refractory or soluble) impact the influence of water uptake on absorption. These AA particles will also be mixed—both internally and externally—with compounds having a wide range of hygroscopic properties to establish how the impact of water uptake on absorption will vary with photochemical processing. These laboratory observations have been compared with commonly used theoretical models, enabling development of empirical models that will facilitate improved representation of absorption by AA particles in regional and global climate models. Overall, our study has contributed to the mission of the Atmospheric System Research program by quantifying how interactions between aerosols and radiation depend on relative humidity. Through this, our work will improve understanding and model representation of aerosol processes as they affect the Earth’s radiation budget.

54 ENVIRONMENTAL SCIENCES

Solar Flares Observed with the Ramaty High Energy Solar Spectroscopic Imager (RHESSI)

Solar flares are impressive examples of explosive energy release in unconfined, magnetized plasma. It is generally believed that the flare energy is derived from the coronal magnetic field. However, we have not been able to establish the specific energy release mechanism(s) or the relative partitioning of the released energy between heating, particle acceleration (electrons and ions), and mass motions. NASA's RHESSI Mission was designed to study the acceleration and evolution of electrons and ions in flares by observing the X-ray and gamma-ray emissions these energetic particles produce. This is accomplished through the combination of high-resolution spectroscopy and spectroscopic imaging, including the first images of flares in gamma rays. RHESSI has observed over 12,000 solar flares since its launch on February 5, 2002. I will demonstrate how we use the RHESSI spectra to deduce physical properties of accelerated electrons and hot plasma in flares. Using images to estimate volumes, w e typically find that the total energy in accelerated electrons is comparable to that in the thermal plasma. I will also present flare observations that provide strong support for the presence of magnetic reconnection in a large-scale, vertical current sheet in the solar corona. RHESSI observations such as these are allowing us to probe more deeply into the physics of solar flares.

Holman, Gordon D.

Final Technical Report on Investigation of Short-range Ordering in Transition Metal Compounds by Diffuse Scattering

Future energy needs and sustainability require new materials with novel properties for such applications as energy production, storage and transport and microelectronics. Quantum materials with several competing interactions at the electronic level offer tremendous opportunity to discover, design and tune properties for such applications. Although it has been recognized that small deviations in atomic positions, driven by the competing electronic interactions, in crystalline materials can have significant impact on properties, it remains a challenge to accurately characterize such deviations (short-range order) due to the lack of advanced instruments and analysis tools to characterize them. This project used the powerful neutron and x-ray scattering instruments recently developed at the DOE user facilities to address this challenge. New methods and efficient analysis tools were employed to uncover the hidden ordering that is behind the unique properties of transition metal compounds. One example of hidden order revealed by this project comes from vanadium (IV) oxide (VO 2 ) and related compounds. The project found that the chemical bonds in VO 2 compete against each other, unlike most crystalline compounds where the chemical bonds cooperate to yield the ordered structure. This helps explain why different measurements yielded different, competing pictures about the nature of VO 2 , which has led to disagreement about where its physical properties come from. Another example from this project of hidden ordering comes from a class of compounds known as condensed Chevrel phases, which are superconducting compounds that are generally believed to be non-magnetic. The neutron scattering methods used in this project revealed evidence of magnetism, which usually does not coexist with superconductivity. In this case, magnetism is believed to be one part of a special type of electronic behavior that can occur in compounds that have one-dimensional bonding character.

36 MATERIALS SCIENCE

Microstructure of the solar wind

In this review microstructure is understood to summarize the dynamical properties of the solar wind that enter the fluid equations, usually employed to describe the overall flow, only in one or the other averaged form. Thus, first a description of the kinetic picture of the solar wind is given; it mainly involves the structure of the particle distributions in velocity space and associated instabilities. Waves and discontinuities are discussed next. Two selected examples are mentioned where the effects of waves and discontinuities play a role. Specific physical properties of the interplanetary magnetic irregularity spectrum and its relevance for cosmic ray propagation are discussed at the end.

Voelk, H. J.

Properties of the X-ray emitting gas in early-type galaxies

The properties of the X-ray emitting gas in a sample of 81 E and S0 galaxies observed with the Einstein Observatory are studied. Measured fluxes for 55 of the galaxies and upper limits for 26 of them are reported. An attempt is made to use consistent optical parameters for the galaxies, including a correction to the velocities for the Virgocentric flow. The sample is then used to explore the contribution from discrete sources, the global physical properties of the hot gas, and the implications for heating by supernovae and gravity. Finally, the question of the presence of heavy halos is addressed.

Canizares, Claude R.

Quantum Filtering and Analysis of Multiplicities in Eigenvalue Spectra

Fine-grained spectral properties of quantum Hamiltonians, including both eigenvalues and their multiplicities, provide useful information for characterizing many-body quantum systems as well as for understanding phenomena such as topological order. Extracting such information with small additive error is #BQP-complete in the worst case. In this work, we introduce QFAMES (quantum filtering and analysis of multiplicities in eigenvalue spectra), a quantum algorithm that efficiently identifies clusters of closely spaced dominant eigenvalues and determines their multiplicities under physically motivated assumptions, which allows us to bypass worst-case complexity barriers. QFAMES also enables the estimation of observable expectation values within targeted energy clusters, providing a powerful tool for studying quantum phase transitions and other physical properties. We validate the effectiveness of QFAMES through numerical demonstrations, including its applications to characterizing quantum phases in the transverse-field Ising model and estimating the ground-state degeneracy of a topologically ordered phase in the two-dimensional toric code model. We also generalize QFAMES to the setting of mixed initial states. Our approach offers rigorous theoretical guarantees and significant advantages over existing subspace-based quantum spectral analysis methods, particularly in terms of the sample complexity and the ability to resolve degeneracies.

97 MATHEMATICS AND COMPUTING

Electrical Switching of Perovskite Thin-Film Resistors

Electronic devices that exploit electrical switching of physical properties of thin films of perovskite materials (especially colossal magnetoresistive materials) have been invented. Unlike some related prior devices, these devices function at room temperature and do not depend on externally applied magnetic fields. Devices of this type can be designed to function as sensors (exhibiting varying electrical resistance in response to varying temperature, magnetic field, electric field, and/or mechanical pressure) and as elements of electronic memories. The underlying principle is that the application of one or more short electrical pulse(s) can induce a reversible, irreversible, or partly reversible change in the electrical, thermal, mechanical, and magnetic properties of a thin perovskite film. The energy in the pulse must be large enough to induce the desired change but not so large as to destroy the film. Depending on the requirements of a specific application, the pulse(s) can have any of a large variety of waveforms (e.g., square, triangular, or sine) and be of positive, negative, or alternating polarity. In some applications, it could be necessary to use multiple pulses to induce successive incremental physical changes. In one class of applications, electrical pulses of suitable shapes, sizes, and polarities are applied to vary the detection sensitivities of sensors. Another class of applications arises in electronic circuits in which certain resistance values are required to be variable: Incorporating the affected resistors into devices of the present type makes it possible to control their resistances electrically over wide ranges, and the lifetimes of electrically variable resistors exceed those of conventional mechanically variable resistors. Another and potentially the most important class of applications is that of resistance-based nonvolatile-memory devices, such as a resistance random access memory (RRAM) described in the immediately following article, Electrically Variable Resistive Memory Devices (MFS-32511-1).

Liu, Shangqing

The Extreme Ultraviolet Normal Incidence Spectrograph (EUNIS)

EUNIS (Extreme Ultraviolet Normal Incidence Spectrograph) is a high-efficiency extreme ultraviolet spectrometer that is expected to fly for the first time in 2004 as a sounding rocket payload. Using two independent optical systems, EUNIS will probe the structure and dynamics of the inner solar corona high spectral resolution in two wavelength regions: 17-21 nm with 3.5 pm resolution and 30-37 nm with 7 pm resolution. The long wavelength channel includes He II 30.4 nm and strong lines from Fe XI-XVI; the short wavelength channel includes strong lines of Fe IX-XIII. Angular resolution of 2 arcsec is maintained along a slit covering a full solar radius. EUNIS will have 100 times the throughput of the highly successful SERTS payloads that have preceded it. There are only two reflections in each optical channel, from the superpolished, off-axis paraboloidal primary and the toroidal grating. Each optical element is coated with a high-efficiency multilayer coating optimized for its spectral bandpass. The detector in each channel is a microchannel plate image intensifier fiber- coupled to three 1K x 1K active pixel sensors. EUNIS will obtain spectra with a cadence as short as 1 sec, allowing unprecedented studies of the physical properties of evolving and transient structures. Diagnostics of wave heating and reconnection wil be studied at heights above 2 solar radii, in the wind acceleration region. The broad spectral coverage and high spectral resolution will provide superior temperature and density diagnostics and will enable underflight calibration of several orbital instruments, including SOHO/CDS and EIT, TRACE, Solar-B/EIS, and STEREO/EUVI. EUNIS is supported by NASA through the Low Cost Access to Space Program in Solar and Heliospheric Physics.

Oegerle, William

Chapter 10 - Remote Sensing Measurements of Aerosol Properties

Satellite instruments have proven especially capable at monitoring the quantity of airborne particles in columns of atmosphere, globally. This chapter describes the principles of satellite measurements and retrieval algorithms, and surveys current instruments and their capabilities. We outline the issues associated with retrieval algorithms, such as surface characterization and aerosol proximity to clouds, and the challenges with interpretation of the results. The relationship between measured aerosol properties and climate-relevant aerosol properties simulated in models is outlined, as well as how measurements are used to evaluate models. Most space-based aerosol instruments are passive sensors that measure reflected sunlight at multiple wavelengths, some at multiple viewing angles. A few are active sensors that send out their own laser light and measure the returned signal. Except when clouds are present, the excess amount of light scattered back to space, beyond that expected from the surface and atmospheric gas, is attributed to aerosol. Satellite measurements are used in many ways in aerosol research. They often provide the only method for monitoring hazardous phenomena such as major wildfire and volcanic eruption plumes, especially in remote areas. Stable, long-term, near-global-scale satellite data records make it possible to identify regional and global aerosol trends. Aerosol radiative effects on climate can be quantified on a near-global scale and used to estimate the strength of aerosol–radiation and aerosol–cloud interactions as well as to evaluate climate model simulations of these interactions. Aerosol-type mapping from satellite imagery is helpful for source attribution, model validation, and to constrain particle light-absorption properties that are essential for radiative forcing calculations. The range of aerosol properties retrieved from satellite observations has grown considerably since the first global estimates of aerosol optical depth (τ a) over ocean were made in the late 1970s. Methods for retrieving particle size and light-absorption properties were explored in the 1990s using multispectral, multi-angle observations, and polarization in visible and near-infrared wavelengths. Sensitivity to particle light absorption, primarily from black or brown carbon content, improved with the inclusion of UV channels, and sensitivity to very thin aerosol layers in the upper troposphere and lower stratosphere was advanced with the use of limb-sounding instruments and active sensors. There are limitations to every measurement technique, including satellite aerosol remote sensing. For wide-swath, passive instruments, aerosol retrievals near clouds can present substantial challenges as far as 15 km away due to cloud-scattered light contaminating the signal. In nearly all cases, retrievals over bright snow and ice surfaces are precluded because surface reflectance uncertainties can overwhelm the aerosol signal. Similarly, meteorological cloud is identified and masked out where possible. Data from passive sensors also lack vertical resolution except those that view toward the limb or where multi-angle imagery is acquired over plumes from wildfires, erupting volcanoes, and wind-blown dust. Yet, passive sensors provide vastly more coverage than the active instruments that mitigate these issues. Particle microphysical information is qualitative from all remote sensing techniques, relying on proxies to infer particle composition, hygroscopicity, and the amount of light-absorbing material. Further, particles smaller than about 200 nm diameter cannot be distinguished from atmospheric gas molecules with remote sensing, which hinders studies of cloud condensation nuclei and their effects on clouds. Most satellite instruments dedicated to aerosol observations are in low-Earth, near-polar, sun-synchronous orbits, which means they cross the equator at the same local time each day. Most are set on cycles that repeat approximately every 16 days, which makes it difficult to monitor aerosol evolution locally. Geostationary satellites make it possible to observe changes occurring from minutes to hours over regions up to 8000 km in size, but lack coverage of high latitudes, and often provide more limited constraints on aerosol properties. Ground-truth data are vital for satellite aerosol-retrieval validation. The AErosol RObotic NETwork (AERONET) of sun photometers was created in 1993 and has become an established global network of over 350 instruments for validating satellite measurements. The network, as well as global networks of ground-based lidars, solar flux radiometers and other sun photometers, are widely used for evaluating global satellite retrievals and model simulations. NASA's Earth Observing System (EOS) program beginning in 1999 led to improvements in reliability, spatial resolution, and spectral resolution (and hence, to improved particle size discrimination and light absorption properties). Satellite payloads include advanced broad-swath and multi-angle imagers, along with the first space-based active sensor focused largely on long-term aerosol monitoring. Since about 2002, Europe's SENTINEL and operational meteorological satellite fleets are also providing sustained aerosol observations, with planned continuation until at least 2030. Satellite remote sensing instruments offer valuable data for evaluating aerosol representations in global climate models. They have been used to assess aerosol optical and physical properties, trends and distributions, and are applied increasingly as direct model constraints in data assimilation to create global aerosol reanalysis products. Aerosol optical depth is the most common quantity adopted for routine model evaluation, including multiwavelength data to loosely constrain particle-size distributions. These evaluations of multiple models have revealed general biases in their regional aerosol amounts and seasonal patterns of transport and removal. Although satellite measurements have near-global coverage, substantial errors can be introduced into the model observation comparison unless attention is paid to spatial and temporal collocation, cloud screening, subgrid-scale variability, and measurement uncertainties that vary with retrieval conditions.

aerosol properties